CN101990898A - Dinotefuran-containing pesticide composition - Google Patents

Dinotefuran-containing pesticide composition Download PDF

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Publication number
CN101990898A
CN101990898A CN2010105643930A CN201010564393A CN101990898A CN 101990898 A CN101990898 A CN 101990898A CN 2010105643930 A CN2010105643930 A CN 2010105643930A CN 201010564393 A CN201010564393 A CN 201010564393A CN 101990898 A CN101990898 A CN 101990898A
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mti
benzoate
emamectin
avermectin
composition
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CN2010105643930A
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Chinese (zh)
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张伟
曹巧利
高超
梁小娟
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Shaanxi Welch Crop Protection Co Ltd
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Shaanxi Welch Crop Protection Co Ltd
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Priority to CN2010105643930A priority Critical patent/CN101990898A/en
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Abstract

The invention discloses a dinotefuran-containing pesticide composition. In a pesticidal composition which contains A and B, A is dinotefuran, B is any one of the following pesticides: abamectin and emamectin benzoate, and a weight part ratio of the two active ingredients A to B is 1-100:1-20. The dinotefuran-containing pesticide composition can prevent and control various pests, has obvious synergy, expands a pesticidal spectrum, has relatively high activity to piercing and sucking pests such as aphids, plant hopper, leafhopper and whiteflies and lepidoptera such as plutella xylostella, spodoptera exigua and fruit tree mites, reduces the using amount of the pesticide, reduces the residue amount of the pesticide on crops, reduces environmental pollution, is safe for people and livestock and has high environmental compatibility, and the pests difficultly generate pesticide resistance.

Description

A kind of composition pesticide that contains MTI-446
Technical field
The invention belongs to technical field of pesticide, relate to a kind of composition pesticide that contains MTI-446.
Background technology
MTI-446, English common name (dinotefuran), chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced do not contain the halogen family element.Simultaneously, also different at aspect of performance with nicotine.So people are referred to as " furans nicotine " at present.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has promptly shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crops such as paddy rice, fruit tree, vegetables.
Avermectin, English common name (abamectin), molecular formula: C 48H 72O 14(B1a) C 47H 70O 14(B1b), Avermectin is tagged, stomach toxicity, penetration be strong.It is a kind of macrolide disaccharide compounds, is the natural products that separates from edaphon, insect and mite class is had tag and stomach poison function and faint fumigation action is arranged, no systemic action.But it has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long.It does not kill ovum.What its mechanism of action was different with general insecticide is that it disturbs the neurophysiology activity, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, the mite class becomes, if mite and insect and larva with paralysis symptom promptly appears after medicament contacts, inertia is not got food, and is dead after 2-4 days.Because of not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, because of plant surface is residual few, therefore little to the damage of beneficial insect.Obvious to the root nematode effect.
Emamectin-benzoate (emamectin benzoate), chemical name: 4 '-Biao-methylamino-4 '-the deoxidation abamectin benzoate, this product is efficient, wide spectrum, the longevity of residure are long, be good insecticidal/acaricidal agent, its mechanism of action hinders pest movements nerve information transmission and makes the health paralysis dead.The mode of action is main action of contace poison with stomach toxicity, and crop is not had interior absorption energy, but effective infiltration of institute used crop epidermal tissue, thereby has the longer longevity of residure.To control cotton bollworm, Lepidoptera, mite class, coleoptera and homoptera pest have high activity, and do not produce and intersect with other crops, soil and in easily degraded noresidue, free from environmental pollution, in the routine dose scope to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, discovery can produce good synergistic effect with MTI-446 and Avermectin, emamectin-benzoate after composite, and still unexposed about the composite relevant report of MTI-446 and Avermectin, emamectin-benzoate.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of the single agent of MTI-446 may bring, the drug effect, the Pesticidal combination that the present invention proposes contains two kinds of active components of A, B, and an amount of surfactant and carrier.
Active component A is selected from MTI-446, and active component B is Avermectin, emamectin-benzoate.
The described Pesticidal combination that contains MTI-446 is characterized in that: the percentage by weight of MTI-446 and Avermectin is 5~30: 1~10.
The described Pesticidal combination that contains MTI-446 is characterized in that: the percentage by weight of MTI-446 and emamectin-benzoate is 5~30: 1~10.
The ratio of weight and number of A, two kinds of active components of B is 1~100: 1~20.Usually active weight percentage is 0.5~90% of a gross weight in the composition, and preferable is 5%~85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1~70% active substance by weight, preferably is 5~50%; Solid pharmaceutical preparation contains 5~85% active substance by weight, preferably is 10~80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5~30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, tea are withered, in the soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described binding agent is selected from: one or more in gum Arabic, xanthans, melon glue, gelatin, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, triethylene glycol, the polyethylene glycol.
Described defoamer is selected from: silicone, C 8~10Aliphatic alcohols, C 10~20In saturated fat acids (as capric acid) and acid amides, isooctanol, isoamyl alcohol, stearic acid, lauric acid, silicone oil, the silicone compound one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the defoamer etc. one or more again.
Pesticidal combination of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent.
When making wetting powder, composition comprises following constituent content: MTI-446 1~100%, active component B1~20%, dispersant 5~10%, wetting agent 2~10%, filler 8~90%.
Active component MTI-446, B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: active component MTI-446 1~100%, B1~20%, dispersant 3~12%, wetting agent 1~8%, disintegrant 1~10%, binding agent 1~8%, filler 10~90%.
Active component MTI-446, B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is made suspending agent: active component MTI-446 1~50%, B1~10%, dispersant 2~10%, wetting agent 2~10%, defoamer 0.1~1%, binding agent 0.1~2%, antifreeze 0.1~8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add active component MTI-446, B, ball milling is 2~3 hours in ball mill, makes diameter of particle all below 5 μ m, makes the suspending agent product of the present composition.
The invention has the advantages that: after (1) MTI-446 and active component B are composite, have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, to aphid, rice fulgorid, rice leaf roller, coleopteran pest, lepidoptera pest such as diamond-back moth, beet armyworm, fruit tree mites etc. all have greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Example one 45% MTI-446 Avermectin wetting powder
MTI-446 30%, Avermectin 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, spaonin powder 5%, white carbon 2%, diatomite add to 100%, and production technology makes 45% MTI-446 Avermectin wetting powder routinely.
Example 2 45% MTI-446 Avermectin wetting powders
MTI-446 40%, Avermectin 5%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F3%, bentonite add to 100%, and production technology makes 45% MTI-446 Avermectin wetting powder routinely.
Example 3 48% MTI-446 Avermectin wetting powders
MTI-446 40%, Avermectin 8%, lignosulfonates 7%, soapberry powder 3%, white carbon 4%, kaolin adds to 100%, and production technology makes 48% MTI-446 Avermectin wetting powder routinely.
Example 4 22% MTI-446 Avermectin water dispersible granules
MTI-446 20%, Avermectin 2%, alkylnaphthalene sulfonate 6%, draw back powder 4%, urea 2%, starch 10%, bentonite and add to 100%, mixed 22% MTI-446 Avermectin water dispersible granules.
Example 5 25% MTI-446 Avermectin water dispersible granules
MTI-446 5%, Avermectin 20%, polycarboxylate 8%, neopelex 6%, spaonin powder 2%, sodium carbonate 5%, starch 15%, diatomite add to 100%, the mixed 25% MTI-446 Avermectin water dispersible granules that gets.
Example 6 40% MTI-446 Avermectin water dispersible granules
MTI-446 32%, Avermectin 8%, alkyl benzene sulfonate calcium salt 8%, lauryl sodium sulfate 6%, ammonium sulfate 2%, bentonite add to 100%, the mixed 40% MTI-446 Avermectin water dispersible granules that gets.
Example 7 9% MTI-446 Avermectin suspending agents
MTI-446 8%, Avermectin 1%, alkylnaphthalene sulfonate 6%, lauryl sodium sulfate 6%, C 8~10Aliphatic alcohols 0.3%, sodium phosphate trimer 0.5%, deionized water adds to 100%, the mixed 9% MTI-446 Avermectin suspending agent that gets.
Example 8 15% MTI-446 Avermectin suspending agents
MTI-446 5%, Avermectin 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%, soapberry powder 5%, silicone oil 0.3%, polyvinylpyrrolidone 0.4%, glycerine 0.5%, deionized water add to 100%, the mixed 15% MTI-446 Avermectin suspending agent that gets.
Example 9 24% MTI-446 Avermectin suspending agents
MTI-446 16%, Avermectin 8%, polycarboxylate 8%, spaonin powder 5%, isooctanol 0.5%, melon glue 0.3%, ethylene glycol 2%, deionized water add to 100%, the mixed 24% MTI-446 Avermectin suspending agent that gets.
Example ten 32% MTI-446 emamectin-benzoate wetting powders
MTI-446 30%, emamectin-benzoate 2%, lignosulfonates 5%, lauryl sodium sulfate 5%, wetting and penetrating agent F 2%, attapulgite add to 100%, and production technology makes 32% MTI-446 emamectin-benzoate wetting powder routinely.
Example ten one 42% MTI-446 emamectin-benzoate wetting powders
MTI-446 40%, emamectin-benzoate 2%, draw back powder 3%, alkylnaphthalene sulfonate 4%, white carbon 2%, kaolin and add to 100%, production technology makes 42% MTI-446 emamectin-benzoate wetting powder routinely.
Example ten two 53% MTI-446 emamectin-benzoate wetting powders
MTI-446 50%, emamectin-benzoate 3%, lignosulfonates 4%, lauryl sodium sulfate 4%, white carbon 5%, diatomite add to 100%, and production technology makes 53% MTI-446 emamectin-benzoate wetting powder routinely.
Example ten three 16% MTI-446 emamectin-benzoate water dispersible granules
MTI-446 15%, emamectin-benzoate 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, spaonin powder 2%, starch 10%, ammonium sulfate 1%, polyvinylpyrrolidone 0.4%, bentonite add to 100%, and production technology makes 16% MTI-446 emamectin-benzoate water dispersible granules routinely.
Example ten four 30% MTI-446 emamectin-benzoate water dispersible granules
MTI-446 25%, emamectin-benzoate 5%, neopelex 4%, alkyl benzene sulfonate calcium salt 7%, urea 1%, sodium carbonate 3%, sodium phosphate trimer 0.5%, diatomite add to 100%, and production technology makes 30% MTI-446 emamectin-benzoate water dispersible granules routinely.
Example ten five 44% MTI-446 emamectin-benzoate water dispersible granules
Add to 100% by MTI-446 40%, emamectin-benzoate 4%, neopelex 5%, alkylnaphthalene sulfonate 6%, urea 1%, ammonium sulfate 4%, gum Arabic 0.3%, kaolin, production technology makes 44% MTI-446 emamectin-benzoate water dispersible granules routinely.
Example ten six 2% MTI-446 emamectin benzoate suspending agents
MTI-446 1%, emamectin-benzoate 1%, polycarboxylate 10%, lauryl sodium sulfate 6%, lauric acid 0.5%, xanthans 1%, deionized water adds to 100%, the mixed 2% MTI-446 emamectin benzoate suspending agent that gets.
Example ten seven 11% MTI-446 emamectin benzoate suspending agents
MTI-446 10%, emamectin-benzoate 1%, lignosulfonates 5%, tea are withered 4%, gum Arabic 0.3%, silicone oil 0.5%, ethylene glycol 0.6%, deionized water adds to 100%, the mixed 11% MTI-446 emamectin benzoate suspending agent that gets.
Example ten eight 18% MTI-446 emamectin benzoate suspending agents
MTI-446 15%, emamectin-benzoate 3%, alkyl benzene sulfonate calcium salt 6%, draw back powder 4%, silicone compound 0.6%, polyvinyl alcohol 0.5%, glycerine 2%, deionized water and add to 100%, mixed 18% MTI-446 emamectin benzoate suspending agent.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC<80 are antagonism, and 80≤CTC≤120 are summation action, and CTC>120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent of MTI-446 effective active composition B is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for examination 3 instar larvaes, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC 50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
To be converted into probit value (y) for examination insect corrected mortality, concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with the MTI-446 is the standard medicament, and its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=MTI-446 of M MTI-446TI * P of+effective active composition B Effective active composition B
In the formula: M is the mixture of different proportionings
P Effective active composition BBe effective active composition B shared ratio in composition
P MTI-446Be MTI-446 shared ratio in composition
A is selected from MTI-446;
B is selected from following any one insecticide: Avermectin, emamectin-benzoate.
Application Example two
For trying insect: rice-stem borer.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of MTI-446, the former medicine of B and the two different proportioning mixture is determined in the process preliminary experiment, and each medicament designs 11 gradient concentrations respectively by active constituent content and handles.
Toxicity test result one
The different proportionings with Avermectin of table 1 MTI-446 are to the toxicity test of rice-stem borer
As shown in Table 1, the proportioning 100: 1 of MTI-446 and abamectin compounded control rice-stem borer, to 1: 20 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 100: 1 to 1: 20 all shows synergistic effect, especially when the proportioning of MTI-446 and Avermectin during at 8: 1 to 1: 4, synergistic effect is more obviously outstanding, thus when MTI-446: Avermectin all had synergistic function between 1: 20 the time at 100: 1, co-toxicity coefficient maximum when MTI-446 and Avermectin weight ratio are 2: 1, synergistic effect is the most obvious.
Toxicity test result two
The different proportionings with emamectin-benzoate of table 2 MTI-446 are to the toxicity test of rice-stem borer
As shown in Table 2, the proportioning of the composite control of MTI-446 and emamectin-benzoate rice-stem borer 100: 1, to 1: 20 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 100: 1 to 1: 20 all shows synergistic effect, especially when MTI-446 and emamectin-benzoate get proportioning at 20: 1 to 1: 1, synergistic effect is more obviously outstanding, thus when MTI-446: emamectin-benzoate all had synergistic function between 1: 20 the time at 100: 1, co-toxicity coefficient maximum when the weight ratio of MTI-446 and emamectin-benzoate is 10: 1, synergistic effect is the most obvious.
Application Example three MTI-446 and Avermectin and the composite control cabbage pieris test of pesticide effectiveness thereof
This experimental establishment is in Shuozhou City vegetables main producing region, Shanxi Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% MTI-446 wetting powder (commercial), 1.8% abamectin emulsifiable concentrate (commercial).
Investigation cabbage pieris insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 3 MTI-446, Avermectin and the composite control cabbage pieris test of pesticide effectiveness thereof
As can be seen from Table 3, MTI-446 and abamectin compounded after can effectively prevent and treat cabbage pieris, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects, and vegetables diamond-back moth, beet armyworm, prodenia litura, aphid etc. are all had preventive effect.
Application Example four MTI-446 and emamectin-benzoate and the composite control rice-stem borer test of pesticide effectiveness thereof
This experimental establishment is at suburb, Honghu City, Hubei Province paddy field, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% MTI-446 wetting powder (commercial), 1% emamectin-benzoate missible oil (commercial).
Investigation rice-stem borer insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 4 MTI-446, emamectin-benzoate and the composite control rice-stem borer test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat rice-stem borer after MTI-446 and emamectin-benzoate are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects, and to rice hoppers, paddy stem borer, rice leaf roller have certain preventive effect.

Claims (7)

1. a composition pesticide that contains MTI-446 comprises effective active component, auxiliary agent and filler, it is characterized in that: A, B percentage by weight are 1~100: 1~20, and described A is selected from MTI-446, and B is selected from Avermectin, emamectin-benzoate.
2. a kind of Pesticidal combination that contains MTI-446 according to claim 1 is characterized in that: the ratio of weight and number of A, two kinds of active components of B is 1~40: 1~15.
3. according to the described Pesticidal combination that contains MTI-446 of claim 2, it is characterized in that: the percentage by weight of MTI-446 and Avermectin is 5~30: 1~10.
4. according to the described Pesticidal combination that contains MTI-446 of claim 2, it is characterized in that: the percentage by weight of MTI-446 and emamectin-benzoate is 5~30: 1~10.
5. according to the Pesticidal combination of the described MTI-446 that contains of claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent.
6. the MTI-446 Pesticidal combination that contains according to claim 1 is in the application of control aspect the crop pests.
7. the MTI-446 Pesticidal combination that contains according to claim 1 is mainly used in control paddy rice, vegetables, cotton, fruit various pests.
CN2010105643930A 2010-11-29 2010-11-29 Dinotefuran-containing pesticide composition Pending CN101990898A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102349505A (en) * 2011-09-13 2012-02-15 广西田园生化股份有限公司 Ultra-low-capacity liquid containing dinotefuran
CN102763668A (en) * 2012-07-04 2012-11-07 河北威远生物化工股份有限公司 Insecticidal composition containing dinotefuran and emamectin benzoate
CN103461373A (en) * 2013-09-13 2013-12-25 陆学云 Dinotefuran and abamectin mixed micro-emulsion pesticide formulation
CN105028456A (en) * 2015-06-12 2015-11-11 福建省德盛生物工程有限责任公司 Low-volume spray containing emamectin benzoate and dinotefuran
CN107136100A (en) * 2017-05-26 2017-09-08 河北威远生化农药有限公司 Synergistic insecticidal compositions containing avermectin B2a and MTI-446
CN111149812A (en) * 2020-01-17 2020-05-15 河南远见农业科技有限公司 Insecticide composition containing emamectin benzoate and dinotefuran and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646018A (en) * 2002-02-21 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticide mixtures
CN102415398A (en) * 2010-09-28 2012-04-18 南京华洲药业有限公司 Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof
CN102415400A (en) * 2010-09-28 2012-04-18 南京华洲药业有限公司 Composite pesticidal composition containing dinotefuran and abamectin and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646018A (en) * 2002-02-21 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticide mixtures
CN102415398A (en) * 2010-09-28 2012-04-18 南京华洲药业有限公司 Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof
CN102415400A (en) * 2010-09-28 2012-04-18 南京华洲药业有限公司 Composite pesticidal composition containing dinotefuran and abamectin and application thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102349505A (en) * 2011-09-13 2012-02-15 广西田园生化股份有限公司 Ultra-low-capacity liquid containing dinotefuran
CN102349505B (en) * 2011-09-13 2013-09-11 广西田园生化股份有限公司 Ultra-low-capacity liquid containing dinotefuran
CN102763668A (en) * 2012-07-04 2012-11-07 河北威远生物化工股份有限公司 Insecticidal composition containing dinotefuran and emamectin benzoate
CN103461373A (en) * 2013-09-13 2013-12-25 陆学云 Dinotefuran and abamectin mixed micro-emulsion pesticide formulation
CN105028456A (en) * 2015-06-12 2015-11-11 福建省德盛生物工程有限责任公司 Low-volume spray containing emamectin benzoate and dinotefuran
CN107136100A (en) * 2017-05-26 2017-09-08 河北威远生化农药有限公司 Synergistic insecticidal compositions containing avermectin B2a and MTI-446
CN111149812A (en) * 2020-01-17 2020-05-15 河南远见农业科技有限公司 Insecticide composition containing emamectin benzoate and dinotefuran and application thereof

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