CN102972416B - A kind of miticide composition containing fluacrypyrim and spiral shell mite ester - Google Patents
A kind of miticide composition containing fluacrypyrim and spiral shell mite ester Download PDFInfo
- Publication number
- CN102972416B CN102972416B CN201210565011.5A CN201210565011A CN102972416B CN 102972416 B CN102972416 B CN 102972416B CN 201210565011 A CN201210565011 A CN 201210565011A CN 102972416 B CN102972416 B CN 102972416B
- Authority
- CN
- China
- Prior art keywords
- spiral shell
- fluacrypyrim
- mite
- mite ester
- shell mite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The present invention relates to a kind of miticide composition containing fluacrypyrim and spiral shell mite ester, its active ingredient is fluacrypyrim and spiral shell mite ester binary built, and all the other are auxiliary element.The mass ratio of fluacrypyrim and spiral shell mite ester is 21:33; 24:30; 27:27; 30:24; 33:21, in preparation, the gross mass of active ingredient fluacrypyrim and spiral shell mite ester accounts for 1% ~ 80% of whole preparation gross mass, and the formulations of pesticide that compound pesticide composition of the present invention can be made are for becoming missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.The insects such as main control two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, pear sucker, oystershell scale and leafhopper class, the mite evil for solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomatoes is administered.
Description
Technical field
The present invention relates to technical field of pesticide combination, particularly relate to a kind of miticide composition containing fluacrypyrim and spiral shell mite ester.
Background technology
Fluacrypyrim is first methoxy acrylic miticide that BASF AG develops the exploitation of Japanese Cao Da company.Have and well tag and stomach poison function, to each feature of evil mite, if comprise ovum mite, one-tenth mite all effectively, and quick-acting is good, and the lasting period is long, is mainly used in the multiple harmful mite preventing and treating fruit tree, as the two spotted spider mite of control mandarin tree, apple tree.The chemistry of fluacrypyrim is called methyl (E)-2-{ α-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-phenoxy group]-0-tolyl }-3-methoxy acrylate
,its chemical structural formula is
.
Spiral shell mite ester has the brand-new mechanism of action, and tool action of contace poison does not have interior absorption.The Fatty synthesis of main suppression mite, blocks the energy metabolism of mite, and each developmental stage of mite is all effective, comprises ovum.The spiral shell mite ester lasting period is long, kills that mite spectrum is wide, strong adaptability, low toxicity, low-residual, safety be good, and without cross resistance between existing miticide, be applicable to for the pest mite class of control to existing miticide generation resistance.Spiral shell mite ester all has fine preventive effect to two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae etc., and the mite evil that can be used for the solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.In addition, spiral shell mite ester has insects such as pear sucker, oystershell scale and leafhopper classes and well doublely controls effect.Spiral shell mite esterification formal name used at school 3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro [4, the 5]-last of the ten Heavenly stems-3-alkene 4-base-2,2-dimethyl butyrate acid esters.Its chemical structural formula is
。
In the real process of agricultural production, using chemical agent is the most effective means of control plant pest, but is the generation of pest resistance to insecticide by the problem that chemical control insect the most easily produces.And long-term use single chemical insecticide continuously high dose, easily cause the series of problems such as the remaining of medicament, environmental pollution.Composite or the mixture of rational chemical insecticide has expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce and remain, delay positive feature such as pest resistance and drug-fast generation and development etc., the composite or mixture of miticide is one of the effective method the most solved the problem.We are on the basis of lab screening and field trial, filter out fluacrypyrim and spiral shell mite ester is composite, have obvious synergistic effect.And about fourth fluacrypyrim and the composite miticide composition of spiral shell mite ester and apply and there is no people at present and reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective agricultural chemicals miticide composition.The insects such as main control two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, pear sucker, oystershell scale and leafhopper class, the mite evil for solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomatoes is administered.
Technical scheme of the present invention is realized by following measures:
A kind of miticide composition containing fluacrypyrim and spiral shell mite ester, in this miticide composition, the mass ratio of active ingredient fluacrypyrim and spiral shell mite ester is 1 ~ 80: 80 ~ 1, described miticide composition of the present invention is through toxicity test experimental verification, when the mass ratio of fluacrypyrim and spiral shell mite ester is 1 ~ 40: 40 ~ 1, synergistic effect is better.
The formulations of pesticide that compound pesticide composition of the present invention can be mixed with are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Fluacrypyrim and spiral shell mite ester gross mass in the formulation account for the 1%-80% of the whole quality of the pharmaceutical preparations, and when wherein accounting for 5%-60%, toxicity reaches good balance with residual, and cost is also lower.
The specific embodiments of the formulations of pesticide that miticide composition of the present invention is mixed with is as follows:
Described miticide composition is cream preparation, and the mass fraction of component is:
Fluacrypyrim 1 ~ 80 part
Spiral shell mite ester 1 ~ 80 part
Conventional emulsifier 10 ~ 30 parts
Conventional solvents 20 ~ 50 parts
Conventional synergist 1 ~ 5 part.
The concrete production stage of this cream preparation be first active ingredient fluacrypyrim and spiral shell mite ester are added dissolve completely in solvent after add emulsifier again, synergist becomes transparent and homogeneous oily liquids after stirring, filling, namely can be made into the cream preparation of the present composition.
Described miticide composition is suspending agent, and the mass fraction of component is:
Fluacrypyrim 1 ~ 80 part
Spiral shell mite ester 1 ~ 80 part
Dispersant 5 ~ 20 parts
Antifreezing agent 1 ~ 5 part
Thickener 0.1 ~ 2 part
Defoamer 0.1 ~ 0.8 part
Penetrating agent 0 ~ 10 part
PH value regulator 0.1 ~ 5 part
Water surplus.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active ingredient fluacrypyrim and spiral shell mite ester, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, namely can be made into the aqueous suspension formulations of the present composition.
Described miticide composition is wetting powder, and the mass fraction of component is:
Fluacrypyrim 1 ~ 80 part
Spiral shell mite ester 1 ~ 50 part
Dispersant 3 ~ 10 parts
Wetting agent 1 ~ 5 part
Filler surplus.
The concrete production stage of this wetting powder is: mixed with spiral shell mite ester and dispersant, wetting agent and filler by active ingredient fluacrypyrim by above-mentioned formula, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
Described miticide composition is water dispersible granules, and the mass fraction of component is:
Fluacrypyrim 1 ~ 80 part
Spiral shell mite ester 1 ~ 50 part
Dispersant 3 ~ 10 parts
Wetting agent 1 ~ 10 part
Disintegrant 1 ~ 5 part
Filler surplus.
The concrete production stage of this water dispersible granules is: mixed with cyflumetofen and dispersant, wetting agent, disintegrant and filler by active ingredient fluacrypyrim by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and to carry out after granulation, drying, screening, through sample analysis, namely can be made into the water dispersible granules of the present composition.
Described miticide composition is aqueous emulsion, and the mass fraction of component is:
Fluacrypyrim 1 ~ 50 part
Spiral shell mite ester 1 ~ 60 part
Emulsifier 3 ~ 30 parts
Solvent 5 ~ 15 parts
Stabilizing agent 2 ~ 15 parts
Antifreezing agent 1 ~ 5 part
Defoamer 0.1 ~ 8 part
Thickener 0.2 ~ 2 part
Water surplus
The concrete production stage of this aqueous emulsion is: first fluacrypyrim and spiral shell mite ester, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, namely can be made into the aqueous emulsion of the present composition.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any one in polyoxyethylene aliphatic alcohol ether or more than one any mixtures than composition.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), and one or more in water equal solvent are arbitrarily than the mixture of composition.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, the one in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
Active ingredient fluacrypyrim and spiral shell mite ester is composite has notable synergistic effect in composition pesticide of the present invention, can reduce effective ingredient consumption, delay the generation of pest resistance to insecticide, and reduce into product cost and use cost, can be used for the improvement of resistant insect.The insects such as main control two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, pear sucker, oystershell scale and leafhopper class, the mite evil for solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomatoes is administered.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all ratio of quality and the number of copies.
Embodiment: fluacrypyrim and spiral shell mite ester different ratio co-toxicity are tested.
1.1 reagent agent
The former medicine of fluacrypyrim of 98%, the former medicine of spiral shell mite ester of 97%, above-mentioned former medicine provides by research and development department of Qingdao Hailir Pesticides and Chemical Co., Ltd..
1.2 test targets
Examination mite picks up from Citrus Research Institute Of Chinese Academy Of Agricultural Sciences test site, cultivation management is consistent, do not use medicament in the recent period, adopt the blade rewinding citrus red mite (crm), for subsequent use raised for 2 generations by fresh citrus leaves under normal temperature laboratory (about 25 DEG C) after.
1.3 single dose assay method slide infusion processes
The female mite that Individual Size is consistent if choose, body colour is scarlet, with writing brush, the examination mite back side is sticked on the slide posting cloth insertion sheet, often open slide dilution intervals, on the basis of prerun, respectively two kinds of former medicines are dissolved in acetone, be diluted to 5 concentration gradient liquids with the 0.1% Tween 80 aqueous solution again, be placed in beaker for subsequent use.5 concentration gradients are 21:33 respectively; 24:30; 27:27; 30:24; 33:21.
The slide of examination mite is had to immerse in good liquid 5 seconds by glutinous, each process four repetition, take out after being tiltedly put in the drying of porcelain dish edge, be put in Glass carrier box, do not add a cover the illumination box putting into (25 ± 1) DEG C, humidity 7O% ~ 80%, illumination every day 10 hours, microscopy mite number (with its foot of fine, soft fur style of writing, nonresponder is dead) anyway after 24 hours.
1.4 data statistics and analysis
According to investigation statistics, calculate the corrected mortality of each process.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1154.7-2006.If contrast lethality <5%, does not correct, contrast lethality, between 5%-20%, corrects by formula 2, and contrast lethality >20%, test need be reformed.
Be independent variable x with the logarithm value of drug concentration (mg/L), with the probability value of corrected mortality for dependent variable y, set up virulence regression equation formula respectively, adopt DPS software to calculate the LC of single dose and each proportioning mixture
50co-toxicity coefficient (CTC) is calculated according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take fluacrypyrim as standard agent, its toxicity index is 100):
The LC of toxicity index (the TI)=fluacrypyrim of spiral shell mite ester
50the LC of/spiral shell mite ester
50× 100
The LC of true toxicity index (the ATI)=fluacrypyrim of M
50the LC of/M
50× 100
TTI × 100 of the ATI/M of co-toxicity coefficient (the CTC)=M of TI × P spiral shell mite ester M of the TI × P fluacrypyrim+spiral shell mite ester of theoretical toxicity index (the TTI)=fluacrypyrim of M
In formula:
M is the mixture of fluacrypyrim and spiral shell mite ester different ratio
P spiral shell mite ester is the ratio of spiral shell mite ester shared by mixture
P fluacrypyrim is the ratio of fluacrypyrim shared by mixture.
2.1 toxicity test results
Table 1 fluacrypyrim, spiral shell mite ester are to the indoor measurement result of citrus red mite (crm)
As can be seen from the table, in different ratio, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein fluacrypyrim: spiral shell mite ester is that the synergistic effect of 27:27 is the most obvious, and co-toxicity coefficient is 164.35.Result of the test shows, the Compositional acaricide of fluacrypyrim and spiral shell mite ester all has higher activity to citrus red mite (crm) in room conditions, suggestion carries out further field control effectiveness test to suitable proportion about 27:27 mixture preparation, to evaluate its field practical application effect.
3 field experiments survey panonychus citri, the experimental result of European red mite
3.1 field experiment control panonychus citris
3.1.1 application method
Panonychus citri experimental establishment is carried out at Zhijiang City, Hubei Province precious jade China citrus orchard.Citrus Cultivars is Wenzhou aspermous orange, and surrounding all plants oranges and tangerines.Grow fine for before the medication of examination oranges and tangerines.Carry out complete stool spraying process, community spouting liquid is used by 675 liters/hectare, only sprays a medicine.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.
3.1.2 investigation method
East, West, South, North, middle five positions that each community is set in every strain mark the tender tip, investigate the movable mite quantity on 25 leaves altogether, hand magnifier directly observes blade face, mite mouth radix is investigated before medicine, after medicine, 3d, 7d, 14d investigate the remaining mite number alive in each community respectively, calculate mite mouth decline rate, and contrast decline rate and compare, calculating relative control effect.
3.1.3 drug effect computational methods
Mite number × 100 before decline rate (%)=(before dispenser after mite number one dispenser mite number)/dispenser
Correct decline rate or preventive effect (%)=(treatment region mite mouth decline rate-check plot mite mouth decline rate)/(1-check plot mite mouth decline rate) × 100.
3.1.4 poisoning investigation method
Whether after dispenser, continuous 14d estimates medicament has poisoning to crop.
3.2 field control effectiveness test result of the tests
Table 2 treatment agent control citrus red mite (crm) field control effectiveness test result
As can be seen from Table 2, the Mixed Pharmacy of different proportion, field experiment is carried out by different consumptions, after medicine each investigation all show its to the control efficiency of panonychus citri be all better than contrast medicament, 54% fluacrypyrim+spiral shell mite ester SC (27:27) 3 days after administration, 7 days, within 14 days, the control efficiency to panonychus citri is obviously better than 3 contrast medicaments, according to the observation to field experiment process whole process, within the scope of test dose, mandarin tree grows fine, and poisoning phenomenon does not all appear in each treatment agent, illustrates that it is safe to oranges and tangerines.In process of the test, testing crew finds that it all has fine preventive effect to the evil such as oranges and tangerines scale insect and rust mite (blister mite) mite.
4.1 field experiment control European red mites
4.1.1 application method
Experimental establishment is carried out in Liquan apple Zhu Zai district of Xianyang, Shanxi province city, and apple grows fine.Carry out complete stool spraying process, community spouting liquid is used by 675 liters/hectare, only sprays a medicine.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.
4.1.2 investigation method
Carry out insect density investigation respectively at 3d, 7d, 14d before dispenser and after dispenser, 1 branch is respectively selected in the East, West, South, North set in each community 4 directions, and every tip marks 5 blades, the movable mite quantity altogether on investigation records 4 tips 20 blades.
4.1.3 drug effect computational methods
By following formulae discovery Revision insect recluced rate and control efficiency.Mite number × 100 alive before Revision insect recluced rate (%)=(mite number of living after mite number-medicine of living before medicine)/medicine
Preventive effect (%)=(treatment region Revision insect recluced rate-contrast Revision insect recluced rate)/(100-check plot Revision insect recluced rate) × 100.
4.1.4 poisoning investigation method
After medicine 3,7, within 14 days, observe apple development situation, range estimation medicament to apple without poisoning.
4.1.5 field control effectiveness test result
Table 3 is treatment agent control European red mite field test results
As can be seen from Table 3, the Mixed Pharmacy of different proportion, field experiment is carried out by different consumptions, after medicine each investigation all show its to the control efficiency of European red mite be all better than contrast medicament, 54% fluacrypyrim+spiral shell mite ester SC (27:27) 3 days after administration, 7 days, within 14 days, the control efficiency to European red mite is obviously better than 3 contrast medicaments, according to the observation to field experiment process whole process, within the scope of test dose, apple tree grows fine, and poisoning phenomenon does not all appear in each treatment agent, illustrates that it is safe to apple.
Described in above twice field experiment result; the miticide composition that the present invention contains fluacrypyrim and spiral shell mite ester shows good control efficiency to the insect such as panonychus citri, European red mite; to Target crops safety; compared with single dose; it is few that Pesticidal combination of the present invention has dosage; instant effect, lasting period be long, delay the advantage that pest resistance to insecticide produces; so; research and development of the present invention and promote raising to the fruit quality in vast fruit tree producing region, orchard worker get rich and the protection tool of local environment is of great significance.
Claims (4)
1. contain a composition pesticide for fluacrypyrim and spiral shell mite ester, it is characterized in that: the active ingredient of this composition pesticide is fluacrypyrim and spiral shell mite ester binary built, and all the other are auxiliary element, and wherein the mass ratio of active ingredient fluacrypyrim and spiral shell mite ester is 21:33; 24:30; 30:24; 33:21.
2. composition pesticide according to claim 1, is characterized in that: fluacrypyrim and the gross mass of spiral shell mite ester in composition pesticide account for 1% ~ 80% of whole composition pesticide quality.
3. composition pesticide according to claim 2, is characterized in that: fluacrypyrim and the gross mass of spiral shell mite ester in composition pesticide account for 5% ~ 60% of whole composition pesticide quality.
4. the composition pesticide according to claim 1 or 2 or 3, is characterized in that: the formulation of composition pesticide is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565011.5A CN102972416B (en) | 2012-12-24 | 2012-12-24 | A kind of miticide composition containing fluacrypyrim and spiral shell mite ester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565011.5A CN102972416B (en) | 2012-12-24 | 2012-12-24 | A kind of miticide composition containing fluacrypyrim and spiral shell mite ester |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102972416A CN102972416A (en) | 2013-03-20 |
| CN102972416B true CN102972416B (en) | 2016-01-06 |
Family
ID=47846991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210565011.5A Active CN102972416B (en) | 2012-12-24 | 2012-12-24 | A kind of miticide composition containing fluacrypyrim and spiral shell mite ester |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102972416B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103493831B (en) * | 2013-09-16 | 2015-12-02 | 陕西农心作物科技有限公司 | A kind of Pesticidal combination containing phonetic mite amine and tetronic acid insecticides |
| CN105104390B (en) * | 2015-08-19 | 2017-05-03 | 陈强发 | Anti-mite composition containing cycloxaprid and spirodiclofen |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008125362A1 (en) * | 2007-04-17 | 2008-10-23 | Bayer Cropscience Ag | Controlling pests by combining insecticides and transgenic plants by applying directly to leaves and roots |
| CN102458130A (en) * | 2009-05-06 | 2012-05-16 | 巴斯夫欧洲公司 | A method for increasing the vigor and/or crop yield of agricultural plants under essentially non-existent pathogen pressure |
| CN103416408A (en) * | 2012-05-18 | 2013-12-04 | 陕西美邦农药有限公司 | Insecticidal combination containing fluacrypyrim |
-
2012
- 2012-12-24 CN CN201210565011.5A patent/CN102972416B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008125362A1 (en) * | 2007-04-17 | 2008-10-23 | Bayer Cropscience Ag | Controlling pests by combining insecticides and transgenic plants by applying directly to leaves and roots |
| CN102458130A (en) * | 2009-05-06 | 2012-05-16 | 巴斯夫欧洲公司 | A method for increasing the vigor and/or crop yield of agricultural plants under essentially non-existent pathogen pressure |
| CN103416408A (en) * | 2012-05-18 | 2013-12-04 | 陕西美邦农药有限公司 | Insecticidal combination containing fluacrypyrim |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102972416A (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103636661A (en) | Insecticide composition containing bifenthrin and flonicamid | |
| CN102986700A (en) | Insecticide composition containing flutenzine and bistrifluron | |
| CN103271035A (en) | Insecticide composition containing flonicamid and pyriproxyfen | |
| CN102986696A (en) | Acaricidal composition containing fluacrypyrim and bifenazate | |
| CN102960353A (en) | Insecticidal and acaricidal composition containing metaflumizone and flufenzine | |
| CN102972413A (en) | Pyridalyl and flutenzine-containing insecticidal compound | |
| CN102972416B (en) | A kind of miticide composition containing fluacrypyrim and spiral shell mite ester | |
| CN101919389A (en) | Miticide and pesticide composition containing bifenazate and spirotetramat | |
| CN102960356A (en) | Parasiticide composite containing bistrifluron and methoxyfenozide | |
| CN103004818A (en) | Insecticide composition containing fipronil and spirotetramat | |
| CN102204555B (en) | Insecticidal and acaricidal composition containing biopesticide and bifenazate | |
| CN103039467A (en) | Insecticidal composition containing flufenzine and spirotetramat | |
| CN103355335A (en) | Acaricide composition containing cyflumetofen and diafenthiuron | |
| CN103503870A (en) | Mite killing composition containing cyflumetofen and chlorfenapyr | |
| CN102369941B (en) | Insecticidal and acaricidal composition containing bifenazate and chlorfenapyr | |
| CN108184857A (en) | A kind of miticide composition containing second azoles mite nitrile with single carbonamidine | |
| CN102972404A (en) | Pesticidal composition containing fluacrypyrim and cyflumetofen | |
| CN108077273A (en) | A kind of miticide composition containing second azoles mite nitrile and Amitraz | |
| CN103416409A (en) | Disinsection composition containing flutenzine and methoxyfenozide | |
| CN103120165A (en) | Insecticidal composition containing spinetoram and cyantraniliprole | |
| CN103125495A (en) | Mite-killing composition containing pyrimidifen and pyridaben | |
| CN102228029B (en) | Pesticidal and acaricidal composition containing sufluoxime and tebufenpyrad | |
| CN102273481B (en) | Dinotefuran-containing pesticidal composition | |
| CN109392909A (en) | A kind of miticide composition containing fluorine pyrrole furanone and chlorfenapyr | |
| CN107361072A (en) | A kind of Pesticidal combination containing emamectin benzoate and cyflumetofen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |