CN106665618A - Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases - Google Patents
Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases Download PDFInfo
- Publication number
- CN106665618A CN106665618A CN201611238747.6A CN201611238747A CN106665618A CN 106665618 A CN106665618 A CN 106665618A CN 201611238747 A CN201611238747 A CN 201611238747A CN 106665618 A CN106665618 A CN 106665618A
- Authority
- CN
- China
- Prior art keywords
- ether amide
- pest
- preventing
- rice
- fipronil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of a pesticide, and relates to a bactericidal pesticidal composition capable of generating a synergistic effect and used for preventing and treating paddy pests and diseases. Two pesticide preparations with different active components are mixed to prevent damage resulting from paddy pests and diseases. The bactericidal pesticidal composition contains effective components of chlorobenzene ether amide or fluorobenzene ether amide taken as a bactericide and flufiprole taken as a pesticide, wherein the mass ratio of chlorobenzene ether amide or fluorobenzene ether amide to flufiprole is 1-10:20-100. Besides, the composition further includes an accessory agent, and the mass percentage of the effective components of chlorobenzene ether amide or fluorobenzene ether amide and flufiprole is 5-90% of that of the composition. The provided bactericidal pesticidal composition is effective, is suitable for preventing and treating paddy sheath blight diseases, rice blast and chilo suppressalis, and is low in toxicity and excellent in pesticidal bactericidal activity. The consumption of the bactericidal pesticidal composition is reduced, generation of the drug resistance is delayed, the duration is extended, and the environmental pollution is limited.
Description
Technical field
The invention belongs to pesticide field, is related to a kind of synergistic sterilization for preventing and treating rice pest of energy generation and kills
Worm compositionss and its using method, are prevented due to rice pest by mixing the pesticidal preparations of two kinds of different activities compositions
The loss for causing.
Background technology
Chlorobenzene ether amide or fluorobenzene ether amide are Central China Normal University's pyrazol acid amide compounds newly developed, to Fructus Cucumidis sativi,
The diseases such as epidemic disease, downy mildew, the tikka of the plants such as Fructus Lycopersici esculenti, Rhizoma Solani tuber osi have good prevention effect, while to Oryza sativa L. and Semen Tritici aestivi
Banded sclerotial blight, powdery mildew etc. have good preventive effect.Field test shows do not have cross resistance with existing antibacterial.Chlorobenzene ether amide
Structural formula（I）With fluorobenzene ether amide（II）It is as follows.
。
Butene-fipronil is also butene-fipronil, is the insecticide of Dalian Rui Ze pesticide chemicals limited company initiative, and it belongs to
In a kind of Phenylpyrazole insecticides, insecticidal spectrum is wide, to insect based on stomach poison function, has concurrently to tag and makees with certain interior suction
Be the chloride metabolism for hindering insecticide γ-aminobutyric acid control with, its mechanism of action, thus to aphid, leafhopper, plant hopper,
The important pests such as lepidopterous larvae, flies and coleoptera have very high insecticidal activity, to crop without poisoning.It is right during foliage spray
Planthopper, rice-stem borer, Yellow Rice Borer, rice leaf roller, striped rice borer, cabbage butterfly, rice thripses etc. have high-level preventive effect,
And the lasting period is long.Structure formula (III) is as follows.
。
Patent CN104557709 discloses chlorobenzene ether amide or fluorobenzene ether amide and is preventing and treating rice sheath blight disease and preventing and treating Fructus Cucumidis sativi
Application in powdery mildew.The compound has good as the antibacterial of active component to rice sheath blight disease and powdery mildew of cucumber
Prevention effect.Disclose in patent CN104886073 the present invention relates to disinfectant use in agriculture field, discloses chlorobenzene ether acyl simultaneously
The bactericidal composition of amine and triazole bactericidal agent, can be used to prevent and treat rice sheath blight disease, treatment and protective effect be had concurrently, with good
Potentiation, and have the advantages that to crop safety.
Patent CN103098808 discloses butene-fipronil and carbamate insecticidess compositionss to be used to prevent and treat agriculture evil
Worm.The prevention effect of the present invention is significantly improved than single dose, reduces the using dosage of pesticide, reduces pesticide to environment
Affect, reduce drug cost.
In the prior art, China is mainly single pest control or single controlling disease for the pesticide of rice seedling,
Can be while pest control and the product development of disease be little.Therefore, the pesticide-germicide combination of exploitation preventing and treating rice seedling pest and disease damage
Thing, for the agriculture large-scale development of propulsion has positive effect.
The content of the invention
It is an object of the invention to provide a kind of sterilization, the Pesticidal combination of preventing and treating rice pest, including antibacterial chlorobenzene
Ether amide or fluorobenzene ether amide and insecticide butene-fipronil.Said composition is used for therapeutic ground and prophylactically prevents and treats causing a disease for plant
Funguses and/or insect, grow wherein including said composition to be applied to plant seed, seedling or Herb or be applied to plant
Or need the soil that plant grows wherein.Especially said composition be used for prevent and treat the diseases such as rice blast, banded sclerotial blight and/or
The insects such as planthopper, striped rice borer, rice leaf roller.And compared with independent pesticide control, there is significant potentiation to prevent to both
Control effect.
Sterilization, Pesticidal combination and its using method for preventing and treating rice pest is to take technical scheme below to realize：
Sterilization, the Pesticidal combination of preventing and treating rice pest, it is characterised in that containing effective ingredient antibacterial chlorobenzene ether amide and
Insecticide butene-fipronil, the wherein quality proportioning of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil are 1~10:20~100.
The quality proportioning of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil is 2~8 in the compositionss:20~80.
The compositionss also contain adjuvant, effective ingredient chlorobenzene ether amide or fluorobenzene ether amide in addition to active ingredient
It is 5-90% with the weight/mass percentage composition that butene-fipronil is accounted in compositionss.
The combination dosage form be cream, microgranule, extrusion granule, wettable powder, aqueous emulsion, water dispersible granules,
Coated granule, suspending agent or microcapsule.
Sterilization, the using method of Pesticidal combination of the preventing and treating rice pest, it is characterised in that with chlorobenzene ether amide
Or fluorobenzene ether amide and butene-fipronil act on pest and disease damage as effective ingredient.
Described pest and disease damage, it is characterised in that the insect pest of preventing and treating rice crop is rice-stem borer, rice leaf roller, rice Ji
Horse；The disease that preventing and treating rice crop pathomycete causes is rice blast, banded sclerotial blight.
Sterilization, the using method of Pesticidal combination of the preventing and treating rice pest, using containing above-mentioned chlorobenzene ether amide
Or the compositionss of fluorobenzene ether amide and butene-fipronil act on pest and disease damage simultaneously, or first make chlorobenzene ether amide or fluorobenzene ether amide and fourth
Any one acts on pest and disease damage to worm nitrile, then makes another kind act on pest and disease damage again.
The compositionss of the present invention represent the various combinations of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil, such as single
" pre-composition " form；The combination spraying mixture being made up of each independent preparation of single-activity component, such as " tank mix "；And
Single-activity composition with consecutive way-i.e. in the period of rationally short（Such as a few hours or a couple of days）When applying one by one
Be used in combination.Preferably, the order of compound chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil is applied generally for realization
The present invention is unimportant.
The present invention has the following advantages that compared with prior art
（1）Expand the preventing and treating spectrum of rice pest；
（2）Delay and administer the Drug resistance of Oryza sativa L. harmful organism；
（3）Significantly lower than similar kind in price with consumption.
The invention provides a kind of insecticidal and bactericidal composition, including the group of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil
Close.It is found by experiment that, the compositionss of the present invention there can not only be additivity to add the action spectrum of plant pathogenic fungi and/or insect
By force, but also at two aspects the action spectrum that can expand compound butene-fipronil, chlorobenzene ether amide or fluorobenzene ether amide is realized
The rate of application of cooperative effect, compound butene-fipronil and chlorobenzene ether amide or fluorobenzene ether amide maintains like good while reduction
Effect.The present composition is particularly well-suited to prevent and treat rice blast, banded sclerotial blight and striped rice borer, rice leaf roller.And with list
Solely using comparing, there is the potentiation prevention effect of reinforcing to both.
Specific embodiment
The following examples are the several specific embodiments for illustrating the present invention, but do not limit the invention to this
A little specific embodiments.One skilled in the art would recognize that present invention encompasses institute may bag in Claims scope
All alternatives, improvement project and the equivalents for including.
In following embodiments material prescription select can treatment in accordance with local conditions, on result without substantial impact.In these embodiments
In, unless otherwise indicated, all percentage ratios are weight percentage.
In the present invention, the ratio of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil is generally 1~10 by weight:20
~100, preferably 2~8:20~80.The compositionss of the present invention also contain adjuvant in addition to effective ingredient.Effective ingredient
Mixed proportion can be 5-90%.Adjuvant can be carrier, emulsifying agent, suspending agent, dispersant, developing solvent, penetrating agent, moistening
Agent, viscosifier, stabilizer etc., can be properly added as needed.Carrier is divided into solid carrier and liquid-carrier.Solid carrier is shallow lake
The animals and plants powder of powder, activated carbon, Semen sojae atricolor powder, wheat flour, wood powder, fish flour, milk powder etc., Talcum, Kaolin, bentonite, carbonic acid
Mineral powder of calcium, zeolite, kieselguhr, white carbon, clay, Alumina, sulfur powder etc. etc.；Liquid-carrier has water, methanol, second
The alcohols of alcohol etc.；The halogen of the arene of dimethylbenzene, trimethylbenzene, durene, hexamethylene, solvent naphtha etc., chloroform, chlorobenzene etc.
For the nitrile of the esters of the amide-type of hydro carbons, dimethylformamide etc., ethyl acetate, fatty glyceride etc., acetonitrile etc., diformazan
Base sulfoxide etc. containing compounds etc..Emulsifying agent, suspending agent, dispersant, developing solvent, penetrating agent, wetting agent etc. can be using each
Plant surfactant.
When the Oryza sativa L. antifungal using the present invention and/insecticidal mixtures prevent the loss that causes due to rice disease
When, described compositionss can directly using using after either being diluted with water or other materials, for cauline leaf process, Shui Chu
The process of reason, soil treatment or raising box.Described compositionss can with other antifungal, Insecticides (tech) ＆ Herbicides (tech), change
Learn fertilizer or soil conditioner is mixed and uses.
The compositionss of the present invention, can be configured to various agriculturally available dosage forms, such as Emulsion, powder, microgranule, granule
The various phychologies of agent, tablet, wettable powder, liquor, water dispersible granules, lake agent, colloidal suspending agent, dry glue suspension, microcapsule etc..
The wherein more preferably form of Emulsion, microgranule, wettable powder, liquor, powder, granule, tablet etc..The preferred cooperation of Emulsion
Ratio is effective ingredient 5-75 weight portions, carrier 90-10 weight portions, surfactant 5-15 weight portions.Other powder,
The optimizing mixing proporiton example of granule and tablet is that effective ingredient 0.1-20 weight portions, carrier 85-99 weight portions and surface are lived
Property agent 0.5-5 weight portions.These preparations can be used directly when actually used, or be diluted to regulation with the diluent of water etc.
Concentration is using.
The present composition can play a role preventing and treating rice crop pest and disease damage, such as rice blast, banded sclerotial blight, rice are recklessly
Numb pinta, rice culm rot, rice leaf roller, striped rice borer, yellow rice borer, rice plant skipper etc..
In addition to the method for harmful organism is processed with the present composition, present invention additionally comprises while with above-mentioned chlorobenzene ether acyl
The method that amine or fluorobenzene ether amide and butene-fipronil process harmful organism, with appointing for chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil
After a kind of chemicals treatment harmful organism, then with the method for another kind of chemicals treatment harmful organism.
Embodiment：
Embodiment 1：25% chlorobenzene ether amide+butene-fipronil suspending agent
Chlorobenzene ether amide 5%
Butene-fipronil 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and water according to formula ratio mix homogeneously, ground and/or height
25% chlorobenzene ether amide+butene-fipronil suspending agent is obtained after speed shearing.
Embodiment 2：25% fluorobenzene ether amide+butene-fipronil suspending agent
Fluorobenzene ether amide 5%
Butene-fipronil 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and water according to formula ratio mix homogeneously, ground and/or height
25% fluorobenzene ether amide+butene-fipronil suspending agent is obtained after speed shearing.
Embodiment 3：25% chlorobenzene ether amide+butene-fipronil wettable powder
Chlorobenzene ether amide 5%
Butene-fipronil 20%
Sodium lauryl sulphate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, Jing after ultra-fine pulverizer disintegrating, that is, is obtained
25% chlorobenzene ether amide+butene-fipronil wettable powder.
Embodiment 4：25% chlorobenzene ether amide+butene-fipronil aqueous emulsion
Chlorobenzene ether amide 5%
Butene-fipronil 20%
N- methyl pyrrolidones 15%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 5%
Water complements to 100%
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare into water phase；
Under high velocity agitation, it is oil phase is mixed with water, 25% chlorobenzene ether amide+butene-fipronil aqueous emulsion is obtained.
The rice leaf roller of test example 1 and banded sclerotial blight are tested
Infect rice leaf roll snout moth's larva and banded sclerotial blight simultaneously on rice crop.Led to the diluent of application concentration needed for following examples
Cross stem and leaf of the sprinkling process to cultivation in the rice crop with one plant of six leaf age in the basin that water logging does not have to spray.And in leaf
Piece still moves into the larva of rice leaf roller under Wet Out.After air-drying, the suspension for spraying sheath blight fungus is inoculated with to plant.
After inoculation, by plant at 20 DEG C, place one week in moist environment, it is then determined that the number of lesion, according to following mark
Prevention index will definitely be arrived.With the killing rate that % forms represent rice leaf roller.100% refers to and has killed all of larva；0% refers to
Larva is not killed.
[standard]
As seen from the above table, potentiation is obvious after chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil are compounded, and vertical to Oryza sativa L. rice
Leaf roll snout moth's larva and rice sheath blight disease have very high preventive effect.
From above-described embodiment and comparative example, chlorobenzene ether amide or fluorobenzene ether amide do not have parasite killing with butene-fipronil single dose
The double effectses of sterilization, chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil mixture, expanding prevention scope.Reach dispenser once i.e.
Can the double effectses that can sterilize again of insect prevention.Mixing medicine at seeding time can once prevent and treat the pest and disease damage of whole Rice Seedlings, reduce labor
Fatigue resistance.
Claims (7)
1. it is a kind of preventing and treating rice pest Fungicidal insecticidal composition, it is characterised in that containing effective ingredient antibacterial chlorobenzene ether acyl
Amine or fluorobenzene ether amide and insecticide butene-fipronil, the wherein quality proportioning of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil are 1
~10:20~100.
2. it is according to claim 1 preventing and treating rice pest Fungicidal insecticidal composition, it is characterised in that the compositionss
The quality proportioning of middle chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil is 2~8:20~80.
3. the Fungicidal insecticidal composition of rice pest is prevented and treated according to claim 1, it is characterised in that the compositionss are removed
Also contain adjuvant outside active ingredient, effective ingredient chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil accounted in compositionss
Weight/mass percentage composition is 5-90%.
4. it is according to claim 1 preventing and treating rice pest Fungicidal insecticidal composition, it is characterised in that the compositionss
Dosage form be cream, microgranule, extrusion granule, wettable powder, aqueous emulsion, water dispersible granules, coated granule, suspending agent
Or microcapsule.
5. it is according to claim 1 preventing and treating rice pest Fungicidal insecticidal composition preventing and treating rice pest in should
With, it is characterised in that pest and disease damage is acted on as effective ingredient using chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil.
6. pest and disease damage according to claim 5, it is characterised in that the insect pest of preventing and treating rice crop is that rice-stem borer, rice are indulged
Leaf roll snout moth's larva, rice thripses；The disease that preventing and treating rice crop pathomycete causes is rice blast, banded sclerotial blight.
7. application of the Fungicidal insecticidal composition of the preventing and treating rice pest described in claim 5 in preventing and treating rice pest,
It is characterized in that making the compositionss of chlorobenzene ether amide or fluorobenzene ether amide and butene-fipronil while acting on pest and disease damage, or first use chlorine
Any one acts on pest and disease damage for phenylate amide or fluorobenzene ether amide and butene-fipronil, then reuses another kind and acts on pest and disease damage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238747.6A CN106665618A (en) | 2016-12-28 | 2016-12-28 | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238747.6A CN106665618A (en) | 2016-12-28 | 2016-12-28 | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106665618A true CN106665618A (en) | 2017-05-17 |
Family
ID=58872246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611238747.6A Pending CN106665618A (en) | 2016-12-28 | 2016-12-28 | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106665618A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109757495A (en) * | 2019-03-07 | 2019-05-17 | 湖南速博生物技术有限公司 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
-
2016
- 2016-12-28 CN CN201611238747.6A patent/CN106665618A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
Non-Patent Citations (1)
| Title |
|---|
| 方圆: ""治稻纵卷叶螟新药——丁烯氟虫腈"", 《江苏农业科技报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109757495A (en) * | 2019-03-07 | 2019-05-17 | 湖南速博生物技术有限公司 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105875613B (en) | A kind of suspension seed-coating agent of disinsection prophylaxis | |
| JP6389610B2 (en) | Herbicidal composition | |
| JP5502854B2 (en) | How to protect soybeans from fungal infection | |
| CN106455573A (en) | Synergistic insecticidal composition comprising neonicotinoid insecticides and pyrethroid insecticides | |
| CN101524075A (en) | Composition containing methylamine-avermetins-benzote | |
| CN104604927A (en) | Seed-treating agent containing clothianidin, pyraclostrobin and metconazole | |
| CN107549190A (en) | Seed treatment composition and its application | |
| CN103329937B (en) | Composition of bactericidal active components | |
| CN103329902B (en) | Insecticidal composition containing spinetoram and monosultap | |
| CN103329924B (en) | Insecticidal composition containing spinetoram and acetamiprid | |
| CN107156158A (en) | A kind of seed treatment compositions containing pyraclostrobin, fluopyram and ethiprole | |
| CN103355301A (en) | Pesticide composition containing pyridalyl | |
| CN105831145A (en) | Pesticide composition containing prochloraz | |
| CN108419804A (en) | A kind of bactericidal composition and its application | |
| CN106665618A (en) | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases | |
| AU731865B2 (en) | Process and composition for the antiparasitic treatment of the surroundings of animals | |
| CN102258022B (en) | Bactericidal and insecticidal composition used for controlling paddy diseases and pests, and application method thereof | |
| CN103493842B (en) | Insecticidal composition | |
| CN104115830B (en) | A kind of Pesticidal combination containing fluorobenzene insect amide and neires toxin | |
| CN106665640A (en) | Clothianidin-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases | |
| CN106665589A (en) | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition | |
| CN104957167A (en) | Thiamethoxam and azoxystrobin pesticide composition | |
| CN105851045A (en) | Pesticide composition containing captan | |
| CN106614662A (en) | Insecticide and fungicide composition containing cycloxaprid | |
| CN109769825A (en) | A kind of multiple killing teichomycin compound pesticide compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |