CN104839171A - Weeding composition containing triazole napropamide and oxyfluorfen - Google Patents
Weeding composition containing triazole napropamide and oxyfluorfen Download PDFInfo
- Publication number
- CN104839171A CN104839171A CN201510216887.2A CN201510216887A CN104839171A CN 104839171 A CN104839171 A CN 104839171A CN 201510216887 A CN201510216887 A CN 201510216887A CN 104839171 A CN104839171 A CN 104839171A
- Authority
- CN
- China
- Prior art keywords
- oxyfluorfen
- grass amine
- acyl grass
- triazole acyl
- triazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to weeding composition containing triazole napropamide and oxyfluorfen. The weight ratio of the effective compoents, triazole napropamide and oxyfluorfen, is 10:1 to 1:5. The weeding composition has remarkable synergistic interaction and is applicable to removing annual weeds in rice fields. Compared with single dosage independently used, weeding effect is remarkably improved, and weeding spectrum is enlarged. Meanwhile, pesticide usage is reduced, the environment pollution is reduced, herbicide resistance of weeds is suppressed, and service life of pesticide is prolonged.
Description
Technical field
The present invention relates to agricultural chemicals Herbicidal combinations and application thereof, specifically a kind of with triazole acyl grass amine and the Oxyfluorfen Herbicidal combinations that is active ingredient binary built, be applied to and prevent and kill off paddy field annual weed.
Background technology
Triazole acyl grass amine (ipfencarbazone): be a kind of novel triazolineone weed killer herbicide, be mainly used in paddy field and prevent and kill off grassy weed, broad leaved weed and the sedge weeds such as barnyard grass, moleplant seed, difformed galingale herb, Monochoria vaginalis, mexicana.
Oxyfluorfen (oxyfluorfen): be contact killing type weed killer herbicide, medicament enters in weeds body mainly through coleoptile, mesocotyl, kills by the young shoot of the weeds of seminal propagation and seedling.This medicament broad weed-killing spectrum, multiple broad leaved weed, sedge weed and grassy weed can be prevented and kill off, as difformed galingale herb, barnyard grass, moleplant seed, needle spikesedge herb, Monochoria vaginalis, water three-coloured amaranth, cyperus iria, sweet wine intestines, dichotomous fimbristylis herb, four leaf duckweeds, false loosestrife, firefly Lin, pondweed, mexicana, short arrowhead, Procumbent Falsepimpernel etc.
By the screening of different pesticide species compounded formula, filter out rational formula, effectively can improve the actual control efficiency to disease pest and weed, expanding prevention is composed, reduce dosage, reduce costs, alleviate the pollution to environment, delaying the drug-fast generation of disease pest and weed, is the important means of the agriculturally disease pest and weed comprehensive regulation.
The composite use of the present inventor to triazole acyl grass amine and Oxyfluorfen conducts in-depth research, a large amount of formula indoors screening and field medicine effect test basis on, surprisingly triazole acyl grass amine and Oxyfluorfen carry out composite, within the scope of certain compound proportion, significant synergistic function is shown to paddy field weed, after further study, the present invention is completed.
Summary of the invention
The object of the present invention is to provide a kind of there is remarkable synergistic function, expand herbicide spectrum, use cost is low, control efficiency good, the active ingredient of safety and environmental protection is triazole acyl grass amine and the Herbicidal combinations of Oxyfluorfen.
Technical scheme: for achieving the above object, the invention provides a kind of Herbicidal combinations being active ingredient with triazole acyl grass amine and Oxyfluorfen, the weight ratio of triazole acyl grass amine and Oxyfluorfen is 10:1 ~ 1:5, triazole acyl grass amine and Oxyfluorfen weight summation percentage by weight are in the composition 0.1 ~ 85%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
Described Herbicidal combinations according to well known to a person skilled in the art method, can be mixed with the application forms of the applicable agricultural uses such as oil-suspending agent, aqueous suspension agent, granule, wetting powder, water dispersible granules, effervescent tablet, aqueous emulsion, microemulsion and film-spreading oil solution.
