CN103109839A - Insecticidal composition containing penta-imidacloprid guanidine and metaflumizone and preparation thereof - Google Patents
Insecticidal composition containing penta-imidacloprid guanidine and metaflumizone and preparation thereof Download PDFInfo
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Abstract
The invention discloses an insecticidal composition containing penta-imidacloprid guanidine and metaflumizone and a preparation thereof, and can improve a control effect on rice leaf folders and beet armyworm pests. The insecticidal composition comprises the components of the penta-imidacloprid guanidine and the metaflumizone which serve as active ingredients, wherein the mass ratio of the penta-imidacloprid guanidine and the metaflumizone (1:20)-(40:1), and the preferable mass ratio is (1:5)-(10:1). The insecticidal composition has the advantages that (1) resistance pests can be controlled, and the development of insecticide resistance is delayed; (2) compared with a single dosage, the composition has a synergistic interaction effect and can improve the control effect; (3) the composition can replace a high-toxicity farm pesticide, the usage amount of the composition is reduced, pesticide residue in ecological environments is effectively reduced, and the composition is more safe and more environment-friendly.
Description
Technical field
The present invention relates generally to a kind of Pesticidal combination and preparation thereof, relates in particular to a kind of Pesticidal combination and preparation thereof that contains penta pyrrole worm guanidine and metaflumizone.
Background technology
Beet armyworm (Beet armyworm) formal name used at school Spodoptera exiguaHiibner is commonly called as the brown noctuid of Chinese cabbage, is under the jurisdiction of Lepidoptera, Noctuidae, be a kind of worldwide distribution, intermittent large occur take danger to vegetables as main polyphagous pest-insect.The vegetables such as shallot, wild cabbage, Chinese cabbage, celery, cauliflower, carrot, asparagus, water spinach, three-coloured amaranth, capsicum, cowpea, cauliflower, eggplant, cabbage mustard, tomato, cabbage heart, a variety of Chinese cabbage, broccoli, spinach, radish there is harm.At present the main chemical control medicament that uses has chlorfenapyr, indoxacarb, pleocidin, worm hydrazides, fluorine pyridine urea, Methomyl, beta-cypermethrin, poisons the medicament such as barnyard grass with poison, but use for a long time single medicament that beet armyworm is developed immunity to drugs, need increase gradually dosage, harm environment and human body are healthy.
Rice leaf roller belongs to Lepidoptera, Pyralidae.Another name is scraped blue or green worm.Distribution North gets Heilungkiang, the Inner Mongol, reach each rice district, the whole nation in Taiwan, Hainan in the south.The main harm paddy rice endangers wheat, sugarcane, grain, grassy weed etc. sometimes.Sew the vertical volume of silk rice leaf adult bud with larva, larva is hidden to occupy and wherein takes food mesophyll, only stays epidermis, forms white streak, causes paddy rice thousand kernel weight and reduces, and blighted grain increases, and causes the underproduction.Use single chemical pesticide such as husky the moon endotoxin medicament and the organophosphorus insecticides such as dimehypo, desinsection list throughout the year, make insect produce high resistance, dosage improves year by year, and the rice residue of pesticide exceed standard.
The inventor finds after deliberation, and the composite use under the certain proportion scope of penta pyrrole worm guanidine and metaflumizone has synergistic effect, and rice leaf roller and beet armyworm are had control efficiency preferably.
Penta pyrrole worm guanidine, English name Guadipyr, chemical name: 1-nitro-3-[(6-chloropyridine-3-yl) methyl]-4-penta methene amido guanidine, belong to nitro contracting aminoguanidine compounds, it is the brand-new insecticide of a kind of efficient, wide spectrum, low toxicity, low-residual, have the architectural feature of anabasine insecticide and sodium-ion channel inhibitor insecticides concurrently, thereby also have the insecticidal spectrum of this two insecticides concurrently, be with a wide range of applications, characteristics with multiaction target, the speed that insect is developed immunity to drugs reduces greatly.This low cost product can be widely used in the control of cereal crops, economic crops, fruit tree, vegetables and injurious forest-insect.
Metaflumizone, english common name: metaflumizone, chemical name: (E+Z)-2-[2-(4-cyano group benzene)-1-(3 trifluoromethylbenzene) ethylidene]-N-(4 trifluomethoxybenzene) hydrazine carbonyl oxamides.Metaflumizone belongs to the semicarbazones insecticides, and mechanism of action is unique, on the acceptor that is attached to sodium-ion channel, hinders sodium ion current, with the compound of chrysanthemum ester class or other kinds without cross resistance.Itself has insecticidal activity, does not need bioactivation.This medicine is mainly to take food to enter in its body by insect stomach toxicity occurs to kill off the insect pests, and action of contace poison is less, without systemic action.Metaflumizone can be prevented and treated larva, the adult of various places lepidoptera pest and some coleoptera effectively, can also be used for the insects such as control ant, termite, fly class, cicada dung beetle, but invalid to ovum and the lepidopterous adult of Lepidoptera and coleoptera.
Due to particular mechanism of action both, can prevent and treat resistant insect, delay drug-fast development, safety is good.
Summary of the invention
The object of the invention is exactly for a kind of Pesticidal combination and preparation thereof that contains penta pyrrole worm guanidine and metaflumizone being provided, can improving the preventive effect to rice leaf roller and beet armyworm insect.。
The present invention is achieved by the following technical solutions:
A kind of Pesticidal combination that contains penta pyrrole worm guanidine and metaflumizone, its active ingredient are penta pyrrole worm guanidine and metaflumizone, and the mass ratio of described penta pyrrole worm guanidine and metaflumizone is 1: 20-40: 1.
The mass ratio of described penta pyrrole worm guanidine and metaflumizone is preferably 1: 5-10: 1.
The present invention contains the Pesticidal combination of penta pyrrole worm guanidine and metaflumizone, can be mixed with any application forms that is fit to agricultural use according to the known side of those skilled in the art of the present technique, preferred dosage form is missible oil, suspending agent, microemulsion, water dispersible granules or wetting powder.Described preparation adds adjuvant in preparation process, in described preparation, the mass percentage content of active ingredient is 1～95%.In described preparation, the mass percentage content of active ingredient is preferably 10-60%.
Usual auxiliaries is one or more the mixing in solvent, emulsifier, dispersant, wetting agent, defoamer, antifreezing agent, stabilizing agent, thickener, PH conditioning agent, filler etc., be known substance, various auxiliary agents commonly used in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
missible oil, spendable auxiliary agent: one or more combinations in cyclohexanone, acetone, dimethylacetylamide, methyl alcohol, dimethyl sulfoxide (DMSO), solvent can be one or more combinations in dimethylbenzene, toluene, vegetable oil, methyl oleate, solvent naphtha, the emulsifier agent can be alkylbenzenesulfonate (No. 500, agriculture breast), fatty alcohol polyoxyethylene ether sulfate (AES), alkylphenol polyoxyethylene (No. 100, agriculture breast), styryl phenol polyethenoxy ether (agricultural emulsifier NO．600), alkylphenol polyoxyethylene formaldehyde condensation products (Nongru-700 number), castor oil polyoxyethylene ether (BY, EL), fatty alcohol-polyoxyethylene ether, the aliphatic alcohol polyethenoxy ester, polyol fatty acid ester and ethylene oxide adduct (Span thereof, Tween series) any one multiple combination in.
Suspending agent, spendable auxiliary agent has: one or more in dispersant such as lignosulfonates, polycarboxylate, alkylnaphthalene sulfonate etc.; One or more in emulsifier such as agriculture breast 600#, Nongru-700 #, agriculture breast 2201, agriculture breast 1601, agriculture breast NP-10, agriculture breast 0425, agriculture breast 0408 etc.; In wetting agent such as alkyl phenol (or fatty alcohol) polyoxyethylene APEO and sulphate thereof (or phosphoric acid fat) salt, alkyl sulfate, alkylsulfonate, naphthalene sulfonate etc. one or more; One or more in thickener such as CMC, xanthic acid, polyvinyl alcohol, sodium alginate, gum Arabic, bentonite, white carbon, starch etc.; In antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, CaCl2, NaCl, PEG etc. one or more; Defoamer such as organic silicon defoamer; One or more in stabilizing agent such as epoxychloropropane, epoxidized vegetable oil, tributyl phosphate, alkylphenol polyoxyethylene phosphoric acid fat and salt thereof etc.
Water dispersible granules, spendable auxiliary agent has: one or more in dispersant such as lignosulfonates, polycarboxylate, alkylnaphthalene sulfonate etc.; One or more in wetting agent such as alkyl sulfate, alkylsulfonate, naphthalene sulfonate etc.; One or more in disintegrant such as sodium chloride, sodium sulphate, sodium carboxymethyl starch, ammonium sulfate, sodium carbonate, urea, sucrose, glucose etc.; One or more in binding agent such as gelatin, diatomite, corn starch, carboxymethyl cellulose, carboxyethyl cellulose, polyvinyl alcohol etc.; One or more in filler such as kaolin, fine particle calcium carbonate, potter's clay, White Carbon black, diatomite, talcum powder etc.
Wetting powder, spendable auxiliary agent has: one or more in dispersant such as lignosulfonates, polycarboxylate, alkylnaphthalene sulfonate etc.; Wetting agent is as one or more in alkyl sulfate, alkylsulfonate, naphthalene sulfonate etc.; One or more in filler such as kaolin, fine particle calcium carbonate, potter's clay, White Carbon black, diatomite, talcum powder etc.
The present invention carries out the indoor virulence biologicall test according to infusion process, take rice leaf roller and beet armyworm as target pest, calculate co-toxicity coefficient and estimate penta pyrrole worm guanidine effect mixed with metaflumizone, result shows co-toxicity coefficient all greater than 120, shows that mixing use both has the notable synergistic effect.In addition, in the test of pesticide effectiveness to rice leaf roller and beet armyworm, the insecticide of employing different proportionings of the present invention and penta pyrrole worm guanidine single dose, metaflumizone single dose compare, and insecticidal effect is higher than each single dose.
Therefore, Pesticidal combination of the present invention can be applied in control rice leaf roller and beet armyworm.
Advantage of the present invention is:
(1) can prevent and treat resistant insect, delay drug-fast development;
(2) compare with single dose, have synergistic effect, can improve control efficiency;
(3) alternative high toxicity agricultural chemicals, and reduce dosage, effectively reduce the ecotope Pesticide Residues, safer environmental protection.
Embodiment
The embodiment of the invention discloses a kind of Pesticidal combination and preparation thereof that contains penta pyrrole worm guanidine and metaflumizone.Those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is, all similarly replace and change apparent to those skilled in the art, and they all are deemed to be included in the present invention.Product of the present invention is described by preferred embodiment, and the related personnel obviously can change product as herein described within not breaking away from content of the present invention, spirit and scope or suitably change and combination, realizes and use the technology of the present invention.
In order further to understand the present invention, below in conjunction with embodiment, a kind of Pesticidal combination and preparation thereof that contains penta pyrrole worm guanidine and metaflumizone provided by the invention is elaborated.
Embodiment 1:
Reagent agent: the 95% penta former medicines of pyrrole worm guanidine, the 95% former medicine of metaflumizone (commercially available)
(1) penta pyrrole worm guanidine and the metaflumizone Toxicity Determination to beet armyworm
Adopt infusion process to carry out the indoor virulence biologicall test, the selection beet armyworm is target pest.Penta pyrrole worm guanidine (956% former medicine) and metaflumizone (95% former medicine) two single doses and different proportioning penta pyrrole worm guanidine metaflumizone mixture are designed respectively 5 concentration for the treatment of, take space management as contrast.Each concentration repeats 4 times, 96h investigation lethality after processing, and the calculation correction lethality, the contrast lethality is invalid test higher than 20%.Carry out statistical analysis with data handling system (DPS) software, obtain the LC50 value (95% confidence limit) of each medicament, press the co-toxicity coefficient (CTI) that the abundant method of Sun Yun is calculated toxicity index (TI) and mixture.The co-toxicity coefficient of mixture (CTI value) calculates by following formula:
ATI=(S/M)*100
In formula:
ATI---mixture actual measurement toxicity index;
The LC50 of S---standard insecticide, unit are mg/l;
The LC50 of M---mixture, unit are mg/l.
TTI=TIA*PA+TIB*PB
In formula:
The theoretical toxicity index of TTI---mixture;
The theoretical toxicity index of TIA---A medicament;
The percentage composition of PA---A medicament in mixture, unit are percentage;
The theoretical toxicity index of TIB---medicament;
The percentage composition of PB---B medicament in mixture, unit are percentage.
CTC=(ATI/TTI)*100
In formula:
CTC---spends coefficient together;
The actual measurement toxicity index of ATI---mixture;
The theoretical toxicity index of TTI---mixture.
CTI is synergistic effect greater than 120, and CTI is antagonism less than 80, and CTI is summation action greater than 80 less than 120.
Penta pyrrole worm guanidine and metaflumizone is composite that result of the test is seen Table 1.
Table 1 penta pyrrole worm guanidine proportionings different from metaflumizone are to beet armyworm toxicity test result
| Medicament | LC50(mg/l) | ATI | TII | CTC |
| Penta pyrrole worm guanidine | 79.31 | 100.00 | -- | -- |
| Metaflumizone | 180.52 | 49.93 | ? | ? |
| Penta pyrrole worm guanidine: metaflumizone=40: 1 | 56.63 | 139.24 | 98.63 | 141.17 |
| Penta pyrrole worm guanidine: metaflumizone=20: 1 | 52.04 | 152.40 | 97.33 | 156.58 |
| Penta pyrrole worm guanidine: metaflumizone=10: 1 | 43.25 | 183.90 | 94.90 | 193.22 |
| Penta pyrrole worm guanidine: metaflumizone=1: 1 | 59.32 | 133.70 | 71.97 | 185.78 |
| Penta pyrrole worm guanidine: metaflumizone=1: 5 | 81.43 | 97.40 | 53.28 | 182.81 |
| Penta pyrrole worm guanidine: metaflumizone=1: 20 | 125.67 | 63.11 | 46.60 | 135.42 |
(2) penta pyrrole worm guanidines and the metaflumizone Toxicity Determination to rice leaf roller
Adopt infusion process to carry out the indoor virulence biologicall test, the selection rice leaf roller is target pest.Penta pyrrole worm guanidine (95% former medicine) and metaflumizone (95% former medicine) two single doses and different proportioning penta pyrrole worm guanidine metaflumizone mixture are designed respectively 5 concentration for the treatment of, take space management as contrast.Each concentration repeats 4 times, 72h investigation lethality after processing, and the calculation correction lethality, the contrast lethality is invalid test higher than 20%.Carry out statistical analysis with data handling system (DPS) software, obtain the LC50 value (95% confidence limit) of each medicament, press the co-toxicity coefficient (CTI) that the abundant method of Sun Yun is calculated toxicity index (TI) and mixture.
Table 2 penta pyrrole worm guanidine proportionings different from metaflumizone are to rice leaf roller toxicity test result
| Medicament | LC50(mg/l) | ATI | TII | CTC |
| Penta pyrrole worm guanidine | 86.32 | 100.00 | -- | -- |
| Metaflumizone | 146.34 | 58.59 | ? | ? |
| Penta pyrrole worm guanidine: metaflumizone=40: 1 | 61.04 | 134.79 | 99.00 | 136.15 |
| Penta pyrrole worm guanidine: metaflumizone=20: 1 | 58.35 | 147.94 | 98.05 | 150.88 |
| Penta pyrrole worm guanidine: metaflumizone=10: 1 | 48.08 | 179.54 | 96.27 | 186.49 |
| Penta pyrrole worm guanidine: metaflumizone=1: 1 | 56.74 | 152.13 | 79.49 | 191.38 |
| Penta pyrrole worm guanidine: metaflumizone=1: 5 | 72.22 | 119.53 | 65.82 | 181.59 |
| Penta pyrrole worm guanidine: metaflumizone=1: 20 | 104.21 | 82.83 | 60.94 | 135.93 |
In table 1 and table 2, data show: penta pyrrole worm guanidine and metaflumizone according to the active ingredient proportioning with 40: 1,20: 1,10: 1,1: 1,1: 5,1: 20, when ratio is composite, co-toxicity coefficient (CTC value) is all greater than 120, show as synergistic function, wherein proportioning 10: 1,1: 1,1: 5 o'clock spend coefficient together more than 180, synergistic effect is especially remarkable.
Embodiment 2:61.5% penta pyrrole worm guanidine metaflumizone missible oil
Penta pyrrole worm guanidine 60%, metaflumizone 1.5%, alkylphenol polyoxyethylene 8%, styryl phenol polyethenoxy ether 8%, methyl alcohol 5%, vegetable oil supply 100%.The method of above raw material being prepared routinely missible oil mixes, and makes 61.5% penta pyrrole worm guanidine metaflumizone missible oil.
In the present embodiment, the mass ratio of penta pyrrole worm guanidine and metaflumizone can be 1: 20-40: change between 1, the gross weight composition is 61.5% constant, forms new embodiment.
Embodiment 3:22% penta pyrrole worm guanidine metaflumizone oil-suspending agent
Penta pyrrole worm guanidine 20%, metaflumizone 2%, agriculture breast 600#5%, white carbon 4%, soybean oil supply 100%.Make up oil the routinely method of suspending agent of above raw material is mixed, be crushed to certain fineness, make 22% penta pyrrole worm guanidine metaflumizone oil-suspending agents.
In the present embodiment, the mass ratio of penta pyrrole worm guanidine and metaflumizone can be 1: 20-40: change between 1, the gross weight composition is 22% constant, forms new embodiment.
Embodiment 4:10% penta pyrrole worm guanidine metaflumizone aqueous suspension agent
Penta pyrrole worm guanidine 5%, metaflumizone 5%, lignosulfonates 3.1%, agriculture breast 600#12%, bentonite 6%, ethylene glycol 4%, water supply 100%.Above raw material is prepared routinely the method for suspending agent, made 10% penta pyrrole worm guanidine metaflumizone aqueous suspension agents
In the present embodiment, the mass ratio of penta pyrrole worm guanidine and metaflumizone can change between 1: 2040: 1, and the gross weight composition is 10% constant, forms new embodiment.
Embodiment 5:25% penta pyrrole worm guanidine metaflumizone water dispersible granules
Penta pyrrole worm guanidine 5%, metaflumizone 20%, sodium lignin sulfonate 8%, calcium dodecyl benzene sulfonate 6%, sodium carbonate 6%, diatomite 10%, bentonite supply 100%.The method of above raw material being prepared routinely water dispersible granules mixes, and obtains 25% penta pyrrole worm guanidine metaflumizone water dispersible granules.
In the present embodiment, the mass ratio of penta pyrrole worm guanidine and metaflumizone can be 1: 20-40: change between 1, the gross weight composition is 25% constant, forms new embodiment.
Embodiment 6:21% penta pyrrole worm guanidine metaflumizone wetting powder
Penta pyrrole worm guanidine 1%, metaflumizone 20%, lignosulfonates 6%, lauryl sodium sulfate 4%, white carbon 20%, kaolin supply 100%.Above raw material is prepared routinely the method for wetting powder and fully mixed, be crushed to certain fineness, make 21% penta pyrrole worm guanidine metaflumizone wetting powders.
In the present embodiment, the mass ratio of penta pyrrole worm guanidine and metaflumizone can be 1: 20-40: change between 1, the gross weight composition is 21%, forms new embodiment.
Embodiment 7: field control effectiveness test
20% penta pyrrole worm guanidine SC, 24% metaflumizone SC do comparative trial with embodiment 2-6 complex preparation and single dose.Subjects is cauliflower field beet armyworm and paddy field rice leaf roller, is watered even spraying.This tests before medicine, 3 days, 10 days investigation results after dispenser.
Drug effect is calculated as follows:
Control efficiency (%)=1-(before the blank district after borer population * treatment region medicine borer population)/(behind the blank district before borer population * treatment region medicine borer population)
Field control effectiveness test the results are shown in Table 3, table 4.
Table 3 is prevented cauliflower beet armyworm result of the test
Table 4 control paddy rice rice leaf roller result of the test
Can find out from table 3,4 test data, complex preparation has control efficiency preferably to beet armyworm mutually with rice leaf roller, and the good lasting effect of quick-acting is better, has reduced dosage.
The explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.
Claims (6)
1. a Pesticidal combination that contains penta pyrrole worm guanidine and metaflumizone, is characterized in that its active ingredient is penta pyrrole worm guanidine and metaflumizone, and the mass ratio of described penta pyrrole worm guanidine and metaflumizone is 1:20-40:1.
2. Pesticidal combination according to claim 1, is characterized in that the mass ratio of described penta pyrrole worm guanidine and metaflumizone is preferably 1:5-10:1.
3. a preparation that contains the Pesticidal combination of penta pyrrole worm guanidine and metaflumizone as claimed in claim 1, is characterized in that, described formulation is missible oil, suspending agent, microemulsion, water dispersible granules or wetting powder.
4. the preparation that contains the Pesticidal combination of penta pyrrole worm guanidine and metaflumizone according to claim 3, it is characterized in that: described preparation adds adjuvant in preparation process, and in described preparation, the mass percentage content of active ingredient is 1～95%.
5. the preparation that contains the Pesticidal combination of penta pyrrole worm guanidine and metaflumizone according to claim 4, it is characterized in that: in described preparation, the mass percentage content of active ingredient is preferably 10-60%.
6. the Pesticidal combination that contains penta pyrrole worm guanidine and metaflumizone according to claim 1, it is characterized in that: this product is mainly used in preventing and treating rice leaf roller and beet armyworm.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103444762A (en) * | 2013-09-26 | 2013-12-18 | 江苏省绿盾植保农药实验有限公司 | Composite pesticide capable of preventing rice pests |
| CN106614695A (en) * | 2016-12-29 | 2017-05-10 | 成都格瑞赛斯科技有限公司 | Rice insecticide and fungicide composition containing guadipyr |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010060231A1 (en) * | 2008-11-25 | 2010-06-03 | Qin Zhaohai | Condensed amino nitroguanidine compounds, synthesis and use as botanical insecticides thereof |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN102771498A (en) * | 2012-07-23 | 2012-11-14 | 河南金田地农化有限责任公司 | Insect-killing composition containing guadipyr and neonicotine pesticide |
| CN102792965A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticide compound comprising guadipyr |
| CN102792964A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticidal composition containing guadipyr and sulfoxaflor |
| CN102792963A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticidal composition containing guadipyr and buprofezin |
-
2013
- 2013-01-15 CN CN201310014717.7A patent/CN103109839B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010060231A1 (en) * | 2008-11-25 | 2010-06-03 | Qin Zhaohai | Condensed amino nitroguanidine compounds, synthesis and use as botanical insecticides thereof |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN102771498A (en) * | 2012-07-23 | 2012-11-14 | 河南金田地农化有限责任公司 | Insect-killing composition containing guadipyr and neonicotine pesticide |
| CN102792965A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticide compound comprising guadipyr |
| CN102792964A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticidal composition containing guadipyr and sulfoxaflor |
| CN102792963A (en) * | 2012-09-06 | 2012-11-28 | 中国农业大学 | Insecticidal composition containing guadipyr and buprofezin |
Non-Patent Citations (2)
| Title |
|---|
| 刘广雷 等: "新型杀虫剂氰氟虫腙作用机理及应用现状", 《河北农业科学》, vol. 14, no. 08, 15 August 2010 (2010-08-15), pages 61 - 63 * |
| 李鑫: "新型杀虫剂氰氟虫腙", 《农药》, vol. 46, no. 11, 15 November 2007 (2007-11-15), pages 774 - 776 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103444762A (en) * | 2013-09-26 | 2013-12-18 | 江苏省绿盾植保农药实验有限公司 | Composite pesticide capable of preventing rice pests |
| CN106614695A (en) * | 2016-12-29 | 2017-05-10 | 成都格瑞赛斯科技有限公司 | Rice insecticide and fungicide composition containing guadipyr |
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