CN104585188A - Weeding composition containing fluorochloropyridyl ester, pyraflufen-ethyl and pinoxaden - Google Patents
Weeding composition containing fluorochloropyridyl ester, pyraflufen-ethyl and pinoxaden Download PDFInfo
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Abstract
The invention relates to a weeding composition containing fluorochloropyridyl ester, pyraflufen-ethyl and pinoxaden. The active ingredients of the weeding composition are fluorochloropyridyl ester, pyraflufen-ethyl and pinoxaden; the weight ratio of fluorochloropyridyl ester to pyraflufen-ethyl to pinoxaden, is (1-10):(1-10):(1-10). The weeding composition has synergetic effect, and is obviously superior to an independently used single agent in the effect of preventing and weeding annular weeds in a wheat field; the weed control spectrum is expanded, and meanwhile, the dosage of pesticide is reduced, the pollution on the environment is reduced, and the drug resistance of the weeds is delayed.
Description
Technical field
The present invention relates to agricultural chemicals Herbicidal combinations and application thereof, specifically a kind of with fluorine chloropyridine ester, pyrrole grass ether, the azoles quinoline grass ester ternary built Herbicidal combinations that is active ingredient, be mainly used in and prevent and kill off wheat paddock annual weed.
Background technology
At present, chemical control remains the means main in the Farmland weed comprehensive regulation.But long-term use single chemical herbicide continuously high dose, easily cause environmental pollution, easily to develop immunity to drugs etc. to crop generation poisoning and weeds problem.Meanwhile, because grass when weeds in field occurs is complicated, of a great variety mutually, as the mixing of the weeds such as grassy weed, broad leaved weed occurs, the use of single variety can not effectively address this problem, all can show defect in a certain respect.Rational chemical herbicide is composite to be had and expands herbicidal spectrum, improves control efficiency, extends the optimum period for applying fertilizer, reduces dosage, reduces poisoning, reduces and remain, delay the plurality of advantages such as drug-fast generation and development.Visible, chemical herbicide is composite is one of the effective method the most solved the problem.
Fluorine chloropyridine ester (halauxifen-methyl): belong to pyridine carboxylic acid class weed killer herbicide, the mechanism of action is auxins growth inhibitor, be mainly used in preventing and treating the broad leaved weed in wheat paddock, especially to clearvers, chickweed and cannabis weeds, there is special efficacy.It is by microorganism fast degradation in the environment, can be succeeding crop plantation and provides larger flexibility.
Pyrrole grass ether (fcarfentrazone-ethyl): belong to triazolineone contact killing type selective herbicide, the mechanism of action is the accumulation by suppressing proporphyrinogen oxidase to cause poisonous intermediate, thus destroy the cell membrane of weeds, make blade withered, dead rapidly.Be applicable to wheat, barley, paddy rice, seeding corn and other crops prevent and kill off broad leaved weed and sedge weed.
Azoles quinoline grass ester (pinoxaden): belong to phenylpyrrazolin class weed killer herbicide, the mechanism of action is the inhibitor of acetyl-CoA carboxylase, can be used for the grassy weed such as wheatland Control Wild oat, Wang grass, hard grass, amur foxtail, Alopecurus.
Variety classes weed killer herbicide mixture, have herbicidal spectrum wide, promote actual effect, delay herbicide resistance, time and labour saving advantage.Being screened by formulation of pesticide, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of herbicide resistance, is the important means that agricultural synthesis is administered.The ternary built of the present inventor to fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester uses and conducts in-depth research, a large amount of formula indoors screening and field medicine effect test basis on, surprisingly fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester carry out ternary built, within the scope of certain compound proportion, significant synergistic function is all shown to the multiple wheat paddock such as amur foxtail, shepherd's purse annual weed, after further study, the present invention is completed.
Not yet find the relevant report of fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester ternary built at present.
Summary of the invention
The object of the present invention is to provide a kind of have remarkable synergistic function, expand herbicide spectrum, use cost is low, control efficiency good, the Wheat field weeding composition of safety and environmental protection.
The technical scheme realizing the object of the invention is: a kind of Herbicidal combinations, active ingredient is fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester, the ratio of weight and number of fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester three kinds of active ingredients is 1 ~ 10:1 ~ 10:1 ~ 10, the weight summation percentage by weight in the composition of fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester three kinds of active ingredients is 5% ~ 95%, and all the other are agriculturally acceptable insecticides adjuvant.
Described Herbicidal combinations can according to well known to a person skilled in the art method, select suitable pesticidal preparations auxiliary element, the application forms that the applicable agricultural productions such as oil-suspending agent, aqueous suspension agent, microemulsion, wetting powder, water dispersible granules and aqueous emulsion use can be processed into.
The auxiliary element that the present invention uses comprises wetting agent, stabilizing agent, dispersant, disintegrant, thickener, pH adjusting agent, defoamer, antifreezing agent, filler etc., be all auxiliary agent conventional in Pesticide formulation, concrete composition and consumption are determined by test according to recipe requirements.
Herbicidal combinations provided by the invention, is applicable to wheat paddock and prevents and kill off annual weed.
The frequency of administration of Herbicidal combinations provided by the invention and amount of application change with crops, weeds, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Product described in the invention can the form of finished product preparation provide, and namely in composition, each material mixes, and the composition of composition also can the form of single dose provide, and directly mixes in tank or bucket, be then diluted to required concentration before using.
Herbicidal combinations provided by the invention has following beneficial effect:
1, Herbicidal combinations provided by the invention, obvious synergy or summation action is shown in certain ratio range, the control efficiency of composition to weeds is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2, Herbicidal combinations provided by the invention, the combination of three kinds of active ingredients, expands herbicidal spectrum, and a drug can solve weed problem, compensate for defect when single dose uses and limitation.
3, Herbicidal combinations provided by the invention, three kinds of active ingredient mechanism of action are not quite identical, can overcome the shortcoming that long-term single use easily produces resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4, Herbicidal combinations provided by the invention, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Embodiment
In order to understand essence of the present invention better; below in conjunction with embodiment, content of the present invention is described further; but can not limitation of the present invention be considered as; the following stated is only for explaining the present invention; for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
Example of formulations
In following each embodiment, active ingredient adopts the former medicine of 93% fluorine chloropyridine ester, the 95% pyrrole grass former medicine of ether and the former medicine of 95% azoles quinoline grass ester, and each component percentages is weight percentage.
Example of formulations 1:65% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester water dispersible granules.
Fluorine chloropyridine ester 20%, pyrrole grass ether 10%, azoles quinoline grass ester 35%, alkylnaphthalene sulfonate 5%, methyl naphthalene sulfonic acid sodium formaldehyde condensation products 5%, to methoxyl group fatty acyl anilinesulfonic acid 5%, sodium hexametaphosphate 3%, hydroxyethylcellulose 0.5%, silicone oil 0.1%, anhydrous calcium chloride 0.1%, diatomite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant, binding agent, defoamer, stabilizing agent and solid carrier are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, 65% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester water dispersible granules can be obtained.
Example of formulations 2:40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester water dispersible granules.
Fluorine chloropyridine ester 5%, pyrrole grass ether 5%, azoles quinoline grass ester 30%, sldium lauryl sulfate 5%, dibutyl naphthalenesulfonic acid formaldehyde condensation products 5%, to methoxyl group fatty acyl anilinesulfonic acid 5%, sodium hexametaphosphate 3%, polyvinyl acetate 0.5%, capric acid 0.1%, anhydrous calcium chloride 0.1%, diatomite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant, binding agent, defoamer, stabilizing agent and solid carrier are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, 40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester water dispersible granules can be obtained.
Example of formulations 3:80% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester wetting powder.
Fluorine chloropyridine ester 10%, pyrrole grass ether 10%, azoles quinoline grass ester 60%, aerosol-OT salt 3%, sodium butylnaphthalenesulfonate 5%, to methoxyl group fatty acyl anilinesulfonic acid 5%, attapulgite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant and solid carrier are mixed, again through air-flow crushing after mechanical crushing, mixes, 80% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester wetting powder can be obtained.
Example of formulations 4:63% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester wetting powder.
Fluorine chloropyridine ester 14%, pyrrole grass ether 7%, azoles quinoline grass ester 42%, Morwet EFW 5%, sldium lauryl sulfate 5%, epoxidized polyether 5%, bentonite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant and solid carrier are mixed, again through air-flow crushing after mechanical crushing, mixes, 63% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester wetting powder can be obtained.
Example of formulations 5:25% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester oil suspending agent.
Fluorine chloropyridine ester 5%, pyrrole grass ether 5%, azoles quinoline grass ester 15%, calcium dodecyl benzene sulfonate 5%, fatty alcohol-polyoxyethylene ether 5%, naphthalene sulfonic acid condensate sodium salt 10%, to methoxyl group fatty acyl anilinesulfonic acid 5%, xanthans 2%, corn oil supplies 100%.By above-mentioned active ingredient, emulsifier, dispersant, thickener and liquid-carrier after sand milling in high speed shear dispersion, sand mill, the high dispersive formed in non-water-medium, stable suspension system, can obtain 25% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester oil suspending agent.
Example of formulations 6:30% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester oil suspending agent.
Fluorine chloropyridine ester 15%, pyrrole grass ether 10%, azoles quinoline grass ester 5%, ethoxylated castor oil 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 5%, epoxidized polyether 10%, to methoxyl group fatty acyl anilinesulfonic acid 5%, polyvinyl acetate 2%, corn oil supplies 100%.By above-mentioned active ingredient, emulsifier, dispersant, thickener and liquid-carrier after sand milling in high speed shear dispersion, sand mill, the high dispersive formed in non-water-medium, stable suspension system, can obtain 30% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester oil suspending agent.
Example of formulations 7:40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester microemulsion.
Fluorine chloropyridine ester 15%, pyrrole grass ether 10%, azoles quinoline grass ester 15%, loose base oil 10%, 2-butyl acetate 10%, phenethyl phenol polyoxyethylene polyoxypropylene ether 10%, epoxidized soybean oil 2%, organosilicon 1%, thiophene ketone 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, 40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester microemulsion can be obtained.
Example of formulations 8:35% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester microemulsion.
Fluorine chloropyridine ester 10%, pyrrole grass ether 10%, azoles quinoline grass ester 15%, ethanol 10%, 2-butyl acetate 10%, alkylaryl polyoxyethylene polyoxypropylene ether 10%, epoxidized soybean oil 2%, organosilicon 1%, thiophene ketone 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, 35% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester microemulsion can be obtained.
Example of formulations 9:40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous emulsion.
Fluorine chloropyridine ester 20%, pyrrole grass ether 10%, azoles quinoline grass ester 10%, alkylaryl polyoxyethylene polyoxypropylene ether 10%, fatty acid methyl ester 10%, 2-butyl acetate 10%, propane diols 2%, silicone oil 0.5%, gum Arabic 0.2%, Sodium Benzoate 0.1%, deionized water complements to 100%.First by active ingredient, emulsifier, solvent together, dissolving becomes uniform oil phase.Then again part water and antifreezing agent, defoamer, thickener, preservative are mixed, dissolve and become uniform aqueous phase.Then aqueous phase is joined oil phase while high-speed stirred in a kettle., slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add remaining water, shear about 30min, 40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous emulsion can be obtained.
Example of formulations 10:16% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous emulsion.
Fluorine chloropyridine ester 2%, pyrrole grass ether 2%, azoles quinoline grass ester 12%, alkylaryl polyoxyethylene polyoxypropylene ether 10%, isopropyl alcohol 10%, 2-butyl acetate 10%, propane diols 2%, capric acid 0.5%, carbonyl methylol 0.2%, Sodium Benzoate 0.1%, deionized water complements to 100%.First by active ingredient, emulsifier, solvent together, dissolving becomes uniform oil phase.Then again part water and antifreezing agent, defoamer, thickener, preservative are mixed, dissolve and become uniform aqueous phase.Then aqueous phase is joined oil phase while high-speed stirred in a kettle., slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add remaining water, shear about 30min, 16% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous emulsion can be obtained.
Example of formulations 11:20% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous suspension agent.
Fluorine chloropyridine ester 10%, pyrrole grass ether 5%, azoles quinoline grass ester 5%, naphthalene sulfonic acid condensate sodium salt 3%, to methoxyl group fatty acyl anilinesulfonic acid 3%, aerosol-OT salt 2%, xanthans 2%, glycerine 2%, silicone oil 0.1%, Sodium Benzoate 0.1%, azone 1.5%, deionized water supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, thickener, antifreezing agent, defoamer, preservative, synergist and deionized water are mixed, sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 20% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous suspension agent.
Example of formulations 12:25% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous suspension agent.
Fluorine chloropyridine ester 10%, pyrrole grass ether 5%, azoles quinoline grass ester 10%, the sodium salt 4% to methoxyl group fatty acyl anilinesulfonic acid 3%, alkyl naphthalene sulfonic acid condensation polymer, sldium lauryl sulfate 2%, sodium alginate 2%, glycerine 2%, silicone oil 0.1%, Sodium Benzoate 0.1%, azone 1.5%, deionized water supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, thickener, antifreezing agent, defoamer, preservative, synergist and deionized water are mixed, sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 25% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous suspension agent.
Assays Example one: toxicity determination test.
Reagent agent: the former medicine of 93% fluorine chloropyridine ester, the 95% pyrrole grass former medicine of ether and the former medicine of 95% azoles quinoline grass ester.
For examination target: amur foxtail (Alopecurus aequalis Sobol.), shepherd's purse (Capsellabursa-pastoris (L.) Medic).
Medicament configuration design: fluorine chloropyridine ester single dose is configured to 1,3,5g a.i./ha solution for standby; Pyrrole grass ether single dose is configured to 1,3,5g.a.i./ha solution for standby; Azoles quinoline grass ester single dose is configured to 8,18,28g.a.i./ha solution for standby; Fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester mixture are configured to 1+1+8,1+1+18,1+1+28,1+3+8,1+3+18,1+3+28,1+5+8,1+5+18,1+5+28,3+1+8,3+1+18,3+1+28,3+3+8,3+3+18,3+3+28,3+5+8,3+5+18,3+5+28,5+1+8,5+1+18,5+1+28,5+3+8,5+3+18,5+3+28,5+5+8,5+5+18,5+5+28ga.i./ha solution for standby.
Test method: at the in-built quantitative soil of the polypots of high 6cm, diameter 9cm, will for 15 ~ 20 sowings of examination target weed seed in polypots, be placed in greenhouse after the fine earth that lid 0.5 ~ 1cm is thick and cultivate, treat that weeds grow to the 2-3 leaf phase and carry out spraying process, every alms bowl spraying liquid 1mL, often process repetition 4 times, and set the process not containing medicament as contrasting.After process, examination material is placed in greenhouse and cultivates, and the growing state of routine observation target weeds, estimates target damage symptoms and growth inhibition situation, and claim acrial part fresh weight after 20d, evaluates medicament to the toxicity action of target weeds with target fresh weight inhibition.
Investigation method: estimate target damage symptoms and growth inhibition situation after test process 20d, and claim acrial part fresh weight, calculate fresh weight inhibition (%).
Synergy evaluation method: evaluate weed killer herbicide mode of application (NY/T1155.7-2006) according to Colby method, its formula is: E
0=X × Y × Z/100
2, in formula, X be fluorine chloropyridine ester alone with certain dosage time be the percentage of contrast to the fresh weight inhibition of target weeds; Y be pyrrole grass ether alone with certain dosage time be the percentage of contrast to the fresh weight inhibition of target weeds; Z be azoles quinoline grass ester alone with certain dosage time be the percentage of contrast to the fresh weight inhibition of target weeds; E
0for when fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester three kinds of pharmacy mix to target weeds fresh weight inhibition being the theoretical value of the percentage contrasted; E is fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester three kinds of pharmacy mix time be the measured value of percentage of contrast to target weeds fresh weight inhibition.
Evaluation criterion: work as E
0synergistic effect is expressed as, as-10%≤E during-E>10%
0be expressed as summation action during-E≤10%, work as E
0antagonism is expressed as during-E<-10%.
As can be seen from the Toxicity Determination result of table 1, fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester Ternary respectively process the E to amur foxtail
0-E (%) value is all greater than 10%, and more than 20%, illustrates that three is composite and have significant synergistic function to amur foxtail; As can be seen from the Toxicity Determination result of table 2, fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester Ternary respectively process the E to shepherd's purse
0-E (%) value is all greater than 10%, and more than 20%, illustrates that three is composite and have significant synergistic function too to shepherd's purse.As can be seen here, fluorine chloropyridine ester, pyrrole grass ether and azoles quinoline grass ester Ternary have reasonability and feasibility.
Table 1, each chemicals treatment are to the Toxicity Determination result of amur foxtail
Table 2, each chemicals treatment are to the Toxicity Determination result of shepherd's purse
Assays Example two: field control effectiveness test.
Drug effect demonstration test is carried out at wheat paddock, 10 process are established in test altogether, often 3 repetitions are established in process, process 1 is 40% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester water dispersible granules (5:5:30), process 2 is 80% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester wetting powder (10:10:60), process 3 is 16% fluorine chloropyridine ester pyrrole grass ether azoles quinoline grass ester aqueous emulsion (2:2:12), process 4 is 10% fluorine chloropyridine ester pyrrole grass ether water dispersible granules (5:5), process 5 is 35% fluorine chloropyridine ester azoles quinoline grass ester water dispersible granules (5:30), process 6 is 35% pyrrole grass ether azoles quinoline grass ester water dispersible granules (5:30), process 7 is 7.5% fluorine chloropyridine emulsifiable concentrate, process 8 is 2% pyrrole grass ether suspending agent, process 9 is 5% azoles quinoline grass emulsifiable concentrate, process 10 is contrast (not dispenser not weeding), 30 days each process weeds death condition of statistics after medicine also calculate preventive effect.
The field control effectiveness test result of table 3, each chemicals treatment eliminating weed in wheat field
As can be seen from Table 3, after medicine, 30 days ternary builts (process 1, process 2 and process 3) use and all obviously will be higher than binary built (process 4, process 5 and process 6) to the preventive effect of the annual weed such as wheat paddock amur foxtail, wild oat, Triticum tauschii, shepherd's purse, Descurainia sophia and clearvers and to use and single dose (process 7, process 8 and process 9) is used alone, and do not find that process 1, process 2 and process 3 pairs of wheats produce poisoning in pilot survey process simultaneously.As can be seen here, ternary weeding composition obvious synergy of the present invention, compares binary built or single dose and is used alone and expands herbicide spectrum, improve preventive effect, effectively can prevent and kill off the various weeds of wheat paddock, to crop safety, be worth applying in agricultural production.
Claims (4)
1. one kind contains the Herbicidal combinations of fluorine chloropyridine ester and pyrrole grass ether and azoles quinoline grass ester, it is characterized in that: active ingredient is fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester, the ratio of weight and number of fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester three kinds of active ingredients is 1 ~ 10:1 ~ 10:1 ~ 10, and the weight summation percentage by weight in the composition of fluorine chloropyridine ester, pyrrole grass ether, azoles quinoline grass ester three kinds of active ingredients is 5% ~ 95%.
2. a kind of Herbicidal combinations containing fluorine chloropyridine ester and pyrrole grass ether and azoles quinoline grass ester according to claim 1, is characterized in that: described Herbicidal combinations also contains pesticidal preparations auxiliary element, to make the application forms of applicable agricultural use.
3. a kind of Herbicidal combinations containing fluorine chloropyridine ester and pyrrole grass ether and azoles quinoline grass ester according to claim 2, is characterized in that: its formulation is the one in oil-suspending agent, aqueous suspension agent, microemulsion, wetting powder, water dispersible granules and aqueous emulsion.
4. a kind of Herbicidal combinations containing fluorine chloropyridine ester and pyrrole grass ether and azoles quinoline grass ester according to claim 1 is to prevent and kill off the application in wheat paddock annual weed.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105340895A (en) * | 2015-11-26 | 2016-02-24 | 北京燕化永乐生物科技股份有限公司 | Weeding composition |
| CN107018982A (en) * | 2017-03-31 | 2017-08-08 | 山东滨农科技有限公司 | A kind of herbicidal composition containing pinoxaden |
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| CN101453894A (en) * | 2005-12-27 | 2009-06-10 | 先正达参股股份有限公司 | Herbicidal composition |
| CN103025166A (en) * | 2010-05-21 | 2013-04-03 | 拜耳知识产权有限责任公司 | Herbicidal agents for tolerant or resistant grain cultures |
| CN104145982A (en) * | 2014-08-28 | 2014-11-19 | 联保作物科技有限公司 | Wheat field weeding composition and medicine preparation thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1376032A (en) * | 1999-09-07 | 2002-10-23 | 辛根塔参与股份公司 | Herbicidal composition |
| CN101453894A (en) * | 2005-12-27 | 2009-06-10 | 先正达参股股份有限公司 | Herbicidal composition |
| CN101360713A (en) * | 2006-01-13 | 2009-02-04 | 美国陶氏益农公司 | 6-(poly-substituted aryl)-4-aminopicolinates and their use as herbicides |
| CN103025166A (en) * | 2010-05-21 | 2013-04-03 | 拜耳知识产权有限责任公司 | Herbicidal agents for tolerant or resistant grain cultures |
| CN104145982A (en) * | 2014-08-28 | 2014-11-19 | 联保作物科技有限公司 | Wheat field weeding composition and medicine preparation thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105340895A (en) * | 2015-11-26 | 2016-02-24 | 北京燕化永乐生物科技股份有限公司 | Weeding composition |
| CN107018982A (en) * | 2017-03-31 | 2017-08-08 | 山东滨农科技有限公司 | A kind of herbicidal composition containing pinoxaden |
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| CN104585188B (en) | 2018-06-19 |
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