CN103704240A - Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide - Google Patents
Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide Download PDFInfo
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- CN103704240A CN103704240A CN201310674930.0A CN201310674930A CN103704240A CN 103704240 A CN103704240 A CN 103704240A CN 201310674930 A CN201310674930 A CN 201310674930A CN 103704240 A CN103704240 A CN 103704240A
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Abstract
The invention belongs to the pesticide field, and relates to an ultralow volume liquid, which contains sulfoxaflor and insect growth regulating pesticide and can be applied to ultralow volume spraying, low volume spraying, or ultralow volume static spraying so as to achieve the effective control on crop insects. The active component of the ultralow volume liquid is prepared by compounding sulfoxaflor and an active component II, and the rest being surfactant and solvent, wherein the active component II is any one component selected from the following components: flufenoxuron, hexaflumuron, flucycloxuron, chlorfluazuron, diflubenzuron, diafenthiuron, buprofezin and tebufenozide. The ultralow volume liquid has the advantages of convenient processing, long lasting period, high work efficiency, difficult generation of drug resistance of the target insects, low environmental pollution, reduction on pesticide and water consumption, and improvement on the pesticide utilization rate; and is capable of controlling a plurality of insects on paddy rice, wheat, corn, vegetable, tobacco, tea tree, fruit tree and sugarcane through the ultralow volume spraying, low volume spraying, or ultralow volume static spraying.
Description
Technical field
The invention belongs to pesticide field, relate to a kind of by using ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray to realize the fluorine-containing pyridine worm amine nitrile of effective control of crop pest and the ultra low volume liquids of insect growth regulator, IGR insecticides.
Background technology
Fluorine pyridine worm amine nitrile is by Tao Shi benefit agriculture development of new insecticide, English name: sulfoxaflor, chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide, molecular formula is C
10h
10f
3n
3oS; Molecular weight: 277.27; CAS:[946578-00-3]; CIPAC No:820; Structural formula:
The mode of action is to activate the acetylcholinergic receptor of insect, but it is different and novel to act on the mode of acceptor.Its maximum feature is to comprise that with existing organic phosphates, carbamates, pyrethroid, anabasine insecticide are cross resistance, homoptera pest is had to excellent insecticidal activity as aphid, plant hopper etc., and there is efficient, quick-acting, low toxicity, low-residual, interior absorption is good, the duration long, to the non-target organism advantage such as safely, be applicable to tree fruit, grape, vegetables, cotton, paddy rice, cereal and large legume crop, can effectively kill aphid, scale insect, plant hopper, aleyrodid, the insects such as fleahopper and thrips.At present about the ultra low volume liquids patent of fluorine pyridine worm amine nitrile and insect growth regulator, IGR insecticides is not also applied for.
Insect growth regulator, IGR is to change the class specific compound that insect growth is grown, and with regard to the possibility and validity of insect growth control, belongs to non-direct insecticide, by artificial method, controls the growth course of insect, thereby reaches the object of Control pests.This compounds has unique mode of action, selectivity is high, using dosage is little, to the mankind, natural enemy and Environmental security, be difficult for to produce resistance, be therefore more and more subject to people's favor, in the present invention, the chemical name of the related insect growth regulator, IGR insecticides of active component II is as follows:
The chemical name of flufenoxuron is 1-(4-(Α-tri-are chloro-to toloxyl for the chloro-Α of 2-, Α)-2-fluorophenyl)-3-(2,6-difluorobenzene formyl) urea;
The chemical name of HEXAFLUMURON is 1-[3, the chloro-4-of 5-bis-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-(2,6-difluoro benzoyl) urea;
The chemical name of flucycloxuron is 1-(α-(the chloro-α-cyclopropyl of 4-benzal amino oxygen)-p-tolyl)-3-(2-difluoro benzoyl) urea;
The chemical name of fluorine pyridine urea is 1-[3, the chloro-4-of 5-bis-(the chloro-5-trifluoromethyl-2-of 3-pyridine oxygen base) phenyl]-3-(2,6-difluoro benzoyl) urea;
The chemical name of diflubenzuron is 1-(4-chlorphenyl)-3-(2,6-difluoro benzoyl) urea;
The chemical name of Buprofezin is 2-tertbutylimido-3-isopropyl-5-phenyl-1,3,5-thiadiazine-4-ketone;
The chemical name of diafenthiuron is 1-tertiary butyl-3-(2,6-diisopropyl-4-Phenoxyphenyl) thiocarbamide;
The chemical name of worm hydrazides is N-tertiary butyl-N'-(4-ethylamino benzonitrile acyl group)-3,5-dimethyl benzene hydrazides
The inventor is by studies have shown that, the ultra low volume liquids that the arbitrary pesticide active ingredient in fluorine pyridine worm amine nitrile and flufenoxuron, HEXAFLUMURON, flucycloxuron, fluorine pyridine urea, diflubenzuron, diafenthiuron, Buprofezin, worm hydrazides is re-dubbed has extremely strong synergistic effect to target pest.
The solvent that ultra low volume liquids is low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, during dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is owing to not containing high volatile volatile composition in droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, has reduced and has volatilized with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Owing to using without being watered, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large area occurs and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
Summary of the invention
The present invention is just for above technical problem, provide easy to process, with low cost, good drug efficacy, holding effect long, coordinate synergy high, save water; Can reduce environmental pollution, improve agricultural chemicals availability, reduce a kind of fluorine-containing pyridine worm amine nitrile of applications of pesticide amount and the ultra low volume liquids preparation of insect growth regulator, IGR insecticides.
Another object of the present invention is to provide and provides the preparation method of the ultra low volume liquids preparation of a kind of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides.
Technical scheme of the present invention is:
The ultra low volume liquids of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides, this ultra low volume liquids comprises active component I, active component II, surfactant and solvent, wherein active component I is fluorine pyridine worm amine nitrile, active component II is any one of flufenoxuron, HEXAFLUMURON, flucycloxuron, fluorine pyridine urea, diflubenzuron, diafenthiuron, Buprofezin, worm hydrazides, and active component I and active component II are composite is active component.
Described active component, the weight content of its total amount is 0.2%～30%, and wherein the weight content of fluorine pyridine worm amine nitrile is 0.1%～15%, and the weight content of active component II is 0.1%～15%, and the weight content of auxiliary agent is 1%～10%, solvent complements to 100%.
Described surfactant is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, Ben-zylphenol Polyoxyethyl Ether, castor oil ethylene oxide adduct, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, N-methyl fatty acyl group sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, aliphatic alcohol sulfate, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, penetrant t, bleeding agent OT, azone, the mixture of one or more in organosilicon.
Described solvent is one or more the mixture in aromatic hydrocarbon solvent, plant oil solvent and polar solvent.Wherein, aromatic hydrocarbon solvent comprises that aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, methoxy toluene, benzyl methyl ether, butylbenzene, methyl naphthalene, repefral, dibutyl phthalate, dioctyl phthalate and two wires oil.Plant oil solvent comprises soybean oil, epoxidized soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate and ethyl oleate.Polar solvent comprises acetophenone, cyclohexanone, butanone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, N, dinethylformamide, DMA, n-hexyl alcohol, n-octyl alcohol, isoamyl alcohol, Liquid Macrogol, PEG400,2-butyl acetate, diethylene glycol acetate, terpineol and ethanol.
The preparation method of the ultra low volume liquids of a kind of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides is: in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, add again auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
The range of application of the ultra low volume liquids of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides is: applicable target crop is the cereal crops such as paddy rice, wheat, the economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, the vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, the ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is applicable to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resembles star stinkbug, green rice bug resembles, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, is secondly low-gallonage spraying and ultra low volume electrostatic spray, and according to controlling object, a situation arises determines suitable dosage, and formulation rate is 75～150g a.i./hm conventionally
2.
Good effect of the present invention is embodied in:
This ultra low volume liquids is easy to process, with low cost, good drug efficacy, holding effect long, coordinate synergy high, save water; Can reduce environmental pollution, improve agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit the scope of the invention.
Embodiment 1:
Preparation quality percentage composition is 4.1% fluorine pyridine worm amine nitrile flufenoxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 4.0 kg
Flufenoxuron 0.1 kg
1-METHYLPYRROLIDONE 5.0 kg
Trimethylbenzene 10.0 kg
Repefral 5.0 kg
N-octyl alcohol 2.0kg
Penetrant t 0.2kg
Calcium dodecyl benzene sulfonate 0.5 kg
Castor oil polyoxyethylene ether 0.5kg
Two wires oil complements to 100 kg.
Preparation technology is: in the reaction vessel stirring at band, first with solvent by after fluorine pyridine worm amine nitrile and Imidacloprid stirring and dissolving, then add auxiliary component, be fully uniformly mixed, obtain 4.1% fluorine pyridine worm amine nitrile flufenoxuron ultra low volume liquids; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
According to the step of preparation process identical with embodiment 1, can prepare following examples.
Embodiment 2:
Preparation quality percentage composition is 8.1% fluorine pyridine worm amine nitrile flufenoxuron 4 ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Flufenoxuron 8.0kg
DMF 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
N-octyl alcohol 3.0kg
Phenmethylol 2.0kg
Azone 0.2 kg
2-butyl acetate 8.0kg
Calcium dodecyl benzene sulfonate 2.0 kg
Alkylphenol polyoxyethylene 3.0kg
Phenethyl phenol polyethenoxy ether 0.5kg
Soybean oil complements to 100 kg.
Embodiment 3:
Preparation quality percentage composition is 15% fluorine pyridine worm amine nitrile flufenoxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 5.0 kg
Flufenoxuron 10.0kg
1-METHYLPYRROLIDONE 8.0 kg
DMA 10.0 kg
Acetophenone 6.0 kg
Epoxidized soybean oil 4.0 kg
O-dichlorohenzene 6.0 kg
Azone 0.3 kg
Calcium dodecyl benzene sulfonate 2.0 kg
OPEO 2.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 1.0 kg
Turpentine oil complements to 100 kg.
Embodiment 4:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile flufenoxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Flufenoxuron 15.0kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Methyl-sulfoxide 5.0 kg
Cyclohexanone 3.0 kg
N-octyl alcohol 3.0kg
Dibutyl phthalate 4.0 kg
Penetrant t 0.3kg
Calcium dodecyl benzene sulfonate 2.3 kg
Alkylphenol polyoxyethylene 3.2 kg
Ben-zylphenol Polyoxyethyl Ether 4.2kg
Rapeseed oil complements to 100 kg.
Embodiment 5:
Preparation quality percentage composition is 5.1% fluorine pyridine worm amine nitrile HEXAFLUMURON ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 5.0 kg
HEXAFLUMURON 0.1 kg
1-METHYLPYRROLIDONE 5.5 kg
DMA 5.0 kg
Butanone 4.0 kg
Durene 7.0 kg
Liquid Macrogol 6.0 kg
Isoamyl alcohol 2.0 kg
Azone 0.2 kg
Calcium dodecyl benzene sulfonate 2.0 kg
OPEO 2.5 kg
Castor oil ethylene oxide adduct 0.4 kg
Cottonseed oil complements to 100 kg.
Embodiment 6:
Preparation quality percentage composition is 10.1% fluorine pyridine worm amine nitrile HEXAFLUMURON ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
HEXAFLUMURON 10.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Ethanol 10.0 kg
Diethylbenzene 3.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 5.5 kg
Cottonseed oil complements to 100 kg.
