CN106212464A - A kind of Pesticidal combination containing ethyl pleocidin - Google Patents
A kind of Pesticidal combination containing ethyl pleocidin Download PDFInfo
- Publication number
- CN106212464A CN106212464A CN201610620995.0A CN201610620995A CN106212464A CN 106212464 A CN106212464 A CN 106212464A CN 201610620995 A CN201610620995 A CN 201610620995A CN 106212464 A CN106212464 A CN 106212464A
- Authority
- CN
- China
- Prior art keywords
- ethyl pleocidin
- insect amide
- ring bromine
- bromine insect
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of containing ring bromine insect amide and the Pesticidal combination of ethyl pleocidin, wherein, the weight ratio of ring bromine insect amide and ethyl pleocidin is 1:50 50:1, in preparation, the weight ratio of effective ingredient ring bromine insect amide and ethyl pleocidin is 0.5 90%, the compositions of the present invention all shows the prevention effect of excellence to various crop pests, such as rice leaf roller, diamondback moth etc., it is worth popularization and application on producing.
Description
Technical field
The present invention relates to field of pesticide preparation, particularly relate to a kind of containing ring bromine insect amide and the agriculture of ethyl pleocidin
Drug composition.
Background technology
Ring bromine insect amide, English general entitled cyclaniliprole, exploitation code name is that IKI-3106, CAS accession number is
1031756-98-5, is the insecticide with biamide structure of Shi Yuan industry companies of Japan exploitation, and the parasite killing with spectrum is lived
Property, can be used for numerous crops such as fruit tree, vegetable, Rhizoma Solani tuber osi, Camellia sinensis, Semen sojae atricolor and Cotton Gossypii, prevent and treat Lepidoptera, coleoptera, tassel wing
Mesh, Diptera and homoptera pest.
Ethyl pleocidin is the one developed by Dow AgroSciences novel pleocidin insecticides, and it is thorn sugar bacterium
One newcomer of element spinosyn insecticides, is to obtain natural product spinosyns through chemical modification, belongs to bionic-type agriculture
Medicine.In spinosyn insecticides, ethyl pleocidin is brand-new, a unique effective ingredient, is a kind of efficient, light
Spectrality insecticide.It is mainly used in preventing and treating Lepidoptera and Thysanoptera larva, to diamondback moth, beet armyworm, Liriomyza, Prodenia litura etc.
The prevention effect that vegetable-crop pest-insect is harmful, is widely used in the resistance management rotation medicine variety of vegetable-crop pest-insect.Due to Oryza sativa L., jade
The raising of the field crop drug costs such as rice, Caulis Sacchari sinensis, ethyl pleocidin is the most gradually in the Pest control of these field crops
Popularization and application, become the rotation kind that the drug resistance such as Rynaxypyr, fluorobenzene insect amide, metaflumizone, indoxacarb are administered,
Preventing and treating medication for lepidoptera pests such as striped rice borer, yellow rice borer, rice leaf roller, Pyrausta nubilalis (Hubern).s.
At present, owing to being easily generated the Pest control of resistance in agricultural production, main way is exploitation and existing pesticide species
Compounding between novel pesticide composition or the existing pesticide species of no interactions resistance, the former is owing to required development cost is high, the cycle
Long, and the speed that development rate produces less than pest resistance to insecticide far away at present.Therefore, for pesticide that the mechanism of action is different
When kind carries out mixture, one preferably selects, and by the most compounding, can improve preventive effect, reduces effective ingredient consumption, joint
About cost, delays the generation of pest resistance to insecticide, and then can alleviate and even avoid pesticide to food and the pollution of environment.
In order to solve pesticide resistance in actual Field information, present inventor through substantial amounts of lab screening and
Field control effectiveness test, after finding ring bromine insect amide and ethyl pleocidin mixture, has significantly rice leaf roller, diamondback moth
Potentiation, can reduce use cost, high to crop safety.
Summary of the invention
It is an object of the invention to provide the ring bromine worm that a kind of component is reasonable, have synergistic function, good disinsection effect
Amide and the Pesticidal combination of ethyl pleocidin.
Another object of the present invention is to provide the application of above-mentioned Pesticidal combination.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that a kind of Pesticidal combination, its active component bag
Including ring bromine insect amide and ethyl pleocidin, wherein, the weight ratio of ring bromine insect amide and ethyl pleocidin is 1:50-50:1,
It is preferably 1:20-50:1.
Further, described compositions medium ring bromine insect amide and ethyl pleocidin account for the percentage ratio of composition total weight and are
0.5-90%, preferably 10-80%, the weight ratio of compositions shared by described active component is closely related with dosage form.
