CN103392737B - Oligosaccharides and sulphur are as the agriculturally useful compositions of building component - Google Patents
Oligosaccharides and sulphur are as the agriculturally useful compositions of building component Download PDFInfo
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- CN103392737B CN103392737B CN201310319358.6A CN201310319358A CN103392737B CN 103392737 B CN103392737 B CN 103392737B CN 201310319358 A CN201310319358 A CN 201310319358A CN 103392737 B CN103392737 B CN 103392737B
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- sulphur
- oligosaccharides
- chitosan oligosaccharide
- composition
- useful compositions
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- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 description 1
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 229940127108 compound 5g Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- CWVRPJSBNHNJSI-XQNSMLJCSA-N coumoxystrobin Chemical compound C1=C2OC(=O)C(CCCC)=C(C)C2=CC=C1OCC1=CC=CC=C1\C(=C/OC)C(=O)OC CWVRPJSBNHNJSI-XQNSMLJCSA-N 0.000 description 1
- YXKMMRDKEKCERS-UHFFFAOYSA-N cyazofamid Chemical compound CN(C)S(=O)(=O)N1C(C#N)=NC(Cl)=C1C1=CC=C(C)C=C1 YXKMMRDKEKCERS-UHFFFAOYSA-N 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 1
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 description 1
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 description 1
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 1
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229960002418 ivermectin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 description 1
- 229960000521 lufenuron Drugs 0.000 description 1
- 229940041033 macrolides Drugs 0.000 description 1
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 description 1
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229940079888 nitenpyram Drugs 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to plant protection art, particularly relate to oligosaccharides and sulphur as the agriculturally useful compositions of building component and preventing and treating the application in agricultural pest.The ratio of quality and the number of copies of oligosaccharides and sulphur is 1:0.1-200, and the ratio of quality and the number of copies of oligosaccharides, sulphur and other farm chemical ingredients is 1:0.1-200:0.1-100.In composition, oligosaccharides is pectic oligosaccharides, sodium alginate oligosaccharide or chitosan oligosaccharide, synergistic composition containing oligosaccharides and sulphur of the present invention can be processed into granule, suspending agent etc. with other Insecticiding-miticiding composition or sterilization component, realize the synergistic effect of agriculturally useful compositions, for preventing and treating crop nematode, two spotted spider mite, blister mite or powdery mildew etc.
Description
Technical field
The invention belongs to plant protection art, particularly relate to oligosaccharides and sulphur as the agriculturally useful compositions of building component and preventing and treating the application in agricultural pest.
Background technology
In agricultural production, the pesticide resistance of crop disease and insect to Pesticidal products strengthens gradually, and, the damage by disease and insect of same crop often occurs simultaneously, peasant often attends to one thing and lose sight of another when independent pest control or disease, not only delays work and misses control opportunity, from and strengthen dosage etc.Due to single and not Scientific Usage of Drugs, cause that peasant's cost improves, the destruction etc. of environmental pollution and ecotope.Carrying out composite with different structure, the different mechanism of action, environmentally friendly active component, and rationally add auxiliary agent and make new agriculturally useful compositions, is reduce and delaying drug resistance insect, expanding prevention target, improve the effective way of drug effect, minimizing environmental pollution.
Sulphur is an important kind in inorganic pesticide.Commodity are yellow solid or powder, have obvious smell, can volatilize.Sulphur aqueous suspensions is subacidity, water insoluble.Sulphur belongs to multipurpose agent, apart from outside bactericidal action, can also kill mite, desinsection, have fertilizer efficiency, to people, animal safety, not easily makes crop produce poisoning.
Oligosaccharides is the bioactivator with specific aggregation degree obtained through special biological enzyme technology process by glycan, its molecular weight is lower, better water-soluble, easily absorbed by organism, there is special biologically active, there is the function of diseases prevention, disease-resistant, regulating plant growth, utilize the oligosaccharides of separate sources can specific aim exploitation series of oligosaccharides biopesticide.
Inventors performed a large amount of oligosaccharides and sulphur as the test of pesticide effectiveness of building component, find many beyond thought effects.This invention improves drug effect and expanding prevention target, be beneficial to reduce times for spraying, reduce agriculture this and improve agricultural product economic benefit.
Summary of the invention
The object of this invention is to provide using oligosaccharides and sulphur as the agriculturally useful compositions of building component, improve drug effect, expanding prevention target, there is fertilizer efficiency.
The invention provides a kind of oligosaccharides and the sulphur agriculturally useful compositions as building component, also containing other farm chemical ingredients in agriculturally useful compositions, the ratio of quality and the number of copies of oligosaccharides and sulphur is 1:0.1-200, and preferably, ratio of quality and the number of copies is 1:1-100.Described oligosaccharides is pectic oligosaccharides, sodium alginate oligosaccharide or chitosan oligosaccharide, and preferably, oligosaccharides is chitosan oligosaccharide.
The invention provides a kind of oligosaccharides and the sulphur agriculturally useful compositions as building component, containing oligosaccharides, sulphur and other Insecticiding-miticiding composition in said composition, wherein, the ratio of quality and the number of copies of oligosaccharides, sulphur and other insecticidal/acaricidal agents is 1:0.1-200:0.1-100, preferably, the ratio of quality and the number of copies of oligosaccharides, sulphur and other insecticidal/acaricidal agents is 1:1-100:0.5-60.In above-mentioned composition, oligosaccharides is pectic oligosaccharides, sodium alginate oligosaccharide or chitosan oligosaccharide, and preferably, oligosaccharides is chitosan oligosaccharide.In above-mentioned composition, Insecticiding-miticiding composition is macrolides Avermectin, emamectin-benzoate (calling emamectin benzoate in the following text), ivermectin, one in pleocidin, or organic phosphates insecticidal constituent fosthiazate, isazofos, chlopyrifos, one in phoxim and Profenofos, or anabasine insecticidal constituent Nitenpyram, Diacloden, Imidacloprid, Acetamiprid, thiacloprid, one in MTI-446 and clothianidin, or amide-type insecticidal constituent cyanogen insect amide, flutolanil, Tolfenpyrad, one in flonicamid and Rynaxypyr, or pyrethroid insecticidal constituent Biphenthrin, ether chrysanthemum ester, gamma cyhalothrin, beta-cypermethrin, one in cypermethrin and tefluthrin, or carbamate insecticide Mobucin, one in thiodicarb, or process for preparation of benzoylurea compounds HEXAFLUMURON, flufenoxuron, chlorfluazuron, lufenuron, fluorine uride, d ichlorbenzuron, one in diflubenzuron and Teflubenzuron, or nereistoxin constituents is selected from Cupric sulfate, dimehypo, one in cartap, or other constituents spiral shell mite ester, Bifenazate, spiral shell worm ethyl ester, pyridaben, chlorfenapyr, indoxacarb, one in pymetrozine.Preferably, Insecticiding-miticiding composition is the one in Avermectin, emamectin benzoate, fosthiazate, isazofos, spiral shell mite ester, Bifenazate, spiral shell worm ethyl ester, pyridaben.
The invention provides a kind of oligosaccharides and the sulphur agriculturally useful compositions as building component, containing oligosaccharides, sulphur and other sterilization component in said composition, wherein, the mass fraction of oligosaccharides, sulphur and other sterilization component is than being 1:0.1-200:0.1-100, preferably, the mass fraction of oligosaccharides, sulphur and other sterilization component is than being 1:1-100:0.5-60.In above-mentioned composition, oligosaccharides is pectic oligosaccharides, sodium alginate oligosaccharide or chitosan oligosaccharide, and preferably, oligosaccharides is chitosan oligosaccharide.In above-mentioned composition, sterilization component is methoxy acrylic composition orysastrobin, pyraclostrobin, oxime bacterium ester, ZEN 90160, alkene oxime amine, ZJ0712, SSF 126, SYP-3375, azoles bacterium ester, Fluoxastrobin, one in 2-cyano-3-amino-3-phenylancryic acetate, or triazole type sterilization component Tebuconazole, propiconazole, Difenoconazole, nitrile bacterium azoles, Flusilazole, triazolone, bromuconazole, own azoles alcohol, metconazole, Triadimenol, epoxiconazole, tetraconazole, one in triticonazole, or sulfur-bearing class sterilization component zineb, S-Ethyl ethylthio sulfonate, Propineb, Carbatene, tpn, carbendazim, thiophanate-methyl, tmtd, asomate, captan, folpet, sulfonat, fenaminosulf, one in ambam, or miazines sterilization component cyprodinil, the phonetic phenol of second, fluorine mepanipyrim, one in mepanipyrim, or biogenic substances sterilization component polyoxin, jinggangmeisu, kasugarnycin, one in Zhongshengmycin, or organic phosphates sterilization component iprobenfos, one in edifenphos, or amide-type sterilization component dimethomorph, zoxamide, mefenoxam, benalaxyl-M, one in fluopicolide, or imidazoles sterilization component Prochloraz, cyazofamid, Fenamidone, a kind of in pefurazoate, or oxazole class sterilization Cheng Fen famoxadone, one in Wakil.Preferably, above-mentioned sterilization component is the one in orysastrobin, pyraclostrobin, Tebuconazole, zineb, S-Ethyl ethylthio sulfonate, cyprodinil, polyoxin.
Above-mentioned agriculturally useful compositions processing of the present invention is mixed with suspending agent, granule, wetting powder, water dispersible granules, microemulsion or aqueous emulsion, preferably, is mixed with suspending agent or granule.
Present invention also offers the purposes of above-mentioned agriculturally useful compositions for controlling crop diseases and insect pests, described damage by disease and insect is nematode, two spotted spider mite, blister mite, trialeurodes vaporariorum, rice fulgorid, diamond-back moth, flea beetle, tea lesser leafhopper, thrips, beet armyworm, rice leaf roller, aphid, scale insect, rice gall midge, powdery mildew, rust, downy mildew, epidemic disease, banded sclerotial blight, spot defoliation, canker etc., preferably, insect is two spotted spider mite or blister mite.Disease is nematode or powdery mildew.
Composition of the present invention compared with prior art, produces following beneficial effect:
(1) oligosaccharides of the present invention and sulphur can improve the effect of other Insecticiding-miticiding composition or sterilization component as building component.
(2) successful of agriculturally useful compositions of the present invention to crop pest or insect pest improves, and is beneficial to and reduces dosage or times for spraying;
(3) composition pesticide expands application target and effect, and a dispenser can pest control simultaneously and disease, improves crop growing state;
(4) mechanism of action due to active component in composition pesticide is different, and according to pest resistance to insecticide theory and practice, its application can delay the resistance development of damage by disease and insect to medicament, extends single dose service life.
Embodiment
The following stated, only for explaining the present invention, for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belongs to the scope of protection of present invention.
Embodiment 160% oligosaccharides sulphur Abamectin
Oligosaccharides 0.5g, sulphur 59g, Avermectin 0.5g, naphthalenesulfonate formaldehyde condensation compound 5g, sodium alkyl benzene sulfonate 5g, fine sand 10g, bentonite 20g are mixed, mixture is carried out granulation after ultra-fine grinding, drying, screening, both made 60% oligosaccharides sulphur Abamectin.
Embodiment 240% oligosaccharides sulphur tebuconazole suspension concentrates
Oligosaccharides 1g, sulphur 29g, Tebuconazole 10g, sodium lignin sulfonate 3g, the withered powder 5g of tea, bentonite 5g, Magnesiumaluminumsilicate 2g, ethylene glycol 5g are fully mixed, the 15g that adds water fully grinds, and water complements to 100g, is mixed with 40% oligosaccharides sulphur tebuconazole suspension concentrates.
Embodiment 3 chitosan oligosaccharide and sulphur prevent and treat the effect of nematode as building component
For macrolide constituents Avermectin, emamectin benzoate and organophosphorus insecticide composition fosthiazate, isazofos, illustrate that chitosan oligosaccharide and sulphur composition prevent and treat the effect of nematode as building component.Compost is mixed into sterilized soil and sterilizing river sand, be mixed into the granule of composition or single dose, fully mix thoroughly, add clear water and make water content 40%, load basin alms bowl, growth 20d cotton plants is transplanted in basin, 10d after transplanting, every basin access Meloidogyne incognita 2 instar larvae 500, be placed in greenhouse, quantitative watering manages.If often process 3 repetitions, according to trial test, if different single doses, binary mixture, ternary mixture and blank process.After 30d, when blank plant rhizosphere has a large amount of root knot, investigation records every strain average root footing, and carry out classification by Liu Weizhi (1995): 0 grade, without root knot; 1 grade, 1-2 root knot; 2 grades, 3-10 root knot; 3 grades, 11-30 root knot; 4 grades, 31-100 root knot; 5 grades, more than 100 root knots.The results are shown in Table 1.
Table 1 chitosan oligosaccharide and sulphur are as the effect of building component to nematode
Chitosan oligosaccharide and sulphur as building component to the effect of Avermectin, emamectin benzoate, fosthiazate, isazofos in table 1.Can find out, under certain medication, the combined treatment of chitosan oligosaccharide and sulphur is few compared with the root knot number of sulphur process and chitosan oligosaccharide process respectively to Levant Cotton Root footing, sulphur and Avermectin combine, sulphur and emamectin benzoate combines, sulphur and fosthiazate combines, sulphur and isazofos combine Levant Cotton Root footing all few compared with the root knot number of its single component, and chitosan oligosaccharide and Avermectin combine, chitosan oligosaccharide and emamectin benzoate combines, chitosan oligosaccharide and fosthiazate combines, chitosan oligosaccharide and isazofos combine Levant Cotton Root footing few compared with the root knot number of its single component; And add the composition of sulphur and chitosan oligosaccharide respectively in Avermectin, emamectin benzoate, fosthiazate, isazofos, Levant Cotton Root footing is 0 or 1 respectively, and sick level is 0 grade or 1 grade.Visible, in four ternary compositions, arbitrary ternary composition is significantly better than the effect of arbitrary single dose and the combination of any two single doses in ternary to the preventive effect of root-knot nematode.Surprisingly, relative to single component, appoint triple combination and appoint binary combination to have cotton plants and promote leaf effect in green, strong sprout, and obvious to the sensory effects of cotton plants relative to binary combination of triple combination.Visible, the composition of chitosan oligosaccharide, sulphur can improve the effect of control nematode as building component, and have promote that leaf is green, strong sprout effect.
Embodiment 4 chitosan oligosaccharide and sulphur are as the effect of building component to apple pest
To kill acaricidal composition spiral shell mite ester, Bifenazate, chitosan oligosaccharide and the sulphur composition effect as building component is described.At experimental field apple flower later stage listing mark, before dispenser investigation list two spotted spider mite on branch, a situation arises for powdery mildew.Accurate respectively different medicine components is mixed with suspending agent, dilutes before carrying out medicine according to dosing, use manual sprayer even spraying, often process spray 1 strain, and establish corresponding medicament to contrast and blank.After medicine, 10d investigation process two spotted spider mite of respectively listing is sprayed 1 time after a situation arises again, and after the 2nd medicine, 7d investigation is listed, and a situation arises for process powdery mildew, and observe growing way situation.Statistics is in table 2.
Table 2 chitosan oligosaccharide and sulphur are as the effect of building component to apple pest
Chitosan oligosaccharide and sulphur as building component to the effect of apple pest in table 2.Can find out, under specific dosage, the combination mixture of sulphur and chitosan oligosaccharide is to the preventive effect of European red mite, apple mildew all higher than the effect of chitosan oligosaccharide single dose, sulphur single dose, and the combination mixture of sulphur and chitosan oligosaccharide is to apple leaf look greener; Chitosan oligosaccharide and spiral shell mite ester combine, chitosan oligosaccharide and Bifenazate combine the effect of European red mite and apple mildew all high compared with the effect of single component, and leaf look greener; Sulphur and spiral shell mite ester combine, sulphur and Bifenazate combine the effect of European red mite all high compared with the effect of its single component, and leaf look greener; In addition, the process adding the composition of sulphur and chitosan oligosaccharide respectively in spiral shell mite ester, Bifenazate to the effect of two spotted spider mite and powdery mildew all higher than triple combination in the effect of arbitrary single dose and the combination of any two single doses, and leaf look dark green.So chitosan oligosaccharide and sulphur have synergistic effect as building component to spiral shell mite ester, Bifenazate, and plant growing way is good, be beneficial to and reduce dosage and increasing both production and income.
Embodiment 5 chitosan oligosaccharide and sulphur are as the effect of building component to oranges and tangerines damage by disease and insect
For insecticidal constituent spiral shell worm ethyl ester, pyridaben, chitosan oligosaccharide and the sulphur composition effect as building component is described.Spend later stage listing mark at experimental field oranges and tangerines, before dispenser investigation list powdery mildew on branch, a situation arises for blister mite.Accurate respectively different medicine components is mixed with suspending agent, dilutes before carrying out medicine according to dosing, use manual sprayer even spraying, often process spray 1 strain, and establish corresponding medicament to contrast and blank.After medicine, 10d sprays 1 time after investigating the generation quantity of process blister mite of respectively listing again, and after the 2nd medicine, 7d investigation is listed, and a situation arises for process powdery mildew, and observe growing way situation.Statistics is in table 3.
Table 3 chitosan oligosaccharide and sulphur are as the effect of building component to oranges and tangerines damage by disease and insect
Chitosan oligosaccharide and sulphur as building component to the effect of oranges and tangerines damage by disease and insect in table 3.Can find out, under specific dosage, the combination of sulphur and chitosan oligosaccharide is to the preventive effect of oranges and tangerines blister mite and oranges and tangerines powdery mildew all higher than the effect of chitosan oligosaccharide single dose, sulphur single dose, and the combination of sulphur and chitosan oligosaccharide is to oranges and tangerines leaf look greener; Chitosan oligosaccharide and spiral shell worm ethyl ester combine, chitosan oligosaccharide and pyridaben combine the effect of the single component that the effect of oranges and tangerines blister mite and oranges and tangerines powdery mildew all comparatively combines high, and leaf look greener; Sulphur and spiral shell worm ethyl ester combine, sulphur and pyridaben combine the effect of oranges and tangerines blister mite all high compared with the effect of its single component, and leaf look greener; In addition, the process adding the composition of sulphur and chitosan oligosaccharide respectively in spiral shell worm ethyl ester, pyridaben to the effect of blister mite and powdery mildew all higher than ternary in the effect of arbitrary single dose and the combination of any two single doses, and leaf look dark green.So chitosan oligosaccharide and sulphur have synergistic effect as building component to spiral shell worm ethyl ester, pyridaben, and plant growing way is good, be beneficial to and reduce dosage and increasing both production and income.
Embodiment 6 chitosan oligosaccharide and sulphur are as the effect of building component to wheat powdery mildew
Single compound or composition are prepared into the suspending agent mother liquor of 1000mg/L.According to trial test, a certain amount of above-mentioned mother liquor 0.1% Tween 80 is diluted, is mixed with the concentration of needs.During mensuration, first liquid medicine jet is imposed on potted plant wheat plant, then inoculate the former bacterium of wheat powdery mildew, moisturizing is placed in greenhouse and cultivates, measure the percentage that plant leaf surface infects after certain hour after cultivating 24h.Use Abbot formula, convert percentage to preventive effect.The results are shown in Table 4.
Table 4 chitosan oligosaccharide and sulphur are as the effect of building component to sterilization component
Chitosan oligosaccharide and sulphur as sterilization building component to the effect of wheat powdery mildew in table 4.Can find out, under specific dosage, the combination of sulphur and chitosan oligosaccharide is to the preventive effect of wheat powdery mildew all higher than the effect of chitosan oligosaccharide single dose, sulphur single dose, and the combination mixture of sulphur and chitosan oligosaccharide is to wheat leaf look greener; Chitosan oligosaccharide and orysastrobin combine, chitosan oligosaccharide and pyraclostrobin combines, chitosan oligosaccharide and Tebuconazole combines, chitosan oligosaccharide and zineb combines, chitosan oligosaccharide and S-Ethyl ethylthio sulfonate, chitosan oligosaccharide and cyprodinil, chitosan oligosaccharide and polyoxin all high compared with the effect of its single component to the effect of wheat powdery mildew, and leaf look greener; And can find out, sulphur and orysastrobin, sulphur and pyraclostrobin, sulphur and Tebuconazole, sulphur and zineb, sulphur and S-Ethyl ethylthio sulfonate, sulphur and cyprodinil, sulphur and polyoxin all high compared with the effect of its single component to the effect of wheat powdery mildew, and leaf look greener; The composition of sulphur and chitosan oligosaccharide is added respectively in orysastrobin, pyraclostrobin, Tebuconazole, zineb, S-Ethyl ethylthio sulfonate, cyprodinil, polyoxin, to the effect of wheat powdery mildew all higher than the effect of single dose arbitrary in ternary and the combination of any two single doses, and leaf look dark green.So chitosan oligosaccharide and sulphur have synergistic effect as sterilization building component to orysastrobin, pyraclostrobin, Tebuconazole, zineb, S-Ethyl ethylthio sulfonate, cyprodinil, polyoxin, and wheat growing way is good, be beneficial to and reduce dosage and increasing both production and income.
Claims (4)
1. oligosaccharides and sulphur are as the agriculturally useful compositions of building component, containing oligosaccharides, sulphur and other Insecticiding-miticiding composition in said composition, wherein, the ratio of quality and the number of copies of oligosaccharides, sulphur and other Insecticiding-miticiding compositions is 1:9:1, in above-mentioned composition, oligosaccharides is chitosan oligosaccharide, and Insecticiding-miticiding composition is the one in Avermectin, emamectin benzoate.
2. agriculturally useful compositions according to claim 1, agriculturally useful compositions is mixed with suspending agent, granule, wetting powder, water dispersible granules, microemulsion or aqueous emulsion.
3. agriculturally useful compositions according to claim 2, agriculturally useful compositions processing is mixed with suspending agent or granule.
4. the agriculturally useful compositions of claim 3 is for preventing and treating the purposes of crop pest, and described disease is nematode.
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