Described Herbicidal combinations is also containing the agriculturally acceptable insecticides adjuvant of preparation needed for pesticidal preparations, be selected from one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, bleeding agent, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, carrier, medium, surfactant, be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
The production technology of the various application forms of described Herbicidal combinations all belongs to existing known technology, does not repeat them here.
Herbicidal combinations provided by the invention, is applied to and prevents and kill off paddy field annual weed.
Compared with prior art, the invention has the advantages that:
1, triazole acyl grass amine and Oxyfluorfen compositely have significant synergistic function, are used alone the control efficiency significantly improved weeds than single dose, expand herbicide spectrum.
2, triazole acyl grass amine and Oxyfluorfen two kinds of active ingredients composite, the mechanism of action is different, can delay the generation of herbicide resistance, extend the Pesticide use life-span.
3, triazole acyl grass amine and Oxyfluorfen two kinds of active ingredients composite, decrease Pesticide use amount, reduce use cost, alleviate pollution to environment.
Embodiment
In order to understand essence of the present invention better; below in conjunction with embodiment, content of the present invention is described further; but can not limitation of the present invention be considered as; the following stated is only for explaining the present invention; for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
(1) Formulation Example
In following each embodiment, active ingredient adopts the 90% triazole acyl grass former medicine of amine and the former medicine of 97% Oxyfluorfen, and each component percentages is weight percentage.
Embodiment 1:40% triazole acyl grass amine Oxyfluorfen water dispersible granules
Triazole acyl grass amine 30%, Oxyfluorfen 10%, lauryl sodium sulfate 10%, glycerine fatty acid fat APEO 10%, to methoxyl group fatty acyl anilinesulfonic acid 10%, ammonium sulfate 3%, Sodium Polyacrylate 2%, fine particle calcium carbonate supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant, binding agent and solid carrier are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, 40% triazole acyl grass amine Oxyfluorfen water dispersible granules can be obtained.
Embodiment 2:60% triazole acyl grass amine Oxyfluorfen wetting powder
Triazole acyl grass amine 45%, Oxyfluorfen 15%, sodium butylnaphthalenesulfonate 10%, aerosol-OT salt 5%, sodium methylene bis-naphthalene sulfonate 5%, attapulgite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant and solid carrier are mixed, again through air-flow crushing after mechanical crushing, mixes, 60% triazole acyl grass amine Oxyfluorfen wetting powder can be obtained.
Embodiment 3:25% triazole acyl grass amine Oxyfluorfen oil-suspending agent
Triazole acyl grass amine 10%, Oxyfluorfen 15%, neopelex 10%, fat dispersing agent MF 15%, the formaldehyde condensation products 10% of methyl naphthalene sulfonic acid sodium, methylcellulose 2%, ethyl acetate supplies 100%.By above-mentioned active ingredient, wetting agent, dispersant, thickener and liquid-carrier after sand milling in high speed shear dispersion, sand mill, the high dispersive formed in non-water-medium, stable suspension system, can obtain 25% triazole acyl grass amine Oxyfluorfen oil-suspending agent.
Embodiment 4:1% triazole acyl grass amine Oxyfluorfen granule
Triazole acyl grass amine 0.5%, Oxyfluorfen 0.5%, sodium butylnaphthalenesulfonate 12%, alkylphenol polyoxyethylene 15%, polyvinyl methyl ethermaleic anhydride 2%, Sodium Polyacrylate 20%, kaolin complements to 100%.Above-mentioned active ingredient, wetting agent, dispersant, sustained release agent, binding agent and solid carrier are mediated through mixing and water adding; pinch-out granulator is used to pinch out and be shaped; afterwards by particle fluid-bed drying, screening, 1% triazole acyl grass amine Oxyfluorfen granule can be obtained.