Further, the bactericidal composition of the present invention can be prepared as by preparation method conventional in Pesticide formulation
For any one dosage form in Pesticide formulation, such as, can be cream, wettable powder, suspending agent, water dispersible granules, water
Emulsion, microemulsion, granule etc..
The compositions of the present invention can be the most blended with each material in the finished product preparation i.e. compositions of form offer, it is also possible to
Unit dose form provides, and is directly mixed in proportion in bucket or tank, is then diluted to required concentration before using.
Further, the compositions of the present invention can also add other agricultural active composition, such as antibacterial, insecticide,
The agricultural active composition such as herbicide, fertilizer.
Technical scheme has the advantages that and comprises ring bromine insect amide and the compounding of ethyl pleocidin kills
Worm agent has obvious potentiation, can delay the generation of pest resistance to insecticide, it is possible to reduces drug cost, reduce pesticide to ring
The risk in border, meets the demand of " medicine fertilizer zero growth rate "；In the compositions of the present invention, the mechanism of action of active component is different, from
And generation and the development of single dose resistance can be delayed.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated, and the percentage ratio in embodiment is all weight percentage,
But the present invention is limited to absolutely not these examples.The following stated is only the preferable embodiment of the present invention, is used only for explaining the present invention, but
Can not be therefore understands that be the restriction to the scope of the claims of the present invention.Should be understood that time, all within the spirit and principles in the present invention
Any amendment, equivalent or the improvement etc. made, should be included within the scope of the present invention, and therefore, the present invention is special
The protection domain of profit should be as the criterion with claims.
1, embodiment 1:51% ring bromine insect amide ethyl pleocidin wettable powder (50:1)
Ring bromine insect amide 50%
Ethyl pleocidin 1%
Dodecylbenzene sodium sulfonate 5%
Fatty alcohol-polyoxyethylene ether 10%
Kieselguhr surplus
The concrete procedure of processing of described wettable powder is: by above-mentioned formula by ring bromine insect amide, ethyl pleocidin, dodecane
Base benzene sulfonic acid sodium salt, fatty alcohol-polyoxyethylene ether and kieselguhr mixing, uniform stirring in stirred tank, after comminution by gas stream, mixing is all
Even, can be prepared by of the present invention containing ring bromine insect amide and the wettable powder of ethyl pleocidin.
2, embodiment 2:21% ring bromine insect amide ethyl pleocidin water dispersible granules (20:1)
Ring bromine insect amide 20%
Ethyl pleocidin 1%
Aliphatic alcohol polyethenoxy base ether 5%
Sodium laurylsulfate 4%
Arabic gum 1%
Ammonium sulfate 2%
Kieselguhr surplus
The concrete procedure of processing of described water dispersible granules is: by above-mentioned formula by ring bromine insect amide, ethyl pleocidin and fat
Alcohol polyoxyethylene ether, sodium laurylsulfate, arabic gum, ammonium sulfate, kieselguhr mix homogeneously, use micro jet powder
Broken, through mediating, subsequently into Squeezinggranulator pelletize, boiling drier is dried, sample analysis after screening, prepares institute of the present invention
State containing ring bromine insect amide and the water dispersible granules of ethyl pleocidin.
3, embodiment 3:22% ring bromine insect amide ethyl pleocidin suspending agent (1:10)
Ring bromine insect amide 2%
Ethyl pleocidin 20%
Alkylaryl polyoxyethylene ether 6%
Sodium lignin sulfonate 4%
Aluminium-magnesium silicate 0.2%
Ethylene glycol 0.5%
Organic silicone 0.2%
Deionized water surplus
The procedure of processing of described suspending agent is: by above-mentioned formula by deionized water and alkylaryl polyoxyethylene ether, sulfomethylated lignin
Acid sodium, aluminium-magnesium silicate, ethylene glycol and organic silicone mixing, through high speed shear mix homogeneously, add ring bromine insect amide and ethyl be many
Bacteriocidin, continues to shear mixing, grinds subsequently in horizontal sand mill, make preparation particle diameter all below 5 microns, prepare this
Described in invention containing ring bromine insect amide and the suspension of ethyl pleocidin.
4, embodiment 3:30% ring bromine insect amide ethyl pleocidin water dispersible granules
Ring bromine insect amide 15%
Ethyl pleocidin 15%
Alkylaryl polyoxyethylene ether 8%
Sodium lauryl sulphate 5%
Aluminium-magnesium silicate 2%
Carbamide 1%
Kieselguhr surplus
The concrete procedure of processing of described water dispersible granules is: by above-mentioned formula by ring bromine insect amide, ethyl pleocidin and alkyl
Aryl polyoxyethylene ether, sodium lauryl sulphate, aluminium-magnesium silicate, carbamide, kieselguhr mix homogeneously, use micro jet powder
Broken, through mediating, subsequently into Squeezinggranulator pelletize, boiling drier is dried, sample analysis after screening, prepares institute of the present invention
State containing ring bromine insect amide and the water dispersible granules of ethyl pleocidin.
Two, Toxicity Determination
1, raw survey embodiment 1: ring bromine insect amide and ethyl pleocidin bacterium are to diamondback moth Toxicity Determination
In order to further appreciate that ring bromine insect amide and the ethyl pleocidin virulence to diamondback moth, carry out the examination of a large amount of recipe determination
Test.Test is with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7 2006) and initiative
Pesticide bioactivity evaluates SOP (insecticide volume), and experiment target is designated as diamondback moth, uses infusion process, and ring bromine insect amide and ethyl are many
Symphyogenetic result of the test after bacteriocidin is compounding is as shown in table 1.
Indoor virulence test result shows, after ring bromine insect amide and ethyl pleocidin compound, in the range of 1:50-50:1,
Preventing and treating to diamondback moth all shows synergistic function.
2, raw embodiment 2 of surveying: ring bromine insect amide and the ethyl pleocidin Toxicity Determination to rice leaf roller
In order to further appreciate that ring bromine insect amide and the ethyl pleocidin virulence to rice leaf roller, carry out a large amount of formula sieve
Choosing test.Test is with reference to reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7
2006) and initiative pesticide bioactivity evaluates SOP (insecticide volume), experiment target is designated as rice leaf roller, employing infusion process, ring bromine
Symphyogenetic result of the test after insect amide and ethyl pleocidin compound is as shown in table 1.
Toxicity Determination result shows, ring bromine insect amide and ethyl pleocidin, in the range of 1:50-50:1, are rolled up rice is vertical
The co-toxicity coefficient of leaf snout moth's larva is all higher than 120, shows synergistic function.
Three, field control effectiveness test
1, in order to preferably verify the practical application effect of the composition pesticide of the present invention, embodiments of the invention preparation is carried out
Preventing and treating diamondback moth field control effectiveness test, crop is Caulis et Folium Brassicae capitatae, carries out dispenser in Caulis et Folium Brassicae capitatae bag heart early stage, and diamondback moth worm state is larva, with
Low instar larvae is main, and application method is blade face even spraying, and test survey is according to medicine inspecting institute of the Ministry of Agriculture " pesticide field efficacy medicine test
The lepidopterous larvae of criterion (one) insecticide control brassicaceous vegetable " specify to carry out, every experimental plot uses at 5 and takes
Sample, every some investigation 2 strains, investigate 10 strain Caulis et Folium Brassicae capitataes altogether.3 days, 7 days, 14 days statistical test effect of chemical control after medicine, test
The results are shown in Table 3.
From table 3 it is observed that the Mixed Pharmacy of different proportion in embodiment, after medicine to diamondback moth 3 days, 7 days, 14 to little
Diamond-back moth all shows the prevention effect of excellence, hence it is evident that be better than the preventive effect of single active component.It addition, in scope of medication, each
Caulis et Folium Brassicae capitatae all without poisoning, meanwhile, is observed in test that aphid, beet armyworm are also had by chemicals treatment the most anti-by chemicals treatment
Effect.
2, in order to preferably verify the practical application effect of the composition pesticide of the present invention, by the group of embodiments of the invention
Compound carries out preventing and treating rice leaf roller field control effectiveness test, and trial crops is single cropping hybrid rice, and dispenser period is rice tillering
Phase, use " closing U.S. " type 16A type knapsack electric sprayer, plant blade face even spraying.Test survey is according to pesticide field
Test of pesticide effectiveness criterion (one) insecticide control Oryza sativa L. Lepidoptera borer pest " regulation carry out, every community use interlacing
Jump 5 samplings, often row investigation 5 clumps, altogether 25 clumps of Oryza sativa L. of investigation, investigate the leaf roll number of every clump and total number of sheets, calculate after medicine 3 respectively
My god, 7 days and 14 days preventive effects, result of the test is shown in Table 4.
As can be seen from Table 4, the Mixed Pharmacy of different proportion in embodiment, after medicine, rice leaf roller is all showed for 3,7,14 days
Go out the prevention effect of excellence, hence it is evident that be better than the preventive effect of single active component.According to experimental observation, in scope of medication, each medicament
Process and Oryza sativa L. is all produced without poisoning.
Comprehensive Toxicity Determination and field control effectiveness test, the ring bromine insect amide of the present invention and ethyl pleocidin rhzomorph
Complex insecticidal composition is compared with single dose, and unit administration amount is few, and quick-acting and lasting effect all show well, therefore, and the present invention's
Compositions has well application and promotional value.
Claims (6)
1. a Pesticidal combination, it is characterised in that active component comprises ring bromine insect amide and ethyl pleocidin.
Pesticidal combination the most according to claim 1, it is characterised in that described ring bromine insect amide and ethyl pleocidin
Weight ratio is 1:50-50:1.
Pesticidal combination the most according to claim 1 and 2, it is characterised in that described ring bromine insect amide and the many sterilizations of ethyl
The weight ratio of element is preferably 1:20-50:1.
4. according to the Pesticidal combination described in claim any one of claim 1-3, it is characterised in that its dosage form is breast
Oil, wettable powder, suspending agent, water dispersible granules, aqueous emulsion, microemulsion, granule.
5. according to the Pesticidal combination described in claim any one of claim 1-4 for preventing and treating the use of crop pests
On the way.
Purposes the most according to claim 5, it is characterised in that described crop pests is rice leaf roller, diamondback moth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620995.0A CN106212464A (en) | 2016-08-02 | 2016-08-02 | A kind of Pesticidal combination containing ethyl pleocidin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620995.0A CN106212464A (en) | 2016-08-02 | 2016-08-02 | A kind of Pesticidal combination containing ethyl pleocidin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106212464A true CN106212464A (en) | 2016-12-14 |
Family
ID=57535633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610620995.0A Pending CN106212464A (en) | 2016-08-02 | 2016-08-02 | A kind of Pesticidal combination containing ethyl pleocidin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106212464A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106359391A (en) * | 2016-08-27 | 2017-02-01 | 深圳诺普信农化股份有限公司 | Cyclaniliprole-containing pesticide composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN101919388A (en) * | 2010-08-27 | 2010-12-22 | 青岛海利尔药业有限公司 | Ethyl pleocidin and tebufenozide-containing insecticidal composition |
| CN102246799A (en) * | 2011-06-26 | 2011-11-23 | 青岛奥迪斯生物科技有限公司 | Insecticidal composition containing spinetoram |
-
2016
- 2016-08-02 CN CN201610620995.0A patent/CN106212464A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN101919388A (en) * | 2010-08-27 | 2010-12-22 | 青岛海利尔药业有限公司 | Ethyl pleocidin and tebufenozide-containing insecticidal composition |
| CN102246799A (en) * | 2011-06-26 | 2011-11-23 | 青岛奥迪斯生物科技有限公司 | Insecticidal composition containing spinetoram |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106359391A (en) * | 2016-08-27 | 2017-02-01 | 深圳诺普信农化股份有限公司 | Cyclaniliprole-containing pesticide composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103392737B (en) | Oligosaccharides and sulphur are as the agriculturally useful compositions of building component | |
| CN101589722A (en) | Insecticides of a kind of chloride worm benzamide and its production and use | |
| CN102326578A (en) | Pesticide composition and preparation thereof | |
| CN104488943B (en) | A kind of Pesticidal combination | |
| CN105010315B (en) | It is a kind of containing Acetamiprid and the dispersible oil-suspending agent of carbosulfan and application | |
| CN104082300A (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN106212464A (en) | A kind of Pesticidal combination containing ethyl pleocidin | |
| CN104381294A (en) | Insect and mite killing composition containing xiaochongliulin and spirodiclofen | |
| CN104920391B (en) | A kind of miticide composition containing cycloxaprid and chlorine fluorine cyanogen insect amide | |
| CN107027800A (en) | A kind of Pesticidal combination containing avermectin B2a | |
| CN104186471B (en) | A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide | |
| CN106818753A (en) | A kind of antiviral composition containing Chinese Stellera Root element and its application | |
| CN106212463B (en) | A kind of composition pesticide containing propylene glycol alginate and methoxyfenozide | |
| CN106342835A (en) | Insecticidal composition containing spinosad | |
| CN106165690A (en) | A kind of composition pesticide containing avilamycin | |
| CN104705318B (en) | A kind of Pesticidal combination containing rosin acid sodium and spiral shell worm ethyl ester | |
| CN104585179B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and spirodiclofen | |
| CN104082323B (en) | There is the insect-killing composition of synergism | |
| CN107637602A (en) | A kind of composition pesticide containing emamectin-benzoate | |
| CN105941423A (en) | Insecticide composition containing chlorfenapyr and cyromazine | |
| CN101731250B (en) | Fenazaquin-containing acaricidal composition | |
| CN106305762A (en) | Synergistic insecticidal composite containing afidopyropen | |
| CN105475339A (en) | Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof | |
| CN106386841A (en) | Eco-friendly compound water-dispersible pesticide and preparation method thereof | |
| CN104642378B (en) | A kind of containing Profenofos and the compound pesticide compositions of ethyl pleocidin and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161214 |
|
| RJ01 | Rejection of invention patent application after publication |