CN102246799A - Insecticidal composition containing spinetoram - Google Patents
Insecticidal composition containing spinetoram Download PDFInfo
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- CN102246799A CN102246799A CN2011101861875A CN201110186187A CN102246799A CN 102246799 A CN102246799 A CN 102246799A CN 2011101861875 A CN2011101861875 A CN 2011101861875A CN 201110186187 A CN201110186187 A CN 201110186187A CN 102246799 A CN102246799 A CN 102246799A
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- ethyl pleocidin
- pesticidal combination
- nicotinic insecticide
- insecticidal composition
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Abstract
The invention relates to a pesticide insecticidal composition. The insecticidal composition comprises the following active ingredients of: (A) spinetoram and (B) nicotinic insecticide, wherein the mass percentage ratio of A to B is 1-80:80-1, and the content of A and B in a compounded preparation is 1-80%. The compounded pesticide composition provided by the invention can be prepared into missible oil, a suspension agent, wettable powder, water dispersible granules, a water emulsion and other dosage forms by using a method known by technicians in the field. The nicotinic insecticide provided by the invention is one selected from thiacloprid, dinotefuran and clothianidin. The insecticidal composition provided by the invention is suitable for controlling various Lepidoptera, Thysanoptera and Coleoptera pests, such as plutella xylostella, beet armyworm, thrips, plant hoppers, whiteflies, aphids, codling moths and the like.
Description
Invention field:
The present invention relates to a kind of composition pesticide with synergistic effect, active ingredient for (A) ethyl pleocidin with (B) be selected from the nicotinic insecticide one or more.
Background technology:
Ethyl pleocidin is the regeneration product that produces pleocidin (apinasad) from actinomycetes thorn saccharopolyspora strains (saccharopolyspora spinosa) fermentation.Its former the effective elements of the medicine is ethyl pleocidin-J and ethyl pleocidin-I compound (ratio is 3: 1), and their biologically active does not have significant difference.
Its mechanism of action is to act on nAChR and r-aminobutyric acid acceptor in the insect nerve, causes polypide insensitive to the signal transfer reaction of excitability or inhibition, influences normal nervous activity, until death.Ethyl pleocidin has tags and stomach poison function, is mainly used in control pests with chewing mouthparts and sucking pest.Its chemical structural formula is:
Nicotinic insecticide is a class efficient pesticides, and its mechanism of action is for acting on acetylcholinergic receptor, interference insect nervous system normal conduction, thus cause the insect paralysis dead.Common anabasine active matter has: Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm amine, thiophene worm quinoline, MTI-446, the pyridine of piperazine worm, thiophene worm piperazine etc.The anabasine active matter is low, environmentally safe to mammalian toxicity, insecticidal activity is high.But anabasine insecticide has the shortcoming that insecticidal spectrum is not wide, the resistance Upside Risk is big.
Summary of the invention:
The object of the present invention is to provide a kind of Synergistic insecticidal compositions, this Pesticidal combination is characterized in that a kind of (B) with ethyl pleocidin (A) and nicotinic insecticide is that active ingredient is mixed, the various pests of control crops.
Technical scheme of the present invention is: a kind of Pesticidal combination, its active ingredient are that the mass ratio of ethyl pleocidin (A) nicotinic insecticide (B) effective constituents A and B is 1～80: 80～1.
Described nicotinic insecticide can be in thiophene worm quinoline, thiophene worm amine, the MTI-446 a kind of.
Pesticidal combination of the present invention is characterized in that through the toxicity test experiment, the mass ratio of effective constituents A and B is preferably 1～20: 20～1.
The formulation that described Pesticidal combination of the present invention can be prepared according to the known method of those skilled in the art of the present technique is formulations such as missible oil, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, microemulsion.
Described effective constituents A and the B gross mass content in preparation is 1～80%, preferred 1%～30%.All the other compositions are to allow in the agricultural chemicals to use and the acceptable auxiliary element.
The auxiliary agent that uses in the Pesticidal combination of the present invention (auxiliary element) comprises solvent, wetting agent, dispersant, antifreezing agent, thickener, defoamer, disintegrant, filler etc., and other are of value to active ingredient stable known substance of bringing into play with drug effect (being the composition of using always in the agricultural chemicals or allowing to use) in preparation, concrete composition and consumption, according to the prescription requirement, determine by normal experiment.
Described emulsifier is selected from any one or more mixtures formed with arbitrary proportion in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styryl phenol APEO, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, the polyoxyethylene aliphatic alcohol ether.
Described solvent is any one or more mixed solvents formed with arbitrary proportion in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), the water equal solvent.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Described wetting agent is selected from: lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX., among the wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described stabilizing agent is selected from: a kind of in sodium citrate, the resorcinol.
Described antifreezing agent is selected from: one or more in ethylene glycol, propane diols, the glycerine.
Described defoamer is selected from: silicone oil, silicone compound, C
10-20Saturated fat acid compounds, C
8-10In the aliphatic alcohols compound one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Pesticidal combination of the present invention has very obvious synergistic effect, can reduce effective ingredient consumption, delays the generation of pest resistance to insecticide, and can be used for the improvement of resistant insect.Be suitable for preventing and treating various Lepidopteras, thrips and coleopteran pest, as diamond-back moth, beet armyworm, thrips, plant hopper, aleyrodid, aphid, the stupid moth of apple etc.Pesticidal combination of the present invention compared with prior art produces following beneficial effect: 1. help delaying the generation of insect pair and anabasine insecticide resistance, prolong medicament service life; 2. has synergistic effect for homoptera pest after being mixed; 3. reduce dosage, for Environmental security.
Embodiment:
The different proportioning co-toxicities of ethyl pleocidin with MTI-446
1.1 reagent agent
The former medicine of 81% ethyl pleocidin, the former medicine of 95% MTI-446, above-mentioned former medicine provides by research and development centre of Qingdao Hailir Pesticides and Chemical Co., Ltd..
1.2 for examination worm source
Indoor potted apple seedling is raised continuously the apple aphid adult in three ages in 10 generations, temperature (25 ± 2) ℃, relative moisture 50% ± 4%, periodicity of illumination 14/10h (L/D).
1.3 single agent assay method
Adopt dip method with two former medicines all with the small amount of acetone dissolving, be diluted to into 5 dense solution of equal difference again with 0.1% Tween solution, be diluted in the beaker with standby, and in contrast with clear water.With of the same size three age the apple aphid adult in the soup that soaks the worm cage, flood 5S, inhale and to go to be placed in the culture dish that diameter is 9cm behind the unnecessary soup, be placed with the fresh apple blade in the ware and add a cover.Every concentration is handled 10, repeats 4 times.If blank.Keep in (27 ± 1) ℃ illumination box checking lethality behind the 24h that it is dead touching the polypide nonresponder with group pin.Lethality Abbott formula correction, again according to the concentration logarithm---the lethality probit value is analyzed (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50Value.
1.4 the joint toxicity measuring method of different proportionings
According to the toxicity test result of single agent, be 10% quality than ethyl pleocidin by active ingredient: MTI-446 was respectively 1: 9,3: 7,5: 5,7: 3,9: 1.Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press the abundant method of Sun Yun and calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula following (with the ethyl pleocidin is the standard medicament, and its toxicity index is 100):
The LC of the toxicity index of pleocidin (TI)=ethyl pleocidin
50The LC of/MTI-446
50* 100
The LC of actual toxicity index (ATI)=ethyl pleocidin of M
50The LC of/M
50* 100
TI * P the MTI-446 of the TI * P ethyl pleocidin+MTI-446 of theoretical toxicity index (TTI)=ethyl pleocidin of M
TTI * 100 of the ATI/M of the co-toxicity coefficient of M (CTC)=M
In the formula:
M is ethyl pleocidin and the mixture of MTI-446 by different proportionings
The P MTI-446 is MTI-446 shared ratio in mixture
The P ethyl pleocidin is ethyl pleocidin shared ratio in mixture
2.1 toxicity test result
Table 1 ethyl pleocidin, MTI-446 are to the indoor measurement result of apple aphid
As can be seen from the table, in being mixed of different proportion, its co-toxicity coefficient shows certain synergistic effect, wherein ethyl pleocidin all greater than 120: MTI-446 is that 5: 5 synergistic effect is the most obvious, and co-toxicity coefficient is 198.84.Result of the test shows, ethyl pleocidin, two kinds of medicaments of MTI-446 all have higher activity to apple aphid under indoor conditions, the result of the test of different proportion proportioning shows, by the active ingredient ethyl pleocidin: MTI-446 is 1: 9,3: 7,5: 5,7: 3,9: 1 o'clock, all show stronger synergistic effect, wherein with ethyl pleocidin: MTI-446 is 5: 5 o'clock, and synergistic effect is best.
3 field trials control apple aphid
3.1 field experiment control apple aphid
3.1 test method
3.1.1 application method
Test is sprayed medicine 1 time altogether, and the dispenser date is June 16.Apple aphid adult major part was in for 2～3 length of times.Weather is cloudy calm during the spray medicine.With the agricultural board level pressure of profit knapsack hand sprayer each is handled even spraying, leave dual sides all requires to be sprayed with the effect soup.Every sub-district soup 2L.
3.1.2 investigation method
Investigate each sub-district and fix 1 strain apple sapling as the investigation strain. write down the adult quantity on whole blades.Investigate the insect population radix before spraying medicine, respectively 3,7 days and investigation in 10 days borer population alive behind the spray medicine.This test is investigated 4 times altogether.
3.1.3 drug effect computational methods
The insect population borer population of living before rate (%)=(borer population of living after the borer population-dispenser of living before the dispenser)/dispenser that goes down) * 100
Preventive effect (%)=(the treatment region insect population rate of going down-check plot insect population go down rate)/(100-check plot insect population go down rate) * 100
3.1.4 poisoning investigation method
Continuous 10d range estimation medicament does not have poisoning to produce apple sapling well-grown to crop after the dispenser.
3.2 field control effectiveness test result
Table 2 is handled chemical control apple aphid field control effectiveness test result
As can be seen from Table 2, the Mixed Pharmacy of different proportion, carry out field experiment by different consumptions, its control efficiency to apple aphid all is better than contrasting medicament behind the medicine, 10% (ethyl pleocidin: MTI-446) (5: 5) behind medicine 10 days, insecticidal effect is respectively 86.69%, 90.20% and 92.94%, and insecticidal effect increases along with the increase of consumption, and difference reaches extremely remarkable between each consumption processing insecticidal effect.According to field range estimation, in the test dose scope, plant growth is normal, and each is handled medicament and poisoning phenomenon to apple all do not occur, illustrates that it is safe to apple.Advise that the insecticide different with the mechanism of action mixes use to delay the generation of pest resistance to insecticide.
4.1 ethyl pleocidin and the test of thiophene worm amine composition field experiment control wild cabbage diamond-back moth
4.1.1 test method
Tested on July 8th, 2010 to July 18 and carry out in wild cabbage plantation, Shouguang City, Shandong Province.Tested on July 8th, 2010 and carry out routine to water spray by each processing design concentration.Spraying equipment is a WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out the routine spraying, makes every effort to evenly thoughtful during the spray medicine.During dispenser the field diamond-back moth be 1～2 age the adult peak period.Every 667m
2To the water yield is 70kg.
Duration of test weather is good, and daily mean temperature is 18.0～26.8 ℃.Dispenser fine day on the same day.
4.1.2 investigation method
Before dispenser in every sub-district by 5 samplings of diagonal. every wild cabbage 3～5 strains (deciding) of choosing diamond-back moth ovum and adult on insect density.Statistics is demarcated a diamond-back moth number in the strain. with this as dispenser before the insect population radix.In after the dispenser the 3rd, 7,10d investigates the diamond-back moth borer population of deciding residual survival in the strain respectively. go down rate as control efficiency to proofread and correct insect population.
4.1.3 drug effect computational methods.
4.1.4 poisoning investigation method
Duration of test is observed and is respectively handled sub-district wild cabbage well-grown, all finds no the poisoning phenomenon and takes place.
4.2 field control effectiveness test result of the test
Table 3 is handled chemical control wild cabbage diamond-back moth field control effectiveness test result
As can be seen from Table 3, the Mixed Pharmacy of different proportion carries out field experiment by different consumptions, its control efficiency to diamond-back moth all is better than contrasting medicament behind the medicine, 10% (ethyl pleocidin: MTI-446) (5: 5) control diamond-back moth quick-acting is fast, and efficiency time is long, and control efficiency is good.10 days insecticidal effect reaches 84.34%, 88.78%, 90.14% respectively behind medicine, and insecticidal effect increases progressively along with the increase of consumption.According to experimental observation, each medication is handled does not all have poisoning to wild cabbage.Suggestion was grasped the diamond-back moth adult before 3 ages in dispenser period, required even spraying during dispenser, blade face, blade back even medicine, advise that the medicament different with other mechanisms of action is used alternatingly, to delay the generation of pest resistance to insecticide.
5, ethyl pleocidin and thiophene worm quinoline are paid pairing paddy rice brown planthopper Toxicity Determination
(1) test medicine
The former medicine of 81% ethyl pleocidin; The former medicine of 95% thiophene worm quinoline
(2) subjects
Paddy rice brown planthopper: pick up from field, Guangxi population, 2 generations of indoor rice seedling captive breeding.
(3) test method
Rice fulgorid: test method is with reference to " the agricultural industry criteria NY/T1154.11-2008 of the People's Republic of China (PRC) ", adopt rice stem infusion process: the rice strain that extracts with root healthy and strong tillering stage to the booting initial stage, clean, be cut into the long company's root rice stem of 15cm, one group of 3 strain, In Shade drying in the air do not have washmarking to the surface.The rice stem was soaked 30 seconds in the good soup of dilution respectively, take out dry after, encase root with the absorbent cotton that soaks and put into and cultivate cup, draw 3 mid-term in age nymph put into and cultivate cup, 20 every glass.If soak clear water is blank, and each concentration repeats 3 times.It is 27 ℃ that processing is placed on temperature, and periodicity of illumination is to cultivate in the incubator of 16h:8h (L:D).All checked death toll in 4 days.
(4) statistical analysis
Carry out statistical analysis with the DPS data processing software, calculate the LC of each medicament
50And 95% confidence limit, estimate the insecticidal activity of reagent agent with this to the examination worm.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
ATI＝(S/M)×100
In the formula:
ATI---mixture actual measurement toxicity index;
S---the LC of standard medicament
50, unit is mg/litre (mg/l);
The LC of M---mixture
50, unit is mg/litre (mg/l).
TTI＝TI
A×P
A+TI
B×P
B
In the formula:
The theoretical toxicity index of TTI---mixture;
TI
A---A medicament toxicity index;
P
A---the percentage composition of A medicament in mixture, unit are percentage;
TI
B---B medicament toxicity index;
P
B---the percentage composition of B medicament in mixture, unit are percentage.
CTC＝(ATI/TTI)×100
In the formula:
CTC---co-toxicity coefficient
ATI---mixture actual measurement toxicity index
The theoretical toxicity index of TTI---mixture
The co-toxicity coefficient of complex preparation (CTC) 〉=120 shows as synergistic effect, and CTC≤80 show as antagonism, and 80＜CTC＜120 show as summation action.
(5) interpretation of result
The composite toxicity test to brown planthopper of ethyl pleocidin and thiophene worm quinoline sees Table 4.
The composite toxicity test result of table 4 ethyl pleocidin and thiophene worm quinoline to brown planthopper
| Medicament | ?LC 50(mg/l) | ATI | TTI | CTC |
| Ethyl pleocidin (A) | 2.34 | 100.00 | —— | —— |
| Thiophene worm quinoline (B) | 11.13 | 21.02 | —— | —— |
| ?A∶B＝9∶1 | 1.67 | 140.12 | 98.45 | 142.32 |
| ?A∶B＝7∶3 | 1.37 | 170.80 | 92.82 | 184.01 |
| ?A∶B＝5∶5 | 1.87 | 125.13 | 60.51 | 206.79 |
| ?A∶B＝3∶7 | 6.23 | 37.56 | 24.79 | 151.54 |
| ?A∶B＝1∶9 | 7.13 | 32.82 | 22.57 | 145.39 |
To sum up result of the test is described, the present invention contains the Pesticidal combination of ethyl pleocidin and nicotinic insecticide, insects such as apple aphid and wild cabbage diamond-back moth and paddy rice brown planthopper are shown good control efficiency, to the target crop safety, compare with single agent, Pesticidal combination of the present invention has mechanism of action uniqueness, the unit administration amount is few, quick-acting is good, the advantage that lasting period is long, so, in research and development of the present invention and popularization the important social meaning is arranged, can produce very big economic benefit, promote peasant's increasing both production and income,, the potentiality that vigorously promote the use are arranged agricultural product and Environmental security.
Claims (6)
1. Pesticidal combination that contains ethyl pleocidin and nicotinic insecticide.
2. Pesticidal combination according to claim 1 is characterized in that: nicotinic insecticide is selected from a kind of in thiophene worm amine, thiophene worm quinoline, the MTI-446.
3. Pesticidal combination according to claim 1 is characterized in that: the mass ratio of ethyl pleocidin and nicotinic insecticide is 1～80: 80～1.
4. Pesticidal combination according to claim 1 is characterized in that: ethyl pleocidin is 1～20: 20～1 with the quality optimization ratio of nicotinic insecticide.
5. Pesticidal combination according to claim 1 is characterized in that: active ingredient ethyl pleocidin and the nicotinic insecticide total mass ratio in composition is 1～80%, preferably than being 1～30%.
6. Pesticidal combination according to claim 1 is characterized in that: adopt the known technical scheme of those skilled in the art can be prepared into formulations such as missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
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|---|---|---|---|
| CN2011101861875A CN102246799A (en) | 2011-06-26 | 2011-06-26 | Insecticidal composition containing spinetoram |
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|---|---|---|---|
| CN2011101861875A CN102246799A (en) | 2011-06-26 | 2011-06-26 | Insecticidal composition containing spinetoram |
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ID=44974662
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102396487A (en) * | 2011-12-20 | 2012-04-04 | 广西田园生化股份有限公司 | Pesticide composition containing spinetoram and thiamethoxam |
| CN102578132A (en) * | 2012-02-13 | 2012-07-18 | 陕西上格之路生物科学有限公司 | Pesticide composition containing spinetoram and neonicotinoid insecticide |
| CN102934638A (en) * | 2012-11-21 | 2013-02-20 | 上海沪联生物药业（夏邑）股份有限公司 | Pesticide composition containing ethyl spinosad and clothianidin and application thereof |
| CN102939983A (en) * | 2012-10-18 | 2013-02-27 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN103461372A (en) * | 2013-09-05 | 2013-12-25 | 江苏龙灯化学有限公司 | Pesticide composition containing imidaclothiz and spinetoram |
| CN104286011A (en) * | 2014-09-29 | 2015-01-21 | 青岛康和食品有限公司 | Efficient insecticide containing efficient cyfluthrin, profenofos, dinotefuran and spinetoram |
| CN106212464A (en) * | 2016-08-02 | 2016-12-14 | 佛山市盈辉作物科学有限公司 | A kind of Pesticidal combination containing ethyl pleocidin |
| CN106577732A (en) * | 2016-12-14 | 2017-04-26 | 安徽东健化工科技有限公司 | Efficient herbicide |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102396487A (en) * | 2011-12-20 | 2012-04-04 | 广西田园生化股份有限公司 | Pesticide composition containing spinetoram and thiamethoxam |
| CN102578132A (en) * | 2012-02-13 | 2012-07-18 | 陕西上格之路生物科学有限公司 | Pesticide composition containing spinetoram and neonicotinoid insecticide |
| CN102939983A (en) * | 2012-10-18 | 2013-02-27 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN102934638A (en) * | 2012-11-21 | 2013-02-20 | 上海沪联生物药业（夏邑）股份有限公司 | Pesticide composition containing ethyl spinosad and clothianidin and application thereof |
| CN103461372A (en) * | 2013-09-05 | 2013-12-25 | 江苏龙灯化学有限公司 | Pesticide composition containing imidaclothiz and spinetoram |
| CN103461372B (en) * | 2013-09-05 | 2015-09-30 | 江苏龙灯化学有限公司 | A kind of agricultural insecticide composition containing imidaclothiz and ethyl pleocidin |
| CN104286011A (en) * | 2014-09-29 | 2015-01-21 | 青岛康和食品有限公司 | Efficient insecticide containing efficient cyfluthrin, profenofos, dinotefuran and spinetoram |
| CN106212464A (en) * | 2016-08-02 | 2016-12-14 | 佛山市盈辉作物科学有限公司 | A kind of Pesticidal combination containing ethyl pleocidin |
| CN106577732A (en) * | 2016-12-14 | 2017-04-26 | 安徽东健化工科技有限公司 | Efficient herbicide |
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Application publication date: 20111123 |