CN102972413A - Pyridalyl and flutenzine-containing insecticidal compound - Google Patents

Pyridalyl and flutenzine-containing insecticidal compound Download PDF

Info

Publication number
CN102972413A
CN102972413A CN2012105179413A CN201210517941A CN102972413A CN 102972413 A CN102972413 A CN 102972413A CN 2012105179413 A CN2012105179413 A CN 2012105179413A CN 201210517941 A CN201210517941 A CN 201210517941A CN 102972413 A CN102972413 A CN 102972413A
Authority
CN
China
Prior art keywords
pyridalyl
flutenzine
fluorine mite
mite piperazine
pesticidal combination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012105179413A
Other languages
Chinese (zh)
Inventor
葛大鹏
韩先正
杨波涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hailir Pesticides and Chemicals Group Co Ltd
Original Assignee
Hailir Pesticides and Chemicals Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hailir Pesticides and Chemicals Group Co Ltd filed Critical Hailir Pesticides and Chemicals Group Co Ltd
Priority to CN2012105179413A priority Critical patent/CN102972413A/en
Publication of CN102972413A publication Critical patent/CN102972413A/en
Pending legal-status Critical Current

Links

Abstract

The invention relates to a pyridalyl and flutenzine-containing insecticidal compound. The compound comprises a dual compound of active ingredients of pyridalyl and flutenzine, and the balance of auxiliary ingredients. The mass ratio of the pyridalyl to the flutenzine is (5-40):(40-5), and the total mass of the active ingredients of the pyridalyl and the flutenzine in the preparation accounts for 1%-80% of the total mass of the preparation. The insecticidal compound can be produced into pesticide formulations of emulsifiable concentrate, suspending agent, wettable powder, water dispersible granule, emulsion in water and microemulsion; and the insecticidal compound is mainly used for preventing panonychus citri mcgregor, phyllocoptruta oleivora ashmead, polyphagotarsonemus latus, tetranychus cinabarinus boisdu and tetranychus urticae, and also has a good prevention and treating effect on lepidoptera pests and thrips.

Description

A kind of Pesticidal combination that contains pyridalyl and fluorine mite piperazine
Technical field
The present invention relates to the agriculture chemical compounding technical field, particularly relate to a kind of Pesticidal combination that contains pyridalyl and fluorine mite piperazine.
Background technology
Pyridalyl (pyridalyl) is the insecticide that the sumitomo chemical company of Tokyo has, pyridalyl has stomach toxicity and action of contace poison simultaneously, lepidoptera pest is had to good control efficiency, in addition thrips is also had to certain activity, to the thrips natural enemies security, integrated control effect is preferably arranged.Pyridalyl chemistry 2-[3-[2 by name, the chloro-4-[(3 of 6-bis-, the chloro-2-acrylic of 3-bis-) the oxygen base] phenoxy group] propoxyl group]-5-(trifluoromethyl) pyrimidine, its chemical structural formula is
Figure 858273DEST_PATH_IMAGE001
.
Fluorine mite piperazine is named again the fluorine mite, has stronger action of contace poison, and ovum children is double kills, kills that the mite spectrum is wide, strong adaptability, lasting period length, low toxicity, low-residual, safety are good.Fluorine mite piperazine all has fine preventive effect to evil mites such as panonychus citri, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticaes, and the mite evil that can be used for the solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.In addition, fluorine mite piperazine has the well double effect of controlling to insects such as pear sucker, oystershell scale and leafhopper classes.The chemistry of fluorine mite piperazine is called the 3-(2-fluorophenyl)-6-(2, the 6-difluorophenyl)-1,2,4, the 5-tetrazine.
In the real process of agricultural production, using chemical agent is the most effectively means of control plant pest, but the problem the most easily produced by the chemical control insect is the generation of pest resistance to insecticide.And long-term use single chemical insecticide continuously high dose, easily cause the series of problems such as residual, environmental pollution of medicament.Reasonably chemical insecticide is composite or be mixed and have the expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay pest resistance and the positive characteristics such as drug-fast generation and development, pesticide compositional or to be mixed be one of the effective method the most addressed the above problem.We filter out pyridalyl and fluorine mite piperazine is composite on the basis of lab screening and field trial, have obvious synergistic effect.And there is no at present the people about pyridalyl and the composite Pesticidal combination of fluorine mite piperazine and application reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective agricultural insecticide composition.Be mainly used in preventing and treating panonychus citri, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae, lepidoptera pest, thrips are also had to control efficiency preferably.
Technical scheme of the present invention realizes by following measures:
A kind of Pesticidal combination that contains pyridalyl and fluorine mite piperazine, in this Pesticidal combination, the mass ratio of active ingredient pyridalyl and fluorine mite piperazine is 5~40: 40~5, described Pesticidal combination of the present invention is through the toxicity test experimental verification, the mass ratio of pyridalyl and fluorine mite piperazine is 5~40: 40~5 o'clock, synergistic effect was better.
The formulations of pesticide that described Pesticidal combination of the present invention can be prepared are the formulations such as missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Pyridalyl and the gross mass of fluorine mite piperazine in preparation account for 1%~80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 5%-50%, and toxicity and the residual balance preferably that reaches, cost is also lower.
The specific embodiments of the formulations of pesticide that Pesticidal combination of the present invention is mixed with is as follows:
Described Pesticidal combination is cream preparation, and the mass fraction of component is: 1~40 part of pyridalyl; 1~40 part of fluorine mite piperazine; 10~30 parts of conventional emulsifiers; 20~50 parts of conventional solvents; 1~5 part of conventional synergist.The concrete production stage of this cream preparation adds emulsifier, the synergist rear oily liquids that becomes transparent and homogeneous that stirs again for first active ingredient pyridalyl and methoxyfenozide being added in solvent after dissolving fully, filling, can be made into the cream preparation of the present composition.
Described Pesticidal combination is suspending agent, and the mass fraction of component is: 1~40 part of pyridalyl; 1~40 part of fluorine mite piperazine; 5~20 parts of dispersants; 1~5 part of antifreezing agent; 0.1~2 part of thickener; 0.1~0.8 part of defoamer; 0~10 part of penetrating agent; 0.1~5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, mix through high speed shear, add active ingredient pyridalyl and methoxyfenozide, in ball crusher, abrading-ball is 2~3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described Pesticidal combination is wetting powder, and the mass fraction of component is: 1~40 part of pyridalyl; 1~40 part of fluorine mite piperazine; 3~10 parts of dispersants; 1~5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: press above-mentioned formula by active ingredient pyridalyl and methoxyfenozide and dispersant, wetting agent and filler mixing, uniform stirring in stirred tank, mixing after airslide disintegrating mill, can be made into the wetting powder of the present composition.
Described Pesticidal combination is water dispersible granules, and the mass fraction of component is: 1~40 part of pyridalyl; 1~40 part of fluorine mite piperazine; 3~10 parts of dispersants; 1~10 part of wetting agent; 1~5 part of disintegrant; The filler surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, active ingredient pyridalyl and methoxyfenozide and dispersant, wetting agent, disintegrant and filler are mixed, with micro jet, pulverize, through mediating, then add in the fluidized bed prilling dryer and carry out granulation, drying, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described Pesticidal combination is aqueous emulsion, and the mass fraction of component is: 1~40 part of pyridalyl; 1~40 part of fluorine mite piperazine; 3~30 parts of emulsifier; 5~15 parts of solvents; 2~15 parts of stabilizing agents; 1~5 part of antifreezing agent; 0.1~8 part of defoamer; 0.2~2 part of thickener; Water surplus.The concrete production stage of this aqueous emulsion is: at first pyridalyl and methoxyfenozide, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added to water, slowly add water until reach the phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described Pesticidal combination is microemulsion, and the mass fraction of component is: 1~40 part of pyridalyl, 1~40 part of fluorine mite piperazine, 10~30 parts of emulsifier, 1~8 part of antifreezing agent, 0.5~10 part of stabilizing agent, 20~50 parts of conventional solvent cosolvents.Pyridalyl and methoxyfenozide are dissolved fully with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, the alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, and diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in the water equal solvent are arbitrarily than the mixture formed.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, the alkylsulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in the fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in the soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C 10-20the saturated fat acid compounds, C 8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention be take the compounded pesticides that pyridalyl and fluorine mite piperazine be active ingredient and is had obvious synergistic effect, delay the drug-fast generation in key, and reduced one-tenth and produced cost and use cost, can be used for the improvement of resistance disease, be mainly used in preventing and treating panonychus citri, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae, lepidoptera pest, thrips are also had to control efficiency preferably.
Embodiment
For making technical scheme of the present invention, purpose and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment: pyridalyl proportioning co-toxicity experiments different from fluorine mite piperazine.
1.1 reagent agent
The former medicine of 98% pyridalyl, the former medicine of 97% fluorine mite piperazine, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test target
The examination mite is picked up from the Citrus Research Institute Of Chinese Academy Of Agricultural Sciences test site, and the cultivation management term harmonization, do not use medicament in the recent period, adopts the blade that rewinds citrus red mite (crm), standby after normal temperature laboratory (25 ℃ of left and right) raised for 2 generations by fresh citrus leaves down.
1.3 single dose assay method
The slide infusion process:
The female mite that Individual Size is consistent, body colour is scarlet if choose, to try the mite back side with writing brush sticks on the slide that posts cloth insertion sheet, every slide dilution intervals, on the basis of prerun, respectively two kinds of former medicines are dissolved in to acetone, be diluted to 5 concentration gradient liquids with the 0.1% Tween 80 aqueous solution again, be placed in beaker standby.The concentration gradient of 5 pyridalyls and fluorine mite piperazine is respectively 6:33,12:27,18:21,24:15,30:9.
The glutinous slide that the examination mite arranged is immersed in good liquid 5 seconds, each processes four repetitions, after taking-up tiltedly is put in porcelain dish edge drying, be put in Glass carrier box, do not add a cover the illumination box of putting into (25 ± 1) ℃, humidity 70%~80%, illumination every day 10 hours, microscopy life or death mite number (with its foot of fine, soft fur style of writing, the nonresponder is dead) after 24 hours.
1.4 data statistics and analysis
According to investigation statistics, calculate the corrected mortality that each is processed.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1 154.7-2006.If contrast lethality<5%, do not proofread and correct, the contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, the contrast lethality > 20%, test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probability value of corrected mortality of take is dependent variable y, sets up respectively the virulence regression equation formula, adopts DPS software to calculate the LC of single dose and each proportioning mixture 50calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take pyridalyl as the standard medicament, its toxicity index is 100):
The LC of the toxicity index (TI) of fluorine mite piperazine=pyridalyl 50the LC of/fluorine mite piperazine 50* 100
The LC of the true toxicity index (ATI) of M=pyridalyl 50the LC of/M 50* 100
The TI of the TI of the theoretical toxicity index (TTI) of M=pyridalyl * P pyridalyl+fluorine mite piperazine * P fluorine mite piperazine
The TTI of the ATI/M of the co-toxicity coefficient of M (CTC)=M * 100
In formula:
M is pyridalyl and the mixture of the different proportionings of fluorine mite piperazine
The P pyridalyl is pyridalyl shared ratio in mixture
P fluorine mite piperazine is fluorine mite piperazine shared ratio in mixture.
2.1 toxicity test result
Table 1 pyridalyl, the fluorine mite piperazine indoor measurement result to citrus red mite (crm)
As can be seen from the table, in different proportionings, its co-toxicity coefficient all is greater than 120, shows certain synergistic effect, wherein pyridalyl: the synergistic effect that fluorine mite piperazine is 18:21 is the most obvious, and co-toxicity coefficient is 177.81.Result of the test shows, under indoor conditions, the Compositional acaricide of pyridalyl and fluorine mite piperazine all has higher activity to citrus red mite (crm), suggestion is carried out further field control effectiveness test to suitable proportion 18:21 left and right mixture preparation, to estimate its field practical application effect.
3 field experiments are surveyed panonychus citri, the experimental result of beet armyworm
3.1 field experiment control panonychus citri
3.1.1 application method
The panonychus citri experimental establishment is carried out at Zhijiang City, Hubei Province precious jade China citrus orchard.Citrus Cultivars is Wenzhou aspermous orange, and surrounding is all planted oranges and tangerines.For growing fine before the medication of examination oranges and tangerines.Carry out the complete stool spraying and process, the community spouting liquid is used by 675 liters/hectare, only sprays medicine one time.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out the routine spraying, makes every effort to evenly thoughtful during the spray medicine.
3.1.2 investigation method
Each community is at East, West, South, North, the tender tip of middle five positions mark of every strain tree, investigate altogether 25 movable mite quantity on leaf, hand magnifier is directly observed blade face, investigation mite mouth radix before medicine, for the first time 7d after medicine, 7d, 14d investigate respectively the remaining mite number alive in each community after medicine for the second time, calculate mite mouth decline rate, and contrast decline rate relatively, the calculating relative control effect.
3.1.3 drug effect computational methods
Mite number * 100 before decline rate (%)=(mite number after the front several dispensers of mite of dispenser)/dispenser
Proofread and correct decline rate or preventive effect (%)=(treatment region mite mouth decline rate-check plot mite mouth decline rate)/(1-check plot mite mouth decline rate) * 100.
3.1.4 poisoning investigation method
After dispenser, whether continuous 7d range estimation medicament has poisoning to crop.
3.2 field control effectiveness test result of the test
Table 2 treatment agent control citrus red mite (crm) field control effectiveness test result
As can be seen from Table 2, the Mixed Pharmacy of different proportion, carry out field experiment by different consumptions, after medicine, each investigation all shows its control efficiency to panonychus citri and all is better than contrasting medicament, 39% pyridalyl fluorine mite piperazine obviously is better than 3 contrast medicaments to the control efficiency of panonychus citri so that the 18:21 ratio is composite after dispenser, according to the observation to field experiment process whole process, in the test dose scope, mandarin tree grows fine, the poisoning phenomenon does not all appear in each treatment agent, illustrates that it is safe to oranges and tangerines.
4.1 field trial control beet armyworm
4.1.1 test method
Test is carried out at Kaiping City, Guangdong Province suburb truck garden.Process design concentration by each and carry out routine to water spray.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out the routine spraying, makes every effort to evenly thoughtful during the spray medicine.During dispenser, the field beet armyworm is 1~2 instar larvae peak period.
Duration of test weather is good, and daily mean temperature is 17.8~26.4 ℃.Dispenser same day is without rain.
3.1.2 investigation method
In dispenser Qian Mei community by 5 samplings of diagonal. every wild cabbage 2~3 strains (depending on insect density) of choosing Beet Armyworm Eggs and larva.Statistics is demarcated beet exigua larvae head number in strain. using this as dispenser before the insect population radix.After dispenser the 7th, 14,21d investigates respectively the beet exigua larvae number of determining residual survival in strain. and using and proofread and correct the insect population decline rate as control efficiency.
4.1.3 drug effect computational methods
Insect population decline rate (%)=(larva number after medicine prelarva number-medicine)/medicine prelarva number * 100
Preventive effect (%)=(treatment region insect population decline rate-contrast insect population decline rate)/(100-check plot insect population decline rate) * 100.
4.1.4 poisoning investigation method
Within 7,14,21 days after medicine, observe the wild cabbage growing state, the range estimation medicament to wild cabbage without poisoning.
4.1.5 field control effectiveness test result
The Mixed Pharmacy of different proportion, tested by different consumptions as can be seen from Table 2, and after medicine, its control to beet armyworm all is better than contrasting medicament.With 18:21 ratio compound insecticidal effect, the increase with dosage increases progressively 39% pyridalyl fluorine mite piperazine.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in each treatment agent, illustrates that it is safe to wild cabbage.Advise that the insecticide different from the mechanism of action mixes use to delay the generation of pest resistance to insecticide.
Above twice field experiment result is described; the Pesticidal combination that the present invention contains pyridalyl and fluorine mite piperazine shows good control efficiency to insects such as panonychus citri, beet armyworms; to the target crop safety; with single dose, compare; it is few that insecticide acaricide composition of the present invention has dosage; the advantage that pest resistance to insecticide produces is grown, delayed to instant effect, lasting period; so; research and development of the present invention and promote the raising to the fruit quality in vast fruit tree producing region, the orchard worker get rich and the protection tool of local environment is of great significance.

