CN105941452A - Synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof - Google Patents

Synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof Download PDF

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Publication number
CN105941452A
CN105941452A CN201610454140.5A CN201610454140A CN105941452A CN 105941452 A CN105941452 A CN 105941452A CN 201610454140 A CN201610454140 A CN 201610454140A CN 105941452 A CN105941452 A CN 105941452A
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China
Prior art keywords
tebufenozide
sulfoxaflor
insecticidal compositions
synergistic insecticidal
synergistic
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Pending
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CN201610454140.5A
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Chinese (zh)
Inventor
邢刚
陈叶青
杨琴
万维肖
程清云
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610454140.5A priority Critical patent/CN105941452A/en
Publication of CN105941452A publication Critical patent/CN105941452A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof

Abstract

The invention discloses a synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof. The insecticide composition takes sulfoxaflor and tebufenozide as main active ingredients, wherein the weight ratio of sulfoxaflor to tebufenozide is (1-60):(1-60). The insecticide composition has preventing and controlling spectrum expanding effect and synergistic effect, can reduce application cost, can be prepared into missible oil, wettable powder, microemulsion, emulsion in water, a suspending agent and water dispersible granules and can be used for preventing and controlling multiple insect pests in lepidoptera, hemiptera, hymenopteram, coleopteran and the like.

Description

A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of tebufenozide and application
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with sulfoxaflor and tebufenozide the Insecticidal combinations as principle active component Thing and application thereof.
Background technology
Sulfoxaflor (Sulfoxaflor), chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide;Molecule Formula: C10H10F3N3OS;Molecular weight: 277.27;CAS:[946578-00-3].
Sulfoxaflor is the sulfimide insecticide of Tao Shi agricultural sciences exploitation, and sulfimide acts on the nervous system of insecticide, I.e. act on binding site unique in cholinoceptor and play insecticidal function.Plant can be entered through leaf, stem, root absorption In, sulfoxaflor is applicable to prevent and treat Cotton Gossypii fleahopper, aphid, aleyrodid, plant hopper and coccid etc.;Efficiently, quickly and residual effect Phase is long, can effectively prevent and treat nicotinoids, chrysanthemum esters, and organophosphate and carbamate pesticide produces the suction juice class pest of resistance.
Tebufenozide (Tebufenozide), molecular formula: chemical name: N-tert-butyl-n-(4-ethylamino benzonitrile acyl group)-3, 5-dimethylbenzohydrazide, structural formula is:
Tebufenozide is on-steroidal Novel insect growth regulator, is the insect hormone insecticides of up-to-date research and development.Tebufenozide pesticide is lived Property high, selectivity is strong, all effective to all lepidopterous larvaes, antagonism insect bollworm, Pieris rapae, diamondback moth, Radix Betae Noctuids etc. have specially good effect.And have extremely strong ovicidal activity, safer to non-target organism.Be mainly used in prevent and treat mandarin orange, Cotton Gossypii, Aphidiadae on ornamental crops, Rhizoma Solani tuber osi, Semen sojae atricolor, Nicotiana tabacum L., fruit tree and vegetable, Cicadellidae, Lepidoptera, Liriomyza, leaf Demodicid mite section, Thysanoptera, root wart Turbatrix, lepidopterous larvae such as oriental fruit months, Fructus Vitis viniferae steinernema, beet armyworm etc. insect.
Insecticide variety containing single component often existing defects in pesticide Pest control: use is easily developed immunity to drugs continuously, Insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, said composition can be used for preventing Agricultural pests are planted by Zhiduo County, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, beet armyworm With Brown Planthopper etc., a drug can be reached and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide and prevent and treat resistance squama wing in preparation Application in the insecticidal materials of one or more insects in mesh, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it with sulfoxaflor with tebufenozide for mainly effectively becoming Point, wherein, the weight ratio of sulfoxaflor and tebufenozide is 1~60:1~60.Preferably sulfoxaflor and the weight ratio of tebufenozide Being 1~40:1~40, the weight ratio of further preferred sulfoxaflor and tebufenozide is 1~30:1~30.Most preferably flonicamid The weight ratio of nitrile and tebufenozide is 1:1.
In some preferred technical schemes: sulfoxaflor and tebufenozide can 1:30,1:29,1:28,1:27,1:26, 1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、 1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、 10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、 25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、 These ratios of 4:5 select.
In the present invention containing sulfoxaflor and the Synergistic insecticidal compositions of tebufenozide, sulfoxaflor and both tebufenozide are in this increasing Weight percentage in effect Pesticidal combination is 2%~80%, and preferably 8%~60%, optimum is 20%~40%.
The above-mentioned Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide is with sulfoxaflor and tebufenozide as principle active component (active component) and insecticides adjuvant are configured on pesticide any one dosage form allowed.The preferred powder of dosage form, wettable powder, Suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene blocked Compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, anti- Freeze agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or also With.
The above-mentioned Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide preparation preventing and treating Lepidoptera, Semiptera, Hymenoptera or Application in the insecticidal materials of one or more insects in coleoptera.Especially at preparation preventing and treating planthopper or the insecticidal materials of snout moths larva In application effect notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll worm, Radix Betae Noctuid, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect;And suppress insect to unitary agent (fluorine Sulfoxaflor or tebufenozide) Drug resistance produce and simultaneously can prevent and treat Hemipteran pest such as Brown Planthopper etc..
The insecticidal materials prepared by the described Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide prevent and treat resistance Lepidoptera, While Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and beet armyworm There is good preventive effect, reach the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, said composition Insect has notable synergistic, hence it is evident that improve prevention effect;(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, subtracts Preventing and treating recruitment cost less;(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and agriculture Medicine remains;(4) have concurrently quick-acting and long-acting;(5) compared with sulfoxaflor single dose, produce and use cost reduces;(6) press down The resistance of pesticide is strengthened by insect processed.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor bioassay, Co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage;On this basis, then carry out field test.
Embodiment 1:
Weigh 80g sulfoxaflor, 2g tebufenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight Percentage composition is the sulfoxaflor tebufenozide cream of 82%.
Embodiment 2:
Weigh 2g sulfoxaflor, 80g tebufenozide, lignin 10g, Negel 2g, add to 100g with Kaolin, Above raw material is mixed in super micron mill, forms the sulfoxaflor worm that principle active component weight percentage is 82% Hydrazides wettable powder.
Embodiment 3:
Weigh 60g sulfoxaflor, 2g tebufenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component Weight percentage is the sulfoxaflor tebufenozide cream of 62%.
Embodiment 4:
Weigh 2g sulfoxaflor, 60g tebufenozide, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g with water, n-butyl alcohol and water-soluble Solving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect, and Continue to shear 10~30 minutes, form the sulfoxaflor tebufenozide water and milk that principle active component weight percentage is 62% Agent.
Embodiment 5:
Weigh 40g sulfoxaflor, 2g tebufenozide, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and former medicine, solvent, emulsifying agent, cosolvent are mixed Close stirring and form homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight Percentage composition is the sulfoxaflor tebufenozide microemulsion of 42%.
Embodiment 6:
Weigh 2g sulfoxaflor, 40g tebufenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight Amount percentage composition is the sulfoxaflor tebufenozide cream of 42%.
Embodiment 7:
Weigh 20g sulfoxaflor, 2g tebufenozide, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill Effect lower form the sulfoxaflor Tebufenozide suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g sulfoxaflor, 20g tebufenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the sulfoxaflor tebufenozide cream of 22%.
Embodiment 9:
Weigh 2g sulfoxaflor, 10g tebufenozide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component Weight percentage is the sulfoxaflor tebufenozide water dispersible granules of 12%.
Embodiment 10:
Weigh 5g sulfoxaflor, 10g tebufenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the sulfoxaflor tebufenozide cream of 15%.
Embodiment 11:
Weigh 10g sulfoxaflor, 10g tebufenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight Percentage composition is the sulfoxaflor tebufenozide cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh sulfoxaflor, tebufenozide employing conventional formulation method is configured to principle active component weight percent by different proportion and contains Amount is the sulfoxaflor tebufenozide cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure sulfoxaflor and tebufenozide and the compounding sample virulence to cotton boll worm thereof, often process weight Multiple 3 times, every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 sulfoxaflor, tebufenozide and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after sulfoxaflor and tebufenozide mixture, cotton boll worm are had potentiation, listed joining in table Being both greater than 120 than co-toxicity coefficient, therefore sulfoxaflor and tebufenozide mixture have significant synergies.
Weigh sulfoxaflor, tebufenozide employing conventional formulation method is configured to principle active component weight percent by different proportion and contains Amount is the sulfoxaflor tebufenozide cream of 30%.Concrete ratio is shown in Table 2.
Use rice-stem dipping method to measure sulfoxaflor and tebufenozide and the compounding sample virulence to Brown Planthopper thereof, often process weight Multiple 3 times, use LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 sulfoxaflor, tebufenozide and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation after sulfoxaflor and tebufenozide mixture to Brown Planthopper, listed joining in table All being much larger than 120 than co-toxicity coefficient, therefore sulfoxaflor and tebufenozide mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 21.8% flonicamid Nitrile SC and 20% tebufenozide SC, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, good at variable rate technology Good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: with tebufenozide built agent, cotton boll worm and Brown Planthopper are had by sulfoxaflor Significantly synergistic insecticidal action;Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll worm insecticidal effect equally It is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (9)

1., containing sulfoxaflor and a Synergistic insecticidal compositions for tebufenozide, it is characterized in that this Synergistic insecticidal compositions is with fluorine pyridine worm Amine nitrile and tebufenozide are principle active component, and wherein, the weight ratio of sulfoxaflor and tebufenozide is 1~60:1~60.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that this parasite killing group The active ingredient sulfoxaflor of compound and the weight ratio of tebufenozide are 1~40:1~40.
The most according to claim 2 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that this parasite killing group The active ingredient sulfoxaflor of compound and the weight ratio of tebufenozide are 1~30:1~30.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that flonicamid Nitrile and both tebufenozide weight percentage in this Synergistic insecticidal compositions are 2%~80%.
The most according to claim 4 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that flonicamid Nitrile and both tebufenozide weight percentage in this Synergistic insecticidal compositions are 8%~60%.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that this potentiation is killed With sulfoxaflor, as principle active component and insecticides adjuvant is configured on pesticide any one agent of permission to worm compositions with tebufenozide Type.
The most according to claim 6 containing sulfoxaflor with the Synergistic insecticidal compositions of tebufenozide, it is characterized in that described dosage form It is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide described in claim 1 is at preparation preventing and treating Lepidoptera, half wing Application in the insecticidal materials of one or more insects in mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions containing sulfoxaflor and tebufenozide is in system Application in the insecticidal materials of standby preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
CN201610454140.5A 2016-06-21 2016-06-21 Synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof Pending CN105941452A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011126837A (en) * 2009-12-21 2011-06-30 Nippon Nohyaku Co Ltd Agricultural and horticultural pest-controlling agent composition, and method for applying them
CN102308834A (en) * 2011-03-17 2012-01-11 陕西汤普森生物科技有限公司 Pesticidal composition containing flonicamid and hormone compounds
CN103704240A (en) * 2013-12-13 2014-04-09 广西田园生化股份有限公司 Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide
CN104738079A (en) * 2013-12-26 2015-07-01 中国中化股份有限公司 Binary insecticide composition and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011126837A (en) * 2009-12-21 2011-06-30 Nippon Nohyaku Co Ltd Agricultural and horticultural pest-controlling agent composition, and method for applying them
CN102308834A (en) * 2011-03-17 2012-01-11 陕西汤普森生物科技有限公司 Pesticidal composition containing flonicamid and hormone compounds
CN103704240A (en) * 2013-12-13 2014-04-09 广西田园生化股份有限公司 Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide
CN104738079A (en) * 2013-12-26 2015-07-01 中国中化股份有限公司 Binary insecticide composition and application thereof

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