CN106665589A - Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition - Google Patents
Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition Download PDFInfo
- Publication number
- CN106665589A CN106665589A CN201611238746.1A CN201611238746A CN106665589A CN 106665589 A CN106665589 A CN 106665589A CN 201611238746 A CN201611238746 A CN 201611238746A CN 106665589 A CN106665589 A CN 106665589A
- Authority
- CN
- China
- Prior art keywords
- pest
- rice
- preventing
- chlorantraniliproles
- fluorobenzene ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention belongs to the technical field of pesticides and relates to a tetra-chlorantraniliprole-containing insecticidal and bactericidal composition which can generate the synergistic effect and is used for preventing and treating rice diseases and insect pests, and loss caused by the rice diseases and insect pests can be prevented by mixing two kinds of pesticide preparations containing different ingredients. The tetra-chlorantraniliprole-containing insecticidal and bactericidal composition is prepared from an effective ingredient bactericide of fluorophenyl ester amide and an insecticide of tetra-chlorantraniliprole, wherein the mass ratio of the fluorophenyl ester amide and the tetra-chlorantraniliprole is (1 to 10):(20 to 100). The tetra-chlorantraniliprole-containing insecticidal and bactericidal composition provided by the invention has excellent insecticidal and bactericidal activity; while the dosage is reduced, the generation of drug resistance is delayed, the lasting period is prolonged, and pollution to an environment is reduced.
Description
Technical field
The invention belongs to pesticide field, specifically fluorobenzene ether amide and four chlorantraniliproles for effective ingredient pesticide-germicide
Compositionss.
Background technology
Fluorobenzene ether amide is Central China Normal University's pyrazol acid amide compounds newly developed, to Fructus Cucumidis sativi, Fructus Lycopersici esculenti, Rhizoma Solani tuber osi etc.
The diseases such as epidemic disease, downy mildew, the tikka of plant have good prevention effect, while the banded sclerotial blight, powdery mildew to Oryza sativa L. and Semen Tritici aestivi
Etc. there is good preventive effect.Field test shows do not have cross resistance with existing antibacterial.Shown in structural formula following (I).
。
Four chlorantraniliproles（Code name SYP9080）Researched and developed by subordinate Shenyang Chemical Engineering Inst of Sinochem Corporation, this is
The first bisamide insecticides product with independent intellectual property right of China.It can be used for prevent and treat Oryza sativa L. on striped rice borer, rice indulge
Leaf roll snout moth's larva etc., and the lepidoptera pest such as the diamondback moth on vegetable, Pieris rapae.Four chlorantraniliproles to mammal low toxicity, to sweet
The lepidoptera pest preventive effect such as dish noctuid, diamondback moth, armyworm, striped rice borer is excellent, with preferable application prospect and Development volue.Knot
Shown in structure formula following (II).
。
In prior art, China is used for the pesticide of rice seedling and is mainly single pest control or single controlling disease, can
Pest control simultaneously and the product development of disease are little.Therefore, the insecticidal and bactericidal composition of exploitation preventing and treating rice seedling pest and disease damage,
For the agriculture large-scale development of propulsion has positive effect.
The content of the invention
It is an object of the invention to provide a kind of sterilization, the Pesticidal combination of preventing and treating rice pest, including antibacterial fluorobenzene
Ether amide and the chlorantraniliprole of insecticide four.Said composition be used for therapeutic ground and prophylactically prevent and treat plant pathomycete and/
Or insect, grow wherein or need including said composition to be applied to plant seed, seedling or Herb or be applied to plant
The soil that plant grows wherein.Especially said composition is used to prevent and treat the diseases such as rice blast, banded sclerotial blight and/or rice flies
The insects such as louse, striped rice borer, rice leaf roller.And compared with independent pesticide control, there is significant potentiation preventing and treating effect to both
Really.
The Fungicidal insecticidal composition and its using method of preventing and treating rice pest is to take technical scheme below to realize：
The Fungicidal insecticidal composition of preventing and treating rice pest, it is characterised in that containing effective ingredient antibacterial fluorobenzene ether amide and killing
The chlorantraniliprole of worm agent four, the wherein quality proportioning of fluorobenzene ether amide and four chlorantraniliproles are 1~10:20~100.
The quality proportioning of fluorobenzene ether amide and four chlorantraniliproles is 2~8 in the compositionss:20~80.
The compositionss also contain adjuvant, effective ingredient fluorobenzene ether amide and four chlorantraniliproles in addition to active ingredient
The weight/mass percentage composition accounted in compositionss is 5-90%.
The combination dosage form be cream, microgranule, extrusion granule, wettable powder, aqueous emulsion, water dispersible granules,
Coated granule, suspending agent or microcapsule.
Sterilization, the using method of Pesticidal combination of the preventing and treating rice pest, it is characterised in that with fluorobenzene ether amide
Pest and disease damage is acted on four chlorantraniliproles as effective ingredient.
The using method of the Fungicidal insecticidal composition of the preventing and treating rice pest, using containing above-mentioned fluorobenzene ether amide and
The compositionss of four chlorantraniliproles act on pest and disease damage simultaneously, or any one acts on disease first to make fluorobenzene ether amide and four chlorantraniliproles
Insect pest, then makes again another kind act on pest and disease damage.
The compositionss of the present invention represent the various combinations of fluorobenzene ether amide and four chlorantraniliproles, such as single " pre-composition "
Form；The combination spraying mixture being made up of each independent preparation of single-activity component, such as " tank mix "；And single-activity
Composition with consecutive way-i.e. in the period of rationally short（Such as a few hours or a couple of days）Combination when applying one by one makes
With.Preferably, the order for applying compound fluorobenzene ether amide and four chlorantraniliproles is of the invention unimportant generally for realizing.
Sterilization, the using method of Pesticidal combination of the preventing and treating rice pest, using fluorobenzene ether amide and tetrachloro worm
The ratio of amide is 1~10 in mass ratio:20~100.
The insect pest of the preventing and treating rice crop includes rice-stem borer, rice leaf roller, rice rice thripses etc., and the preventing and treating Oryza sativa L. makees
The disease that thing pathomycete causes includes rice blast, banded sclerotial blight etc..
By the present invention, it is possible to provide while improving the effect of preventing and treating rice insect pest and preventing and treating fungus-caused rice disease
The new antifungal of effect and/insecticidal mixtures and its prevention and controls.
The pest control method discovery of the antifungal of rice crop of the present invention and/insecticidal mixtures and rice crop,
The compositionss of fluorobenzene ether amide and four chlorantraniliproles, for the disease such as rice blast that phytopathogenic fungi causes, linum speckle
Disease, banded sclerotial blight etc. and rice-stem borer, rice leaf roller, thrips etc. can play potentiation.The compositionss of the present invention
And its method, for the effect of the preventing and treating with potentiation of phytopathogenic fungi and insect.The effect has and has from each single medicament
Various disease and insects prevent and kill off the unpredictable effect for arriving in characteristic.
The present invention has the following advantages that compared with prior art
（1）Expand the preventing and treating spectrum of rice pest；
（2）Delay and administer the Drug resistance of Oryza sativa L. harmful organism；
（3）Significantly lower than similar kind in price with consumption.
The invention provides a kind of insecticidal and bactericidal composition, including the combination of fluorobenzene ether amide and four chlorantraniliproles.Pass through
Test finds that the compositionss of the present invention can not only have additivity to strengthen the action spectrum of plant pathogenic fungi and/or insect, and
The cooperative effect that can expand compound tetrachloro insect amide, the action spectrum of fluorobenzene ether amide, compound are also realized at two aspects
The rate of application of four chlorantraniliproles and fluorobenzene ether amide maintains like good effect while reduction.The present composition is especially fitted
For preventing and treating rice blast, banded sclerotial blight and striped rice borer, rice leaf roller.And compared with exclusive use, both are had strong
The potentiation prevention effect of change.
Specific embodiment
The following examples are the several specific embodiments for illustrating the present invention, but do not limit the invention to this
A little specific embodiments.One skilled in the art would recognize that present invention encompasses institute may bag in Claims scope
All alternatives, improvement project and the equivalents for including.
In following embodiments material prescription select can treatment in accordance with local conditions, on result without substantial impact.In these embodiments
In, unless otherwise indicated, all percentage ratios are weight percentage.
In the present invention, the ratio of fluorobenzene ether amide and four chlorantraniliproles is generally 1~10 by weight:20~100, it is excellent
Select 2~8:20~80.The compositionss of the present invention also contain adjuvant in addition to effective ingredient.The mixed proportion of effective ingredient
Can be 5-90%.Adjuvant can be carrier, emulsifying agent, suspending agent, dispersant, developing solvent, penetrating agent, wetting agent, thickening
Agent, stabilizer etc., can be properly added as needed.Carrier is divided into solid carrier and liquid-carrier.Solid carrier is starch, activity
The animals and plants powder of charcoal, Semen sojae atricolor powder, wheat flour, wood powder, fish flour, milk powder etc., Talcum, Kaolin, bentonite, Calcium Carbonate, zeolite,
Mineral powder of kieselguhr, white carbon, clay, Alumina, sulfur powder etc. etc.；Liquid-carrier has the alcohol of water, methanol, ethanol etc.
Class；The halogenated hydrocarbon of the arene of dimethylbenzene, trimethylbenzene, durene, hexamethylene, solvent naphtha etc., chloroform, chlorobenzene etc.,
The nitrile of the esters of the amide-type of dimethylformamide etc., ethyl acetate, fatty glyceride etc., acetonitrile etc., dimethyl sulfoxide
Deng containing compounds etc..Emulsifying agent, suspending agent, dispersant, developing solvent, penetrating agent, wetting agent etc. can use various surfaces
Activating agent.
When the Oryza sativa L. antifungal using the present invention and/insecticidal mixtures prevent the loss that causes due to rice disease
When, described compositionss can directly using using after either being diluted with water or other materials, for cauline leaf process, Shui Chu
The process of reason, soil treatment or raising box.Described compositionss can with other antifungal, Insecticides (tech) ＆ Herbicides (tech), change
Learn fertilizer or soil conditioner is mixed and uses.
The compositionss of the present invention, can be configured to various agriculturally available dosage forms, such as Emulsion, powder, microgranule, granule
The various phychologies of agent, tablet, wettable powder, liquor, water dispersible granules, lake agent, colloidal suspending agent, dry glue suspension, microcapsule etc..
The wherein more preferably form of Emulsion, microgranule, wettable powder, liquor, powder, granule, tablet etc..The preferred cooperation of Emulsion
Ratio is effective ingredient 5-75 weight portions, carrier 90-10 weight portions, surfactant 5-15 weight portions.Other powder,
The optimizing mixing proporiton example of granule and tablet is that effective ingredient 0.1-20 weight portions, carrier 85-99 weight portions and surface are lived
Property agent 0.5-5 weight portions.These preparations can be used directly when actually used, or be diluted to regulation with the diluent of water etc.
Concentration is using.
The present composition can play a role preventing and treating rice crop pest and disease damage, such as rice blast, banded sclerotial blight, rice are recklessly
Numb pinta, rice culm rot, rice leaf roller, striped rice borer, yellow rice borer, rice plant skipper etc..
In addition to the method for harmful organism is processed with the present composition, present invention additionally comprises while with above-mentioned fluorobenzene ether acyl
The method that amine and four chlorantraniliproles process harmful organism, is harmful to any one chemicals treatment of fluorobenzene ether amide and four chlorantraniliproles
After biology, then with the method for another kind of chemicals treatment harmful organism.
Embodiment：
Embodiment 1：The chlorantraniliprole suspending agent of 25% fluorobenzene ether amide+four
Fluorobenzene ether amide 5%
Four chlorantraniliproles 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and water according to formula ratio mix homogeneously, ground and/or height
The chlorantraniliprole suspending agent of 25% fluorobenzene ether amide+four is obtained after speed shearing.
Embodiment 2：The chlorantraniliprole wettable powder of 25% fluorobenzene ether amide+four
Fluorobenzene ether amide 5%
Four chlorantraniliproles 20%
Sodium lauryl sulphate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, Jing after ultra-fine pulverizer disintegrating, that is, is obtained
The chlorantraniliprole wettable powder of 25% fluorobenzene ether amide+four.
Embodiment 3：The chlorantraniliprole aqueous emulsion of 25% fluorobenzene ether amide+four
Fluorobenzene ether amide 5%
Four chlorantraniliproles 20%
N- methyl pyrrolidones 15%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 5%
Water complements to 100%
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare into water phase；
Under high velocity agitation, it is oil phase is mixed with water, the chlorantraniliprole aqueous emulsion of 25% fluorobenzene ether amide+four is obtained.
The rice leaf roller of test example 1 and banded sclerotial blight are tested
Infect rice leaf roll snout moth's larva and banded sclerotial blight simultaneously on rice crop.Led to the diluent of application concentration needed for following examples
Cross stem and leaf of the sprinkling process to cultivation in the rice crop with one plant of six leaf age in the basin that water logging does not have to spray.And in leaf
Piece still moves into the larva of rice leaf roller under Wet Out.After air-drying, the suspension for spraying sheath blight fungus is inoculated with to plant.
After inoculation, by plant at 20 DEG C, place one week in moist environment, it is then determined that the number of lesion, according to following mark
Prevention index will definitely be arrived.With the killing rate that % forms represent rice leaf roller.100% refers to and has killed all of larva；0% refers to
Larva is not killed.
[standard]
| Prevention index | Preventive effect |
| 5 | Prevention value 95% or more |
| 4 | Prevention value 85%-94% |
| 3 | Prevention value 60%-84% |
| 2 | Prevention value 40%-59% |
| 1 | Prevention value 1%-39% |
| Process | G active component/hectare | Prevention index | Mortality rate/%（7 days） |
| Embodiment 1 | 200 | 5 | 92 |
| Embodiment 2 | 200 | 5 | 95 |
| Embodiment 3 | 200 | 5 | 95 |
| 5% fluorobenzene ether amide water dispersible granules | 300 | 3 | 5 |
| 20% 4 chlorantraniliprole water dispersible granules | 300 | 1 | 80 |
As seen from the above table, after fluorobenzene ether amide and four chlorantraniliproles compounding potentiation substantially, and to paddy rice rice leaf roller and
Rice sheath blight disease has very high preventive effect.
From above-described embodiment and comparative example, fluorobenzene ether amide is not double with pesticide-germicide with four chlorantraniliprole single doses
Weight effect, fluorobenzene ether amide and four chlorantraniliprole mixtures, expanding prevention scope.Reach what insect prevention by dispenser once can sterilize again
Double effectses.Mixing medicine at seeding time can once prevent and treat the pest and disease damage of whole Rice Seedlings, reduce labor intensity.
Claims (6)
1. it is a kind of preventing and treating rice pest Fungicidal insecticidal composition, it is characterised in that containing effective ingredient antibacterial fluorobenzene ether acyl
Amine and the chlorantraniliprole of insecticide four, the wherein quality proportioning of fluorobenzene ether amide and four chlorantraniliproles are 1~10:20~100.
2. it is according to claim 1 preventing and treating rice pest Fungicidal insecticidal composition, it is characterised in that the compositionss
The quality proportioning of middle fluorobenzene ether amide and four chlorantraniliproles is 2~8:20~80.
3. sterilization, the Pesticidal combination of rice pest are prevented and treated according to claim 1, it is characterised in that the compositionss are removed
Also contain adjuvant, the quality percentage that effective ingredient fluorobenzene ether amide and four chlorantraniliproles are accounted in compositionss outside active ingredient
Content is 5-90%.