Embodiment 5:30% triazole acyl grass amine Oxyfluorfen effervescent tablet
Triazole acyl grass amine 10%, Oxyfluorfen 20%, lauryl sodium sulfate 5%, fatty alcohol-polyoxyethylene ether 12%, low-substituted hydroxypropyl cellulose 3%, citric acid 10%, saleratus 15%, calcium stearate 5%, sodium alginate 2%, kaolin complements to 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant, solid acid, carbonate, flowing regulator, binding agent and solid carrier are fully mixed, then 0.3 ~ 5 μm is crushed to the broken machine of low-temperature submicron powder, then the binding agent with water furnishing pasty state is added, tablet press machine film-making is used after stirring, finally by oven dry, whole grain, detect, pack after, 30% triazole acyl grass amine Oxyfluorfen effervescent tablet can be obtained.
Embodiment 6:35% triazole acyl grass amine oxyfluorfen water emulsion
Triazole acyl grass amine 15%, Oxyfluorfen 20%, Ben-zylphenol Polyoxyethyl Ether 20%, 2-butyl acetate 10%, cyclohexanone 5%, propane diols 2%, silicone oil 0.2%, gum Arabic 0.2%, deionized water complements to 100%.First by active ingredient, emulsifier, solvent together, dissolving becomes uniform oil phase.Then again part water and antifreezing agent, defoamer, thickener are mixed, dissolve and become uniform aqueous phase.Then aqueous phase is joined oil phase while high-speed stirred in a kettle., slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add remaining water, shear about 30min, 35% triazole acyl grass amine oxyfluorfen water emulsion can be obtained.
Embodiment 7:15% triazole acyl grass amine Oxyfluorfen film-spreading oil solution
Triazole acyl grass amine 10%, Oxyfluorfen 5%, fatty acid methyl ester 15%, nitrogen methyl pyrrolidone 5%, alkylphenol polyoxyethylene 10%, OPEO phosphate 10%, ethyl acetate complements to 100%.After active ingredient solvent is fully dissolved, first add dispersant, finally add film forming agent, be fully uniformly mixed to transparent, 15% triazole acyl grass amine Oxyfluorfen film-spreading oil solution can be obtained.
Embodiment 8:40% triazole acyl grass amine Oxyfluorfen microemulsion
Triazole acyl grass amine 25%, Oxyfluorfen 15%, dimethyl carbonate 15%, cyclohexanone 5%, alkaryl phenol polyethenoxy ether phosphate 15%, xylitol 2%, organosilicon 1%, double to kill 2.5%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, the triazole acyl grass amine Oxyfluorfen microemulsion of 40% can be obtained.
Embodiment 9:20% triazole acyl grass amine oxyfluorfen water suspension
Triazole acyl grass amine 15%, Oxyfluorfen 5%, neopelex 15%, naphthalene sulfonic acid-formaldehyde condensation product 10%, polycarboxylate 10%, xanthans 3%, glycerine 2%, silicone oil 0.2%, deionized water supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, thickener, antifreezing agent, defoamer and deionized water are mixed, sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 20% triazole acyl grass amine oxyfluorfen water suspension.
(2) indoor biological determination of activity embodiment
Reagent agent: the 90% triazole acyl grass former medicine of amine and the former medicine of 97% Oxyfluorfen.
For examination target: Monochoria vaginalis (Monochoria vaginalis), barnyard grass (Echinochloacrusgalli), difformed galingale herb (Cyperus difformis).
Test method: at the in-built quantitative soil of the polypots of high 6cm, diameter 9cm, will for 15 ~ 20 sowings of examination target weed seed in polypots, be placed in greenhouse after the fine earth that lid 0.5 ~ 1cm is thick and cultivate, treat that weeds grow to the 1-2 leaf phase and carry out spraying process, every alms bowl spraying liquid 1mL, often process repetition 4 times, and set the process not containing medicament as contrasting.After process, examination material is placed in greenhouse and cultivates, and the growing state of routine observation target weeds, estimates target damage symptoms and growth inhibition situation, and claim acrial part fresh weight after 20d.Carry out statistical analysis with DPS statistical analysis software, calculate the ED of each medicament
50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 1, triazole acyl grass amine and Oxyfluorfen are to the synergy measurement result of Monochoria vaginalis
As shown in Table 1, triazole acyl grass amine and Oxyfluorfen composite in the scope of 10:1 ~ 1:5 (by weight) time, co-toxicity coefficient is all greater than 120, illustrates and shows synergistic function to Monochoria vaginalis; Especially composite with 3:1 (by weight), synergistic function is the most remarkable, and co-toxicity coefficient is 306.71.Visible triazole acyl grass amine and Oxyfluorfen is composite has reasonability and feasibility.
Table 2, triazole acyl grass amine and Oxyfluorfen are to the synergy measurement result of barnyard grass
As shown in Table 2, triazole acyl grass amine and Oxyfluorfen composite in the scope of 10:1 ~ 1:5 (by weight) time, co-toxicity coefficient is all greater than 120, illustrates and shows synergistic function to barnyard grass; Especially composite with 3:1 (by weight), synergistic function is the most remarkable, and co-toxicity coefficient is 297.10.Visible triazole acyl grass amine and Oxyfluorfen is composite has reasonability and feasibility.
Table 3, triazole acyl grass amine and Oxyfluorfen are to the synergy measurement result of difformed galingale herb
As shown in Table 3, triazole acyl grass amine and Oxyfluorfen composite in the scope of 10:1 ~ 1:5 (by weight) time, co-toxicity coefficient is all greater than 120, illustrates and shows synergistic function to difformed galingale herb; Especially composite with 3:1 (by weight), synergistic function is the most remarkable, and co-toxicity coefficient is 310.85.Visible triazole acyl grass amine and Oxyfluorfen is composite has reasonability and feasibility.
(3) field efficacy checking embodiment
Selecting weeds that more paddy field occurs is test plot.6 process are established in test altogether, often 3 repetitions are established in process, process 1 is 60% triazole acyl grass amine Oxyfluorfen wetting powder (45:15), process 2 is 40% triazole acyl grass amine Oxyfluorfen water dispersible granules (30:10), process 3 is 20% triazole acyl grass amine oxyfluorfen water suspension (15:5), process 4 is 10% triazole acyl grass amine wetting powder, process 5 is 240 grams per liter oxyfluorfen ECs, process 6 is contrast (not dispenser not weeding), within after medicine 30 days, adds up each process number of weeds amount and calculates preventive effect.
Table 4, each chemicals treatment prevent and kill off the field control effectiveness test result of paddy field annual weed
As can be seen from the field test results of table 4, the preventive effect of the weeds such as process 1 in 30 days after medicine, process 2 and the process barnyard grass of 3 pairs of paddy fields, moleplant seed, difformed galingale herb, mexicana, Monochoria vaginalis and short arrowhead significantly better than process 4 and process 5, will not find in pilot survey process that process 1, process 2 and process 3 pairs of paddy rice produce poisoning simultaneously.As can be seen here, Herbicidal combinations obvious synergy of the present invention, compare single dose be used alone expand herbicide spectrum, improve preventive effect, effectively can prevent and kill off the various weeds of paddy field, to crop safety, be worth applying in agricultural production.
Claims (3)
1. one kind contains the Herbicidal combinations of triazole acyl grass amine and Oxyfluorfen, it is characterized in that: active ingredient is triazole acyl grass amine and Oxyfluorfen, the weight ratio of triazole acyl grass amine and Oxyfluorfen is 10:1 ~ 1:5, triazole acyl grass amine and Oxyfluorfen weight summation percentage by weight are in the composition 0.1 ~ 85%, and all the other are the auxiliary element allowing in agricultural chemicals to use.
2. the Herbicidal combinations containing triazole acyl grass amine and Oxyfluorfen according to claim 1, is characterized in that: the formulation of described Herbicidal combinations can be the one in oil-suspending agent, aqueous suspension agent, granule, wetting powder, water dispersible granules, effervescent tablet, aqueous emulsion, microemulsion or film-spreading oil solution.
3. the Herbicidal combinations containing triazole acyl grass amine and Oxyfluorfen according to claim 1 is preventing and kill off the application in paddy field annual weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510216887.2A CN104839171B (en) | 2015-04-29 | 2015-04-29 | Herbicidal combinations containing three azole amides and Oxyfluorfen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510216887.2A CN104839171B (en) | 2015-04-29 | 2015-04-29 | Herbicidal combinations containing three azole amides and Oxyfluorfen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104839171A true CN104839171A (en) | 2015-08-19 |
| CN104839171B CN104839171B (en) | 2018-04-27 |
Family
ID=53839481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510216887.2A Active CN104839171B (en) | 2015-04-29 | 2015-04-29 | Herbicidal combinations containing three azole amides and Oxyfluorfen |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104839171B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106982845A (en) * | 2017-05-19 | 2017-07-28 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing the Evil humulones of ring penta and three azole amides |
| CN110839648A (en) * | 2018-08-21 | 2020-02-28 | 燕化永乐（乐亭）生物科技有限公司 | Weeding composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
| CN104430465A (en) * | 2014-11-18 | 2015-03-25 | 山东滨农科技有限公司 | Herbicide composition containing clefoxidim |
-
2015
- 2015-04-29 CN CN201510216887.2A patent/CN104839171B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
| CN104430465A (en) * | 2014-11-18 | 2015-03-25 | 山东滨农科技有限公司 | Herbicide composition containing clefoxidim |
Non-Patent Citations (1)
| Title |
|---|
| 陈亮: "四唑酰草胺――一种新颖的稻田除草剂", 《世界农药》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106982845A (en) * | 2017-05-19 | 2017-07-28 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing the Evil humulones of ring penta and three azole amides |
| CN110839648A (en) * | 2018-08-21 | 2020-02-28 | 燕化永乐（乐亭）生物科技有限公司 | Weeding composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104839171B (en) | 2018-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104255750A (en) | Herbicide composition containing pyraclonil and pretilachlor | |
| CN103766372A (en) | Weeding composition containing flucarbazone sodium and saflufenacil | |
| CN102326551B (en) | Weeding composition containing diflufenican | |
| CN103283778A (en) | Weeding composition comprising glufosinate and saflufenacil | |
| CN103749480A (en) | Paddy field herbicide composition and application | |
| CN104585206A (en) | Weeding composition containing pretilachlor, pyriminobac-methyl and metazosulfuron | |
| CN104255749A (en) | Herbicide composition containing pyraclonil and benzobicylon | |
| CN101564038B (en) | Insecticidal composition containing metaflumizone | |
| CN104012548A (en) | Weed control composition containing pyraclonil and penoxsulam | |
| CN104542663A (en) | Weeding composition containing halosulfuron-methyl and quinclorac as well as fluroxypyr | |
| CN104824006A (en) | Weed killing composition containing ipfencarbazone and benzobicylon | |
| CN105028449A (en) | Pesticide composition of herbicide of penoxsulam and oxaziclomefone as well as sulfonylurea | |
| CN102273476B (en) | Pesticide composition containing bispyribac-sodium | |
| CN105284829A (en) | Weeding composition containing (E)-pyriminobac-methyl, oxyfluorfen and oxadiargyl | |
| CN104839171A (en) | Weeding composition containing triazole napropamide and oxyfluorfen | |
| CN104823987A (en) | Weeding composition containing ipfencarbazone and oxadiargyl | |
| CN105076200A (en) | Weeding composition containing glyphosate and florasulam | |
| CN105052973A (en) | Pesticide composition containing pyriminobac-methyl, oxadiargyl and sulfonylurea herbicide | |
| CN104222112A (en) | Weeding composition for paddy field | |
| CN105265464A (en) | Weeding composition containing pyrithiobac-sodium, oxyfluorfen and sulfonylurea herbicide | |
| CN104585188A (en) | Weeding composition containing fluorochloropyridyl ester, pyraflufen-ethyl and pinoxaden | |
| CN104012547A (en) | Weed control composition containing pyraclonil and cyhalofop-butyl | |
| CN104719317A (en) | Weeding composition containing halauxifen-methyl, carfentrazone-ethyl and mesosulfuron-methyl | |
| CN105265441B (en) | Herbicidal combinations containing KIH 6127 and Oxyfluorfen and pretilachlor | |
| CN104396985A (en) | Sorghum field herbicide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |