CN102972421B - A kind of Pesticidal combination containing emamectin benzoate and triflumuron - Google Patents
A kind of Pesticidal combination containing emamectin benzoate and triflumuron Download PDFInfo
- Publication number
- CN102972421B CN102972421B CN201210565649.9A CN201210565649A CN102972421B CN 102972421 B CN102972421 B CN 102972421B CN 201210565649 A CN201210565649 A CN 201210565649A CN 102972421 B CN102972421 B CN 102972421B
- Authority
- CN
- China
- Prior art keywords
- triflumuron
- emamectin benzoate
- active ingredient
- pesticidal combination
- cabbage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The present invention relates to a kind of Pesticidal combination containing emamectin benzoate and triflumuron, its active ingredient is that emamectin benzoate and triflumuron two yuan are composite; Wherein the mass ratio of emamectin benzoate and triflumuron is 1:11,2:10,3:9,4:8,5:7, in preparation, the gross mass of active ingredient emamectin benzoate and triflumuron accounts for the 1%-80% of whole preparation gross mass, and all the other are the auxiliary element allowing in agricultural chemicals to use and accept, and the formulations of pesticide that Pesticidal combination of the present invention can be made are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Be mainly used in control apple leaf miner, cabbage caterpillar, diamond-back moth, wheat mythimna separata, pine caterpillars red tape leaf roller, cigarette aphid noctuid, cotton bollworm, maduca sexta, beet armyworm, nonirrigated farmland covet noctuid, confused Autographa spp, cabbage looper, imported cabbageworm, cabbage heart snout moth's larva, wild cabbage horizontal stripe snout moth's larva, tomato hawkmoth, colorado potato beetle etc.Be widely used in the coleoptera on control of maize, cotton, forest, fruit and soybean, diptera, lepidoptera pest.
Description
Technical field
The present invention relates to technical field of pesticide combination, particularly relate to a kind of Pesticidal combination containing emamectin benzoate and triflumuron.
Background technology
Emamectin benzoate full name emamectin-benzoate, it is the new and effective semisynthetic antibiotics insecticide of one of synthesis from fermented product AVERMECTIN B1, it has super-high-efficient, low toxicity (preparation is closely nontoxic), low-residual, the nuisanceless feature waiting biopesticide, with Avermectin first insecticidal activity improve 3 orders of magnitude, to the larva of lepidopterous insects and the activity of other many insect high, existing stomach poison function is double action of contace poison again, under low-down dosage (0.084 ~ 2g/ha), there is good effect, and in the process of pest control, beneficial insect is not injured, be conducive to the integrated control to insect, expand insecticidal spectrum in addition, reduce the toxicity to people and animals.Emamectin benzoate has the incomparable activity of other agricultural chemicals to a lot of insect, especially to Lepidoptera, diptera, super-high-efficient, as noctuid, confused Autographa spp, cabbage looper, imported cabbageworm, cabbage heart snout moth's larva, wild cabbage horizontal stripe snout moth's larva, tomato hawkmoth, colorado potato beetle, Mexico ladybug etc. are coveted in red tape leaf roller, cigarette aphid noctuid, cotton bollworm, maduca sexta, diamond-back moth mythimna separata, beet armyworm, nonirrigated farmland.The chemical name of emamectin benzoate: 4'-table-methylamino-4'-deoxidation abamectin benzoate, its chemical structural formula
.
Triflumuron series of products are a kind of Chitin synthesis inhibitors, and it is the insect growth regulator, IGR of benzoyl area kind.It, to insect mainly stomach poison function, has certain action of contace poison, but without systemic action, has good ovicidal action.Because it is efficient, low toxicity and wide spectrum, can be used for the coleoptera on control of maize, cotton, forest, fruit and soybean, diptera, lepidoptera pest, harmless to natural enemy.The chloro-N-of chemical name 2-((4-(trifluoromethoxy) phenyl) the is amino) benzamide of triflumuron, its chemical structural formula is
.
Be used alone emamectin benzoate and triflumuron, there is cost compare large, quick-acting or lasting effect poor, single dose uses the easily shortcoming such as generation resistance.In order to develop quick-acting and lasting effect is good, lower-cost agricultural chemicals, we are on the basis of lab screening and field trial, filter out emamectin benzoate and triflumuron carries out composite, have obvious synergistic effect.And there is no people at present about emamectin benzoate and the composite Pesticidal combination of triflumuron and application and reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective agricultural insecticide composition.This agricultural insecticide composition is mainly used in control apple leaf miner, noctuid, confused Autographa spp, cabbage looper, imported cabbageworm, cabbage heart snout moth's larva, wild cabbage horizontal stripe snout moth's larva, tomato hawkmoth, colorado potato beetle etc. are coveted in cabbage caterpillar, diamond-back moth, wheat mythimna separata, pine caterpillars red tape leaf roller, cigarette aphid noctuid, cotton bollworm, maduca sexta, beet armyworm, nonirrigated farmland.Be widely used in the coleoptera on control of maize, cotton, forest, fruit and soybean, diptera, lepidoptera pest.
Technical scheme of the present invention is realized by following measures:
Contain a Pesticidal combination for emamectin benzoate and triflumuron, the active ingredient of this Pesticidal combination is emamectin benzoate and triflumuron binary built, and all the other are auxiliary element, in wherein said Pesticidal combination, the mass ratio of active ingredient emamectin benzoate and triflumuron is 1:11,2:10,3:9,4:8,5:7.
The formulations of pesticide that described Pesticidal combination of the present invention can be prepared are the formulations such as missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Wherein active ingredient emamectin benzoate and triflumuron gross mass in the formulation accounts for 1% ~ 80% of the whole quality of the pharmaceutical preparations, and when wherein accounting for 5% ~ 45%, toxicity reaches good balance with residual, and cost is also lower.
The specific embodiments of the formulations of pesticide that desinsection of the present invention and composition are mixed with is as follows:
Described Pesticidal combination is cream preparation, and the mass fraction of component is:
Emamectin benzoate 1 ~ 80 part
Triflumuron 1 ~ 80 part
Conventional emulsifier 10 ~ 30 parts
Conventional solvents 20 ~ 50 parts
Conventional synergist 1 ~ 5 part.
The concrete production stage of this cream preparation be first active ingredient emamectin benzoate and triflumuron to be added in solvent dissolve completely after add emulsifier again, synergist becomes transparent and homogeneous oily liquids after stirring, filling, namely can be made into the cream preparation of the present composition.
Described Pesticidal combination is suspending agent, and the mass fraction of component is:
Emamectin benzoate 1 ~ 80 part
Triflumuron 1 ~ 80 part
Dispersant 5 ~ 20 parts
Antifreezing agent 1 ~ 5 part
Thickener 0.1 ~ 2 part
Defoamer 0.1 ~ 0.8 part
Penetrating agent 0 ~ 10 part
PH value regulator 0.1 ~ 5 part
Water surplus.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active ingredient emamectin benzoate and triflumuron abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, namely can be made into the aqueous suspension formulations of the present composition.
Described Pesticidal combination is wetting powder, and the mass fraction of component is:
Emamectin benzoate 1 ~ 80 part
Triflumuron 1 ~ 50 part
Dispersant 3 ~ 10 parts
Wetting agent 1 ~ 5 part
Filler surplus.
The concrete production stage of this wetting powder is: by above-mentioned formula by active ingredient emamectin benzoate and triflumuron and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
Described Pesticidal combination is water dispersible granules, and the mass fraction of component is:
Emamectin benzoate 1 ~ 80 part
Triflumuron 1 ~ 50 part
Dispersant 3 ~ 10 parts
Wetting agent 1 ~ 10 part
Disintegrant 1 ~ 5 part
Filler surplus.
The concrete production stage of this water dispersible granules is: active ingredient emamectin benzoate, triflumuron and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and to carry out after granulation, drying, screening, through sample analysis, namely can be made into the water dispersible granules of the present composition.
The emulsifier used in described Pesticidal combination is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any one in polyoxyethylene aliphatic alcohol ether or more than one any mixtures than composition.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), and one or more in water equal solvent are arbitrarily than the mixture of composition.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, the one in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
Active ingredient emamectin benzoate and triflumuron is composite has obvious synergistic effect in Pesticidal combination of the present invention, can reduce effective ingredient consumption, delay the generation of pest resistance to insecticide, and reduce into product cost and use cost, can be used for the improvement of resistant insect.Be mainly used in control apple leaf miner, cabbage caterpillar, diamond-back moth, wheat mythimna separata, pine caterpillars red tape leaf roller, cigarette aphid noctuid, cotton bollworm, maduca sexta, beet armyworm, nonirrigated farmland covet noctuid, confused Autographa spp, cabbage looper, imported cabbageworm, cabbage heart snout moth's larva, wild cabbage horizontal stripe snout moth's larva, tomato hawkmoth, colorado potato beetle etc.Be widely used in the coleoptera on control of maize, cotton, forest, fruit and soybean, diptera, lepidoptera pest.This invention significantly can make up the deficiency of agricultural chemicals emamectin benzoate and triflumuron single dose lasting effect aspect, accomplishes that quick-acting and lasting effect are taken into account, and compares chemical classes agricultural chemicals, residual low, easily decomposes, more environmental protection.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all ratio of quality and the number of copies.
Embodiment: emamectin benzoate and triflumuron proportioning co-toxicity are tested.
1.1 reagent agent
The former medicine of emamectin benzoate of 90%, the former medicine of triflumuron of 99%, above-mentioned former medicine provides by research and development department of Qingdao Hailir Pesticides and Chemical Co., Ltd..
1.2 test targets
Indoor raised for 5 generations continuously and the third-instar larvae of its Individual Size responsive type beet armyworm consistent with physiological status.Temperature (25 ± 2) DEG C.Relative moisture 65% ± 5%, periodicity of illumination 12/12h (L/D).
1.3 experimental procedure
1.3.1 medicament preparation
First use the former medicine of acetone solution, appropriate two former medicines are made into 5 different ratio by the result according to preliminary experiment, then it is stand-by each process to be diluted to respectively 5 concentration gradients with acetone, the ratio of 5 emamectin benzoate and triflumuron different ratio active ingredient is respectively 1:11,2:10,3:9,4:8,5:7.
1.3.2 chemicals treatment
The drop method adopting NY/T1 154.1-2006 to recommend measures.By micro intravenous drip device solvent clean, regulate dropper to stand-by state.The examination worm CO of neat and consistent is chosen with writing brush
2mild paralysis is placed in 9cm culture dish, then with micro intravenous drip device, medicament is dripped to the belly of polypide by head, every some drops physic liquor 0.1L, and the process of the corresponding acetone contained with drop 0.1L is contrast, and the examination worm after drop is moved to (28
2) DEG C, normally cultivate in the culture dish of relative moisture 75%.Often process and repeat for 4 times, often repeat 20 examination worms.
1.4 control time
After process, 24h investigation examination worm death condition (judging that examination worm death standard gently stings without autonomic response with pin), records total borer population and dead borer population.
1.5 data statistics and analysis
According to investigation statistics, calculate the corrected mortality of each process.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1 154.7-2006.If contrast lethality <5%, does not correct, contrast lethality, between 5%-20%, corrects by formula 2, and contrast lethality >20%, test need be reformed.
Be independent variable x with the logarithm value of drug concentration (mg/L), with the probability value of corrected mortality for dependent variable y, set up virulence regression equation formula respectively, adopt DPS software to calculate the LC of single dose and each proportioning mixture
50co-toxicity coefficient (CTC) is calculated according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take emamectin benzoate as standard agent, its toxicity index is 100):
The LC of toxicity index (the TI)=emamectin benzoate of triflumuron
50the LC of/triflumuron
50× 100
The LC of true toxicity index (the ATI)=emamectin benzoate of M
50the LC of/M
50× 100
TI × P triflumuron of TI × P emamectin benzoate+triflumuron of theoretical toxicity index (the TTI)=emamectin benzoate of M
TTI × 100 of the ATI/M of co-toxicity coefficient (the CTC)=M of M
In formula:
M is the mixture of emamectin benzoate and triflumuron different ratio
P emamectin benzoate is the ratio of emamectin benzoate shared by mixture
P triflumuron is the ratio of triflumuron shared by mixture.
2.1 toxicity test results
Table 1 emamectin benzoate, triflumuron are to the indoor measurement result of beet pretty young woman at night
As can be seen from the table, in active ingredient emamectin benzoate: triflumuron ratio is 1:11; 2:10; 3:9; 4:8; When 5:7 dilutes respectively, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein emamectin benzoate: triflumuron is that the synergistic effect of 1:11 is the most obvious, and co-toxicity coefficient is 189.15.Result of the test shows, emamectin benzoate and triflumuron all have higher activity to beet armyworm in room conditions, advises carrying out further field control effectiveness test to suitable proportion about 1:11 mixture preparation, to evaluate its field practical application effect.
The experimental result of 3 field trial control beet armyworms, paddy rice rice leaf roller
3.1 field trial control beet armyworms
3.1.1 test method
Test is carried out at Kaiping City of Guangdong Province suburb truck garden.Routine is carried out to water spray by each process design concentration.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.During dispenser, field beet armyworm is 1 ~ 2 instar larvae peak period.
Duration of test weather is good, and daily mean temperature is 17.8 ~ 26.4 DEG C.Dispenser same day is without rain.
3.1.2 investigation method
In dispenser Qian Mei community by diagonal 5 sampling. often some wild cabbage 2 ~ 3 strain (depending on insect density) choosing Beet Armyworm Eggs and larva.Beet exigua larvae head number in probability demarcation strain. in this, as insect population radix before dispenser.After dispenser the 3rd, 7,10d investigates the beet exigua larvae number determining residual survival in strain respectively. to correct Revision insect recluced rate as control efficiency
3.1.3 drug effect computational methods
Revision insect recluced rate (%)=(after medicine prelarva number-medicine larva number)/medicine prelarva number × 100
Preventive effect (%)=(treatment region Revision insect recluced rate-contrast Revision insect recluced rate)/(100-check plot Revision insect recluced rate) × 100.
3.1.4 poisoning investigation method
Within 1,3,7,14 days after medicine, observe wild cabbage growing state, estimate medicament to wild cabbage without poisoning.
3.1.5 field control effectiveness test result
The experimental result of table 2 treatment agent control beet armyworm
The Mixed Pharmacy of different proportion as can be seen from Table 2, tests by different consumptions, and after medicine, it is all better than contrasting medicament to the control of beet armyworm.6% emamectin benzoate (0.5%) triflumuron (5.5%) insecticidal effect of 14 days after medicine is respectively 88.24,90.64,92.61..Insecticidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in individual treatment agent, illustrates that it is safe to wild cabbage.Advise that the insecticide different from the mechanism of action is used in combination with the generation delaying pest resistance to insecticide.
4.1 field experiment control paddy rice rice leaf roller
4.1.1 test method
Test in Xiangyin, Hunan institute of agricultural sciences experimental field.Routine is carried out to water spray by each process design concentration.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.During dispenser, field rice leaf roller is 1 ~ 2 instar larvae peak period.Every 667 m
2be 50kg to the water yield.
Duration of test weather is good, and daily mean temperature is 19.0 ~ 28.2 DEG C.Dispenser same day is without rain.
4.1.2 investigation method
Adopt 5 point samplings, 5 points are selected in every community, every community 20m
2, 5 clumps often, investigate 25 clumps of paddy rice altogether.Before dispenser and after dispenser the 3rd, 7d investigates whole blades of 25 clumps respectively, and win all the old and new worm bags, then the residual borer population of living of stripping bag record, calculates Revision insect recluced rate and Rectifying efficacies; After medicine, investigation leaf roll number during 20d harm in present age sizing, calculates leaf roll rate and preventive effect.Note viewing test chemicals treatment to paddy rice with or without poisoning.
4.1.3 drug effect computational methods.
Revision insect recluced rate (%)=
× 100
Rectifying efficacies (%)=
× 100;
Leaf roll preventive effect (%)=
× 100.
4.1.4 poisoning investigation method
It is good that duration of test observes each process community paddy growth, all finds no poisoning phenomenon and occur.
4.2 field control effectiveness test result of the tests
Table 3 treatment agent control paddy rice rice leaf roller field control effectiveness test result
As can be seen from Table 3, the Mixed Pharmacy of different proportion, carries out field trial by different consumptions, and after medicine, it is all better than contrasting medicament to the control efficiency of paddy rice rice leaf roller, 6% emamectin benzoate (0.5%) triflumuron (5.5%) control paddy rice rice leaf roller is effective, and the lasting period reaches more than 20d.After medicine, the insecticidal effect of 7 days is respectively 86.62 %, 89.76% and 93.86%, and insecticidal effect increases progressively along with the increase of consumption.20d after medicine, this process leaf roll preventive effect reaches more than 85%, shows that this patent has very strong desinsection and protecting effect of leaves.According to experimental observation, each medication process all without poisoning, finds that this compound product also has good preventive effect to rice fulgorid to paddy rice simultaneously.Advise in insect egg hatching peak period to the phase dispenser of 1--2 instar larvae.It is to crop and Environmental security, and be worth promoting use.
Surveyed and field experiment by raw above; we can know that the compounded pesticides that the present invention contains emamectin benzoate and triflumuron has good control efficiency to insects such as beet armyworm, paddy rice rice leaf roller; to Target crops safety; compared with single dose; Pesticidal combination of the present invention has mechanism of action uniqueness; consumption is few; instant effect; the advantage that lasting period is long; so; very large economic benefit is had, to the volume increase of peasant household crop with increase income and be of great significance the protection tool of local environment in research and development of the present invention and popularization.
Claims (4)
1. the Pesticidal combination containing emamectin benzoate and triflumuron is preparing the application in the pesticidal preparations preventing and treating beet armyworm, it is characterized in that: this Pesticidal combination is for active ingredient carries out mixture between two with emamectin benzoate and triflumuron, all the other are auxiliary element, and wherein the mass ratio of active ingredient emamectin benzoate and triflumuron is 1:11.
2. application according to claim 1, is characterized in that: active ingredient emamectin benzoate and the triflumuron gross weight in pesticidal preparations accounts for 1% ~ 80% of the whole quality of the pharmaceutical preparations.
3. application according to claim 2, is characterized in that: active ingredient emamectin benzoate and the triflumuron gross weight in pesticidal preparations accounts for 5% ~ 45% of the whole quality of the pharmaceutical preparations.
4. the application according to claim 1 or 2 or 3, is characterized in that: the formulation of this pesticidal preparations is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565649.9A CN102972421B (en) | 2012-12-24 | 2012-12-24 | A kind of Pesticidal combination containing emamectin benzoate and triflumuron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565649.9A CN102972421B (en) | 2012-12-24 | 2012-12-24 | A kind of Pesticidal combination containing emamectin benzoate and triflumuron |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102972421A CN102972421A (en) | 2013-03-20 |
| CN102972421B true CN102972421B (en) | 2015-10-28 |
Family
ID=47846996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210565649.9A Active CN102972421B (en) | 2012-12-24 | 2012-12-24 | A kind of Pesticidal combination containing emamectin benzoate and triflumuron |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102972421B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UY37780A (en) | 2017-06-26 | 2019-01-31 | Merial Inc | COMPOSITIONS OF PARASITICIATED GRANULES WITH DOUBLE ACTIVE PRINCIPLE, ITS METHODS AND USES |
| CN107156116A (en) * | 2017-07-14 | 2017-09-15 | 安徽金农康农药检测有限公司 | A kind of emamectin-benzoate and triflumuron compounding suspending agent and preparation method thereof |
| CN108041064A (en) * | 2018-01-26 | 2018-05-18 | 山东汤普乐作物科学有限公司 | A kind of desinsection microcapsule suspension-suspendinagent agent containing bistrifluron and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1957705A (en) * | 2006-06-07 | 2007-05-09 | 通化绿地农药化学有限公司 | Composite preparation of pesticide between triflumuron and antibiotic insecticide |
| CN101617686A (en) * | 2009-04-25 | 2010-01-06 | 吴汇峰 | Compound pesticide of tetrachlorvinphos and triflumuron |
-
2012
- 2012-12-24 CN CN201210565649.9A patent/CN102972421B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1957705A (en) * | 2006-06-07 | 2007-05-09 | 通化绿地农药化学有限公司 | Composite preparation of pesticide between triflumuron and antibiotic insecticide |
| CN101617686A (en) * | 2009-04-25 | 2010-01-06 | 吴汇峰 | Compound pesticide of tetrachlorvinphos and triflumuron |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102972421A (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102986700A (en) | Insecticide composition containing flutenzine and bistrifluron | |
| CN102972421B (en) | A kind of Pesticidal combination containing emamectin benzoate and triflumuron | |
| CN102972430A (en) | Insecticidal composition containing thiamethoxam and acetamiprid | |
| CN109392942A (en) | A kind of Pesticidal combination containing indoxacarb and bistrifluron | |
| CN103168787A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN102960353A (en) | Insecticidal and acaricidal composition containing metaflumizone and flufenzine | |
| CN102972413A (en) | Pyridalyl and flutenzine-containing insecticidal compound | |
| CN103125496A (en) | Novel insecticide composition compounding pymetrozine | |
| CN102428922A (en) | Diacylhydrazine pesticide compounded pesticidal composition | |
| CN102960356A (en) | Parasiticide composite containing bistrifluron and methoxyfenozide | |
| CN103004818A (en) | Insecticide composition containing fipronil and spirotetramat | |
| CN103004857B (en) | A kind of Pesticidal combination containing Biphenthrin and chlorfenapyr | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile | |
| CN107361072A (en) | A kind of Pesticidal combination containing emamectin benzoate and cyflumetofen | |
| CN103609571A (en) | Emamectin benzoate and abamectin containing pesticidal composition | |
| CN104522041A (en) | Flonicamid and efficient cyhalothrin containing insecticide composition | |
| CN103719139A (en) | Insecticide composition containing dinotefuran and diafenthiuron | |
| CN103120165A (en) | Insecticidal composition containing spinetoram and cyantraniliprole | |
| CN103651473A (en) | Insecticidal combination containing metaflumizone and cyantraniliprole | |
| CN103636642A (en) | Insecticide composition containing chlorantraniliprole and bistrifluron | |
| CN103202311A (en) | Insecticide composition containing dinotefuran and novaluron | |
| CN103190407A (en) | Insecticide composition containing methoxyfenozide and chlorfenapyr | |
| CN102972416A (en) | Acaricidal composition containing fluacrypyrim and spirodiclofen | |
| CN103300030B (en) | A kind of Pesticidal combination containing carbosulfan and chlorfenapyr | |
| CN103053553A (en) | Insecticidal composition containing emamectin benzoate and methoxyfenozide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |