CN103563904B - A kind of miticide composition containing phonetic mite amine and tebufenpyrad - Google Patents
A kind of miticide composition containing phonetic mite amine and tebufenpyrad Download PDFInfo
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- CN103563904B CN103563904B CN201310555392.3A CN201310555392A CN103563904B CN 103563904 B CN103563904 B CN 103563904B CN 201310555392 A CN201310555392 A CN 201310555392A CN 103563904 B CN103563904 B CN 103563904B
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Abstract
The invention discloses a kind of miticide composition containing phonetic mite amine and tebufenpyrad, its effective active composition is phonetic mite amine and tebufenpyrad, and the weight ratio of phonetic mite amine and tebufenpyrad is 1:5 ~ 5:1.This composition can be mixed with suspending agent, wetting powder, water dispersible granules, missible oil or micro-emulsion form.Instant component is reasonable, good disinsection effect, and its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and there is significant synergistic effect, good to crop safety, meet the security requirement of pesticidal preparations, the present invention has significant control efficiency to citrus red mite, European red mite, cotton red spider.
Description
Technical field
The present invention relates to a kind of miticide composition, main active is phonetic mite amine and tebufenpyrad, belongs to technical field of compounded pesticide.
Background technology
Harmful mite in agricultural production is also two spotted spider mite, yellow spider etc., belongs to arachnids Acarina.The crop such as main harm oranges and tangerines, apple, cotton, vegetables, wheat, evil mite be gathered in vacuum side of blade more, with adult, nymph with mouthpart thrust in leaf suck juice harm.When evil mite occurs, preventing and treating with miticide is the most effective means, Avermectin, pyridaben, propargite, fenbutatin oxide etc. are mainly contained at present at the medicament of Ministry of Agriculture's registration control Agricultural Mites, evil mite produces resistance to it, in the urgent need to inventing a kind of agricultural chemicals effectively can preventing and treating harmful mite and safety nuisance free.
Phonetic mite amine, English common name: pyriminostrobin, its structural formula is as follows:
Phonetic mite amine is methoxy acrylic miticide, has bactericidal activity simultaneously, if all have greater activity to one-tenth mite mite, ovum, quick-acting is good, and lasting effect is general.As a kind of new miticide, in use there is resistance risk in phonetic mite amine, and rationally uses with from the miticide of the different mechanism of action, for fully effectively promoting phonetic mite amine, extending its service life and having important function.
Tebufenpyrad, chemical name: N-(the special butylbenzene methyl of 4-) the chloro-3-ethyl of-4--1-methyl-5-pyrazolecarboxamide, English name: tebufenpyrad.Tebufenpyrad belongs to amide-type miticide, has action of contace poison, and all have good preventive effect to the vegetative period of various mite class, the lasting period is long, and toxicity is low, without interior absorption, but has permeability.
Inventor does not also find that there is through retrieval the bibliographical information being used for phonetic mite amine and tebufenpyrad mixture to prevent and treat Agricultural Mites, find phonetic mite amine and tebufenpyrad mixture to use have good control efficiency to Agricultural Mites by lot of experiments, have significant synergies, have received beyond thought effect, can use cost be reduced, effectively solve the problem of control of pest mite difficulty.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, remarkable synergy, miticidal effect is good, the miticide composition containing phonetic mite amine and tebufenpyrad that drug cost is low.
Another object of the present invention is to provide the miticide composition containing phonetic mite amine and tebufenpyrad preventing and treating the purposes on Agricultural Mites.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention solves like this:
Contain a miticide composition for phonetic mite amine and tebufenpyrad, its active component is phonetic mite amine and tebufenpyrad, and wherein the weight ratio of phonetic mite amine and tebufenpyrad is 1:5 ~ 5:1, is preferably 1:3 ~ 3:1, is more preferably 1:2 ~ 2:1, most preferably is 1:1.The content sum of phonetic mite amine and tebufenpyrad is 10% ~ 80% of described composition total weight.
Present composition formulation is suspending agent, wetting powder, water dispersible granules, missible oil or microemulsion, can be used for preventing and treating Agricultural Mites, and described Agricultural Mites is citrus red mite, European red mite or cotton red spider.
To suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, Huntsman Corporation of TERSPERSE2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), one or more in TERSPERSE4894; Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500 one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
For missible oil, spendable auxiliary agent has: emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, Span-60#(common name: sorbitan monostearate), emulsifier T-60(common name: sorbitan monostearate APEO), TX-10(common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), in agriculture breast 600#, agriculture breast 400# one or more; Solvent is as dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, biodiesel, methylated vegetable oil; In ethyl acetate, methyl alcohol, dimethyl formamide, cyclohexanone, acetone, MEK one or more.
To microemulsion, spendable auxiliary agent has: emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), TX-10(common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), in agriculture breast 600#, agriculture breast 400# one or more; Assistant for emulsifying agent as in methyl alcohol, isopropyl alcohol, n-butanol, ethanol one or more; Solvent as cyclohexanone, 1-METHYLPYRROLIDONE, dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200) one or more; Water is deionized water.
Instant component is reasonable, and miticidal effect is good, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has good control efficiency to all kinds of harmful mite in agricultural production.
Embodiment
In order to prevent and treat the harmful mite in agricultural production, inventor has carried out mutual composite synergy with phonetic mite amine and tebufenpyrad and has studied.Concrete grammar is:
Subjects be citrus red mite (
panonychuscitfimcGregor), European red mite (
panonychusulmi), cotton red spider (TetranychuscinnabarinnumBoisduval).Former medicine is mixed with the test medicine of needs, test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.13-2008 ".First single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, two spotted spider mite lethality sets by geometric progression in the scope of 5% ~ 90%).Examination worm is the two spotted spider mite of picking up from field, select the one-tenth mite of uniformity in the length of time in laboratory, put into blade-carrying culture dish, every ware 40 cephalont, often process 4 culture dishes, repeat 3 times, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 3ml, then the culture dish processed is put into 12H/12H illumination box to cultivate, within 48 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water
,calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: phonetic mite amine and tebufenpyrad are that 1:5 ~ 5:1 is mixed with weight ratio all has good virulence to citrus red mite, European red mite and cotton red spider, has significant synergistic effect.
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Take 5% phonetic mite amine, 25% tebufenpyrad, Huntsman Corporation of the 3%TERSPERSE4894(U.S. produce), Huntsman Corporation of the 1%TERSPERSE2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 30% phonetic mite amine tebufenpyrad suspending agent obtained after sand mill sand milling.
Example of formulations 2
Take 10% phonetic mite amine, 10% tebufenpyrad, Huntsman Corporation of 4%TERSPERSE4894,1.5%TERSPERSE2500,1%TERSPERSE2020(U.S. produce), 0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 20% phonetic mite amine tebufenpyrad suspending agent obtained after sand mill sand milling.
Example of formulations 3
Take 10% phonetic mite amine, 20% tebufenpyrad, 4%GY-D06,3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.Above-mentioned raw materials is prepared into 30 phonetic mite amine tebufenpyrad wetting powders through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 4
Take 50% phonetic mite amine, 10% tebufenpyrad, 4% calcium lignosulfonate, 3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.Above-mentioned raw materials is prepared into 60% phonetic mite amine tebufenpyrad wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 5
Take 20% phonetic mite amine, 60% tebufenpyrad, 2%TERSPERSE2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 80% phonetic mite amine tebufenpyrad water dispersible granules.
Example of formulations 6
Take 20% phonetic mite amine, 10% tebufenpyrad, 4%GY-D06(polycarboxylate), 3% dispersing agent NNO, 2% Nekal BX, 2%K-12,5% diatomite, 8% bentonite, attapulgite add to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 30% phonetic mite amine tebufenpyrad water dispersible granules.
Example of formulations 7
Take 18% phonetic mite amine, 6% tebufenpyrad, 4% agriculture breast 500#, 2% agriculture breast 600#, 3% agriculture breast 2201#, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 24% phonetic mite amine tebufenpyrad missible oil completely afterwards.
Example of formulations 8
Take 10% phonetic mite amine, 30% tebufenpyrad, 5% agriculture breast 500#, 3%TX-10,4% agriculture breast 1601#, 5% cyclohexanone, solvent naphtha S-150 add to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 40% phonetic mite amine tebufenpyrad missible oil completely afterwards.
Example of formulations 9
Take 5% phonetic mite amine, 5% tebufenpyrad, 4%TX-10,5% Nongru-700 #, 6% agriculture breast 500#, 4% agriculture breast 1601#, 5% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 10% phonetic mite amine tebufenpyrad microemulsion after stirring.
Example of formulations 10
Take 12% phonetic mite amine, 24% tebufenpyrad, 5% Nongru-700 #, 3% agriculture breast 500#, 6% agriculture breast 600#, 5% dimethylbenzene, 20% cyclohexanone, 5% ethanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 36% phonetic mite amine tebufenpyrad microemulsion after stirring.
Biological Examples: control citrus red mite field trial
Inventor has carried out example of formulations 2(20% phonetic mite amine tebufenpyrad suspending agent in May, 2013 in Hanzhong City Chenggu County, Shaanxi Province) prevent and treat the field control effectiveness test of citrus red mite, demonstrate this medicament to the control efficiency of citrus red mite, effective dose and the safety to oranges and tangerines.Test medicine and extension rate refer to table 4, separately establish clear water blank.Often process and repeat for 4 times, every plot area 5 tree, Gong24Ge community, random district group arranges.Manual sprayer is adopted evenly to spray.Borer population investigation is respectively once remained respectively at before medicine, after medicine 1 day, 7 days, 14 days.2 trees are looked in every community, and every tree looks into 5 leaves respectively by orientation, 4, the four corners of the world, and every community looks into 40 leaves altogether, record mite number of living, carry out control efficiency statistics.Viewing test medicament produces with or without poisoning oranges and tangerines simultaneously.
Computational methods:
Control efficiency (%)=[1-(before the medicine of check plot after borer population × treatment region medicine borer population)/(before borer population after the medicine of check plot × treatment region medicine borer population)] × 100
Result of the test shows, 20% phonetic mite amine tebufenpyrad missible oil dilutes 2000 times, 2500 times, 3000 times, good control efficiency is had to citrus red mite, after medicine, the preventive effect of 1,7,14 day is all more than 91.6%, show excellent quick-acting and lasting effect, be obviously better than the control efficiency (table 4) of 10% phonetic mite amine suspending agent 1000 times, 20% tebufenpyrad missible oil 1500 times.Advise that 20% phonetic mite amine tebufenpyrad suspending agent control citrus red mite dilution 2000 ~ 3000 times is advisable.
Security survey, duration of test is observed, and all reagent agents, to Citrus leaf, the tender tip, flower, growth of young safety, occur without poisoning phenomenon.
Result of the test shows, after phonetic mite amine and tebufenpyrad mixture, significantly improves the control efficiency to citrus red mite, and synergistic effect is obvious, shows excellent quick-acting and lasting period, reduces dosage, saved drug cost, to Ci trus growth safety.
In sum, composition of the present invention is employing two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (10)
1. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 5% phonetic mite amine, 25% tebufenpyrad, 3%TERSPERSE4894,1%TERSPERSE2500,0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.
2. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 10% phonetic mite amine, 10% tebufenpyrad, 4%TERSPERSE4894,1.5%TERSPERSE2500,1%TERSPERSE2020,0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.
3. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 10% phonetic mite amine, 20% tebufenpyrad, 4%GY-D06,3% alkylnaphthalene sulfonate formaldehyde condensation products, 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.
4. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 50% phonetic mite amine, 10% tebufenpyrad, 4% calcium lignosulfonate, 3% alkylnaphthalene sulfonate formaldehyde condensation products, 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.
5. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 20% phonetic mite amine, 60% tebufenpyrad, 2%TERSPERSE2700,2% sodium lignin sulfonate, 1% Nekal BX, 1%K-12, the 1%PVA of molecular weight 2000,2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.
6. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 20% phonetic mite amine, 10% tebufenpyrad, 4%GY-D06,3% dispersing agent NNO, 2% Nekal BX, 2%K-12,5% diatomite, 8% bentonite, attapulgite add to 100% weight portion.
7. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 18% phonetic mite amine, 6% tebufenpyrad, 4% agriculture breast 500#, 2% agriculture breast 600#, 3% agriculture breast 2201#, dimethylbenzene adds to 100% weight portion.
8. containing a miticide composition for phonetic mite amine and tebufenpyrad, it is characterized in that: take 10% phonetic mite amine, 30% tebufenpyrad, 5% agriculture breast 500#, 3%TX-10,4% agriculture breast 1601#, 5% cyclohexanone, solvent naphtha S-150 add to 100% weight portion.
9. one kind contains the miticide composition of phonetic mite amine and tebufenpyrad, it is characterized in that: take 5% phonetic mite amine, 5% tebufenpyrad, 4%TX-10,5% Nongru-700 #, 6% agriculture breast 500#, 4% agriculture breast 1601#, 5% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 10% phonetic mite amine tebufenpyrad microemulsion after stirring.
10. one kind contains the miticide composition of phonetic mite amine and tebufenpyrad, it is characterized in that: take 12% phonetic mite amine, 24% tebufenpyrad, 5% Nongru-700 #, 3% agriculture breast 500#, 6% agriculture breast 600#, 5% dimethylbenzene, 20% cyclohexanone, 5% ethanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 36% phonetic mite amine tebufenpyrad microemulsion after stirring.
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| CN1164228A (en) * | 1994-11-17 | 1997-11-05 | 巴斯福股份公司 | 2[(2-Alkoxy-6-trifluoromethyl pyrimidine-4-yl)-oxymethylene]-phenyl-acetic acid derivatives, process and intermediate products for their production and their use |
| US6114342A (en) * | 1995-05-21 | 2000-09-05 | Basf Aktiengesellschaft | 2-(O-[pyrimidin-4-yl]methylenoxy)phenylacetic acid derivatives and their use for controlling harmful fungi and animal pests |
| CN101311170B (en) * | 2007-05-25 | 2010-09-15 | 中国中化股份有限公司 | Substituted pyrimidine ether compounds and uses thereof |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
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| CN103907612B (en) * | 2012-12-31 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Pyriminostrobin-containing insecticidal composition |
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| CN1164228A (en) * | 1994-11-17 | 1997-11-05 | 巴斯福股份公司 | 2[(2-Alkoxy-6-trifluoromethyl pyrimidine-4-yl)-oxymethylene]-phenyl-acetic acid derivatives, process and intermediate products for their production and their use |
| US6114342A (en) * | 1995-05-21 | 2000-09-05 | Basf Aktiengesellschaft | 2-(O-[pyrimidin-4-yl]methylenoxy)phenylacetic acid derivatives and their use for controlling harmful fungi and animal pests |
| CN101311170B (en) * | 2007-05-25 | 2010-09-15 | 中国中化股份有限公司 | Substituted pyrimidine ether compounds and uses thereof |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
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Address after: 710065 Shaanxi city of Xi'an province high tech Zone Feng Hui Road No. 36 block B block 18F oak Patentee after: Agricultural core crop Technology Co., Ltd. Address before: 710075 Shaanxi city of Xi'an province high tech Zone Feng Hui Road No. 36 block B block 18F oak Patentee before: Shaanxi Norsyn Crop Technology Co., Ltd. |