CN104522041A - Flonicamid and efficient cyhalothrin containing insecticide composition - Google Patents
Flonicamid and efficient cyhalothrin containing insecticide composition Download PDFInfo
- Publication number
- CN104522041A CN104522041A CN201410850035.4A CN201410850035A CN104522041A CN 104522041 A CN104522041 A CN 104522041A CN 201410850035 A CN201410850035 A CN 201410850035A CN 104522041 A CN104522041 A CN 104522041A
- Authority
- CN
- China
- Prior art keywords
- flonicamid
- pesticidal combination
- gamma cyhalothrin
- composition
- cyhalothrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a flonicamid and efficient cyhalothrin containing insecticide composition. The effective ingredients in the composition are prepared through binary compounding of flonicamid and efficient cyhalothrin, wherein the mass ratio of the flonicamid and the efficient cyhalothrin is 30-1:1-30, and the optimal mass ratio is 10-1:1-10. The total mass of the effective ingredients, namely the flonicamid and the efficient cyhalothrin in the composition accounts for 5%-50% of the mass of the composition and are accepted auxiliary ingredients allowed to be used in pesticides. The insecticide composition can be processed to produce missible oil, suspending agents, wettable powder, water dispersible granules, concentrate emulsion, microemulsion, granules and micro-capsula. The insecticide composition is mainly used for preventing and controlling piercing-sucking mouthparts and also has good prevention and control effect on coleopteran and lepidoptera pests.
Description
Technical field
The present invention relates to technical field of pesticide combination, particularly relate to the Pesticidal combination containing flonicamid and gamma cyhalothrin.
Background technology
Flonicamid is a kind of novel low-toxicity picolinamide class insect growth regulator, IGR insecticides of the former industry development of Japanese stone, flonicamid is tagged and stomach poison function except having, also there is good never poison and quick Antifeedant Effects, for numerous crop control sucking pest.The chemical structure names of flonicamid is: N-cyanogen methyl-(trifluoromethyl)-vitamin PP.Chemical structural formula is
Gamma cyhalothrin is also known as cyhalothrin, and chemical name: 3-(2-chloro-3,3,3 ,-trifluoropropene base)-2,2-dimethyl cyclopropane carboxylic acid's alpha-cyano-3-phenoxybenzyl ester, chemical structural formula is
Gamma cyhalothrin is a kind of widely used pyrethroid insecticides, is high-efficient broad-spectrum insecticide, and tool is tagged good with stomach poison function quick-acting.Effective especially to coleoptera and lepidoptera pest, there is certain preventive effect to the insect of sucking mouth parts and evil mite.Gamma cyhalothrin decomposes soon in plant corpus, residual hazard is low, to person poultry safety, on environment without impact.
In agricultural production real process, chemical pesticide control plant pest is used to be still the most effective means, but use single agricultural chemicals easily to make worm develop immunity to drugs, and long-term high dose continuously uses single agricultural chemicals easily to cause residue of pesticide to exceed standard, the problems such as environmental pollution increases the weight of, reasonably by composite for chemical pesticide use, not only can expand the insecticidal spectrum of agricultural chemicals, improve control efficiency, and minimizing dosage, reduce poisoning, reduce residue of pesticide, delay pest resistance and resistance generation, ask on test of pesticide effectiveness basis at laboratory reagent experiment sieving and field, selected flonicamid and gamma cyhalothrin Pesticidal combination, there is notable synergistic effect, this Pesticidal combination composite, there is no report at present.
Summary of the invention
The object of the present invention is to provide a kind of new and effective Pesticidal combination, it mainly contains effective constituent is flonicamid and gamma cyhalothrin, is mainly used in preventing and treating sucking pest, also has good control efficiency to coleoptera, lepidoptera pest.
Technical scheme of the present invention is realized by following measures:
1, a kind of Pesticidal combination containing flonicamid and gamma cyhalothrin, in said composition, the mass ratio of effective ingredient flonicamid and gamma cyhalothrin is 1-30: 30-1, when the mass ratio that indoor biometrics tests preferred flonicamid and gamma cyhalothrin is 1-10: 10-1, synergistic effect is better.
2, this Pesticidal combination can be processed into missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations.Can reach medication when the gross mass of flonicamid and gamma cyhalothrin accounts for the 5%-50% of the whole quality of the pharmaceutical preparations in above-mentioned preparation less, drug effect is high, lower-cost effect.
Pesticidal combination of the present invention is as follows in pesticidal preparations embodiment:
1, described Pesticidal combination is cream preparation, and constituent mass mark is:
Flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Emulsifier 8-15 part; Organic solvent 30-50 part; Stabilizing agent 1-5 part.
The missible oil production stage of this Pesticidal combination is: first active principle flonicamid and gamma cyhalothrin are added in organic solvent and fully dissolve, then add emulsifier and stabilizing agent to stir quality transparent profit liquid, by analysis the filling cream preparation product being this Pesticidal combination after the assay was approved.
2, described Pesticidal combination is suspending agent, and constituent mass mark is:
1. flonicamid 10-1; 2. gamma cyhalothrin 1-10; 3. dispersant 10-18 part; 4. suspending agent 0.1-1.5 part; 5. bleeding agent 1-3 part; 6. antifreezing agent 3-5 part; 7. defoamer 0.5-1.0 part; 8. stabilizing agent 1-3 part; 9. water supplies surplus.
The suspending agent production stage of this Pesticidal combination is: first will 1. 2. 3. 7. 8. 9. material add respectively mixing axe in, after stirring, 30-50 minute is being pulverized through the circulation of pipeline macerator pump, and then be ground to granularity through two-stage sand mill and reach 5 below μ, material is put into modulator, add 4. 5. 6. material stirring evenly after, analyze and detect filling, be the suspending agent product of this Pesticidal combination.
3, described Pesticidal combination is wetting powder, and the mass fraction of component is:
Flonicamid 10-1; Gamma cyhalothrin 1-10 part; Lubricant 3-5 part; Dispersant 3-10 part; Synergist 1-3 part; Surplus supplied by filler.
The wetting powder production stage of this Pesticidal combination is: joined by various material in twin-spiral mixer and carry out supplementary mixing.The material mixed is crushed to 800 orders once through airslide disintegrating mill again, packs after analytical control is qualified, is the wetting powder product of this Pesticidal combination.
4, described Pesticidal combination is water dispersible granules, and the mass fraction of component is:
Flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Dispersant 3-10 part; Wetting agent 2-6 part; Disintegrant 3-5 part; Surplus supplied by filler.
The water dispersible granules production stage of this Pesticidal combination is: first this Pesticidal combination is added into wetting powder by 3 steps, then be typed in fluidized-bed granulation dryer after this wetting powder being mixed carry out granulation, drying, screening is collected needs the product of particle size range, analytical control, packing are the water dispersible granules product of this Pesticidal combination.
5, described Pesticidal combination is aqueous emulsion, and the mass fraction of component is:
Flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Emulsifier 5-25 part; Organic solvent 5-20 part; Stabilizing agent 3-5 part; Antifreezing agent 3-5 part; Defoamer 0.1-1 part; Thickener 0.1-2.0 part; Water supplies surplus.
The aqueous emulsion production stage of this Pesticidal combination is: first flonicamid and gamma cyhalothrin, organic solvent, emulsifier are added together and make it be dissolved into uniform oil phase, part water, antifreezing agent, defoamer is added together and forms homogeneous aqueous phase; By while aqueous phase high-speed stirred in high shear axe, oil phase is added in aqueous phase, slowly adds surplus water, and start high shear machine and carry out high speed shear to 30-40 minute, form the aqueous emulsion of water colour oil type, be up to the standards by analysis, the filling aqueous emulsion finished product namely obtaining this Pesticidal combination.
6, described Pesticidal combination is microemulsion, and the mass fraction of component is: flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Organic solvent 15-30 part; Emulsifier 12-26 part; Antifreezing agent 3-8 part; Stabilizing agent 0.5-1.2 part;
The microemulsion production stage of this Pesticidal combination is: first by flonicamid and gamma cyhalothrin organic solvent dissolution, then adds emulsifier, antifreezing agent, stabilizing agent Homogeneous phase mixing, finally adds the water of surplus, after stirring, obtains microemulsion.
7, described Pesticidal combination is granule, and the mass fraction of component is:
Flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Wetting agent 3-5 part; Dispersant 5-10 part; Stabilizing agent 0.1-2 part; Synergist 3-5 part; Surplus supplied by vegetable oil.
The granule production stage of this Pesticidal combination is: mixed in proportion with gamma cyhalothrin, wetting agent, dispersant, stabilizing agent, synergist by flonicamid, put into ball mill grinding, send in mixer for well-distribution and carry out homogeneous granulation, obtain the granule product of this insecticide mixtures.
8, described Pesticidal combination is microcapsule formulations, and the mass fraction of component is:
Flonicamid 10-1 part; Gamma cyhalothrin 1-10 part; Self-control Lauxite 5-20 part; Emulsifier 3-10 part; Dispersant 5-10 part; Antifreezing agent 3-5 part; Thickener 0.1-2 part; Defoamer 0.1-0.8 part; Water supplies surplus.
The microcapsule formulations production stage of this Pesticidal combination is: be first dissolved in cyclohexane by flonicamid and gamma cyhalothrin, and in this solution, add the water of emulsifier, dispersant, antifreezing agent, thickener, defoamer and surplus, make stable emulsion through vigorous stirring.Homemade urea resin prepolymer is added in above-mentioned emulsion and regulates pH value, polymerization reaction take place in acid condition, oil phase substance in emulsion is wrapped up, form microcapsule granule, slow intensification, solidification, temperature controls, 40-50 DEG C of solidification 1 hour, to obtain stable microcapsule formulations.
The above emulsifier is selected from the mixture of any one or more than one arbitrary proportions composition in calcium dodecyl benzene sulfonate, aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene, polyoxyethylene aliphatic alcohol ether.
The above organic solvent is mainly the mixture of one or more arbitrary proportions composition in toluene, dimethylbenzene, methyl alcohol, ethanol pine base oil, dimethyl formamide, cyclohexanol, n-butanol, isopropyl alcohol.
The above dispersant is selected from the one or more mixtures formed with arbitrary proportion in sodium lignin sulfonate, alkylphenol polyoxyethylene, formal sulphate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, aliphatic amine polyoxyethylene ether, glycerine fatty acid APEO.
The above wetting agent is selected from dodecyl sodium nitrate, dodecyl nitrate of lime, Nekal BX, one or more mixtures formed with any ratio in alkylbenzenesulfonate polyoxyethylene phosphate, wetting and penetrating agent F.
The above thickener is selected from the mixture of in xanthans, aluminium-magnesium silicate, carboxymethyl cellulose, hydroxyethylcellulose, acid polyethylene a kind of two kinds.
The above disintegrant be selected from uric acid, ammonium sulfate, sodium sulphate, sodium chloride one or both.
The above stabilizing agent is mainly sodium citrate, resorcinol, black network tropine, selects wherein a kind of according to the stability of the former medicine of difference.
The above antifreezing agent is selected from one or both mixture of ethylene glycol, propane diols, glycerine.
The above defoamer mainly select in n-octyl alcohol, methyl-silicone oil, silicone compound one or both.
The above filler be selected from kaolin, diatomite, white carbon, concave convex rod, lightweight calcium phosphate one or both.
Above the present invention is effectively to become flonicamid and high-efficient lambda-cyhalothrin compound has notable synergistic effect, and expand insecticidal spectrum, sucking pest can not only be prevented and treated as insects such as trialeurodes vaporariorum, aphid, pear sucker, thrips, also have good control efficiency to coleoptera, lepidoptera pest.
Embodiment
For making technical scheme of the present invention, object, advantage clearly understand, the mode that effect of the present invention takes indoor biometrics and field control effectiveness test to combine is illustrated.
Specific embodiment 1:
Flonicamid and the indoor independent determination test of gamma cyhalothrin different ratio
1.1 reagent agents: the former medicine of 95% flonicamid, the former medicine of 99% gamma cyhalothrin
1.2 test targets:
Beet armyworm: indoor 5 generations of raising continuously, the third-instar larvae of the susceptibility beet armyworm that its Individual Size is consistent with physiological status, temperature 25 ± 2 DEG C, relative moisture 65 ± 5%.
1.3 experimental procedures:
1.3.1 medicament preparation
First use the former medicine of acetone solution, appropriate two former medicines are made into several different ratio by the result according to preliminary experiment, then it is stand-by with acetone, each process to be diluted to several concentration gradients respectively.
1.3.2 chemicals treatment
The drop method adopting NY/T1 154.1-2006 to recommend measures.By micro intravenous drip device solvent clean, regulate dropper to stand-by state.The examination worm CO of neat and consistent is chosen with writing brush
2mild paralysis is placed in 9cm culture dish, then with micro intravenous drip device, medicament is dripped to the belly of polypide by head, every some drops physic liquor 0.1L, the process of the corresponding acetone contained with drop 0.1L is contrast, examination worm after drop is moved to (25 ± 2) DEG C, normally cultivates in the culture dish of relative moisture 75%.Often process and repeat for 4 times, often repeat 20 examination worms.
1.4 control time
After process, 24h investigation examination worm death condition (judging that examination worm death standard gently stings without autonomic response with pin), records total borer population and dead borer population.
1.5 data statistics and analysis
According to investigation statistics, calculate the corrected mortality of each process.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1 154.7--2006.If contrast lethality < 5%, does not correct, contrast lethality, between 5%-20%, corrects by formula 2, and contrast lethality > 20%, test need be reformed.
Be independent variable X with the logarithm value of drug concentration (mg/L), with the probability value of corrected mortality for dependent variable y, set up virulence regression equation formula respectively, adopt DPS software to calculate the LC of single dose and each proportioning mixture
50calculate according to the abundant method of Sun Yun and spend coefficient (CTC) together.Spend coefficient CTC together, computing formula is as follows: (take emamectin benzoate as standard agent, its toxicity index is 100):
The EC of toxicity index (the TI)=emamectin benzoate of flonicamid
50the EC of/flonicamid
50× 100
The EC of true toxicity index (the ATI)=emamectin benzoate of M
50the EC of/M
50× 100
TI × P flonicamid of TI × P emamectin benzoate+flonicamid of theoretical toxicity index (the TTI)=emamectin benzoate of M
TTI × 100 of the ATI/M of co-toxicity coefficient (the CTC)=M of M
In formula:
M is the mixture of emamectin benzoate and flonicamid different ratio
P emamectin benzoate is the ratio of emamectin benzoate shared by mixture
P flonicamid is the ratio of flonicamid shared by mixture.
1.6 indoor measurement results:
Table 1 flonicamid and gamma cyhalothrin are to beet armyworm indoor measurement result
As can be seen from the table, effectively form flonicamid: when gamma cyhalothrin ratio is 1: 30 ~ 30: 1, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect.Result of the test shows, flonicamid: when gamma cyhalothrin is 1: 10 ~ 10: 1, and synergistic effect is more obvious.This ratio mixture preparation is recommended to carry out field efficacy popularization.
Specific embodiment 2: the test of field trial control Laphygma exigua Hubner, cotton aphid, capsicum thrips
2.1 field control Laphygma exigua Hubner tests
2.1.1 test medicine: flonicamid: gamma cyhalothrin aqueous emulsion
2.1.2 test method: test and carry out at Sanya, Hainan suburban area truck garden, spray by every mu of amount of design, spraying period is the 1-2 instar larvae phase at Laphygma exigua Hubner
2.1.3 investigation method:
Diagonal 5 sampling is pressed, often some wild cabbage 2-3 strain (depending on insect density) choosing Beet Armyworm Eggs and larva in dispenser Qian Mei community.Beet exigua larvae head number in probability demarcation strain, in this, as insect population radix before dispenser.Within the 7th day, 14 days, 21 days after dispenser, investigate the beet exigua larvae number determining residual survival in strain respectively.To correct Revision insect recluced rate as control efficiency.
2.1.4 drug effect computational methods:
Revision insect recluced rate (%)=(after medicine prelarva number-medicine larva number)/medicine prelarva number × 100
Preventive effect (%)=(treatment region Revision insect recluced rate-contrast Revision insect recluced rate)/(100-check plot Revision insect recluced rate) × 100
2.1.5 poisoning investigation method
Within 7 days, observe wild cabbage growing state after administration, estimate medicament to wild cabbage without poisoning.
2.1.6 Laphygma exigua Hubner field control effectiveness test result is prevented and treated
Table 2 field control Laphygma exigua Hubner test of pesticide effectiveness result
As can be seen from Table 2, flonicamid and gamma cyhalothrin with 2: 1 ratio mixture, field experiment is carried out by different amounts, the effect of its control beet armyworm is all better than single dose, effectively can control the harm of Laphygma exigua Hubner to host vegetables, be that dosage is few, instant effect, lasting period is long, has stronger application value.
2.2 field control cotton aphid tests
2.2.1 test medicine: flonicamid and gamma cyhalothrin suspending agent
2.2.2 test method: test and carry out at suburb, Nantong Cotton Fields, soil is clay, middle fertility, water and fertilizer management uniformity, and cotton variety is transgenic cotton against pests Lumianyan 15.
2.2.3 investigation method:
The sampling of 5, laboratory's inner opposite angle line, fixes 4 strains at often, and 3, upper, middle and lower leaf is fixed in every strain, fixes investigation 20 strain 60 leaves altogether, and after medicine * and dispenser, the remaining borer population of living of 7d, 14d, 21d investigation, calculates Revision insect recluced rate and control efficiency.
2.2.4 drug effect computational methods:
Revision insect recluced rate (%)=(after medicine prelarva number-medicine larva number)/medicine prelarva number × 100
Preventive effect (%)=(treatment region Revision insect recluced rate-contrast Revision insect recluced rate)/(100-check plot Revision insect recluced rate) × 100
2.2.5 poisoning investigation method
Within 7 days, observe cotton growth situation after administration, estimate medicament to cotton without poisoning.
2.2.6 control cotton aphid field test results
Table 3 field control cotton aphid test of pesticide effectiveness result
As can be seen from Table 3, flonicamid and gamma cyhalothrin with 2: 1 ratio mixture, carry out field experiment by different amounts, drug effect is a little more than arbitrary single dose, and this is mainly because gamma cyhalothrin is mainly a little to coleoptera, lepidoptera pest better effects if, and flonicamid is better to sucking pest control efficiency, Aphis sucking pest, but general effect is still good, especially increases efficiency time, control efficiency, close to 90%, has wide market prospects.
2.3 field control capsicum thrips tests
2.3.1 test medicine: flonicamid and gamma cyhalothrin suspending agent
2.3.2 test method: test at Xianyang city Jingyang County vegetable field, is just locating thrips and is containing the phase of sending out during test, adopt WF-16 type knapsack hand sprayer spraying agent, dispenser is carried out at fine day, and temperature is at 15.6-25.4 DEG C.
2.3.3 investigation method:
Investigation insect population radix before dispenser, the sampling of 5, every experimental plot, the total head number of interior thrips is spent, 3d, 7d, 10d after same method dispenser in often 10, random searching plant middle and upper part, checks remaining borer population of living, calculates Revision insect recluced rate and control efficiency.
2.3.4 drug effect computational methods:
Revision insect recluced rate (%)=(after medicine prelarva number-medicine larva number)/medicine prelarva number × 100
Preventive effect (%)=(treatment region Revision insect recluced rate-contrast Revision insect recluced rate)/(100-check plot Revision insect recluced rate) × 100
2.3.5 poisoning investigation method
Within 7 days, observe chili growth situation after administration, range estimation capsicum grows fine, without poisoning.
2.3.6 the result of the test of field control capsicum thrips
The field test results of capsicum thrips prevented and treated by table 4
As can be seen from Table 4, flonicamid and gamma cyhalothrin, with the ratio mixture of 3: 1, carry out field experiment by different amounts, after dispenser, single dose test is better than to the control efficiency of thrips, and it is few to have dosage, the advantage that control efficiency is good, has application value.
Comprehensive indoor biometrics result of the test and three field efficacy results, Pesticidal combination containing flonicamid and gamma cyhalothrin of the present invention shows good control efficiency to beet armyworm, cotton aphid, capsicum thrips insect, compared with single dose, there is single dose dosage reduce, good drug efficacy, lasting period is long, and broadening advantage is composed in pest control.
Claims (5)
1. one kind contains the Pesticidal combination of flonicamid and gamma cyhalothrin, it is characterized in that, the effective ingredient of this Pesticidal combination is flonicamid and gamma cyhalothrin binary built, and wherein the mass ratio of flonicamid and gamma cyhalothrin is 30-1: 1-30.
2. Pesticidal combination according to claim 1, is characterized in that: flonicamid is 10-1: 1-10 with the preferred mass ratio of gamma cyhalothrin.
3. Pesticidal combination according to claim 1, is characterized in that: effective ingredient flonicamid and gamma cyhalothrin gross mass in the formulation accounts for the 5%-50% of the whole quality of the pharmaceutical preparations, and all the other are the auxiliary ingredients allowing in agricultural chemicals to use and accept.
4. Pesticidal combination according to claim 1, is characterized in that: the formulation of this Pesticidal combination is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations.
5. Pesticidal combination according to claim 1, is characterized in that: Pesticidal combination is applied on water prevention rice borer, cabbage caterpillar, beet armyworm, also for preventing and treating sucking pest, as trialeurodes vaporariorum, aphid, pear sucker, leafhopper, thrips.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410850035.4A CN104522041A (en) | 2014-12-23 | 2014-12-23 | Flonicamid and efficient cyhalothrin containing insecticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410850035.4A CN104522041A (en) | 2014-12-23 | 2014-12-23 | Flonicamid and efficient cyhalothrin containing insecticide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104522041A true CN104522041A (en) | 2015-04-22 |
Family
ID=52837821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410850035.4A Pending CN104522041A (en) | 2014-12-23 | 2014-12-23 | Flonicamid and efficient cyhalothrin containing insecticide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104522041A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113826627A (en) * | 2020-06-23 | 2021-12-24 | 江苏功成生物科技有限公司 | Insecticidal composition containing flonicamid and pyrethroids and application |
| WO2022034559A1 (en) * | 2020-08-14 | 2022-02-17 | Upl Limited | A storage stable insecticidal composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1947514A (en) * | 2006-11-05 | 2007-04-18 | 深圳诺普信农化股份有限公司 | Pesticide of synergistic effect contg. fipronil and cyfluthrin |
| CN101700036A (en) * | 2009-08-01 | 2010-05-05 | 深圳诺普信农化股份有限公司 | Pesticide composition and application thereof |
| CN103053604A (en) * | 2011-10-20 | 2013-04-24 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing flonicamid and silafluofen and application thereof |
-
2014
- 2014-12-23 CN CN201410850035.4A patent/CN104522041A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1947514A (en) * | 2006-11-05 | 2007-04-18 | 深圳诺普信农化股份有限公司 | Pesticide of synergistic effect contg. fipronil and cyfluthrin |
| CN101700036A (en) * | 2009-08-01 | 2010-05-05 | 深圳诺普信农化股份有限公司 | Pesticide composition and application thereof |
| CN103053604A (en) * | 2011-10-20 | 2013-04-24 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing flonicamid and silafluofen and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113826627A (en) * | 2020-06-23 | 2021-12-24 | 江苏功成生物科技有限公司 | Insecticidal composition containing flonicamid and pyrethroids and application |
| WO2022034559A1 (en) * | 2020-08-14 | 2022-02-17 | Upl Limited | A storage stable insecticidal composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103636661A (en) | Insecticide composition containing bifenthrin and flonicamid | |
| CN103190433A (en) | Pesticide composition with spirotetramat and dinotefuran | |
| CN103271035A (en) | Insecticide composition containing flonicamid and pyriproxyfen | |
| CN102972430A (en) | Insecticidal composition containing thiamethoxam and acetamiprid | |
| CN104054736A (en) | Insecticidal combination containing sulfoxaflor and spirotetramat | |
| CN103355324A (en) | Insecticidal composition containing fipronil and pyriproxyfen | |
| CN103168787A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN104522041A (en) | Flonicamid and efficient cyhalothrin containing insecticide composition | |
| CN102972421B (en) | A kind of Pesticidal combination containing emamectin benzoate and triflumuron | |
| CN103004818A (en) | Insecticide composition containing fipronil and spirotetramat | |
| CN103181388A (en) | Pesticide composition containing pyridalyl and methoxyfenozide | |
| CN103609571A (en) | Emamectin benzoate and abamectin containing pesticidal composition | |
| CN103719139A (en) | Insecticide composition containing dinotefuran and diafenthiuron | |
| CN103190407A (en) | Insecticide composition containing methoxyfenozide and chlorfenapyr | |
| CN103636642A (en) | Insecticide composition containing chlorantraniliprole and bistrifluron | |
| CN103004857B (en) | A kind of Pesticidal combination containing Biphenthrin and chlorfenapyr | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile | |
| CN103503870A (en) | Mite killing composition containing cyflumetofen and chlorfenapyr | |
| CN103202311A (en) | Insecticide composition containing dinotefuran and novaluron | |
| CN107361072A (en) | A kind of Pesticidal combination containing emamectin benzoate and cyflumetofen | |
| CN103719146A (en) | Insecticide composition containing emamectin benzoate and triazophos | |
| CN103190422B (en) | A kind of Pesticidal combination containing methoxyfenozide and Methomyl | |
| CN103598183A (en) | Insecticidal composition containing spinetoram and chlorfenapyr | |
| CN103300030B (en) | A kind of Pesticidal combination containing carbosulfan and chlorfenapyr | |
| CN103609584A (en) | Insecticidal composition containing thiacloprid and flonicamid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |
|
| RJ01 | Rejection of invention patent application after publication |