4. it is according to claim 1 preventing and treating rice pest sterilization, Pesticidal combination, it is characterised in that the compositionss
Dosage form be cream, microgranule, extrusion granule, wettable powder, aqueous emulsion, water dispersible granules, coated granule, suspending agent
Or microcapsule.
5. application of the Fungicidal insecticidal composition of the preventing and treating rice pest described in claim 1 in preventing and treating rice pest,
It is characterized in that acting on pest and disease damage as effective ingredient using fluorobenzene ether amide and four chlorantraniliproles；The preventing and treating rice crop
Insect pest is rice-stem borer, rice leaf roller, rice thripses, and the disease that the preventing and treating rice crop pathomycete causes is Oryza sativa L. rice
Pestilence, banded sclerotial blight.
6. application of the Fungicidal insecticidal composition of the preventing and treating rice pest described in claim 5 in preventing and treating rice pest,
It is characterized in that making the compositionss of fluorobenzene ether amide and four chlorantraniliproles while acting on pest and disease damage, or first use fluorobenzene ether amide
Any one acts on pest and disease damage with four chlorantraniliproles, then reuses another kind and acts on pest and disease damage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238746.1A CN106665589A (en) | 2016-12-28 | 2016-12-28 | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238746.1A CN106665589A (en) | 2016-12-28 | 2016-12-28 | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106665589A true CN106665589A (en) | 2017-05-17 |
Family
ID=58872208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611238746.1A Pending CN106665589A (en) | 2016-12-28 | 2016-12-28 | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106665589A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
| CN104642348B (en) * | 2015-03-13 | 2016-10-19 | 河北博嘉农业有限公司 | A kind of insecticidal and bactericidal composition containing thifluzamide |
-
2016
- 2016-12-28 CN CN201611238746.1A patent/CN106665589A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
| CN104642348B (en) * | 2015-03-13 | 2016-10-19 | 河北博嘉农业有限公司 | A kind of insecticidal and bactericidal composition containing thifluzamide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105875613B (en) | A kind of suspension seed-coating agent of disinsection prophylaxis | |
| JP5502854B2 (en) | How to protect soybeans from fungal infection | |
| CN106455573A (en) | Synergistic insecticidal composition comprising neonicotinoid insecticides and pyrethroid insecticides | |
| CN105613537A (en) | Active component composition | |
| CN101524075A (en) | Composition containing methylamine-avermetins-benzote | |
| CN104604927A (en) | Seed-treating agent containing clothianidin, pyraclostrobin and metconazole | |
| CN106818764A (en) | A kind of Pesticidal combination of novel pesticide | |
| CN103329924B (en) | Insecticidal composition containing spinetoram and acetamiprid | |
| CN103329902B (en) | Insecticidal composition containing spinetoram and monosultap | |
| CN107549190A (en) | Seed treatment composition and its application | |
| CN103329937B (en) | Composition of bactericidal active components | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN107156158A (en) | A kind of seed treatment compositions containing pyraclostrobin, fluopyram and ethiprole | |
| CN103355301A (en) | Pesticide composition containing pyridalyl | |
| CN108419804A (en) | A kind of bactericidal composition and its application | |
| CN106359430A (en) | Pesticide composition | |
| AU731865B2 (en) | Process and composition for the antiparasitic treatment of the surroundings of animals | |
| CN106665618A (en) | Flufiprole-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases | |
| CN102258022B (en) | Bactericidal and insecticidal composition used for controlling paddy diseases and pests, and application method thereof | |
| CN106665589A (en) | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition | |
| CN103493842B (en) | Insecticidal composition | |
| CN106797941A (en) | A kind of bactericidal composition with cooperative effect and application thereof | |
| CN106305751A (en) | Pesticide composition | |
| CN106665640A (en) | Clothianidin-containing bactericidal pesticidal composition for preventing and treating paddy pests and diseases | |
| CN105851045A (en) | Pesticide composition containing captan |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |