CN105104390B - Anti-mite composition containing cycloxaprid and spirodiclofen - Google Patents
Anti-mite composition containing cycloxaprid and spirodiclofen Download PDFInfo
- Publication number
- CN105104390B CN105104390B CN201510510728.3A CN201510510728A CN105104390B CN 105104390 B CN105104390 B CN 105104390B CN 201510510728 A CN201510510728 A CN 201510510728A CN 105104390 B CN105104390 B CN 105104390B
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- CN
- China
- Prior art keywords
- cycloxaprid
- envidor
- agent
- spirodiclofen
- pesticidal preparations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 title claims abstract description 58
- NDHXMRFNYMNBKO-PWSUYJOCSA-N chembl2227757 Chemical compound [O-][N+](=O)C([C@H]1CC[C@H](O1)N1CC2)=C1N2CC1=CC=C(Cl)N=C1 NDHXMRFNYMNBKO-PWSUYJOCSA-N 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000005664 Spirodiclofen Substances 0.000 title abstract description 14
- 239000000642 acaricide Substances 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 21
- 239000004480 active ingredient Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003905 agrochemical Substances 0.000 claims description 11
- -1 cycloxaprid Compound Chemical class 0.000 claims description 9
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000004530 micro-emulsion Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 8
- 239000004563 wettable powder Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000006184 cosolvent Substances 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 150000002148 esters Chemical group 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- 239000007884 disintegrant Substances 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 150000003457 sulfones Chemical class 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 3
- 229920000578 graft copolymer Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 claims description 2
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims description 2
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 claims description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000468 ketone group Chemical group 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 15
- 241000488583 Panonychus ulmi Species 0.000 abstract description 10
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000011109 contamination Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 231100000419 toxicity Toxicity 0.000 description 10
- 230000001988 toxicity Effects 0.000 description 10
- 241000607479 Yersinia pestis Species 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000002265 prevention Effects 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 241000219146 Gossypium Species 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 230000000749 insecticidal effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000488581 Panonychus citri Species 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 241000238876 Acari Species 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 239000005663 Pyridaben Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 2
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000241602 Gossypianthus Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 125000003473 lipid group Chemical group 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- PEQJBOMPGWYIRO-UHFFFAOYSA-N n-ethyl-3,4-dimethoxyaniline Chemical class CCNC1=CC=C(OC)C(OC)=C1 PEQJBOMPGWYIRO-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000008288 physiological mechanism Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the technical field of pesticide application, particularly relates to an anti-mite composition containing cycloxaprid and spirodiclofen. The anti-mite composition containing cycloxaprid and spirodiclofen is provided. The anti-mite composition is a two-element compound by taking cycloxaprid and spirodiclofen as effective ingredients, and the mass ratio of cycloxaprid to spirodiclofen is 1: 50 to 50: 1. The composition provided by the present invention has a significant control efficiency on orange red spiders, apple red spiders and cotton red spiders. The composition provided by the present invention has advantages of having the significant synergism, reducing the pesticide dosage, reducing the control cost, delaying the occurrence of resistance and reducing environmental contamination.
Description
Technical field
The invention belongs to pesticides application technical field, is related to a kind of composition pesticide, it is specifically a kind of to contain epoxy insect
Pyridine and the miticide composition of Envidor.
Background technology
Cycloxaprid is along nitre alkene by East China University of Science, the autonomous class formulated of Shengnong Biological-Chemical Products Co., Ltd., Shanghai
Oxygen bridge heterocycle anabasine insecticide.Its insecticidal spectrum is wide, drug effect is high, no interactions resistance, to crop without poisoning, low toxicity, low-residual,
The activity of antagonism insect is better than imidacloprid.Research shows that cycloxaprid applicable crops include paddy rice, vegetables, fruit tree, wheat, cotton
Flower, corn etc., can be not only used for cauline leaf process, can also carry out Seed Treatment.Controlling object includes various pests.National 14
Provinces and cities carried out 2 years manyly, the field control effectiveness test of various pests and preventing and treating plant hopper and rice leaf roller field demonstration examination
Test, its drug effect is notable.
Envidor is first spirocyclic tetronic acid class acaricide that Beyer Co., Ltd finds and develops, registration in 2003 and on
City.In recent years, the sales volume of Envidor was substantially increased year by year, incessantly.2008, its sales volume exceeded propargite, into
For sales volume highest kind in acaricide, since then, it is sure to occupy always the chief status in acaricide.In 2007-2009
3 years in, more than 20%, sales volume is respectively 50,000,000,60,000,000 and 75,000,000 dollars to the annual growth of Envidor；
Portion also rises year by year in acaricide.2010, its sales volume was even more and has increased substantially 1/3, up to 1.0 hundred million dollars.2011
Year, the sales volume of Envidor is further promoted to 1.10 hundred million dollars, accounts for the 14.8% of acaricide sales volume.
At present, Envidor more than 50 country's registration and listing in the world.Over more than 10 years, Envidor registration and list
Major country includes：Brazil, Japan, China, Canada, USA and EU etc..The big agricultural chemicals such as North America, Latin America, Europe and Asia
State is received to the greatest extent in it.On June 30th, 2005, Envidor obtains registration, the same year listing in the U.S..On August 1st, 2010, Envidor is made
The registered active ingredient list of European Union's agriculture chemical registration regulations (1107/2009) is listed in for new active ingredient.
Envidor is lipid biosynthesis inhibitors, and it blocks the energetic supersession of mite by the Fatty synthesis of suppression mite, does
Disturb the growth of mite.Envidor is a kind of efficient, low toxicity, wide spectrum, selectivity, non-internal-suction type acaricide, with action of contace poison.With it is fast
The acaricide that speed is knocked down is compared, and causes effect aobvious slow；Compared with chitin insect growth regulator, IGR class acaricide, drug effect is very fast.But spiral shell
The mite ester lasting period is longer, and fast-acting type acaricide (such as sweep mite net, Fenpropathrin, pyridaben) can be coordinated to use.
Agricultural Mites, also known as red spider, belong to Arachnoidea Acarina, are the main of the crops such as harm fruit tree, cotton, tealeaves
One of insect, has a strong impact on the growing way of fruit tree and crops.Because the generation of mite class is more, breeding spreads soon, and many generations
Alternately grow up, thus preventing and treating gets up extremely difficult.In addition, mite class is different from general agricultural pestses physiological mechanism, common insecticide
Generally to mite class almost without prevention effect.At present, China be used for prevent and treat mite class specialized acaricide it is less, peasant household is usually used
Dicofol, pyridaben, propargite, isocarbophos, azacyclotin and their mixture, but these effect of chemical control are not
It is good, thus peasant household is required for applying substantial amounts of agricultural chemicals every year and mite pest is prevented and treated.For a long time, it is indiscriminate due to agricultural chemicals
With mite pest generates serious resistance to common agricultural chemicals, and causes these effect of chemical control to reduce year by year.Therefore, agriculture
It is badly in need of efficient, low toxicity, non-harmful Pesticidal products in family.
At present, the pesticide active ingredient of the different mechanisms of action is carried out into compounding is development pesticide new product and prevents and treats resistance disease
A kind of effective quick way of insect pest.After different pesticide active ingredients are compounded, three kinds of type of action can be shown：It is added
Effect, synergistic effect and antagonism.Generally, only just can be learnt after different pesticide active ingredient compoundings by substantial amounts of test
Type of action.The Recompounded pesticide of screening tool synergistic effect, can significantly improve prevention effect, reduce Pesticide use amount, reduce
Cost accounting, can be composed with expanding prevention, delay the generation of pest and disease damage resistance, be the important means of current integrated pest prevention and control
One of.
Inventor is tested and field control effectiveness test by a large amount of indoor biometricses, filters out the mite killing of cycloxaprid and Envidor
Composition, said composition has within the specific limits synergistic effect.So far, with cycloxaprid and Envidor as active ingredient
Miticide composition, at home and abroad there is not yet relevant report.
The content of the invention
The present invention for conventional acaricide dosage it is big, cost accounting is high, insecticidal spectrum is narrow, resistance produces fast protrusion and asks
A kind of topic, there is provided miticide composition containing cycloxaprid and Envidor, said composition tool improves prevention effect, expands desinsection
There is, reduce the advantage of pesticide dosage and reduces cost in spectrum, delaying drug resistance.
Technical scheme provided by the present invention is：
A kind of miticide composition containing cycloxaprid and Envidor, the miticide composition is with cycloxaprid and Envidor
The two-spot carried out for active ingredient is compounded, and the cycloxaprid and Envidor mass ratio are 1:50-50:1.
Preferably, the mass ratio of cycloxaprid and Envidor is 1 in the miticide composition:30-50:1.
The invention also discloses a kind of pesticidal preparations containing the acaricide composition, wherein cycloxaprid and Envidor
Quality account for the 1-80% of the pesticidal preparations gross mass, remaining is the auxiliary element for allowing to use in agricultural chemicals.
Preferably, the auxiliary element for using is allowed in the agricultural chemicals by solvent, cosolvent, emulsifying agent, wetting agent, dispersion
One or more compositions in agent, thickener, antifreezing agent, carrier and disintegrant.
Preferably, the solvent is esters or sulfone class, the esters are sec-butyl acetate and ethyl acetate；Sulfone class is two
Methyl sulfoxide.
Preferably, the cosolvent is ketone or higher alcohol, the ketone is cyclohexanone and N- pyrrolidones；Higher alcohol
For n-butanol.
Preferably, the emulsifying agent, wetting agent, dispersant are nonionic surfactant or anion surface active
Agent, the nonionic surfactant is castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxy second
Alkene polyethenoxy ether, aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer, tristyrylphenyl APEO and 12
Alkyl benzene calcium sulfonate castor oil polyoxyethylene ether；Anion surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate
Lauryl sodium sulfate, thermally coupled distillation columns and aliphatic alcohol polyoxyvinethene phosphate ammonium salt.
Preferably, the thickener is xanthans, Arabic gum, Magnesiumaluminumsilicate and polyvinyl alcohol.
Preferably, the antifreezing agent is polyalcohol, the polyalcohol is ethylene glycol, glycerine and propane diols.
Preferably, the carrier is white carbon, kaolin or diatomite.
Preferably, the disintegrant is ammonium sulfate, sodium chloride or ammonium sulfate.
Preferably, described mite and insect killing agent composition can be prepared into suitable agricultural using method well known in the art making
The formulations of pesticide.
Preferably, aqueous emulsion, microemulsion, suspending agent, wettable powder or water dispersible granules can be prepared into.
Preferably, described insecticidal/acaricidal composition is to agriculturals such as citrus red mite, European red mite and cotton red spiders
Evil mite has preferable prevention effect.
Compared with prior art, the invention has the beneficial effects as follows：
1. after the composition pesticide of the present invention is using two kinds of active ingredient compoundings of cycloxaprid and Envidor, with obvious
Synergistic effect, improves prevention effect.
2. the composition pesticide of the present invention uses no interactions resistance between two kinds of active ingredients of cycloxaprid and Envidor, because
And compound after using can with the generation of delaying drug resistance with development.
3. the composition pesticide of the present invention can reduce the usage amount of agricultural chemicals, reduce cost accounting, reduce environmental pollution, mitigate
Pressure to environment.
Specific embodiment
Present invention specific examples below is described in detail its advantage.
First, indoor virulence test is determined
1. experiment material：Test medicine is using 95% cycloxaprid and 95% Envidor active compound；Test worm is to adopt from field
Cotton tetranychid, in Jing rooms steamed bun breeding hatching first generation deutonymph.
2. test method：Leaf butterfly spray-on process is adopted, each single dose arranges 5 different concentration (in preparation examination with Mixed Pharmacy
On the basis of testing result, the cotton tetranychid deutonymph death rate is set in the range of 5-90% by geometric progression), often process and set 3 times
Repeat, blank is made with clear water.
3. operating procedure：The consistent cotton leaf of growth is first taken, with card punch leaf butterfly is made, one is placed in culture dish wet
Sponge block, puts thereon filter paper, foliation butterfly on filter paper, puts 3 pieces of leaf butterflies per ware, select indoor feeding, health, age it is consistent
Tetranychid nymph is inoculated on leaf butterfly cotton, and 20 are inoculated with per leaf butterfly.
The culture dish for being connected to leaf butterfly is placed under potter spray towers, is sprayed under 50PSI pressure, spray amount is 1ml, sunk
Culture dish is taken out after drop 1min, then the culture dish for processing is put in 12H/12H lighting box and is cultivated, 48h checks dead borer population,
Calculate the death rate.Often process and set 3 repetitions, blank is made with clear water.
4. computational methods：Test data is analyzed with DPS statistical analysis softwares, is calculated the LC50 of each medicament, come
Evaluate the insecticidal activity of each medicament.And the co-toxicity coefficient (CTC values) of mixture is calculated according to the abundant methods of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agents LC50) × 100.
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T1154.13-2008 insecticide combinations：Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect is acted on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80<Co-toxicity coefficient (CTC)<120 show as summation action.
5. result of the test：Refer to table 1-3.
The indoor joint toxicity measuring of the cycloxaprid of table 1 and Envidor to citrus red mite deutonymph
The indoor joint toxicity measuring of the cycloxaprid of table 2 and Envidor to European red mite deutonymph
The indoor joint toxicity measuring of the cycloxaprid of table 3 and Envidor to cotton red spider deutonymph
Toxicity Determination result shows：The mass ratio of cycloxaprid and Envidor is 1 in the miticide composition of the present invention:
50-50:In the range of 1, co-toxicity coefficient is all higher than 120, i.e. said composition to citrus red mite, European red mite and cotton red spider
Biologically active show as synergistic effect；Especially the mass ratio of cycloxaprid and Envidor is 1:30-50:It is malicious altogether in the range of 1
More than 130, synergistic effect becomes apparent from coefficient.
2nd, agricultural chemicals prepares embodiment
(1) preparation of aqueous emulsion
Embodiment 1：1% cycloxaprid spirodiclofen water emulsion
Embodiment 2：10% cycloxaprid spirodiclofen water emulsion
Embodiment 3：15% cycloxaprid spirodiclofen water emulsion
The preparation method of the above aqueous emulsion is：Active ingredient cycloxaprid and Envidor solvent, cosolvent are filled
After dividing dissolving, input emulsifying agent, dispersant, wetting agent form oil phase after being sufficiently stirred for；Antifreezing agent is added to the water into dissolving, is formed
Water phase；Water is mutually slowly added in oil phase, is sheared using high-speed shearing machine, you can obtain aqueous emulsion.
(2) preparation of microemulsion
Embodiment 4：5% cycloxaprid spirodiclofen microemulsion
Embodiment 5：8% cycloxaprid spirodiclofen microemulsion
Embodiment 6：15% cycloxaprid spirodiclofen microemulsion
The preparation method of the above microemulsion is：Active component cycloxaprid and Envidor solvent, cosolvent are filled
After dividing dissolving, emulsifying agent is put into, oil phase is formed after being sufficiently stirred for；Antifreezing agent is added to the water and obtains water phase；Water is mutually slowly added
In entering oil phase, sheared using high-speed shearing machine, you can obtain transparent microemulsion.
(3) preparation of suspending agent
Embodiment 7：20% cycloxaprid Envidor suspending agent
Embodiment 8：30% cycloxaprid Envidor suspending agent
Embodiment 9：50% cycloxaprid Envidor suspending agent
Cycloxaprid (active ingredient) 5.0%
Envidor (active ingredient) 45%
Aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer (dispersant) 1%
The preparation method of the above suspending agent is：Active component cycloxaprid and Envidor are used into airslide disintegrating mill powder
After broken, in input stirred tank, while dispersant, wetting agent, antifreezing agent and water are put into, after being sufficiently stirred for, by material suction sand milling
It is fully ground in machine, after the completion of grinding, in suction high-speed shearing machine, after adding thickener, is carried out high speed shear, has been sheared
Suspending agent is obtained into rear.
(4) preparation of wettable powder
Embodiment 10：50% cycloxaprid Envidor wettable powder
Embodiment 11：60% cycloxaprid Envidor wettable powder
Embodiment 12：80% cycloxaprid Envidor wettable powder
The preparation method of the above wettable powder is：By formula rate, active ingredient and preparation auxiliary element are mixed
Close uniform, Jing airslide disintegrating mills are crushed, remix uniform, i.e., prepared wettable powder.
(5) moisture dissipates the preparation of granular agent
Embodiment 13：25% cycloxaprid spirodiclofen water dispersible granule
Embodiment 14：50% cycloxaprid spirodiclofen water dispersible granule
Embodiment 15：70% cycloxaprid spirodiclofen water dispersible granule
The preparation method of above water dispersible granules is：It is by formula rate, active ingredient and the mixing of preparation auxiliary element is equal
After even, Jing airslide disintegrating mills are crushed, and are well mixed again, then, add a certain amount of water to mediate in this mixture, and extruding is made
Grain, drying screening, that is, obtain water dispersible granules.
Presently preferred embodiments of the present invention is the foregoing is only, the substantial technological content of the present invention is not limited to
Scope, the substantial technological content of the present invention is broadly defined in the right of application, any skill that other people complete
Art or method, if it is identical with defined in claims hereof scope, or a kind of simply equivalent replacement,
It is considered to be covered by among the right.
Claims (6)
1. a kind of miticide composition containing cycloxaprid and Envidor, it is characterised in that：The miticide composition is with cycloxaprid
Compound for the two-spot that active ingredient is carried out with Envidor, the mass ratio of the cycloxaprid and Envidor is 1:50-50:1.
2. the miticide composition containing cycloxaprid and Envidor according to claim 1, it is characterised in that：It is described effectively into
The mass ratio for dividing cycloxaprid and Envidor is 1:30-50:1.
3. a kind of pesticidal preparations comprising arbitrary miticide composition in claim 1-2, it is characterised in that：The agricultural chemicals system
The quality of active ingredient cycloxaprid and Envidor accounts for the 1-80% of pesticidal preparations gross mass in agent, and remaining is to allow to make in agricultural chemicals
Auxiliary element.
4. pesticidal preparations according to claim 3, it is characterised in that：The auxiliary element for using is allowed in the agricultural chemicals by molten
One or more compositions in agent, cosolvent, emulsifying agent, wetting agent, dispersant, thickener, antifreezing agent, carrier and disintegrant；
The solvent is esters or sulfone class, and the cosolvent is ketone or higher alcohol, and described higher alcohol is n-butanol；The emulsification
Agent, wetting agent, dispersant are nonionic surfactant or anion surfactant, and the thickener is xanthans, I
Primary glue, Magnesiumaluminumsilicate and polyvinyl alcohol, the antifreezing agent be polyalcohol, the carrier be white carbon, kaolin or diatomite, institute
Disintegrant is stated for sodium chloride or ammonium sulfate.
5. pesticidal preparations according to claim 4, it is characterised in that：The esters are sec-butyl acetate and ethyl acetate；Sulfone
Class is dimethyl sulfoxide (DMSO)；The ketone is cyclohexanone and N- pyrrolidones；The nonionic surfactant is castor oil polyoxy
Vinethene, NPE, styryl phenyl polyoxyethylene poly-oxygen propylene aether, aliphatic alcohol polyethenoxy polyoxypropylene
Graft copolymer, tristyrylphenyl APEO and calcium dodecyl benzene sulfonate castor oil polyoxyethylene ether；Anion
Surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate lauryl sodium sulfate, NPE phosphoric acid
Ester and aliphatic alcohol polyoxyvinethene phosphate ammonium salt；The polyalcohol is ethylene glycol, glycerine and propane diols.
6. pesticidal preparations according to claim 3, it is characterised in that：The formulation of the pesticidal preparations be aqueous emulsion, microemulsion,
Suspending agent, wettable powder or water dispersible granules.
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