CN109757495A - Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide - Google Patents
Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide Download PDFInfo
- Publication number
- CN109757495A CN109757495A CN201910169748.7A CN201910169748A CN109757495A CN 109757495 A CN109757495 A CN 109757495A CN 201910169748 A CN201910169748 A CN 201910169748A CN 109757495 A CN109757495 A CN 109757495A
- Authority
- CN
- China
- Prior art keywords
- fipronil
- butene
- bromine worm
- worm fluorobenzene
- fluorobenzene bisamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide, effective component is butene-fipronil and bromine worm fluorobenzene bisamide, the weight fraction ratio of butene-fipronil and bromine worm fluorobenzene bisamide in the composition is 20:1~1:20, the weight percent of butene-fipronil and bromine worm fluorobenzene bisamide weight summation in the composition be 1%~85%, remaining be can agriculturally receive and allow using auxiliary ingredients for pesticide preparations.Composition pesticide of the present invention has significant synergistic function, to the various pests occurred on crops, especially has excellent control efficiency to pests such as homoptera pest, lepidoptera pest, Thysanoptera, coleopteran pests；The present invention can reduce Pesticide use amount, reduce use cost, mitigate the pollution to environment, delay the generation of pest resistance to insecticide, increase the Pesticide use service life.
Description
Technical field
The present invention relates to composition pesticide and its application fields, and in particular to one kind is with butene-fipronil and bromine worm fluorobenzene bisamide
Composition pesticide and its application for effective component.
Background technique
Butene-fipronil (flufiprole): for Phenylpyrazole insecticides, insecticidal mechanism is novel, unique, activity is high, mainly
The chloride metabolism for hindering the control of insect γ-aminobutyric acid, has stomach toxicity, tags and certain systemic action, can be applied to water
The larva and adult of Lepidoptera, coleoptera, Homoptera etc. are prevented and treated on the crops such as rice, cotton, vegetables, corn, fruit tree.
Bromine worm fluorobenzene bisamide (broflanilide): formamido group benzamide insecticides, control caterpillar and
There is brilliance in terms of a variety of pests with chewing mouthparts such as beetle, can be applied to special and row crop, and in non-crop
Region prevention and control termite, ant, cockroach and fly.
The resistance problem of pest is a global problem in agricultural production, is always what agricultural science and technology worker paid close attention to
Key issues.With the increase that uses the continuity year in year out of chemical pesticide control pest, Pesticide use amount and not scientific
Using factors such as pesticides, the resistance of pest is caused to get worse, the pest species for generating resistance are increasing.Meanwhile it is high-intensitive
Use pesticide, result in Practice for Pesticide Residue in Agricultural Products it is exceeded, pollution environment and peasant's drug cost increase a series of problems, such as, no
Conducive to the sustainable development of agricultural.
The present inventor is during furtheing investigate butene-fipronil and bromine worm fluorobenzene bisamide compounded formula, it has unexpectedly been found that fourth
Worm nitrile and bromine worm fluorobenzene bisamide are compounded, to the various pests occurred on crops within the scope of certain compound proportion,
Especially there is significant synergistic function, warp to homoptera pest, lepidoptera pest, Thysanoptera and coleopteran pest
Further research, completes the present invention.
Summary of the invention
The purpose of the present invention is to provide a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide.
It is same in the pest of prevention and treatment crops, especially prevention and treatment that another object of the present invention is to provide above-mentioned composition pesticides
Wing mesh pest, lepidoptera pest, Thysanoptera, coleopteran pest purposes.
Technical solution of the present invention: to achieve the above object, the present invention provides a kind of double containing butene-fipronil and bromine worm fluorobenzene
The composition pesticide of amide, effective component are butene-fipronil and bromine worm fluorobenzene bisamide, and butene-fipronil and bromine worm fluorobenzene bisamide are in group
Closing the weight fraction ratio in object is 20:1~1:20, the weight of butene-fipronil and bromine worm fluorobenzene bisamide weight summation in the composition
Percentage be 1%~85%, remaining be can agriculturally receive and allow using auxiliary ingredients for pesticide preparations.
Further, the preferred weight portion rate of butene-fipronil and bromine worm fluorobenzene bisamide in the composition is 10:1~1:10,
The preferred weight percent of butene-fipronil and bromine worm fluorobenzene bisamide weight summation in the composition is 5%~75%.
Composition pesticide of the present invention can be prepared into any dosage form used in suitable agricultural production, and relatively good dosage form has
Aqueous suspension agent, dispersible oil-suspending agent, water dispersible granules, missible oil, seed treatment suspending agent etc..
It further include in pesticide other than effective active composition in the various application forms of composition pesticide preparation of the present invention
Allow using with the various auxiliary elements of acceptable.
Auxiliary element in aqueous suspension agent includes but is not limited to: dispersing agent can be selected from alkylnaphthalene sulfonate, polycarboxylate, wood
One of mahogany sulfonate, polyoxyethylene ether phosphate etc. or more than one a mixture of arbitrary proportions；Wetting agent is optional
From one of fatty alcohol polyoxyethylene ether, Pluronic PE 6800, fatty alcohol polyoxyethylene ether sulfate etc. or more than one
A mixture of arbitrary proportions；Thickener can be selected from xanthan gum, polyvinyl alcohol, bentonite, aluminium-magnesium silicate, carboxymethyl cellulose,
One of carboxyethyl cellulose, methylcellulose etc. or more than one a mixture of arbitrary proportions；Preservative can be selected from first
One of aldehyde, benzoic acid, sodium benzoate, potassium sorbate, isothiazolinone etc. or more than one a mixture of arbitrary proportions；
Defoaming agent can be selected from silicone oil, silicone compound, C10-20Saturated fat acids compound, C8-10Fatty alcohols, hexanol, butanol,
One of octanol etc. or more than one a mixture of arbitrary proportions；Antifreezing agent can be selected from ethylene glycol, propylene glycol, glycerine,
One of polyethylene glycol, sorbierite, urea, inorganic salts etc. or more than one a mixture of arbitrary proportions；Water be go from
Sub- water.
Auxiliary element in dispersible oil-suspending agent includes but is not limited to: dispersing agent can be selected from lignosulfonates, poly- carboxylic
One of hydrochlorate, naphthalene sulfonate, polyox-yethylene-polyoxypropylene block copolymer etc. or more than one any mixing than composition
Object；Emulsifier can be selected from alkylbenzene sulfonate, dioctyl sulfosuccinate, fatty alcohol polyoxyethylene ether, castor oil polyoxy second
Alkene ether, anhydrous sorbitol polyoxyethylene polyoxypropylene, styryl phenyl polyoxyethylene ether, styrene phenol formaldehyde resin polyoxy
One of vinethene etc. or more than one a mixture of arbitrary proportions；Thickener can be selected from white carbon black, polyvinyl alcohol, swelling
One of soil, xanthan gum, aluminium-magnesium silicate, carboxymethyl cellulose etc. or more than one a mixture of arbitrary proportions；Dispersion is situated between
Matter can be selected from methyl oleate, soybean oil, rapeseed oil, cottonseed oil, palm oil, linseed oil, turpentine oil, corn oil, solvent naphtha (board
Number: S-150, S-180, S-200) etc. one of or more than one a mixture of arbitrary proportions.
Auxiliary element in water dispersible granules includes but is not limited to: dispersing agent can be selected from di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, polyoxy
Ethylene-polyoxypropylene block copolymers, APES formaldehyde condensation products sulfat, calcium lignosulfonate, polycarboxylic acids
One of salt, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt, maleic acid-acrylic acid copolymer salt etc. or more than one arbitrarily compare group
At mixture；Wetting agent can be selected from neopelex, sodium lignin sulfonate, fatty acid amide N methyl taurine sodium
Salt, lauryl sodium sulfate, aliphatic alcohol sulfate, a- sulfo methyl ester, sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl fourth
One of two acid esters sulfonate sodiums etc. or more than one a mixture of arbitrary proportions；Disintegrating agent can be selected from sodium sulphate, chlorination
One of calcium, polyvinyl pyrrolidone, sodium carboxymethyl starch, starch, ammonium sulfate, sodium chloride, bentonite etc. or more than one
It anticipates than the mixture of composition；Carrier can be selected from kaolin, diatomite, precipitated calcium carbonate, white carbon black, attapulgite, cornstarch,
What one of sepiolite, calcite, silica, pyrophyllite, xylitol, montmorillonite, clay etc. or more than one any ratios formed
Mixture.
Auxiliary element in missible oil includes but is not limited to: emulsifier can be selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxy
Vinethene, castor oil polyoxyethylene ether, linear dodecylbenzene sulfoacid calcium, styryl phenol polyethenoxy
Ether, octyl phenol polyoxyethylene ether phosphate, polyol fatty acid ester, triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether
Deng one of or more than one a mixture of arbitrary proportions；Stabilizer can be selected from antioxidant BHT, epoxidized soybean oil, 1,
One of 2- butanediol, propylene glycol, isopropyl phosphoric acid ester, epoxychloropropane etc. or more than one any mixing than composition
Object；Solvent can be selected from sec-Butyl Acetate, alcohol, loose ester group vegetable oil, dimethyl sulfoxide, solvent naphtha (trade mark: S-150, S-180,
One of) etc. or more than one a mixture of arbitrary proportions S-200.
Auxiliary element in seed treatment suspending agent includes but is not limited to: dispersing agent can be selected from polycarboxylate, sulfomethylated lignin
Hydrochlorate, APES formaldehyde condensation products sulfat, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkane
In base phenol polyethenoxy ether, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, glycerol fatty acid ester polyoxyethylene ethe etc.
One or more kinds of a mixture of arbitrary proportions；Film forming agent can be selected from methylcellulose, sodium carboxymethylcellulose, polyethylene
One of alcohol, polyvinyl acetate, polyethylene glycol, polyacrylamide etc. or more than one a mixture of arbitrary proportions；?
Toner can be selected from basic rhodamine, aqueous rhodo, acid scarlet, Fluoresceinred5B, Red-8110, Red-131, FGR-
One of 131 grades or more than one a mixture of arbitrary proportions；Thickener can be selected from xanthan gum, aluminium-magnesium silicate, bentonite
Deng one of or more than one a mixture of arbitrary proportions；Preservative can be selected from benzoic acid, benzaldehyde, sodium benzoate, benzene
One of potassium formate, sorbic acid, sodium salicylate, 2- xenol, parahydroxyben-zaldehyde and 1,2- benzothiazoline -3- ketone etc.
Or more than one a mixture of arbitrary proportions；Antifreezing agent can be selected from ethylene glycol, propylene glycol, glycerine, hexylene glycol, urea, sulphur
One of sour ammonium, sodium chloride, calcium chloride etc. or more than one a mixture of arbitrary proportions；Water is deionized water.
The production technology of the various preparation formulations of composition pesticide belongs to existing known technology, no longer superfluous herein
It states.
Compared with the prior art, the advantages of the present invention are as follows:
1, instant component is reasonable, good disinsection effect, and its activity and insecticidal effect are not the active simple superposition of each component, and
It is to have significant synergistic effect, extends the service life of medicament, is conducive to overcome and delay the generation of pest resistance to insecticide；
2, two kinds of effective component compoundings, expand prevention spectrum, good to crop safety, meet the security requirement of pesticidal preparations；
3, two kinds of effective components compounding, reduces Pesticide use amount, to reduce drug cost, reduces pesticide residue and right
The pollution of environment.
Specific embodiment
To better understand the essence of the present invention, below with reference to embodiment, the content of the present invention will be further explained,
But limitation of the present invention cannot be considered as, the following description is only for the purpose of explaining the present invention, for without departing from spirit of that invention and principle
Modification, replacement or the improvement made, fall within the scope of the claimed invention.
One: 20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent of embodiment
The content of following substance is weight percentage: butene-fipronil 15%, bromine worm fluorobenzene bisamide 5%, polyoxyethylene ether phosphorus
Acid esters 6%, Pluronic PE 6800 4%, xanthan gum 2%, benzoic acid 0.1%, silicone compound 0.1%, propylene glycol 3%, deionization
Water complements to 100%.Above-mentioned material is mixed in proportion, after being uniformly dispersed through high speed shear, being sanded in sand mill, can be prepared by
20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent.
The 20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent using above-mentioned preparation is for preventing and treating capsicum thrips, by table 1
It can be seen that: 3d, 7d, 14d are respectively to the preventive effect of capsicum thrips after the application of 20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent
83.67%, 91.34% and 88.75%, hence it is evident that be better than 15% butene-fipronil aqueous suspension agent and 5% bromine worm fluorobenzene bisamide aqueous suspension agent point
It is not used alone.Meanwhile do not find during the test application 20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent after to peppery
Green pepper generates phytotoxicity.
The test result of 1 20% butene-fipronil bromine worm fluorobenzene bisamide aqueous suspension agent of table prevention and treatment capsicum thrips
Oil-suspending agent can be dispersed in two: 10% butene-fipronil bromine worm fluorobenzene bisamide of embodiment
The content of following substance is weight percentage: butene-fipronil 5%, bromine worm fluorobenzene bisamide 5%, polyoxyethylene-polyoxy
Propylene-based block copolymer 10%, castor oil polyoxyethylene ether 8%, bentonite 3%, cottonseed oil complements to 100%.By above-mentioned material press than
Example mixing, after being uniformly dispersed through high speed shear, being sanded in sand mill, can be prepared by 10% butene-fipronil bromine worm fluorobenzene bisamide can
Disperse oil-suspending agent.
Oil-suspending agent can be dispersed for preventing and treating wild cabbage pickles using 10% butene-fipronil bromine worm fluorobenzene bisamide of above-mentioned preparation
Moth, 3d, 7d, 14d are to wild cabbage pickles after oil-suspending agent application can be dispersed from 2: 10% butene-fipronil bromine worm fluorobenzene bisamide of table
The preventive effect of moth is respectively 87.56%, 96.31% and 92.63%, hence it is evident that being better than 5% butene-fipronil can be dispersed oil-suspending agent and 5% bromine worm
Fluorobenzene bisamide can be dispersed oil-suspending agent and use individually.Meanwhile 10% butene-fipronil bromine of application is not found during the test
Worm fluorobenzene bisamide generates phytotoxicity to wild cabbage after oil-suspending agent can be dispersed.
The test result of oil-suspending agent prevention and treatment wild cabbage plutella xylostella can be dispersed in 2 10% butene-fipronil bromine worm fluorobenzene bisamide of table
Three: 60% butene-fipronil bromine worm fluorobenzene bisamide water dispersible granules of embodiment
The content of following substance is weight percentage: butene-fipronil 15%, bromine worm fluorobenzene bisamide 45%, alkyl naphthalene sulfonic acid first
Aldehyde condensate sodium salt 10%, sodium lignin sulfonate 8%, sodium carboxymethyl starch 5%, diatomite complements to 100%.By above-mentioned material press than
Example mixing can be prepared by the double acyls of 60% butene-fipronil bromine worm fluorobenzene after being uniformly mixed through air-flow crushing, mediating granulation, dry screening
Aqueous amine dispersible granule.
The 60% butene-fipronil bromine worm fluorobenzene bisamide water dispersible granules using above-mentioned preparation are for preventing and treating rice cnaphalocrocis
Snout moth's larva, seen from table 3: 3d, 7d, 14d are to rice cnaphalocrocis after the application of 60% butene-fipronil bromine worm fluorobenzene bisamide water dispersible granules
The preventive effect of snout moth's larva is respectively 89.12%, 98.91% and 93.46%, hence it is evident that is better than 15% butene-fipronil water dispersible granules and 45% bromine worm fluorine
Benzene bisamide water dispersible granules use individually.Meanwhile 60% butene-fipronil bromine worm fluorobenzene of application is not found during the test
Phytotoxicity is generated to rice after bisamide water dispersible granules.
The test result of 3 60% butene-fipronil bromine worm fluorobenzene bisamide water dispersible granules of table prevention and treatment paddy rice rice leaf roller
Example IV: 32% butene-fipronil bromine worm fluorobenzene bisamide missible oil
The content of following substance is weight percentage: butene-fipronil 28%, bromine worm fluorobenzene bisamide 4%, styryl phenol are poly-
Ethylene oxide ether 12%, cyclohexanone 5%, epoxidized soybean oil 4%, solvent naphtha (trade mark: S-150) complement to 100%.By above-mentioned material press than
Example mixing, is dissolved after mixing evenly, can be prepared by 32% butene-fipronil bromine worm fluorobenzene bisamide missible oil.
The 32% butene-fipronil bromine worm fluorobenzene bisamide missible oil using above-mentioned preparation, can by table 4 for preventing and treating rice hoppers
See: 3d, 7d, 14d are respectively to the preventive effect of rice hoppers after the application of 32% butene-fipronil bromine worm fluorobenzene bisamide missible oil
75.55%, 84.27% and 78.24%, hence it is evident that being better than 28% butene-fipronil missible oil and 4% bromine worm fluorobenzene bisamide missible oil individually makes
With.Meanwhile phytotoxicity is generated to rice after not finding 32% butene-fipronil bromine worm fluorobenzene bisamide missible oil of application during the test.
The test result of 4 32% butene-fipronil bromine worm fluorobenzene bisamide emulsion prevention rice hoppers of table
Five: 40% butene-fipronil bromine worm fluorobenzene bisamide seed treatment suspending agent of embodiment
The content of following substance is weight percentage: butene-fipronil 5%, bromine worm fluorobenzene bisamide 35%, polycarboxylate 7%, carboxylic
Sodium carboxymethylcellulose pyce 8%, xanthan gum 2%, aqueous rhodo 2%, sodium benzoate 0.2%, propylene glycol 2%, deionized water complements to 100%.
40% butene-fipronil bromine worm fluorobenzene bisamide seed is made after above-mentioned each material is mixed ground and/or high speed shear in proportion
Handle suspending agent.
It is prevented and treated using 40% butene-fipronil bromine worm fluorobenzene bisamide seed treatment suspending agent of above-mentioned preparation for Dressing
Corn grub, from 15d, 30d couple after 5: 40% butene-fipronil bromine worm fluorobenzene bisamide seed treatment suspending agent Dressing of table
The preventive effect of corn grub is respectively 84.56% and 77.29%, hence it is evident that is better than 5% butene-fipronil seed treatment suspending agent and 35% bromine worm
Fluorobenzene bisamide seed treatment suspending agent uses individually.Meanwhile 40% butene-fipronil bromine of application is not found during the test
Phytotoxicity is generated to corn after worm fluorobenzene bisamide seed treatment suspending agent.
The test result of 5 40% butene-fipronil bromine worm fluorobenzene bisamide seed treatment suspending agent of table prevention and treatment corn grub
Embodiment six: butene-fipronil and bromine worm fluorobenzene bisamide compound the indoor toxicity determination test to eggplant thrips
Test method: referring to " farm-chemical indoor determination test rule insecticidal n Y/T 1154.6-2006 ", using leaching worm
Method.
It is for statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC value), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 < co-toxicity coefficient (CTC) < 120 show as summation action.
6 butene-fipronil of table and bromine worm fluorobenzene bisamide compound the The Toxicity Determination result to eggplant thrips
As can be seen from Table 6, butene-fipronil and bromine worm fluorobenzene bisamide 20:1~1:20(by weight) in the range of compound when, altogether
Malicious coefficient (CTC) is all larger than 120, illustrates to show synergistic function to eggplant thrips；Butene-fipronil and bromine worm fluorobenzene bisamide
10:1~1:10(by weight) in the range of compound when, synergistic function is more significant, and co-toxicity coefficient (CTC) is 150
More than；And butene-fipronil and bromine worm fluorobenzene bisamide with 30:1(by weight) and 1:30(is by weight) compounding when, co-toxicity coefficient (CTC)
Respectively less than 120, it is showed only as simple summation action.
Embodiment seven: butene-fipronil and bromine worm fluorobenzene bisamide compound the indoor toxicity determination test to cotton boll worm
Test method: referring to " farm-chemical indoor determination test rule insecticidal n Y/T 1154.2-2006 ", using folder poison
Blade method.
It is for statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC value), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 < co-toxicity coefficient (CTC) < 120 show as summation action.
7 butene-fipronil of table and bromine worm fluorobenzene bisamide compound the The Toxicity Determination result to cotton boll worm
As can be seen from Table 7, butene-fipronil and bromine worm fluorobenzene bisamide 20:1~1:20(by weight) in the range of compound when, altogether
Malicious coefficient (CTC) is all larger than 120, illustrates to show synergistic function to cotton boll worm；Butene-fipronil and the double acyls of bromine worm fluorobenzene
Amine 10:1~1:10(by weight) in the range of compound when, synergistic function is more significant, and co-toxicity coefficient (CTC) exists
150 or more；And butene-fipronil and bromine worm fluorobenzene bisamide with 30:1(by weight) and 1:30(is by weight) compounding when, co-toxicity coefficient
(CTC) 120 are respectively less than, simple summation action is showed only as.
Embodiment eight: butene-fipronil and bromine worm fluorobenzene bisamide compound the indoor toxicity determination test to radish striped flea-beetle
Test method: referring to " farm-chemical indoor determination test rule insecticidal n Y/T 1154.6-2006 ", using leaching worm
Method.
It is for statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC value), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 < co-toxicity coefficient (CTC) < 120 show as summation action.
8 butene-fipronil of table and bromine worm fluorobenzene bisamide compound the The Toxicity Determination result to radish striped flea-beetle
As can be seen from Table 8, butene-fipronil and bromine worm fluorobenzene bisamide 20:1~1:20(by weight) in the range of compound when, altogether
Malicious coefficient (CTC) is all larger than 120, illustrates to show synergistic function to radish striped flea-beetle；Butene-fipronil and bromine worm fluorobenzene are double
Amide 10:1~1:10(by weight) in the range of compound when, synergistic function is more significant, and co-toxicity coefficient (CTC) exists
170 or more；And butene-fipronil and bromine worm fluorobenzene bisamide with 30:1(by weight) and 1:30(is by weight) compounding when, co-toxicity coefficient
(CTC) 120 are respectively less than, simple summation action is showed only as.
Nine butene-fipronil of embodiment and bromine worm fluorobenzene bisamide compound the indoor toxicity determination test to wheat aphid
Test method: referring to " farm-chemical indoor determination test rule insecticidal n Y/T 1154.6-2006 ", using leaching worm
Method.
It is for statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC value), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 < co-toxicity coefficient (CTC) < 120 show as summation action.
9 butene-fipronil of table and bromine worm fluorobenzene bisamide compound the The Toxicity Determination result to wheat aphid
As can be seen from Table 9, butene-fipronil and bromine worm fluorobenzene bisamide 20:1~1:20(by weight) in the range of compound when, altogether
Malicious coefficient (CTC) is all larger than 120, illustrates to show synergistic function to wheat aphid；Butene-fipronil and bromine worm fluorobenzene bisamide
10:1~1:10(by weight) in the range of compound when, synergistic function is more significant, and co-toxicity coefficient (CTC) is 170
More than；And butene-fipronil and bromine worm fluorobenzene bisamide with 30:1(by weight) and 1:30(is by weight) compounding when, co-toxicity coefficient (CTC)
Respectively less than 120, it is showed only as simple summation action.
In conclusion a kind of composition pesticide containing by butene-fipronil and bromine worm fluorobenzene bisamide provided by the invention, collaboration
Synergistic effect is significant, is used alone compared to each single dose, and preventive effect significantly improves, and can effectively prevent a variety of evils occurred on crops
Worm, the lasting period is long, to Crop securify, is worth promoting and applying in agricultural production.
Claims (5)
1. a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide, it is characterised in that: effective component is butene-fipronil
With bromine worm fluorobenzene bisamide, the weight fraction ratio of butene-fipronil and bromine worm fluorobenzene bisamide in the composition is 20:1~1:20.
2. a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide according to claim 1, feature exist
In: the weight fraction ratio of butene-fipronil and bromine worm fluorobenzene bisamide in the composition is 10:1~1:10.
3. a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide according to claim 1, feature exist
In: the weight percent of butene-fipronil and bromine worm fluorobenzene bisamide weight summation in the composition is 1%~85%, remaining is agriculturally
Can receive and allow using auxiliary ingredients for pesticide preparations.
4. a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide according to claim 1, feature exist
In: the application forms of the composition pesticide in actual use be aqueous suspension agent, dispersible oil-suspending agent, water dispersible granules,
One of missible oil, seed treatment suspending agent.
5. a kind of composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide according to claim 1 is in prevention and treatment farming
The application of the homoptera pest, lepidoptera pest, Thysanoptera, coleopteran pest of object.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910169748.7A CN109757495A (en) | 2019-03-07 | 2019-03-07 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910169748.7A CN109757495A (en) | 2019-03-07 | 2019-03-07 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109757495A true CN109757495A (en) | 2019-05-17 |
Family
ID=66457813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910169748.7A Pending CN109757495A (en) | 2019-03-07 | 2019-03-07 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109757495A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115943956A (en) * | 2022-09-21 | 2023-04-11 | 上海生农生化制品股份有限公司 | Bromodifenoxanil dispersible oil suspending agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302022A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN103109823A (en) * | 2013-01-17 | 2013-05-22 | 湖南农大海特农化有限公司 | Butene-fipronil and chlorantraniliprole pesticide composition |
| CN106061254A (en) * | 2013-10-18 | 2016-10-26 | 巴斯夫农业化学品有限公司 | Use of pesticidal active carboxamide derivative in soil and seed application and treatment methods |
| CN106665618A (en) * | 2016-12-28 | 2017-05-17 | 成都格瑞赛斯科技有限公司 | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases |
-
2019
- 2019-03-07 CN CN201910169748.7A patent/CN109757495A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302022A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN103109823A (en) * | 2013-01-17 | 2013-05-22 | 湖南农大海特农化有限公司 | Butene-fipronil and chlorantraniliprole pesticide composition |
| CN106061254A (en) * | 2013-10-18 | 2016-10-26 | 巴斯夫农业化学品有限公司 | Use of pesticidal active carboxamide derivative in soil and seed application and treatment methods |
| CN106665618A (en) * | 2016-12-28 | 2017-05-17 | 成都格瑞赛斯科技有限公司 | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases |
Non-Patent Citations (1)
| Title |
|---|
| 齐浩亮等: "溴虫氟苯双酰胺对小菜蛾的毒力及相关酶活性的影响", 《植物保护》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115943956A (en) * | 2022-09-21 | 2023-04-11 | 上海生农生化制品股份有限公司 | Bromodifenoxanil dispersible oil suspending agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104026143B (en) | Binary pesticide composition and uses thereof | |
| CN103250720B (en) | A kind of containing chlorfluazuron and ZJ4042 agricultural pesticide composition | |
| CN103120166B (en) | Hymexazol-containing sterilizing composition | |
| CN102084862A (en) | Insecticidal composition containing ethiprole | |
| CN101755767A (en) | Pesticidal composition containing buprofezin and flubendiamide | |
| CN103404530B (en) | Insecticide compound and application and preparation thereof | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN102986712A (en) | Insecticidal composition containing dinotefuran and abamectin | |
| CN109757495A (en) | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide | |
| CN101406197A (en) | Compositional mite-killing composition containing spirodiclofen and ivermectin | |
| CN106472529A (en) | Herbicidal combinations and its application | |
| CN102228056A (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN103688979A (en) | Pesticidal composition containing thiamethoxam and spirotetramat | |
| CN102696651A (en) | Spirodiclofen-containing compound pesticidal composition and preparation thereof | |
| CN101926331A (en) | Insecticidal composite containing spinosad and flubendiamide | |
| CN102077833A (en) | Pesticide composition | |
| CN101779661B (en) | Compound insecticide prepared from emamectin benzoate and pyridaphethione | |
| CN104472489A (en) | Insecticidal composition containing pyridalyl and cyhalodiamide | |
| CN101263824A (en) | Insecticidal composition | |
| CN104686562A (en) | Pesticide | |
| CN103109839A (en) | Insecticidal composition containing penta-imidacloprid guanidine and metaflumizone and preparation thereof | |
| CN103329900A (en) | Weeding composition containing butachlor and mesotrione | |
| CN104082323B (en) | There is the insect-killing composition of synergism |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190517 |
|
| WD01 | Invention patent application deemed withdrawn after publication |