Embodiment 7:
Preparation quality percentage composition is 18% fluorine pyridine worm amine nitrile HEXAFLUMURON ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 10.0 kg
HEXAFLUMURON 8.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Ethanol 10.0 kg
Diethylbenzene 3.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 8:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile HEXAFLUMURON ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
HEXAFLUMURON 15.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Methyl-sulfoxide 7.0 kg
Isoamyl alcohol 3.0 kg
Diethylbenzene 6.0 kg
Butanone 5.0 kg
Azone 0.2 kg
Turpentine oil 7.0 kg
Ethyl oleate 2.0 kg
N-methyl fatty acyl group sodium taurocholate 6.0 kg
OPEO 2.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether phosphate 1.5 kg
Corn oil complements to 100 kg.
Embodiment 9:
Preparation quality percentage composition is 2.1% fluorine pyridine worm amine nitrile flucycloxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 2.0 kg
Flucycloxuron 0.1 kg
DMF 5.0 kg
Methyl-propyl benzene 3.0 kg
Dioctyl phthalate 2.0 kg
Methyl naphthalene 4.0 kg
N-octyl alcohol 1.0kg
Bleeding agent OT 0.2 kg
Alkylphenol polyoxyethylene formaldehyde condensation products sulphate 2.0 kg
Castor oil polyoxyethylene ether 1.5 kg
Alkylphenol polyoxyethylene phosphate 5.5 kg
Castor oil complements to 100kg.
Embodiment 10:
Preparation quality percentage composition is the fluorine pyridine worm amine nitrile flucycloxuron ultra low volume liquids of 5.1 %, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Flucycloxuron 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Butylbenzene 5.0 kg
Benzyl methyl ether 3.0 kg
PEG400 4.0 kg
Turpentine oil 2.0 kg
N-octyl alcohol 1.5kg
Bleeding agent OT 0.2 kg
Calcium dodecyl benzene sulfonate 3.0 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphoesterase 30 .2 kg
Cottonseed oil complements to 100kg.
Embodiment 11:
Preparation quality percentage composition is 13% fluorine pyridine worm amine nitrile flucycloxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 8.0 kg
Flucycloxuron 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Cyclohexanone 5.0 kg
Methoxy toluene 3.0 kg
Methyl naphthalene 4.0 kg
Organosilicon 0.1 kg
Sodium sulfate of polyethenoxy ether of fatty alcohol 0.3 kg
Castor oil polyoxyethylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphate 1.0 kg
Two wires oil complements to 100 kg.
Embodiment 12:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile flucycloxuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Flucycloxuron 15.0 kg
1-METHYLPYRROLIDONE 12.0 kg
DMF 16.0 kg
Ethyl oleate 3.0 kg
O-dichlorohenzene 7.0 kg
Terpineol 3.0 kg
Aliphatic alcohol sulfate 3.0 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 3.5 kg
Castor oil polyoxyethylene ether 3.5 kg
Cottonseed oil complements to 100 kg.
Embodiment 13:
Preparation quality percentage composition is 3.1% fluorine pyridine worm amine nitrile fluorine pyridine urea ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 3.0 kg
Fluorine pyridine urea 0.1 kg
1-METHYLPYRROLIDONE 5.0 kg
DMA 4.0 kg
Butanone 5.0 kg
Durene 7.0 kg
Liquid Macrogol 3.0 kg
Isoamyl alcohol 2.0 kg
Azone 0.2 kg
Calcium dodecyl benzene sulfonate 2.0 kg
OPEO 2.5 kg
Castor oil ethylene oxide adduct 0.4 kg
Cottonseed oil complements to 100 kg.
Embodiment 14:
Preparation quality percentage composition is 10.1% fluorine pyridine worm amine nitrile fluorine pyridine urea ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Fluorine pyridine urea 10.0 kg
1-METHYLPYRROLIDONE 11.0 kg
Ethanol 10.0 kg
Durene 4.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 15:
Preparation quality percentage composition is 16% fluorine pyridine worm amine nitrile fluorine pyridine urea ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 10.0 kg
Fluorine pyridine urea 6.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Cyclohexanone 4.0 kg
Ethanol 5.0 kg
Diethylbenzene 3.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 16:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile fluorine pyridine urea ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Fluorine pyridine urea 15.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Methyl-sulfoxide 7.0 kg
Isoamyl alcohol 3.0 kg
O-dichlorohenzene 6.0 kg
Butanone 5.0 kg
Azone 0.2 kg
Turpentine oil 7.0 kg
Ethyl oleate 2.0 kg
N-methyl fatty acyl group sodium taurocholate 3.0 kg
OPEO 2.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether phosphate 4.5 kg
Corn oil complements to 100 kg.
Embodiment 17:
Preparation quality percentage composition is 3.1% fluorine pyridine worm amine nitrile diflubenzuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Diflubenzuron 3.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMA 4.0 kg
Butanone 5.0 kg
Durene 7.0 kg
Liquid Macrogol 3.0 kg
Isoamyl alcohol 2.0 kg
Azone 0.2 kg
Calcium dodecyl benzene sulfonate 2.0 kg
OPEO 2.5 kg
Castor oil ethylene oxide adduct 0.4 kg
Cottonseed oil complements to 100 kg
Embodiment 18:
Preparation quality percentage composition is 7.1% fluorine pyridine worm amine nitrile diflubenzuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 7.0 kg
Diflubenzuron 0.1 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Butylbenzene 5.0 kg
Benzyl methyl ether 3.0 kg
PEG400 4.0 kg
Turpentine oil 2.0 kg
N-octyl alcohol 1.5kg
Bleeding agent OT 0.2 kg
Calcium dodecyl benzene sulfonate 3.0 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphate 3.5 kg
Cottonseed oil complements to 100kg.
Embodiment 19:
Preparation quality percentage composition is 12% fluorine pyridine worm amine nitrile diflubenzuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 7.0 kg
Diflubenzuron 5.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Ethanol 10.0 kg
Diethylbenzene 3.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 20:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile diflubenzuron 4 ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Diflubenzuron 15.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Methyl-sulfoxide 7.0 kg
Isoamyl alcohol 3.0 kg
Diethylbenzene 4.0 kg
Butanone 5.0 kg
Azone 0.2 kg
Turpentine oil 7.0 kg
Ethyl oleate 2.0 kg
N-methyl fatty acyl group sodium taurocholate 1.0 kg
OPEO 2.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether phosphate 1.5 kg
Corn oil complements to 100 kg.
Embodiment 21:
Preparation quality percentage composition is 2.1% fluorine pyridine worm amine nitrile diafenthiuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 2.0 kg
Diafenthiuron 0.1 kg
1-METHYLPYRROLIDONE 5.0 kg
Trimethylbenzene 10.0 kg
Repefral 5.0 kg
N-octyl alcohol 2.0kg
Penetrant t 0.2kg
Calcium dodecyl benzene sulfonate 1.5 kg
Castor oil polyoxyethylene ether 1.8kg
Fatty alcohol-polyoxyethylene ether 1.0 kg
Two wires oil complements to 100 kg.
Embodiment 22:
Preparation quality percentage composition is 5.1% fluorine pyridine worm amine nitrile diafenthiuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Diafenthiuron 5.0 kg
DMF 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
N-octyl alcohol 3.0kg
Phenmethylol 2.0kg
Azone 0.2 kg
Diethylene glycol acetate 8.0kg
Calcium dodecyl benzene sulfonate 2.0 kg
Alkylphenol polyoxyethylene 3.0kg
Phenethyl phenol polyethenoxy ether 0.5kg
Soybean oil complements to 100 kg.
Embodiment 23:
Preparation quality percentage composition is 15% fluorine pyridine worm amine nitrile diafenthiuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 8.0 kg
Diafenthiuron 7.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Cyclohexanone 5.0 kg
Methoxy toluene 3.0 kg
Methyl naphthalene 4.0 kg
Organosilicon 0.1 kg
Sodium sulfate of polyethenoxy ether of fatty alcohol 0.3 kg
Castor oil polyoxyethylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphate 5.0 kg
Two wires oil complements to 100 kg.
Embodiment 24:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile diafenthiuron ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Diafenthiuron 15.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Methyl-sulfoxide 5.0 kg
Cyclohexanone 3.0 kg
N-octyl alcohol 3.0kg
Dibutyl phthalate 4.0 kg
Organosilicon 0.3kg
Calcium dodecyl benzene sulfonate 2.3 kg
Alkylphenol polyoxyethylene 3.2 kg
Ben-zylphenol Polyoxyethyl Ether 1.2kg
Rapeseed oil complements to 100 kg.
Embodiment 25:
Preparation quality percentage composition is 2.1% fluorine pyridine worm amine nitrile Buprofezin ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 2.0 kg
Buprofezin 0.1 kg
DMF 5.0 kg
Methyl-propyl benzene 3.0 kg
Dioctyl phthalate 2.0 kg
Methyl naphthalene 4.0 kg
N-octyl alcohol 1.0kg
Bleeding agent OT 0.2 kg
Alkylphenol polyoxyethylene formaldehyde condensation products sulphate 2.0 kg
Castor oil polyoxyethylene ether 1.5 kg
Alkylphenol polyoxyethylene phosphate 1.5 kg
Castor oil complements to 100kg.
Embodiment 26:
Preparation quality percentage composition is 5.1 % fluorine pyridine worm amine nitrile Buprofezin ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Buprofezin 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Durene 5.0 kg
Benzyl methyl ether 3.0 kg
Macrogol 200 4.0 kg
Epoxidized soybean oil 2.0 kg
N-octyl alcohol 1.5kg
Bleeding agent OT 0.2 kg
Calcium dodecyl benzene sulfonate 3.0 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphoesterase 30 .2 kg
Cottonseed oil complements to 100kg.
Embodiment 27:
Preparation quality percentage composition is 13% fluorine pyridine worm amine nitrile Buprofezin ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 8.0 kg
Buprofezin 5.0 kg
1-METHYLPYRROLIDONE 5.0 kg
DMF 7.0 kg
Cyclohexanone 5.0 kg
Methoxy toluene 3.0 kg
Butanone 4.0 kg
Organosilicon 0.1 kg
Sodium sulfate of polyethenoxy ether of fatty alcohol 0.3 kg
Castor oil polyoxyethylene ether 3.5 kg
Phenethyl phenol polyethenoxy ether phosphate 1.0 kg
Two wires oil complements to 100 kg.
Embodiment 28:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile Buprofezin ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Buprofezin 15.0 kg
1-METHYLPYRROLIDONE 12.0 kg
DMF 16.0 kg
Methyl oleate ester 4.0 kg
O-dichlorohenzene 7.0 kg
Ethanol 3.0 kg
Aliphatic alcohol sulfate 3.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 3.5 kg
Castor oil polyoxyethylene ether 3.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 29:
Preparation quality percentage composition is 3.1% fluorine pyridine worm amine nitrile worm hydrazides ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 3.0 kg
Worm hydrazides 0.1 kg
1-METHYLPYRROLIDONE 5.0 kg
Butanone 5.0 kg
Durene 7.0 kg
PEG400 3.0 kg
Isoamyl alcohol 2.0 kg
Azone 0.2 kg
Calcium dodecyl benzene sulfonate 2.0 kg
OPEO 2.5 kg
Castor oil ethylene oxide adduct 0.4 kg
Cottonseed oil complements to 100 kg.
Embodiment 30:
Preparation quality percentage composition is 10.1% fluorine pyridine worm amine nitrile worm hydrazides ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 0.1 kg
Worm hydrazides 10.0 kg
1-METHYLPYRROLIDONE 11.0 kg
Ethanol 10.0 kg
Durene 4.0 kg
N-hexyl alcohol 6.0 kg
Azone 0.2 kg
Methyl oleate 8.0 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 31:
Preparation quality percentage composition is 16% fluorine pyridine worm amine nitrile worm hydrazides ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 10.0 kg
Worm hydrazides 6.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Cyclohexanone 4.0 kg
Ethanol 5.0 kg
Diethylbenzene 3.0 kg
N-hexyl alcohol 6.0 kg
Organosilicon 0.2 kg
Lauryl sodium sulfate 2.0 kg
OPEO 2.5 kg
Aliphatic alcohol polyoxyvinethene phosphate 1.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 32:
Preparation quality percentage composition is 30% fluorine pyridine worm amine nitrile worm hydrazides ultra low volume liquids, and its composition and content are respectively:
Fluorine pyridine worm amine nitrile 15.0 kg
Worm hydrazides 15.0 kg
1-METHYLPYRROLIDONE 6.0 kg
Methyl-sulfoxide 7.0 kg
Isoamyl alcohol 3.0 kg
O-dichlorohenzene 6.0 kg
N-octyl alcohol 5.0 kg
Azone 0.2 kg
Corn oil 7.0 kg
Ethyl oleate 2.0 kg
N-methyl fatty acyl group sodium taurocholate 3.0 kg
OPEO 2.5 kg
Alkylaryl polyoxyethylene polyoxypropylene ether phosphate 4.5 kg
Corn oil complements to 100 kg
Prepared fluorine-containing pyridine worm amine nitrile and the ultra low volume liquids outward appearance of insect growth regulator, IGR insecticides are homogeneous oily liquids; Under 5 ℃ of conditions of the good ， of low-temperature phase capacitive –, refrigeration 7d is crystallization and suspension not; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, without poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10
-6～1 * 10
-10within the scope of s/cm.
The furthermore bright beneficial effect of the present invention of field efficacy measurement result carrying out in conjunction with the application embodiment of the present invention more below.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80 < CTC < 120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field control effectiveness test.
Application Example 1:
Controlling object: beet armyworm
Experiment place: cotton field, Xianyang, Shanxi province city
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2
Contrast medicament: 1.8% Avermectin EC, preparation mu consumption 200ml, is diluted with water to the conventional spraying of 30L
Table 1: control beet armyworm field control effectiveness test result
As can be seen from Table 1: ultra low volume liquids of the present invention adopts ultra low volume spraying method control beet armyworm, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 2:
Controlling object: eggplant thrips
Experiment place: Nanning City's five pool field of vegetables
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2.
Contrast medicament: 2.5% time aqueous emulsion, preparation mu consumption 200ml, is diluted with water to the conventional spraying of 30L
Table 2: control eggplant thrips field control effectiveness test result
As can be seen from Table 2: ultra low volume liquids of the present invention adopts ultra low volume spraying method control horse eggplant thrips, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Claims (8)
1. the ultra low volume liquids of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides, it is characterized in that: this ultra low volume liquids comprises active component I, active component II, surfactant and solvent, wherein active component I is fluorine pyridine worm amine nitrile, active component II is any one of flufenoxuron, HEXAFLUMURON, flucycloxuron, fluorine pyridine urea, diflubenzuron, diafenthiuron, Buprofezin, worm hydrazides, and active component I and active component II are composite is active component.
2. ultra low volume liquids according to claim 1, it is characterized in that: described active component, the weight content of its total amount is 0.2%～30%, wherein the weight content of fluorine pyridine worm amine nitrile is 0.1%～15%, the weight content of active component II is 0.1%～15%, the weight content of auxiliary agent is 1%～10%, and solvent complements to 100%.
3. ultra low volume liquids according to claim 1, it is characterized in that: described surfactant is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, Ben-zylphenol Polyoxyethyl Ether, castor oil ethylene oxide adduct, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, N-methyl fatty acyl group sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, aliphatic alcohol sulfate, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, penetrant t, bleeding agent OT, azone, the mixture of one or more in organosilicon.
4. ultra low volume liquids according to claim 1, is characterized in that: described solvent is one or more the mixture in aromatic hydrocarbon solvent, plant oil solvent and polar solvent.
5. ultra low volume liquids according to claim 4, is characterized in that: described aromatic hydrocarbon solvent comprises that aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, methoxy toluene, benzyl methyl ether, butylbenzene, methyl naphthalene, repefral, dibutyl phthalate, dioctyl phthalate and two wires oil.
6. ultra low volume liquids according to claim 4, is characterized in that: described plant oil solvent comprises soybean oil, epoxidized soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate and ethyl oleate.
7. ultra low volume liquids according to claim 4, it is characterized in that: described polar solvent comprises acetophenone, cyclohexanone, butanone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, N, dinethylformamide, DMA, n-hexyl alcohol, n-octyl alcohol, isoamyl alcohol, Liquid Macrogol, PEG400,2-butyl acetate, diethylene glycol acetate, terpineol and ethanol.
8. the preparation method of the ultra low volume liquids of a fluorine-containing pyridine worm amine nitrile as claimed in claim 1 and insect growth regulator, IGR insecticides, it is characterized in that: in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, add again auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids of fluorine-containing pyridine worm amine nitrile and insect growth regulator, IGR insecticides; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941452A (en) * | 2016-06-21 | 2016-09-21 | 南京华洲药业有限公司 | Synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof |
| CN106070289A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of furan tebufenozide and application |
| CN106070290A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of methoxyfenozide and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
| CN102202511A (en) * | 2008-10-08 | 2011-09-28 | 先正达参股股份有限公司 | Pesticidal combinations containing sulfoxaflor |
| CN102224826A (en) * | 2011-04-23 | 2011-10-26 | 青岛海利尔药业有限公司 | High-performance and friendly-environmental pesticide compound composition |
| JP2012153620A (en) * | 2011-01-24 | 2012-08-16 | Nissan Chem Ind Ltd | Insecticidal, miticidal, nematicidal, molluscicidal, fungicidal, or bactericidal composition |
| CN102648712A (en) * | 2011-02-23 | 2012-08-29 | 广西田园生化股份有限公司 | Ultralow-volume liquid containing buprofezin |
| CN102835414A (en) * | 2012-09-27 | 2012-12-26 | 广西农喜作物科学有限公司 | Composition containing sulfoxaflor and amide pesticides |
-
2013
- 2013-12-13 CN CN201310674930.0A patent/CN103704240A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
| CN102202511A (en) * | 2008-10-08 | 2011-09-28 | 先正达参股股份有限公司 | Pesticidal combinations containing sulfoxaflor |
| JP2012153620A (en) * | 2011-01-24 | 2012-08-16 | Nissan Chem Ind Ltd | Insecticidal, miticidal, nematicidal, molluscicidal, fungicidal, or bactericidal composition |
| CN102648712A (en) * | 2011-02-23 | 2012-08-29 | 广西田园生化股份有限公司 | Ultralow-volume liquid containing buprofezin |
| CN102224826A (en) * | 2011-04-23 | 2011-10-26 | 青岛海利尔药业有限公司 | High-performance and friendly-environmental pesticide compound composition |
| CN102835414A (en) * | 2012-09-27 | 2012-12-26 | 广西农喜作物科学有限公司 | Composition containing sulfoxaflor and amide pesticides |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941452A (en) * | 2016-06-21 | 2016-09-21 | 南京华洲药业有限公司 | Synergistic insecticide composition containing sulfoxaflor and tebufenozide and application thereof |
| CN106070289A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of furan tebufenozide and application |
| CN106070290A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of methoxyfenozide and application |
| CN106070289B (en) * | 2016-06-21 | 2018-11-09 | 南京华洲药业有限公司 | A kind of Synergistic insecticidal compositions and its application containing sulfoxaflor and furan tebufenozide |
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