Claims (4)

1. a Pesticidal combination that contains pyridalyl and fluorine mite piperazine, it is characterized in that: the active ingredient of this Pesticidal combination is pyridalyl and fluorine mite piperazine binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient pyridalyl and fluorine mite piperazine is 5~40: 40~5.
2. Pesticidal combination according to claim 1, it is characterized in that: pyridalyl and the gross weight of fluorine mite piperazine in preparation account for 1%~80% of the whole quality of the pharmaceutical preparations.
3. Pesticidal combination according to claim 2, it is characterized in that: pyridalyl and the gross weight of fluorine mite piperazine in preparation account for 5%~50% of the whole quality of the pharmaceutical preparations.
4. according to claim 1 or 2 or 3 described Pesticidal combinations, it is characterized in that: the formulations of pesticide that this Pesticidal combination can be mixed with are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion .
CN2012105179413A 2012-12-06 2012-12-06 Pyridalyl and flutenzine-containing insecticidal compound Pending CN102972413A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012105179413A CN102972413A (en) 2012-12-06 2012-12-06 Pyridalyl and flutenzine-containing insecticidal compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012105179413A CN102972413A (en) 2012-12-06 2012-12-06 Pyridalyl and flutenzine-containing insecticidal compound

Publications (1)

Publication Number Publication Date
CN102972413A true CN102972413A (en) 2013-03-20

Family

ID=47846988

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012105179413A Pending CN102972413A (en) 2012-12-06 2012-12-06 Pyridalyl and flutenzine-containing insecticidal compound

Country Status (1)

Country Link
CN (1) CN102972413A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105475294A (en) * 2015-12-19 2016-04-13 青岛奥迪斯生物科技有限公司 Insecticidal composition containing flutenzine and semiamitraz
CN105532678A (en) * 2015-12-19 2016-05-04 青岛奥迪斯生物科技有限公司 Flutenzine-and-chlorfenapyr-containing acaricidal composition
CN111937888A (en) * 2020-08-21 2020-11-17 青岛瀚生生物科技股份有限公司 Insecticidal composition and application thereof
CN114041466A (en) * 2021-12-09 2022-02-15 中国农业科学院棉花研究所 Insecticidal composition and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007085565A1 (en) * 2006-01-26 2007-08-02 Basf Se Methods to use 3-pyridyl derivatives as pesticides
CN101664032A (en) * 2009-09-08 2010-03-10 深圳诺普信农化股份有限公司 Pesticide combination

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007085565A1 (en) * 2006-01-26 2007-08-02 Basf Se Methods to use 3-pyridyl derivatives as pesticides
CN101664032A (en) * 2009-09-08 2010-03-10 深圳诺普信农化股份有限公司 Pesticide combination

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
倪珏萍: "2000年后杀虫杀螨剂研发进展", 《农药研究与应用》 *
杨吉春 等: "含氟农药开发的新进展", 《农药》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105475294A (en) * 2015-12-19 2016-04-13 青岛奥迪斯生物科技有限公司 Insecticidal composition containing flutenzine and semiamitraz
CN105532678A (en) * 2015-12-19 2016-05-04 青岛奥迪斯生物科技有限公司 Flutenzine-and-chlorfenapyr-containing acaricidal composition
CN111937888A (en) * 2020-08-21 2020-11-17 青岛瀚生生物科技股份有限公司 Insecticidal composition and application thereof
CN114041466A (en) * 2021-12-09 2022-02-15 中国农业科学院棉花研究所 Insecticidal composition and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN103636661A (en) Insecticide composition containing bifenthrin and flonicamid
CN102986700A (en) Insecticide composition containing flutenzine and bistrifluron
CN102972413A (en) Pyridalyl and flutenzine-containing insecticidal compound
CN103271035A (en) Insecticide composition containing flonicamid and pyriproxyfen
CN102960353A (en) Insecticidal and acaricidal composition containing metaflumizone and flufenzine
CN102986696A (en) Acaricidal composition containing fluacrypyrim and bifenazate
CN102428922A (en) Diacylhydrazine pesticide compounded pesticidal composition
CN103181388A (en) Pesticide composition containing pyridalyl and methoxyfenozide
CN102960356A (en) Parasiticide composite containing bistrifluron and methoxyfenozide
CN103004818A (en) Insecticide composition containing fipronil and spirotetramat
CN102972416B (en) A kind of miticide composition containing fluacrypyrim and spiral shell mite ester
CN103039467A (en) Insecticidal composition containing flufenzine and spirotetramat
CN103355335A (en) Acaricide composition containing cyflumetofen and diafenthiuron
CN103503870A (en) Mite killing composition containing cyflumetofen and chlorfenapyr
CN103120165A (en) Insecticidal composition containing spinetoram and cyantraniliprole
CN103636642A (en) Insecticide composition containing chlorantraniliprole and bistrifluron
CN103609571A (en) Emamectin benzoate and abamectin containing pesticidal composition
CN103416409A (en) Disinsection composition containing flutenzine and methoxyfenozide
CN103202311A (en) Insecticide composition containing dinotefuran and novaluron
CN102369941B (en) Insecticidal and acaricidal composition containing bifenazate and chlorfenapyr
CN109392928A (en) A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile
CN107361072A (en) A kind of Pesticidal combination containing emamectin benzoate and cyflumetofen
CN102972404A (en) Pesticidal composition containing fluacrypyrim and cyflumetofen
CN103125495A (en) Mite-killing composition containing pyrimidifen and pyridaben
CN103355329A (en) Acaricide composition containing cyflumetofen and spirotetramat

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20130320