CN103918696A - Insecticidal composition containing compound improved from chlorantraniliprole and anabasine compounds - Google Patents

Insecticidal composition containing compound improved from chlorantraniliprole and anabasine compounds Download PDF

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Publication number
CN103918696A
CN103918696A CN201310015879.2A CN201310015879A CN103918696A CN 103918696 A CN103918696 A CN 103918696A CN 201310015879 A CN201310015879 A CN 201310015879A CN 103918696 A CN103918696 A CN 103918696A
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insect amide
chlorantraniliprole
tetrachloro insect
tetrachloro
weight ratio
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张秋芳
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Shanxi Thompson Biological Technology Co Ltd
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Shanxi Thompson Biological Technology Co Ltd
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Abstract

A disclosed insecticidal composition containing a compound improved from chlorantraniliprole (the compound has a full name of 3-bromo-N-(2,4-chloro-6-(methylformamide)phenyl)-1-(3,5-dichloro-2-pyridinyl)-1H-pyrazole-5-carboxamide and CAS No. 1104384-14-6) and anabasine insecticide is an insecticide composition containing an active composition A and an active composition B, wherein the active composition A is the compound improved from chlorantraniliprole, and the active composition B is any one selected from the following compounds: thiamethoxam, thiacloprid, imidacloprid, nitenpyram, clothianidin, acetamiprid and dinotefuran, and the weight ratio of the active composition A to the active composition B is 1:80-60:1. The composition has synergic effect on multiple insects harmful to agriculture production, the pesticide usage amount is reduced, the pesticide residual quantity on crops is reduced, the environment pollution is mitigated, and the composition is safe to people and livestock, good in environment compatibility and insusceptible to enable insects to generate pesticide resistance.

Description

A kind of Pesticidal combination containing tetrachloro insect amide and anabasine
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of Pesticidal combination containing tetrachloro insect amide and anabasine on crop pests.
Background technology
Tetrachloro insect amide: compound insecticidal spectrum approaches Rynaxypyr, laboratory's activity, the imitation of leaf roll snout moth's larva and borer is equal to or higher than 20% Rynaxypyr, but use 15 milliliters of meterings/bag higher than Rynaxypyr (equaling 1.5 bag Rynaxypyr doses), so in actual use, extremely worm velocity ratio is very fast, the lasting period is longer.
Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid or MTI-446 all belong to Novel tobacco alkaloid compound, act on the nicotinic acid acetylcholinergic receptor of insect, having stronger interior suction, tag and stomach poison function, is the specific drug of controlling sucking insects and chewing type insect.
But in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really have a synergistic effect composite seldom, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, find after tetrachloro insect amide and Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446 is composite to produce good synergistic effect, and not yet open about the composite relevant report of tetrachloro insect amide and Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good Pesticidal combination containing tetrachloro insect amide and anabasine.The Pesticidal combination that the present invention proposes contains active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from tetrachloro insect amide, active component B is selected from the one in Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446, and active components A and the preferred weight ratio of active component B are 1 ︰ 60 ~ 40 ︰ 1; More preferably the weight ratio of tetrachloro insect amide and Diacloden is 1 ︰ 20 ~ 10 ︰ 1, the weight ratio of tetrachloro insect amide and thiacloprid is 1 ︰ 30 ~ 10 ︰ 1, the weight ratio of tetrachloro insect amide and Imidacloprid is 1 ︰ 20 ~ 10 ︰ 1, the weight ratio of tetrachloro insect amide and Nitenpyram is 1 ︰ 20 ~ 20 ︰ 1, the weight ratio of tetrachloro insect amide and clothianidin is 1 ︰ 20 ~ 10 ︰ 1, the weight ratio of tetrachloro insect amide and Acetamiprid is 1 ︰ 20 ~ 20 ︰ 1, and the weight ratio of tetrachloro insect amide and MTI-446 is 1 ︰ 20 ~ 5 ︰ 1; The weight ratio that most preferably is tetrachloro insect amide and Diacloden or Imidacloprid is 1 ︰ 10 ~ 5 ︰ 1, the weight ratio of tetrachloro insect amide and thiacloprid is 1 ︰ 15 ~ 5 ︰ 1, the weight ratio of tetrachloro insect amide and Nitenpyram is 1 ︰ 10 ~ 10 ︰ 1, and the weight ratio of tetrachloro insect amide and clothianidin is 1 ︰ 10 ~ 5 ︰ 1; The weight ratio of tetrachloro insect amide and Acetamiprid is 1 ︰ 10 ~ 10 ︰ 1; The weight ratio of tetrachloro insect amide and MTI-446 is 1 ︰ 12 ~ 1 ︰ 1.
The purposes of the Pesticidal combination containing tetrachloro insect amide that the present invention proposes for preventing and treating insect on crops, described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop; Described insect comprises that rice leaf roller, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, flea beetle, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resemble, heart-eating worm, rice leafhopper or apple leaf miner.
The weight ratio of active components A, active component B is 1 ︰ 80 ~ 60 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5%~90%, is preferably 5%~80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%~70% active substance by weight, is preferably 5%~50%; Solid pharmaceutical preparation contains 5%~80% active substance by weight, is preferably 10%~80%.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Pesticidal combination of the present invention, can be processed on demand acceptable formulation on any agricultural chemicals, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, microcapsule suspending agent, suspension emulsion, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, defoamer 0.01% ~ 2%, solvent 1% ~ 15%, thickener 0 ~ 2%, emulsifier 2% ~ 12%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making microemulsion, composition comprises following component and content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0 ~ 8%, thickener 0 ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 1% ~ 10%, defoamer 0.01% ~ 2%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, organic solvent 1% ~ 15%, emulsifier 1% ~ 6%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) tetrachloro insect amide and Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446 composite after, there is obvious synergy and lasting effect; (2) cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop insect are all had to greater activity; (3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1~18 wetting powder
Tetrachloro insect amide, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, after airslide disintegrating mill is pulverized, mix again, can make wetting powder product of the present invention, specifically in table 1.
The each component of table 1 embodiment 1~18 and weight portion
Embodiment 19~36 water dispersible granules
Tetrachloro insect amide, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can make water dispersible granules product of the present invention, specifically in table 2.
The each component of table 2 embodiment 19~36 and weight portion
Embodiment 37~54 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), mix through high speed shear, add tetrachloro insect amide, active component B, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in table 3.
The each component of table 3 embodiment 37~54 and weight portion
Embodiment 55~72 aqueous emulsions
Tetrachloro insect amide, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in table 4.
The each component of table 4 embodiment 55~72 and weight portion
Embodiment 73~79 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), deionized water are mixed through high speed shear, add tetrachloro insect amide, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, make tetrachloro insect amide suspending agent, then by active component B, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.Specifically in table 4.
The each component of table 5 embodiment 73~79 and content
Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446 in table 1 ~ 5 are exchanged, can make novel formulation.
Embodiment 80~82 microemulsions
Tetrachloro insect amide, active component B are dissolved in the homogenizer that solvent is housed, emulsifier, antifreeze (can add and can not add), defoamer are joined in the homogenizer that above-mentioned solution is housed, surplus gives strong mixing and homogenize after supplying by deionized water, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance, specifically in table 6.
The each component of table 6 embodiment 80~82 and content
Embodiment 83,84 microcapsule suspending agents
Tetrachloro insect amide, active component B, macromolecule cyst material, solvent, defoamer are mixed, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, and bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, make the finely disseminated microcapsule suspending agent product of the present composition, specifically in table 7.
Table 7 embodiment 83,84 each component and weight portions
Embodiment 85,86 microcapsule suspensions~suspending agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add tetrachloro insect amide, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, makes the finely disseminated microcapsule suspension ~ suspending agent of present composition product.Specifically in table 8.
Table 9 embodiment 85,86 each component and content
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration when test, is placed in respectively beaker for subsequent use.Adopt and first soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination larva, under 25 DEG C of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC 50value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament, calculates co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (taking tetrachloro insect amide as standard medicament, its toxicity index is 100):
TI × the P of theoretical toxicity index (TTI)=tetrachloro insect amide of M tetrachloro insect amide+tI × P of effective active composition B effective active composition B
In formula: the mixture that M is different proportionings
P effective active composition Bfor effective active composition B shared ratio in composition
P tetrachloro insect amidefor tetrachloro insect amide shared ratio in composition
B is selected from the one in Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446.
Application Example two:
For trying insect: paddy rice rice leaf roller
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and Diacloden and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 9 tetrachloro insect amide and the Thiamethoxam compound toxicity test analysis of results table to paddy rice rice leaf roller
Reagent agent Proportioning LC 50(ugmL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.57 -
Diacloden - 1.03 -
Four chlorantraniliprole ︰ Diaclodens 60∶1 0.325 176.68
Four chlorantraniliprole ︰ Diaclodens 40∶1 0.311 185.30
Four chlorantraniliprole ︰ Diaclodens 20∶1 0.302 192.84
Four chlorantraniliprole ︰ Diaclodens 10∶1 0.294 202.08
Four chlorantraniliprole ︰ Diaclodens 5∶1 0.286 215.33
Four chlorantraniliprole ︰ Diaclodens 1∶1 0.325 225.81
Four chlorantraniliprole ︰ Diaclodens 1∶2 0.341 238.02
Four chlorantraniliprole ︰ Diaclodens 1∶4 0.378 234.62
Four chlorantraniliprole ︰ Diaclodens 1∶6 0.412 224.16
Four chlorantraniliprole ︰ Diaclodens 1∶10 0.445 215.64
Four chlorantraniliprole ︰ Diaclodens 1∶20 0.473 209.70
Four chlorantraniliprole ︰ Diaclodens 1∶40 0.506 199.63
Four chlorantraniliprole ︰ Diaclodens 1∶60 0.537 189.30
Four chlorantraniliprole ︰ Diaclodens 1∶80 0.578 176.44
As shown in Table 9, tetrachloro insect amide and Diacloden to paddy rice rice leaf roller proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and Diacloden is during at 1 ︰ 20 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 200.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and Diacloden weight ratio are 1:2, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and Diacloden proportioning are 10:1 through applicant, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example three
For trying insect: rice hoppers
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and thiacloprid and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice hoppers of table 10 tetrachloro insect amide and thiacloprid
Reagent agent Proportioning LC 50(ugmL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.59 -
Thiacloprid - 1.25 -
Four chlorantraniliprole ︰ thiacloprids 60∶1 0.298 199.72
Four chlorantraniliprole ︰ thiacloprids 40∶1 0.286 208.99
Four chlorantraniliprole ︰ thiacloprids 20∶1 0.275 220.08
Four chlorantraniliprole ︰ thiacloprids 10∶1 0.271 228.69
Four chlorantraniliprole ︰ thiacloprids 5∶1 0.268 241.39
Four chlorantraniliprole ︰ thiacloprids 1∶1 0.315 254.49
Four chlorantraniliprole ︰ thiacloprids 1∶3 0.357 273.62
Four chlorantraniliprole ︰ thiacloprids 1∶6 0.402 268.10
Four chlorantraniliprole ︰ thiacloprids 1∶12 0.446 258.06
Four chlorantraniliprole ︰ thiacloprids 1∶15 0.472 247.52
Four chlorantraniliprole ︰ thiacloprids 1∶20 0.498 238.31
Four chlorantraniliprole ︰ thiacloprids 1∶30 0.533 226.35
Four chlorantraniliprole ︰ thiacloprids 1∶40 0.562 216.51
Four chlorantraniliprole ︰ thiacloprids 1∶60 0.594 206.65
Four chlorantraniliprole ︰ thiacloprids 1∶80 0.651 189.40
As shown in Table 10, tetrachloro insect amide and thiacloprid to rice hoppers proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and thiacloprid is during at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 225.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and thiacloprid weight ratio are 1:3, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and thiacloprid proportioning are 10:1 through applicant, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1:20, 1:25, when 1:30, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example four
For trying insect: rice hoppers
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and Imidacloprid and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice hoppers of table 11 tetrachloro insect amide and Imidacloprid
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.61 -
Imidacloprid - 1.12 -
Four chlorantraniliprole ︰ Imidacloprids 60∶1 0.331 185.68
Four chlorantraniliprole ︰ Imidacloprids 40∶1 0.316 195.21
Four chlorantraniliprole ︰ Imidacloprids 20∶1 0.307 203.10
Four chlorantraniliprole ︰ Imidacloprids 10∶1 0.292 217.93
Four chlorantraniliprole ︰ Imidacloprids 5∶1 0.289 228.41
Four chlorantraniliprole ︰ Imidacloprids 1∶1 0.328 240.80
Four chlorantraniliprole ︰ Imidacloprids 1∶2 0.345 253.88
Four chlorantraniliprole ︰ Imidacloprids 1∶4 0.386 248.59
Four chlorantraniliprole ︰ Imidacloprids 1∶6 0.414 241.67
Four chlorantraniliprole ︰ Imidacloprids 1∶10 0.452 230.28
Four chlorantraniliprole ︰ Imidacloprids 1∶20 0.491 219.37
Four chlorantraniliprole ︰ Imidacloprids 1∶40 0.523 209.87
Four chlorantraniliprole ︰ Imidacloprids 1∶60 0.558 198.00
Four chlorantraniliprole ︰ Imidacloprids 1∶80 0.592 187.26
As shown in Table 11, tetrachloro insect amide and Imidacloprid to rice hoppers proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and Imidacloprid is during at 1 ︰ 20 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and Imidacloprid weight ratio are 1:2, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and Imidacloprid proportioning are 10:1 through applicant, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example five
For trying insect: view and admire chrysanthemum aleyrodid
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and Nitenpyram and the two different proportioning mixture through preliminary experiment.
Table 12 tetrachloro insect amide and Nitenpyram are composite to viewing and admiring the toxicity test analysis of results table of chrysanthemum aleyrodid
Reagent agent Proportioning LC 50(ugmL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.55 -
Nitenpyram - 0.59 -
Four chlorantraniliprole ︰ Nitenpyrams 60∶1 0.295 186.65
Four chlorantraniliprole ︰ Nitenpyrams 40∶1 0.274 201.06
Four chlorantraniliprole ︰ Nitenpyrams 20∶1 0.261 211.41
Four chlorantraniliprole ︰ Nitenpyrams 10∶1 0.249 222.25
Four chlorantraniliprole ︰ Nitenpyrams 4∶1 0.235 237.26
Four chlorantraniliprole ︰ Nitenpyrams 2∶1 0.227 247.89
Four chlorantraniliprole ︰ Nitenpyrams 1∶1 0.221 257.60
Four chlorantraniliprole ︰ Nitenpyrams 1∶2 0.232 248.29
Four chlorantraniliprole ︰ Nitenpyrams 1∶4 0.245 237.36
Four chlorantraniliprole ︰ Nitenpyrams 1∶10 0.258 227.18
Four chlorantraniliprole ︰ Nitenpyrams 1∶20 0.273 215.37
Four chlorantraniliprole ︰ Nitenpyrams 1∶40 0.287 205.21
Four chlorantraniliprole ︰ Nitenpyrams 1∶60 0.295 199.76
Four chlorantraniliprole ︰ Nitenpyrams 1∶80 0.314 187.73
As shown in Table 12, tetrachloro insect amide and Nitenpyram are to viewing and admiring chrysanthemum aleyrodid proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and Nitenpyram is during at 1 ︰ 20 ~ 20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 210.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and Nitenpyram weight ratio are 1:1, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and Nitenpyram proportioning are 20:1 through applicant, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example six
For trying insect: tomato aleyrodid
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and clothianidin and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to tomato aleyrodid of table 13 tetrachloro insect amide and clothianidin
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.58 -
Clothianidin - 0.94 -
Four chlorantraniliprole ︰ clothianidins 60∶1 0.321 181.83
Four chlorantraniliprole ︰ clothianidins 40∶1 0.303 193.22
Four chlorantraniliprole ︰ clothianidins 20∶1 0.291 203.02
Four chlorantraniliprole ︰ clothianidins 10∶1 0.284 211.59
Four chlorantraniliprole ︰ clothianidins 5∶1 0.271 228.61
Four chlorantraniliprole ︰ clothianidins 1∶1 0.295 243.18
Four chlorantraniliprole ︰ clothianidins 1∶2 0.304 256.20
Four chlorantraniliprole ︰ clothianidins 1∶4 0.337 248.13
Four chlorantraniliprole ︰ clothianidins 1∶6 0.359 240.51
Four chlorantraniliprole ︰ clothianidins 1∶10 0.395 225.26
Four chlorantraniliprole ︰ clothianidins 1∶20 0.423 215.84
Four chlorantraniliprole ︰ clothianidins 1∶40 0.457 202.62
Four chlorantraniliprole ︰ clothianidins 1∶60 0.484 192.26
Four chlorantraniliprole ︰ clothianidins 1∶80 0.521 179.05
As shown in Table 13, tetrachloro insect amide and clothianidin to tomato aleyrodid proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and clothianidin is during at 1 ︰ 20 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 210.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and clothianidin weight ratio are 1:2, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and clothianidin proportioning are 10:1 through applicant, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example seven
For trying insect: vegetable aphid
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and Acetamiprid and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to vegetable aphid of table 14 tetrachloro insect amide and Acetamiprid
Reagent agent Proportioning LC 50(ugmL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.62 -
Acetamiprid - 0.75 -
Four chlorantraniliprole ︰ Acetamiprids 60∶1 0.337 184.50
Four chlorantraniliprole ︰ Acetamiprids 40∶1 0.301 206.85
Four chlorantraniliprole ︰ Acetamiprids 20∶1 0.29 215.57
Four chlorantraniliprole ︰ Acetamiprids 10∶1 0.281 224.17
Four chlorantraniliprole ︰ Acetamiprids 4∶1 0.275 233.55
Four chlorantraniliprole ︰ Acetamiprids 2∶1 0.271 242.81
Four chlorantraniliprole ︰ Acetamiprids 1∶1 0.264 257.13
Four chlorantraniliprole ︰ Acetamiprids 1∶2 0.281 249.47
Four chlorantraniliprole ︰ Acetamiprids 1∶4 0.305 236.00
Four chlorantraniliprole ︰ Acetamiprids 1∶10 0.327 225.07
Four chlorantraniliprole ︰ Acetamiprids 1∶20 0.342 217.13
Four chlorantraniliprole ︰ Acetamiprids 1∶40 0.363 205.56
Four chlorantraniliprole ︰ Acetamiprids 1∶60 0.385 194.14
Four chlorantraniliprole ︰ Acetamiprids 1∶80 0.404 185.16
As shown in Table 14, tetrachloro insect amide and Acetamiprid to vegetable aphid proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and Acetamiprid is during at 1 ︰ 20 ~ 20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and Acetamiprid weight ratio are 1:1, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and Acetamiprid proportioning are 20:1 through applicant, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example eight
For trying insect: rice hoppers
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of tetrachloro insect amide and MTI-446 and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice hoppers of table 15 tetrachloro insect amide and MTI-446
Reagent agent Proportioning LC 50(ugmL) Co-toxicity coefficient (CTC)
Tetrachloro insect amide - 0.52 -
MTI-446 - 2.37 -
Four chlorantraniliprole ︰ MTI-446 60∶1 0.286 184.17
Four chlorantraniliprole ︰ MTI-446 40∶1 0.274 193.46
Four chlorantraniliprole ︰ MTI-446 20∶1 0.269 200.77
Four chlorantraniliprole ︰ MTI-446 10∶1 0.251 223.00
Four chlorantraniliprole ︰ MTI-446 5∶1 0.253 236.27
Four chlorantraniliprole ︰ MTI-446 1∶1 0.345 247.21
Four chlorantraniliprole ︰ MTI-446 1∶3 0.495 253.40
Four chlorantraniliprole ︰ MTI-446 1∶6 0.582 269.99
Four chlorantraniliprole ︰ MTI-446 1∶9 0.674 259.36
Four chlorantraniliprole ︰ MTI-446 1∶12 0.741 251.12
Four chlorantraniliprole ︰ MTI-446 1∶15 0.797 243.27
Four chlorantraniliprole ︰ MTI-446 1∶20 0.853 237.59
Four chlorantraniliprole ︰ MTI-446 1∶40 0.976 223.44
Four chlorantraniliprole ︰ MTI-446 1∶60 1.125 199.06
Four chlorantraniliprole ︰ MTI-446 1∶80 1.249 181.77
As shown in Table 15, tetrachloro insect amide and MTI-446 to rice hoppers proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of tetrachloro insect amide and MTI-446 is during at 1 ︰ 20 ~ 5 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 235.Wherein co-toxicity coefficient maximum in the time that tetrachloro insect amide and MTI-446 weight ratio are 1:6, synergistic effect is the most obvious.Test and find that tetrachloro insect amide and MTI-446 proportioning are 5:1 through applicant, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:10, 1:15, when 1:20, to the rice leaf roller in various crop, flea beetle, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the control of rice leafhopper or apple leaf miner has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Effect experiment part: test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 10% tetrachloro insect amide suspending agent (autogamy), 25% Diacloden wetting powder (commercial), 40% thiacloprid suspending agent (autogamy), 10% imidacloprid wettable powder (commercial), 10% Nitenpyram aqua (commercial), 50% clothianidin wetting powder (autogamy), 3% acetamiprid EC (commercial), 20% MTI-446 wetting powder (autogamy).
Application Example nine tetrachloro insect amides and active component B and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
This test arrangement is at Shaanxi Province's Hanzhong City, and before medicine, investigation paddy rice rice leaf roller insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 15 days, 30 days.Result of the test is as follows:
Table 16 tetrachloro insect amide and active component B and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 16, after tetrachloro insect amide and active component B are composite, can effectively prevent and treat paddy rice rice leaf roller, also can effectively prevent and treat rice hoppers, striped rice borer, paddy stem borer, rice stinkbug, rice leafhopper through inventor's evidence tetrachloro insect amide and active component B after composite, control efficiency is all higher than 96%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten tetrachloro insect amides and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and before medicine, investigation cucumber powder mite evil index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 17 tetrachloro insect amide and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof
As can be seen from Table 17, after tetrachloro insect amide and active component B are composite, can effectively prevent and treat cucumber aleyrodid, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 tetrachloro insect amides and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This test arrangement is in Weinan City Dali County, Shaanxi Province, and before medicine, investigation cotton cotton bollworm insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 10 days, 30 days.Result of the test is as follows:
Table 18 tetrachloro insect amide and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 18, tetrachloro insect amide and active component B and composite control cotton cotton bollworm thereof, also can effectively prevent and treat cotton aphid, pink bollworm, cotton boll after composite through inventor's evidence tetrachloro insect amide and active component B resembles, control efficiency is all higher than 97%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 12 tetrachloro insect amides and active component B and the composite control pear tree pear sucker test of pesticide effectiveness thereof
This test arrangement is in Xianyang, Shanxi province city, and before medicine, investigation pear tree pear sucker insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 10 days, 30 days.Result of the test is as follows:
Table 19 tetrachloro insect amide and active component B and the composite control pear tree pear sucker test of pesticide effectiveness thereof
As can be seen from Table 19, after tetrachloro insect amide and active component B are composite, can effectively prevent and treat pear tree pear sucker, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, also can effectively prevent and treat pear tree heart-eating worm through inventor's evidence tetrachloro insect amide and active component B after composite, control efficiency, all higher than 97%, has no adverse effects to target crop in test scope of medication.
Application Example 13 tetrachloro insect amides and active component B and the composite control ornamental plants thrips test of pesticide effectiveness thereof
This test arrangement is in nursery, Xi'an City, Shanxi Province, and before medicine, investigation ornamental plants thrips insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 20 tetrachloro insect amide and active component B and the composite control ornamental plants thrips test of pesticide effectiveness thereof
As can be seen from Table 20, tetrachloro insect amide and active component B and composite control ornamental plants thrips thereof, also can effectively prevent and treat ornamental plants flea beetle, aphid, scale insect through inventor's evidence tetrachloro insect amide and active component B after composite, control efficiency is all higher than 97%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 14 tetrachloro insect amides and active component B and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
This test arrangement is in Xi'an City, Shanxi Province, and before medicine, investigation wild cabbage diamond-back moth insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 21 tetrachloro insect amide and active component B and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
As can be seen from Table 21, tetrachloro insect amide and active component B and composite control wild cabbage diamond-back moth thereof, also can effectively prevent and treat cabbage pieris, beet armyworm, prodenia litura through inventor's evidence tetrachloro insect amide and active component B after composite, control efficiency is all higher than 97%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten the May 4th chlorantraniliproles and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This test arrangement is at Shaanxi Province's Hanzhong City, and investigation rice hoppers insect pest index before medicine, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 22 tetrachloro insect amide and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 22, tetrachloro insect amide and active component B and the composite rice hoppers of preventing and treating thereof, also can effectively prevent and treat rice-stem borer, paddy stem borer, rice leaf roller through inventor's evidence tetrachloro insect amide and active component B after composite, control efficiency is all higher than 97%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through different local throughout the country tests, tetrachloro insect amide and Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid, MTI-446 is composite to the rice leaf roller in various crop, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, flea beetle, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resembles, heart-eating worm, the preventive effect of the common insect such as rice leafhopper or apple leaf miner is all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.

Claims (6)

1. the Pesticidal combination containing tetrachloro insect amide and anabasine, effective active composition is active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from tetrachloro insect amide, and active component B is selected from the one in Diacloden, thiacloprid, Imidacloprid, Nitenpyram, clothianidin, Acetamiprid or MTI-446.
2. the Pesticidal combination containing tetrachloro insect amide and anabasine according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60 ~ 40 ︰ 1.
3. the Pesticidal combination containing tetrachloro insect amide and anabasine according to claim 2, is characterized in that:
The weight ratio of tetrachloro insect amide and Diacloden is 1 ︰ 20 ~ 10 ︰ 1;
The weight ratio of tetrachloro insect amide and thiacloprid is 1 ︰ 30 ~ 10 ︰ 1;
The weight ratio of tetrachloro insect amide and Imidacloprid is 1 ︰ 20 ~ 10 ︰ 1;
The weight ratio of tetrachloro insect amide and Nitenpyram is 1 ︰ 20 ~ 20 ︰ 1;
The weight ratio of tetrachloro insect amide and clothianidin is 1 ︰ 20 ~ 10 ︰ 1;
The weight ratio of tetrachloro insect amide and Acetamiprid is 1 ︰ 20 ~ 20 ︰ 1;
The weight ratio of tetrachloro insect amide and MTI-446 is 1 ︰ 20 ~ 5 ︰ 1.
4. according to the Pesticidal combination containing tetrachloro insect amide and anabasine described in any one in claims 1 to 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the purposes of the Pesticidal combination containing tetrachloro insect amide and anabasine according to claim 4 for preventing and treating insect on crops.
6. purposes according to claim 5, is characterized in that: described insect comprises that rice leaf roller, diamond-back moth, beet armyworm, prodenia litura, cabbage caterpillar, aleyrodid, tea lesser leafhopper, scale insect, aphid, thrips, rice fulgorid, flea beetle, longicorn, striped rice borer, paddy stem borer, rice stinkbug, pear sucker, cotton bollworm, pink bollworm, cotton boll resemble, heart-eating worm, rice leafhopper or apple leaf miner.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104186527A (en) * 2014-08-11 2014-12-10 广东中迅农科股份有限公司 Insecticidal composition containing 3-bromo-N-[2,4-dichloro-6-(methylamino formyl)phenyl]-1-(3,5-dichloro-2-pyridyl)-1H-pyrazole-5-carboxamide and dinotefuran
CN104413038A (en) * 2013-09-06 2015-03-18 沈阳化工研究院有限公司 Binary insecticide composition and application
CN104814023A (en) * 2015-05-02 2015-08-05 广东中迅农科股份有限公司 Insecticidal composition containing tetrachlorantraniliprole and hexaflumuron
CN107258793A (en) * 2017-05-28 2017-10-20 陕西康禾立丰生物科技药业有限公司 A kind of Pesticidal combination containing four Tolfenpyrads and anabasine
CN108651487A (en) * 2018-05-02 2018-10-16 赖振明 A kind of composition pesticide containing cephalotaxus alkaloids and four chlorantraniliproles
CN111513071A (en) * 2020-06-01 2020-08-11 沈阳化工研究院(南通)化工科技发展有限公司 Composition containing tetrachlorantraniliprole and dinotefuran and application thereof
CN111820223A (en) * 2020-06-18 2020-10-27 沈阳化工研究院(南通)化工科技发展有限公司 Tetrachlorantraniliprole and thiacloprid pesticide composition

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104413038A (en) * 2013-09-06 2015-03-18 沈阳化工研究院有限公司 Binary insecticide composition and application
CN104186527A (en) * 2014-08-11 2014-12-10 广东中迅农科股份有限公司 Insecticidal composition containing 3-bromo-N-[2,4-dichloro-6-(methylamino formyl)phenyl]-1-(3,5-dichloro-2-pyridyl)-1H-pyrazole-5-carboxamide and dinotefuran
CN104814023A (en) * 2015-05-02 2015-08-05 广东中迅农科股份有限公司 Insecticidal composition containing tetrachlorantraniliprole and hexaflumuron
CN104814023B (en) * 2015-05-02 2018-06-19 广东中迅农科股份有限公司 A kind of Pesticidal combination containing four chlorantraniliproles and flubenzuron
CN107258793A (en) * 2017-05-28 2017-10-20 陕西康禾立丰生物科技药业有限公司 A kind of Pesticidal combination containing four Tolfenpyrads and anabasine
CN108651487A (en) * 2018-05-02 2018-10-16 赖振明 A kind of composition pesticide containing cephalotaxus alkaloids and four chlorantraniliproles
CN111513071A (en) * 2020-06-01 2020-08-11 沈阳化工研究院(南通)化工科技发展有限公司 Composition containing tetrachlorantraniliprole and dinotefuran and application thereof
CN111820223A (en) * 2020-06-18 2020-10-27 沈阳化工研究院(南通)化工科技发展有限公司 Tetrachlorantraniliprole and thiacloprid pesticide composition

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