CN103444725B - A kind of miticide composition containing phonetic mite amine and clofentezine - Google Patents
A kind of miticide composition containing phonetic mite amine and clofentezine Download PDFInfo
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- CN103444725B CN103444725B CN201310411378.6A CN201310411378A CN103444725B CN 103444725 B CN103444725 B CN 103444725B CN 201310411378 A CN201310411378 A CN 201310411378A CN 103444725 B CN103444725 B CN 103444725B
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Abstract
The invention discloses a kind of miticide composition and the application thereof that contain phonetic mite amine and clofentezine, effective active composition is made up of the phonetic mite amine of the first active component and the second active component clofentezine, and the weight ratio of the first active component and the second active component is 1:10 ~ 10:1.This composition can be mixed with the suspending agent, wetting powder, the water dispersible granules that agriculturally allow or dispersible oil-suspending agent formulation.Instant component is reasonable, good disinsection effect, and its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and there is significant synergistic effect, good to crop safety, meet the security requirement of pesticidal preparations, the present invention has significant control efficiency to citrus red mite, European red mite, cotton red spider.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, be made up of the phonetic mite amine of the first active component and the second active component clofentezine, belong to technical field of compounded pesticide.
Background technology
Harmful mite in agricultural production is also two spotted spider mite, yellow spider etc., belongs to arachnids Acarina.The crop such as main harm oranges and tangerines, apple, cotton, vegetables, wheat, evil mite be gathered in vacuum side of blade more, with adult, nymph with mouthpart thrust in leaf suck juice harm.When evil mite occurs, preventing and treating with miticide is the most effective means, Avermectin, pyridaben, propargite, fenbutatin oxide etc. are mainly contained at present at the medicament of Ministry of Agriculture's registration control Agricultural Mites, evil mite produces resistance to it, in the urgent need to inventing a kind of agricultural chemicals effectively can preventing and treating harmful mite and safety nuisance free.
Phonetic mite amine, English common name: pyriminostrobin, its structural formula is as follows:
Phonetic mite amine is methoxy acrylic miticide, has bactericidal activity simultaneously, if all have greater activity to one-tenth mite mite, ovum, quick-acting is good, and lasting effect is general.As a kind of new miticide, in use there is resistance risk in phonetic mite amine, and rationally uses with from the miticide of the different mechanism of action, for fully effectively promoting phonetic mite amine, extending its service life and having important function.
Clofentezine, has another name called Apollo, chemical name: 3,6-two (2-chlorphenyl)-1,2,4,5-tetrazine, english common name clofentezine.Clofentezine mainly acts on mite ovum, also has certain effect to young mite, invalid to one-tenth mite, harmless to Predatory Mites natural enemy.This medicine effect is comparatively slow, and within after general medication 2 weeks, just can reach the highest preventive effect, the lasting period is longer.But clofentezine is longer for service time, and resistance increases gradually, when, temperature large in the density of mite is higher, effect is not ideal, and quick-acting is poor, there is the defect to becoming mite invalid.
Inventor does not also find that there is through retrieval the bibliographical information being used for phonetic mite amine and clofentezine mixture to prevent and treat Agricultural Mites, find phonetic mite amine and clofentezine mixture to use have good control efficiency to Agricultural Mites by lot of experiments, have the advantages that quick-acting is good, the lasting period is long, there is significant synergistic effect, have received beyond thought effect, can use cost be reduced, effectively solve the problem of control of pest mite difficulty.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, remarkable synergy, miticidal effect is good, the miticide composition of the phonetic mite amine that drug cost is low and clofentezine.
The miticide composition preparation formulation provided containing phonetic mite amine and clofentezine is provided.
Another object of the present invention is the application of the miticide composition providing phonetic mite amine and clofentezine.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention solves like this:
Containing the Pesticidal combination of phonetic mite amine and clofentezine, comprising:
A) the phonetic mite amine of the first active component;
B) the second active component clofentezine;
The weight ratio of the first active component and the second active component is 1:10 ~ 10:1.
The content sum of the first active component and the second active component is 10% ~ 80% of described composition total weight, is preferably 20% ~ 70%.
The miticide composition of the phonetic mite amine of the present invention and clofentezine, the preparation formulation can prepared according to the method that the art personnel are known is suspending agent, wetting powder, water dispersible granules or dispersible oil-suspending agent.
To suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produces) in one or more; Wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S. produce) in one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To dispersibling oil-suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more, emulsifier is as BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produce) in one or more, wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S. produce) in one or more, thickener as in white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more, antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more, dispersion medium as in soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil one or more.
Instant component is reasonable, good disinsection effect, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has good control efficiency to all kinds of harmful mite in agricultural production.
In order to prevent and treat the harmful mite in agricultural production, we have carried out mutual composite synergy with phonetic mite amine and clofentezine and have studied.Concrete grammar is:
Subjects be citrus red mite (
panonychus citfimcGregor), European red mite (
panonychus ulmi), cotton red spider (Tetranychus cinnabarinnum Boisduval).Former medicine is mixed with the test medicine of needs, test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.13-2008 ".First single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, two spotted spider mite lethality sets by geometric progression in the scope of 5% ~ 90%).Examination worm is the two spotted spider mite of picking up from field, if select the mite of uniformity in the length of time in laboratory, put into blade-carrying culture dish, 40, every ware, often process 4 culture dishes, repeat 3 times, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 3ml, then the culture dish processed is put into 12H/12H illumination box to cultivate, within 48 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water
.calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: phonetic mite amine and clofentezine are that 1:10 ~ 10:1 is mixed with weight ratio all has good virulence to citrus red mite, European red mite and cotton red spider, has significant synergistic effect.
Toxicity Determination result shows: phonetic mite amine and clofentezine are that 1:10 ~ 10:1 is mixed with weight ratio all has good virulence to citrus red mite, European red mite and cotton red spider, has significant synergistic effect.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Take 5% phonetic mite amine, 25% clofentezine, Huntsman Corporation of the 3%TERSPERSE 4894(U.S. produce), Huntsman Corporation of the 1%TERSPERSE 2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 30% phonetic mite amine clofentezine suspension agent obtained after sand mill sand milling.
Example of formulations 2
Take 15% phonetic mite amine, 5% clofentezine, Huntsman Corporation of the 4%TERSPERSE 4894(U.S. produce), Huntsman Corporation of the 1.5%TERSPERSE 2500(U.S. produces), Huntsman Corporation of the 1%TERSPERSE 2020(U.S. produces), 0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 20% phonetic mite amine clofentezine suspension agent obtained after sand mill sand milling.
Example of formulations 3
Take 20% phonetic mite amine, 10% clofentezine, 4%GY-D06,3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.Above-mentioned raw materials is through mixing, the obtained 30% phonetic mite amine clofentezine wettable powder of ultra micro air-flow crushing, hybrid technique step.
Example of formulations 4
Take 5% phonetic mite amine, 50% clofentezine, 4% calcium lignosulfonate, 3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.Above-mentioned raw materials is prepared into 55% phonetic mite amine clofentezine wettable powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 5
Take 20% phonetic mite amine, 60% clofentezine, 2% TERSPERSE 2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 80% phonetic mite amine Bifenazate water dispersible granules.
Example of formulations 6
Take 30% phonetic mite amine, 3% clofentezine, 4% GY-D06(polycarboxylate), 3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 2%K-12(lauryl sodium sulfate), 5% diatomite, 8% bentonite, attapulgite add to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 33% phonetic mite amine clofentezine water dispersible granule.
Example of formulations 7
Take 5% phonetic mite amine, 5% clofentezine, Huntsman Corporation of the 2%TERSPERSE 2020(U.S. produce), 4% this dish-60#, 3% Tween-60 #, 4% agriculture breast 2201#, 3% Huntsman Corporation of Nongru-700 #, 1%TERSPERSE 2500(U.S. produce), 0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 10% phonetic mite amine clofentezine obtained after sand mill sand milling.
Example of formulations 8
Take 8% phonetic mite amine, 16% clofentezine, 2% dispersing agent NNO, 3% agriculture breast 2201#, 10% Huntsman Corporation of BY-110,1%TERSPERSE 2500(U.S. produce), 1% aluminium-magnesium silicate, 3% glycerine, soybean oil add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 24% phonetic mite amine clofentezine obtained after sand mill sand milling.
Biological Examples: control citrus red mite field trial
Inventor has carried out example of formulations 2(20% phonetic mite amine clofentezine suspension agent in April, 2013 in Deqing County, Zhaoqing City of Guangdong Province) prevent and treat the field control effectiveness test of citrus red mite, demonstrate this medicament to the control efficiency of citrus red mite, effective dose and the safety to oranges and tangerines.Test medicine and extension rate refer to table 4, separately establish blank.Often process and repeat for 4 times, every plot area 5 tree, Gong24Ge community, random district group arranges.Manual sprayer is adopted evenly to spray.Borer population investigation is respectively once remained respectively at before medicine, after medicine 1 day, 7 days, 14 days.2 trees are looked in every community, and every tree looks into 5 leaves respectively by orientation, 4, the four corners of the world, and every community looks into 40 leaves altogether, record mite number of living, carry out control efficiency statistics.Viewing test medicament produces with or without poisoning oranges and tangerines simultaneously.
Computational methods:
Control efficiency (%)=[1-(before the medicine of check plot after borer population × treatment region medicine borer population)/(before borer population after the medicine of check plot × treatment region medicine borer population)] × 100
Result of the test shows, 20% phonetic mite amine clofentezine suspension agent dilutes 2000 times, 2500 times, 3000 times, good control efficiency is had to citrus red mite, after medicine, the preventive effect of 1,7,14 day is all more than 90.0%, show excellent quick-acting and lasting effect, be obviously better than the control efficiency (table 4) of 10% phonetic mite amine suspending agent 1000 times, 20% clofentezine suspension agent 1000 times.Advise that 20% phonetic mite amine clofentezine control citrus red mite dilution 2000-3000 times is advisable.
Security survey, duration of test is observed, and all reagent agents, to Citrus leaf, the tender tip, flower, growth of young safety, occur without poisoning phenomenon.
Result of the test shows, after phonetic mite amine and clofentezine mixture, significantly improves the control efficiency to citrus red mite, and synergistic effect is obvious, shows excellent quick-acting and lasting period, reduces dosage, saved drug cost, to Ci trus growth safety.
In sum, composition of the present invention is employing two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (4)
1. the miticide composition containing phonetic mite amine and clofentezine is preventing and treating the purposes on Agricultural Mites, and described Agricultural Mites is citrus red mite or European red mite, and the weight ratio of phonetic mite amine and clofentezine is 1:10 ~ 1:5, or 2:1 ~ 10:1.
2. purposes according to claim 1, it is characterized in that, the content sum of phonetic mite amine and clofentezine is 10% ~ 80% of described composition total weight.
3. purposes according to claim 2, it is characterized in that, the content sum of phonetic mite amine and clofentezine is 20% ~ 60% of described composition total weight.
4. purposes according to claim 1, is characterized in that described combination dosage form is suspending agent, wetting powder, water dispersible granules or dispersibles oil-suspending agent.
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| CN103734146B (en) * | 2014-01-26 | 2016-04-20 | 上海艳紫化工科技有限公司 | Kill mite oil-suspending agent |
| CN103814906B (en) * | 2014-01-26 | 2015-11-18 | 上海艳紫化工科技有限公司 | Phonetic mite amine and the composite oil-suspending agent of clofentezine |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| EP2604118A1 (en) * | 2011-12-15 | 2013-06-19 | Bayer CropScience AG | Active ingredient combinations having insecticidal and acaricidal properties |
| CN103518764A (en) * | 2012-07-02 | 2014-01-22 | 中国中化股份有限公司 | Acaricidal composition and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| EP2604118A1 (en) * | 2011-12-15 | 2013-06-19 | Bayer CropScience AG | Active ingredient combinations having insecticidal and acaricidal properties |
| CN103518764A (en) * | 2012-07-02 | 2014-01-22 | 中国中化股份有限公司 | Acaricidal composition and application thereof |
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Address after: 710065 Shaanxi city of Xi'an province high tech Zone Feng Hui Road No. 36 block B block 18F oak Patentee after: Agricultural core crop Technology Co., Ltd. Address before: 710065 Shaanxi city of Xi'an province high tech Zone Feng Hui Road No. 36 block B block 18F oak Patentee before: Shaanxi Norsyn Crop Technology Co., Ltd. |