CN106472529A - Herbicidal combinations and its application - Google Patents
Herbicidal combinations and its application Download PDFInfo
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- CN106472529A CN106472529A CN201610788635.1A CN201610788635A CN106472529A CN 106472529 A CN106472529 A CN 106472529A CN 201610788635 A CN201610788635 A CN 201610788635A CN 106472529 A CN106472529 A CN 106472529A
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- quinmerac
- fluroxypyr
- florasulam
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations and its application, with quinmerac, fluroxypyr and florasulam as principle active component, the weight of quinmerac, fluroxypyr and florasulam is than for 1 150 for Herbicidal combinations:1‑50:0 40, preferably 1 150:1‑20:0.1 40, for wheat paddock after seedling cauline leaf process, prevent and kill off broad leaved weed, potentiation is notable.
Description
Technical field:
The invention belongs to agriculture herbicide field, be related to a kind of containing quinmerac, fluroxypyr and florasulam
Composite wheat field herbicide, prevents and kill off broad leaved weed for wheat paddock after seedling cauline leaf process.
Technical background:
Quinmerac (Quinmerac), is quinmerac, chemistry is entitled, and (the chloro- 8-Quinoline Carboxylic Acid of 3- methyl -7-, is Seedling again
The hormone like herbicide that front or after seedling uses, can be absorbed by the root of plant and leaf, then shifts to the top of plant and base portion.Quinoline
Oxalic acid is the quinoline carboxylic acid herbicide developed by BASF AG it is adaptable to cereal crop, Semen Tritici aestivi and Radix Betae, prevents and kill off pig calamity
Calamity, Herba veronicae and other weeds, wherein umbellate form section crop is very sensitive to it.
Fluroxypyr (fluroxypyr), No. CAS is:69377-81-7, fluroxypyr is inner sucting conduction type
Herbicide after seedling, is absorbed by plants after medicine quickly, makes sensitive plant the reaction of classical hormones class herbicide, plant deformity,
Distortion, finally withered.It is applied to the ground such as Semen Tritici aestivi, Fructus Hordei Vulgaris, Semen Maydiss, Fructus Vitis viniferae, orchard, pasture, forest land, lawn and prevent and kill off broad leaved weed,
As Herba Galii Teneri, volume stem smartweed, Herba Portulacae, Herba Solani Nigri, Herba seu Flos Convolvuli arvensves, knotweed, Herba Amaranthi tricoloriss etc..
Florasulam (Diclosulam), CAS registration number:145701-21-9, structural formula is as follows:
Florasulam is the triazolopyrimidine sulfonamides herbicide developed by Dow Agrosciences LLC, can be used to
Preventing and treating broad leaved weed such as Herba Galii Teneri, Herba stellariae mediae, Polygonum weeds, compositae weeds etc..
After the herbicide of single-activity component is used for controlling weeds for a long time, the resistance of weeds can be made to strengthen, make the quick of weeds
Perception declines, and can increase formulation rate, thus causing the pollution of environment.And the development difficulty of new herbicide is increasing, expend
Time and financial resources also increasing, therefore rational mixture herbicide is to improve a kind of selection that herbicidal effect becomes current.
Herbicide rational mixture not only can expand herbicidal spectrum, delays the generation of Weed Resistance, and good compounding can also improve weeding effect
Really, play potentiation it will be apparent that improving the effect of herbicide.
Content of the invention:
It is an object of the invention to provide the low herbicidal composition of drug cost, the broad leaved weed of wheat paddock is had relatively
Good prevention effect, can be used for wheat paddock after seedling cauline leaf process, prevents and kill off broad leaved weed.The technical solution adopted in the present invention
For:
A kind of containing quinmerac, fluroxypyr and florasulam compound herbicide it is characterised in that described
Herbicide with quinmerac, fluroxypyr and florasulam as principle active component, quinmerac, fluroxypyr and double
The weight of penoxsulam is than for 1-150:1-50:0-40, preferably 1-150:1-20:0.1-40, more preferably 5-150:
1-20:0.1-5.In compound herbicide, the content of effective ingredient is 1-85%, preferably 20-75%.
The herbicide of the present invention is used for wheat paddock after seedling cauline leaf process, prevents and kill off broad leaved weed.
The preparation formulation that herbicide of the present invention can be prepared according to the method well known to those skilled in the art of the present technique, including
Water dispersible granules, wettable powder, wet seed dressing, cream, suspending agent, oil suspending agent, suspension emulsion, suspension seed-coating agent, aqueous emulsion, micro-
Emulsion etc.;
Known auxiliary agent has emulsifying agent, wetting dispersing agent, suspending agent, disintegrating agent, binding agent, antifreezing agent, thickening agent, stablizes
Agent, defoamer etc.;
The emulsifying agent that can be applicable in the insecticides adjuvant of the present invention includes but is not limited to phenethyl phenol polyoxyethylene polyoxy
Propylene ether, styrylphenol formaldehyde resin PULLRONIC F68 block type polyethers, aliphatic acid polyethenoxy ether, polyoxy
Ethylene fatty alcohol ether, trilaurin polyoxyethylene ether, two Bian xenyl polyoxyethylene ether, glyceryl monolaurate polyoxy
Vinyl Ether, styrylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, ethoxy castor oil polyoxyethylene ether, alkyl phenol
Polyoxyethylene polyoxypropylene ether, styryl phenyl polyoxyethylene ether, secondary octyl phenol polyethenoxy ether, Nonyl pheno
Ether, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylphenol polyoxyethylene, sorbitan fatty acid ester polyoxyethylene groups
Ether, aliphatic alcohol polyoxyethylene sulfonate, polyoxyethylene alkylphenol formaldehyde condensation products, dodecyl sodium sulfonate calcium, decanol polyoxy second
Alkene ether sulfosuccinic acid sodium, APES formaldehyde condensation product sodium sulfate, alkylphenol polyoxyethylene succinate monoester
Sulfonate, alkylphenol-polyethenoxy phosphate ester, alkylphenol polyoxyethylene sulfosuccinates, polyoxyethylene fatty acid fat, poly-
Acrylic acid methyl ester., Polyoxyethylene fatty ammonia, ethoxy castor oil, alkyl-diethylene glycol ether-sodium sulfonate, fatty acid polyglycol ethylene glycol
One or more of ester, fast penetration enhancer T, Oleic acid PEG400 ester and fatty alcohol-polyoxyethylene ether;
Dispersant in the aforementioned insecticides adjuvant that can be applicable to the present invention includes but is not limited to sodium lignin sulfonate, methylene
Base sodium dinaphthalenesulfonate, calcium lignosulfonate, sodium polyacrylate, sodium methylene bis-naphthalene sulfonate, dispersing agent MF, poly-
Vinylpyrrolidone, alkyl amide taurate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer and the contracting of sodium methylene bis-naphthalene sulfonate formaldehyde
One or more of compound;
Wetting agent is selected from Negel, sodium lauryl sulphate, Teepol, dodecylbenzene sodium sulfonate,
Fatty alcohol polyglycol ether sulfate, fatty alcohol-polyoxyethylene ether, NPE, sorbitan fatty acid ester gather
Oxygen vinyl Ether, the mixture of alkyl naphthalene formaldehyde condensation substance, alkylnaphthalene sulfonate and anion wetting agent;
Described solvent includes water, N-Methyl pyrrolidone, DMF, tributyl phosphate, tetrahydrofurfuryl alcohol, first
Benzene, dimethylbenzene, dimethyl sulfoxide, oxolane, 1,4 dioxane, Hexalin, Ketohexamethylene, epoxy soybean oil, plant Semen sojae atricolor
Oil, liquid wax, lubricating oil or solvent naphtha 100, No. 150, No. 180, No. 200 etc., can also be other solvents commonly used in the art;
Described filler is selected from white carbon, Kaolin, precipitated calcium carbonate, kieselguhr, corn starch, quartz sand, Pulvis Talci, sulfur
One or more of sour ammonium, sodium sulfate, sodium chloride, potassium chloride, fine particle calcium carbonate etc.;
Antifreezing agent is selected from one or more of ethylene glycol, propylene glycol, carbamide, diethylene glycol, glycerol etc.;
Thickening agent be selected from xanthan gum, polyvinyl alcohol, organobentonite, hydroxymethyl cellulose, aluminium-magnesium silicate etc. one kind or
Several.
The advantage of the compound herbicide of the present invention is:
Rationally, potentiation is notable, can be used for wheat paddock after seedling cauline leaf process and prevents and kill off broad leaved weed for component.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage ratio in embodiment is weight ratio, but this
Bright it is not limited thereto.
1st, toxicity measures
For further appreciating that the synergy to weeds for the mixture of the application, the present inventor is to quinmerac, chlorine fluorine pyrrole oxygen second
The mixture of acid and florasulam has carried out cauline leaf process synergy toxicity and has measured.
Test material:Herba Galii Teneri, Herba stellariae mediae.
Test method:Weigh a certain amount of weeding effective ingredient active compound, after fully dissolving, be configured to single dose mother solution respectively,
Serial proportioning is arranged according to mixture purpose, each proportioning arranges 5~7 Concentraton gradient.Select that there is generation according to single dose herbicidal spectrum
The susceptible weeds seed of table, cultivates standby to 3 leaf 1 heart.After the weeds cauline leaf process that will select to number, it is placed on illumination box
Middle incubated at room temperature 20 days, calculates prevention effect (fresh weight preventive effect or strain preventive effect), then calculates ED with method of least square50(95% puts
Letter limit), then calculate co-toxicity coefficient (CTC) with the abundant method of Sun Yun.Co-toxicity coefficient (CTC) >=120 shows as potentiation;Co-toxicity coefficient
(CTC)≤80 show as antagonism;80 < co-toxicity coefficient (CTC) < 120 show as summation action.Test result is shown in Table 1-4.
The synergy measurement result to Herba Galii Teneri for the table 1 different ratio quinmerac fluroxypyr
Medicament | Proportioning | ED50(ga.i/ mu) | Co-toxicity coefficient |
Quinmerac (abbreviation quinoline) | —— | 10.52 | —— |
Fluroxypyr (abbreviation chlorine) | —— | 12.39 | —— |
Quinoline chlorine | 1:50 | 10.22 | 120.81 |
Quinoline chlorine | 5:45 | 9.29 | 131.04 |
Quinoline chlorine | 10:40 | 9.17 | 130.48 |
Quinoline chlorine | 30:30 | 6.89 | 165.15 |
Quinoline chlorine | 50:10 | 8.82 | 122.35 |
Quinoline chlorine | 100:5 | 7.89 | 134.30 |
Quinoline chlorine | 150:1 | 8.71 | 120.90 |
The synergy measurement result to Herba Galii Teneri for the table 2 different ratio quinmerac fluroxypyr florasulam
Medicament | Proportioning | ED50(ga.i/ mu) | Co-toxicity coefficient |
Quinmerac (abbreviation quinoline) | —— | 10.52 | —— |
Fluroxypyr (abbreviation chlorine) | —— | 12.39 | —— |
Florasulam (referred to as double) | —— | 13.17 | —— |
Quinoline chlorine is double | 1:1:40 | 10.81 | 120.93 |
Quinoline chlorine is double | 2:1:2 | 9.36 | 126.38 |
Quinoline chlorine is double | 5:20:1 | 9.91 | 121.16 |
Quinoline chlorine is double | 8:1:3 | 9.07 | 123.77 |
Quinoline chlorine is double | 10:10:1 | 6.63 | 172.74 |
Quinoline chlorine is double | 20:1:2 | 8.61 | 125.20 |
Quinoline chlorine is double | 50:10:1 | 7.99 | 135.46 |
Quinoline chlorine is double | 150:1:5 | 8.62 | 122.95 |
Table 3, the synergy measurement result to Herba stellariae mediae for the different ratio quinmerac fluroxypyr
Medicament | Proportioning | ED50(ga.i/ mu) | Co-toxicity coefficient |
Quinmerac (abbreviation quinoline) | —— | 12.07 | —— |
Fluroxypyr (abbreviation chlorine) | —— | 13.01 | —— |
Quinoline chlorine | 1:50 | 10.72 | 121.18 |
Quinoline chlorine | 5:45 | 10.45 | 123.54 |
Quinoline chlorine | 10:40 | 10.21 | 125.47 |
Quinoline chlorine | 30:30 | 7.23 | 173.20 |
Quinoline chlorine | 50:10 | 9.42 | 129.69 |
Quinoline chlorine | 100:5 | 10.09 | 120.04 |
Quinoline chlorine | 150:1 | 10.05 | 120.16 |
The synergy measurement result to Herba stellariae mediae for the table 4 different ratio quinmerac fluroxypyr florasulam
Medicament | Proportioning | ED50(ga.i/ mu) | Co-toxicity coefficient |
Quinmerac (abbreviation quinoline) | —— | 12.07 | —— |
Fluroxypyr (abbreviation chlorine) | —— | 13.01 | —— |
Florasulam (referred to as double) | —— | 14.37 | —— |
Quinoline chlorine is double | 1:1:40 | 11.81 | 120.83 |
Quinoline chlorine is double | 2:1:2 | 10.62 | 123.33 |
Quinoline chlorine is double | 5:20:1 | 10.01 | 128.51 |
Quinoline chlorine is double | 8:1:3 | 9.27 | 136.49 |
Quinoline chlorine is double | 10:10:1 | 8.13 | 154.98 |
Quinoline chlorine is double | 20:1:2 | 9.66 | 127.12 |
Quinoline chlorine is double | 50:10:1 | 9.94 | 123.21 |
Quinoline chlorine is double | 150:1:5 | 10.02 | 121.14 |
The measurement result of table 1-4 shows, quinmerac and fluroxypyr, quinmerac, fluroxypyr and double fluorine sulphur
Careless amine is respectively in 1-150-1-50 and 1-150:1-20:In the proportion of 0.1-40, it is respectively provided with obvious potentiation.
2nd, example of formulations
Embodiment 1,51% quinmerac fluroxypyr wettable powder
Quinmerac 1%, fluroxypyr 50%, sodium lignin sulfonate 9%, dodecylbenzene sodium sulfonate 8%, ethyoxyl
Castor oil polyoxyethylene ether 5%, Kaolin add to 100%, and mixture carries out comminution by gas stream, and 51% quinmerac chlorine fluorine pyrrole is obtained
Fluoroacetic acid wettable powder.
Embodiment 2,50% quinmerac fluroxypyr water dispersible granules
Quinmerac 5%, fluroxypyr 45%, alkylnaphthalene sulfonate 6.5%, lauryl sulphate acid calcium 8%, alkyl phenol
Polyoxyethylene ether sulfosuccinates 5%, glycerol 1%, Kaolin add to 100%, are mixed to prepare 50% quinmerac chlorine fluorine
Pyrrole fluoroacetic acid water dispersible granules.
Embodiment 3,50% quinmerac fluroxypyr suspending agent
Quinmerac 10%, fluroxypyr 40%, arylphenol polyoxyethylene succinate sulfonate 5%, ethyoxyl castor
Oleum Sesami 5%, pull open powder 6%, organosilicon 0.5%, xanthan gum 3%, ethylene glycol 0.5%, deionized water add to 100%, mixing system
Obtain 50% quinmerac fluroxypyr suspending agent.
Embodiment 4,60% quinmerac fluroxypyr suspension emulsion
Quinmerac 30%, fluroxypyr 30%, alkylaryl polyoxyethylene ether 8%, wetting and penetrating agent F 4%, tell
Temperature 80 6%, silicone oil 0.5%, polyvinyl alcohol 5%, propylene glycol 0.5%, deionized water add to 100%, are mixed to prepare 60% quinoline grass
Sour fluroxypyr suspension emulsion.
Embodiment 5,60% quinmerac fluroxypyr microemulsion
Quinmerac 50%, fluroxypyr 10%, dimethyl sulfoxide 5%, 3-methyl cyclohexanol ketenes 7%, dodecyl
Sodium sulfate 8%, diethylene glycol 0.5%, silicone oil 0.5%, methylcellulose 8%, deionized water supplies 100%, is mixed to prepare 60%
Quinmerac fluroxypyr microemulsion.
Embodiment 6,21% quinmerac fluroxypyr cream
Quinmerac 20%, fluroxypyr 1%, calcium dodecyl benzene sulfonate 16%, fatty alcohol-polyoxyethylene ether 4%,
Single oleamide polyoxyethylene groups disodium sulfosuccinate 13%, propylene glycol 1%, N-Methyl pyrrolidone supplies 100%.Will be above-mentioned
Raw material mix homogeneously remembers 21% quinmerac fluroxypyr cream.
Embodiment 7,15.1% quinmerac fluroxypyr florasulam oil-suspending agent
Quinmerac 15%, fluroxypyr 0.1%, sodium alkyl benzene sulfonate 13%, styrene phenol polyoxyethylene ether
4%, fatty acid polyethylene glycol ester 5%, glycerol 3%, soybean oil adds to 100% weight portion.Blended through raw material, high speed shear
Dispersion 30min, with being obtained 15.1% quinmerac fluroxypyr oil-suspending agent after sand mill sand milling.
Embodiment 8,42% quinmerac fluroxypyr florasulam suspending agent
Quinmerac 1%, fluroxypyr 1%, florasulam 40%, alkylphenol polyoxyethylene 11%, dodecane
Base benzene sulfonic acid sodium salt 3%, polycarboxylate 3%, xanthan gum 5%, glycerol 1%, water to 100%, join according to conventional formulation method
Make the quinmerac fluroxypyr florasulam suspending agent that weight/mass percentage composition is 41%.
Embodiment 9,50% quinmerac fluroxypyr florasulam wettable powder
Quinmerac 20%, fluroxypyr 10%, florasulam 20%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 11%, wooden
Plain sodium sulfonate 1%, sorbitan fatty acid ester polyoxyethylene ether 5%, alkylphenol polyoxyethylene 5%, white carbon 4%,
Kaolin supplies 100%, is configured to, according to conventional formulation method, the quinmerac chlorine fluorine pyrrole oxygen that weight/mass percentage composition is 50%
Acetic acid florasulam wettable powder.
Embodiment 10,26% quinmerac fluroxypyr florasulam water dispersible granules
Quinmerac 5%, fluroxypyr 20%, florasulam 1%, polycarboxylate 17%, alkylnaphthalene sulfonate first
Aldehyde condensate 5%, ethoxy castor oil 9%, calcium dodecyl benzene sulfonate 5%, White Carbon black 1%, kieselguhr adds to 100% weight
Part.The frequent regulation of above-mentioned raw materials fetch water dispersible granule method mix, ultra micro comminution by gas stream, mixing, granulation step are produced
26% quinmerac fluroxypyr florasulam water dispersible granules.
Embodiment 11,24% quinmerac fluroxypyr florasulam aqueous emulsion
Quinmerac 16%, fluroxypyr 2%, florasulam 6%, sorbitan fatty acid ester polyoxyethylene groups
Ether 15%, alkylphenol polyoxyethylene 15%, glycerol 1%, xanthan gum 2%, water supplies 100%, according to conventional preparation side
Method is configured to the quinmerac fluroxypyr florasulam aqueous emulsion that weight/mass percentage composition is 24%.
Embodiment 12,21% quinmerac fluroxypyr florasulam cream
By quinmerac 10%, fluroxypyr 10%, florasulam 1%, calcium dodecyl benzene sulfonate 15%, fat
Polyoxyethylenated alcohol 15%, single oleamide polyoxyethylene groups disodium sulfosuccinate 19%, Oleic acid 11%, dimethyl sulfoxide are supplied
100%, mix homogeneously, both obtained 21% quinmerac fluroxypyr florasulam cream preparation.
Embodiment 13,23% quinmerac fluroxypyr florasulam oil-suspending agent
Quinmerac 20%, fluroxypyr 1%, florasulam 2%, sodium alkyl benzene sulfonate 13%, styrene phenol
Polyoxyethylene ether 15%, epoxy soybean oil 6%, glycerol 2%, Oleum Ricini adds to 100% weight portion.Blended through raw material, high
Speed shearing dispersion 30min, is suspended with 23% quinmerac fluroxypyr florasulam oil is obtained after sand mill sand milling
Agent.
Embodiment 14,61% quinmerac fluroxypyr florasulam suspending agent
Quinmerac 50%, fluroxypyr 10%, florasulam 1%, aryl phenol polyoxyethylene succinate sulfonic acid
Salt 5%, ethoxy castor oil 5%, Polyvinylpyrrolidone 3%, organosilicon 0.5%, xanthan gum 3%, ethylene glycol 0.5%, go
Ionized water adds to 100%, is mixed to prepare 61% quinmerac fluroxypyr florasulam suspending agent.
Embodiment 15,15.6% quinmerac fluroxypyr florasulam suspension emulsion
Quinmerac 15%, fluroxypyr 0.1%, florasulam 0.5%, alkylaryl polyoxyethylene ether 8%, fat
Fat alcohol polyethylene glycol ether sulfate 14%, dispersant NNO 6%, silicone oil 0.5%, polyvinyl alcohol 5%, propylene glycol 0.5%, go from
Sub- water adds to 100%, is mixed to prepare 15.6% quinmerac fluroxypyr florasulam suspension emulsion.
3rd, field control effectiveness test
Reagent agent:Complex weedicide in embodiment 1-15.
Comparison medicament:20% fluroxypyr cream (comparison medicament 1), 20% florasulam suspending agent (comparison medicine
Agent 2), 50% quinmerac wettable powder (comparison medicament 3).
Preventing and treating crop:Semen Tritici aestivi.
Prevent and kill off object:Herba Galii Teneri, Herba stellariae mediae, Stellaria alsine Grim., Herba veronicae.
Test method:Test and carry out in wheat paddock, each group processes 3 repetitions, processing area is about 20m2, according to
The area of experimental plot, the good various medicaments of precise, after seedling cauline leaf process.30d weeds death condition after statistics administration, compares
The activity of weeding of various medicaments.The results are shown in Table 5.
30d herbicidal effect after the compositionss medicine containing quinmerac for the table 5
Field experiment result shows, quinmerac fluroxypyr, quinmerac fluroxypyr double fluorine sulphur grass
The preventive effect of the broad leaved weeds such as the compounding Herba Galii Teneri to wheat paddock of amine, Herba stellariae mediae, Stellaria alsine Grim., Herba veronicae is all preferable, compared with single dose,
Activity of weeding is enhanced, and potentiation is obvious.Estimated according to field, in the range of test dose, plant growth is just
Often, have no that plant produces poisoning and abnormal phenomena, to Semen Tritici aestivi safety.Illustrate, quinmerac fluroxypyr, quinmerac chlorine
After fluorine pyrrole fluoroacetic acid florasulam compounds, can have complementary advantages, expand weed control spectrum, reduce each plant demand, reduce use
Cost.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this
A little simple variant belong to protection scope of the present invention.
Claims (6)
1. a kind of containing quinmerac, fluroxypyr and florasulam compound herbicide it is characterised in that described removes
Careless agent with quinmerac, fluroxypyr and florasulam as principle active component, quinmerac, fluroxypyr and double fluorine
The weight ratio of sulphur grass amine is for 1-150:1-50:0-40.
2. compound herbicide according to claim 1 is it is characterised in that quinmerac, fluroxypyr and florasulam
Weight than for 1-150:1-20:0.1-40, preferably 5-150:1-20:0.1-5.
3. according to the arbitrary described compound herbicide of claim 1-2 it is characterised in that the content of effective ingredient is 1-85%, excellent
Select 20-75%.
4. according to the arbitrary described compound herbicide of claim 1-3 it is characterised in that compound herbicide and insecticides adjuvant are prepared
Any one dosage form allowing is become on pesticide.
5. according to the arbitrary described compound herbicide of claim 1-4 it is characterised in that the dosage form of described herbicide dissipates for moisture
Granule, wettable powder, cream, aqueous suspension agent, oil suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
6. the arbitrary described compound herbicide of claim 1-5 prevents and kill off broad leaved weed for wheat paddock after seedling cauline leaf process.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019030614A1 (en) * | 2017-08-08 | 2019-02-14 | Upl Ltd | Synergistic herbicidal combinations |
CN111449071A (en) * | 2020-05-12 | 2020-07-28 | 侨昌现代农业有限公司 | Suspending emulsion type mixed herbicide and its production process |
WO2022204753A1 (en) * | 2021-03-29 | 2022-10-06 | Adama Australia Pty Limited | Highly loaded florasulam formulations |
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CN102318618A (en) * | 2011-07-07 | 2012-01-18 | 陕西美邦农药有限公司 | Weeding composition containing florasulam and fluroxypyr |
CN102630685A (en) * | 2012-04-25 | 2012-08-15 | 河南省农业科学院 | Composite weedicide |
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CN111449071A (en) * | 2020-05-12 | 2020-07-28 | 侨昌现代农业有限公司 | Suspending emulsion type mixed herbicide and its production process |
WO2022204753A1 (en) * | 2021-03-29 | 2022-10-06 | Adama Australia Pty Limited | Highly loaded florasulam formulations |
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