CN105432657A - Efficient insecticide containing biopesticide lepimectin, chlorpyrifos and spirotetramat - Google Patents

Efficient insecticide containing biopesticide lepimectin, chlorpyrifos and spirotetramat Download PDF

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Publication number
CN105432657A
CN105432657A CN201410521300.4A CN201410521300A CN105432657A CN 105432657 A CN105432657 A CN 105432657A CN 201410521300 A CN201410521300 A CN 201410521300A CN 105432657 A CN105432657 A CN 105432657A
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China
Prior art keywords
parts
pest
efficient pesticides
killing
pesticides composition
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CN201410521300.4A
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Chinese (zh)
Inventor
关丽
方清平
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QINGDAO KANGHE FOOD Co Ltd
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QINGDAO KANGHE FOOD Co Ltd
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Priority to CN201410521300.4A priority Critical patent/CN105432657A/en
Publication of CN105432657A publication Critical patent/CN105432657A/en
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Abstract

The invention relates to an efficient insecticide containing a biopesticide lepimectin, chlorpyrifos and spirotetramat. The insecticide is composed of the following components in parts by weight: 20-60 parts of the biopesticide lepimectin, 10-30 parts of chlorpyrifos and 35-55 parts of spirotetramat. The insecticidal composition provided by the invention has an obvious synergic effect and is safe and harmless to human, livestock, crops and natural environment, resistance to pesticides is hard to generated for injurious insects, and the insecticidal composition has a remarkable killing effect on injurious insects such as plutella xylostella, beet armyworms, cotton bollworms, striped rice borers, mealybugs, homoptera piercing-sucking mouthparts which are mainly planthoppers, aphids, brown planthoppers and the like. Meanwhile, the efficient insecticide further can reduce the damages on the environment.

Description

A kind of efficient pesticides containing biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester
Technical field
The present invention relates to the field of pesticides for agricultural insect pests control, particularly a kind of efficient pesticides containing biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester.
Background technology
Insecticide residues and the toxicity problem to animal in agricultural product are the focuses that people pay close attention to always.
Biopesticide lepimectin:
Physicochemical property: a kind of 16 membered macrolide antibiotic, are made up of derivative L .A3 and L.A4 of milbemycinA3/A4, wherein L.A3≤20%, L.A4 >=80%.Its CA accession number is respectively: 171249-10-8 (L.A3) and 171249-05-1 (L.A4).
Biopesticide lepimectin is the derivative being total to mibemycin (milbemycin) A3/A4 that company finds by Japan three, uses in 2006 in Japan's registration.Lepimectin is as the activator of glutamic acid, the open frequency of GluCl-can be increased, thus cause film to increase C1-permeability, cause the hyperpolarization of neuron resting potential, make it be difficult to depolarising, nerve conduction is obstructed, thus cause the flaccid paralysis of insect body wall muscle, block the wriggling of insect pharyngeal muscle, cause ingestion difficulty and cause death.
Vegetables and the fruit such as wild cabbage, tomato, oranges and tangerines, strawberry and grape is used for, main insect such as control Lepidoptera and Homoptera etc. as novel pesticide.This medical instrument has insecticidal activity high, and dosage is few, to person poultry safety, free from environmental pollution, and selectivity is strong, does not injure natural enemy, also not easily produces the features such as resistance, can use with avermectins rotation, in case Avermectin produces resistance.Therefore it is called as one of the most promising wide spectrum, efficient, the novel insecticide without cross resistance at present.
Chlorine pyrazothion:
Chinese another name: O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) thiophosphate
English name: chlorpyrifos (ANSI, ISO, BSI)
Molecular formula: C 9h 11cl 3nO 3pS
Molecular weight: 350.5
Structural formula:
Toxicity: belong to moderate toxicity insecticide.Former medicine rat acute LD50 of passing through mouth is 163mg/kg, acute through skin LD50>2g/kg; Have slight stimulation to experimental animal eyes, have obvious stimulation to skin, long-time multiple-contact can produce and burn.The sub-anxious per os action-less dose of rat is 0.03mg/kg, and chronic per os action-less dose is 0.1mg/kg.The chronic per os action-less dose of dog is 0.03mg/kg.Teratogenesis, mutagenesis, carcinogenesis is had no under test dose.In room air, maximum permissible concentration is (TLV) 0.2mg/m.To fish and aquatic toxicity higher, trout LC50 is 15mg/L (96 hours, 72 DEG C), poisonous to honeybee.Chlopyrifos 40.7% missible oil, rat acute LD50 of passing through mouth is 590mg/kg, exempt from acute through skin LD50 be 2330mg/kg, irritant to skin, eyes.Kill the impatient LD50 of passing through mouth >2g/kg of the blue pearl 14% granule rat of worm, acute through skin >2g/kg, Acute inhalation LC50>0.007 μ g/L (7 hours), irritant to eyes, skin.
Formulation: 40.7% missible oil, 14% granule.
Chlopyrifos is a kind of efficient, broad-spectrum organophosphorous pesticide, have insect tag, stomach toxicity and fumigation action, especially have extraordinary effect to the control of brown planthopper.
Spiral shell worm ethyl ester is tetronic acid compounds, belongs to similar compound with insecticidal/acaricidal agent spiral shell mite ester (spirodiclofen) of Bayer company and Spiromesifen (spiromesifen).Spiral shell worm ethyl ester has unique function Characteristics, is one of modern pesticides so far with two-way Uptake and translocation performance.This compound upwards can move down in whole plant corpus, arrives at blade face and bark, thus control is as on romaine lettuce and Chinese cabbage internal lobe, and the corticole insect of fruit.The interior absorption of this uniqueness can protect newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another feature is that the lasting period is long, can provide the effective control reaching 8 weeks.
Spiral shell worm ethyl ester high-efficiency broad spectrum, can effectively prevent and treat various sucking pest, as aphid, thrips, wood louse, mealybug, aleyrodid and scale insect etc.Applicable chief crop comprises, cotton, soybean, oranges and tangerines, tropical fruit tree, nut, grape, lupulus, potato and vegetables etc.Research shows it to important beneficial insect as ladybug, syrphus fly and parasitic wasp have good selectivity.
Summary of the invention
For the defect existed in prior art, the object of the present invention is to provide a kind of efficient pesticides containing biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester.
For reaching above object, the technical scheme that the present invention takes is:
For killing an efficient pesticides composition for pest, be made up of according to parts by weight following component:
Biopesticide lepimectin:20-60 part; Chlorine pyrazothion: 10-30 part; Spiral shell worm ethyl ester: 25-55 part.
On the basis of such scheme, a kind of efficient pesticides composition for killing pest, is made up of according to parts by weight following component:
Biopesticide lepimectin:30-50 part; Chlorine pyrazothion: 15-25 part; Spiral shell worm ethyl ester: 30-50 part.
On the basis of such scheme, a kind of efficient pesticides composition for killing pest, is made up of according to parts by weight following component:
Biopesticide lepimectin:40 part; Chlorine pyrazothion: 20 parts; Spiral shell worm ethyl ester: 40 parts.
The above-mentioned efficient pesticides composition for killing pest, the formulation that can prepare is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion or microemulsion.
The above-mentioned efficient pesticides composition for killing pest, is mainly used in control lepidopterous insects and Homoptera sucking pest.
Above-mentioned is mainly diamond-back moth, beet armyworm, cotton bollworm, striped rice borer, mealybug class for the efficient pesticides composition killing pest for the lepidopterous insects prevented and treated, and Homoptera sucking pest is mainly plant hopper, aphid, conspicuous plant hopper.
Advantage of the present invention: Pesticidal combination of the present invention has obvious synergistic effect, effective ingredient consumption can be reduced, reduce use cost, delay the generation of pest resistance to insecticide, effective minimizing environmental pollution and residue of pesticide, to beet armyworm, cotton bollworm, striped rice borer, mealybug class, Homoptera sucking pest is mainly the insects such as conspicuous plant hopper, plant hopper, aphid and has significant killing effect, meanwhile, the destruction to environment can be reduced.
Embodiment
Below the present invention is described in further detail.
Embodiment 1
The present invention contains the cream preparation of the efficient pesticides of biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester, concrete constituent following (every part of 1000g):
Biopesticide lepimectin:20 part; Chlorine pyrazothion: 10 parts; Spiral shell worm ethyl ester: 25 parts;
The concrete production stage of this cream preparation dissolves completely for first active ingredient biopesticide lepimectin, chlorine pyrazothion, spiral shell worm ethyl ester being added in solvent according to this area conventional steps, add emulsifier again, synergist becomes transparent and homogeneous oily liquids after stirring, filling, namely can be made into the cream preparation of the present composition.
Embodiment 2
The present invention contains the suspending agent of the efficient pesticides of biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester, concrete constituent following (every part of 1000g):
Biopesticide lepimectin:60 part; Chlorine pyrazothion: 30 parts; Spiral shell worm ethyl ester: 55 parts;
The concrete production stage of this suspending agent is the Conventional suspending agents preparation method of this area, first other auxiliary agents (dispersant, antifreezing agent, thickener, defoamer, penetrating agent and pH value regulator) are mixed, mix through high speed shear, add active ingredient biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester, abrading-ball 2 ~ 4 hours in ball crusher, make a diameter all at below 5mm, namely can be made into the aqueous suspension formulations of the present composition.
Embodiment 3
The present invention contains the water dispersible granules of the efficient pesticides of biopesticide lepimectin, chlorine pyrazothion and spiral shell worm ethyl ester, concrete constituent following (every part of 1000g):
Biopesticide lepimectin:40 part; Chlorine pyrazothion: 20 parts; Spiral shell worm ethyl ester: 40 parts.
The concrete production stage of this water dispersible granules is the customary preparation methods of the water dispersible granules of this area: active ingredient biopesticide lepimectin, chlorine pyrazothion, spiral shell worm ethyl ester, dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and to carry out after granulation, drying, screening, through sample analysis, namely can be made into the water dispersible granules of the present composition.
Medicine prepared by embodiment of the present invention 1-3, carry out field experiment, after medicine, it is all better than existing medicament to the control efficiency of striped rice borer, and medicine effect of the present invention is fast, and efficiency time is long, and control efficiency is good.After medicine, the insecticidal effect of 10 days reaches 78.9% respectively, and 86.7%, 92.8%.
Above-mentioned detailed description of the present invention being carried out with reference to embodiment; illustrative instead of determinate; several embodiments can be listed according to institute's limited range, therefore in the change do not departed under general plotting of the present invention and amendment, all belong within protection scope of the present invention.

Claims (6)

1., for killing an efficient pesticides composition for pest, it is characterized in that being made up of according to parts by weight following component:
Biopesticide lepimectin:20-60 part; Chlorine pyrazothion: 10-30 part; Spiral shell worm ethyl ester: 25-55 part.
2. a kind of efficient pesticides composition for killing pest according to claim 1, is characterized in that being made up of according to parts by weight following component:
Biopesticide lepimectin:30-50 part; Chlorine pyrazothion: 15-25 part; Spiral shell worm ethyl ester: 30-50 part.
3. a kind of efficient pesticides composition for killing pest according to claim 2, is characterized in that being made up of according to parts by weight following component:
Biopesticide lepimectin:40 part; Chlorine pyrazothion: 20 parts; Spiral shell worm ethyl ester: 40 parts.
4. the efficient pesticides composition for killing pest according to any one of claim 1-3, is characterized in that: the present invention is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion or microemulsion for the formulation that the efficient pesticides composition killing pest can be prepared.
5. the efficient pesticides composition for killing pest according to any one of claim 1-3, is characterized in that: Pesticidal combination of the present invention is mainly used in control lepidopterous insects and Homoptera sucking pest.
6. the efficient pesticides composition for killing pest according to claim 5, it is characterized in that: the efficient pesticides composition for killing pest of the present invention is mainly diamond-back moth, beet armyworm, cotton bollworm, striped rice borer, mealybug class for the lepidopterous insects prevented and treated, Homoptera sucking pest is mainly plant hopper, aphid, conspicuous plant hopper.
CN201410521300.4A 2014-09-30 2014-09-30 Efficient insecticide containing biopesticide lepimectin, chlorpyrifos and spirotetramat Pending CN105432657A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105994353A (en) * 2016-06-21 2016-10-12 南京华洲药业有限公司 Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105994353A (en) * 2016-06-21 2016-10-12 南京华洲药业有限公司 Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof

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Application publication date: 20160330