CN105994275A - Pesticide composition containing chromafenozide and biogenic sources - Google Patents
Pesticide composition containing chromafenozide and biogenic sources Download PDFInfo
- Publication number
- CN105994275A CN105994275A CN201610328834.4A CN201610328834A CN105994275A CN 105994275 A CN105994275 A CN 105994275A CN 201610328834 A CN201610328834 A CN 201610328834A CN 105994275 A CN105994275 A CN 105994275A
- Authority
- CN
- China
- Prior art keywords
- pleocidin
- ring tebufenozide
- avilamycin
- ethyl
- benzoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 239000000575 pesticide Substances 0.000 title claims abstract description 42
- 230000000035 biogenic effect Effects 0.000 title claims abstract description 7
- 239000005887 Chromafenozide Substances 0.000 title abstract description 12
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 title abstract description 12
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- 239000005937 Tebufenozide Substances 0.000 claims description 236
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 claims description 206
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 98
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Abstract
The invention discloses pesticide composition containing chromafenozide and biogenic sources. The composition is mainly characterized by comprising an active ingredient A and an active ingredient B, wherein the active ingredient A is chromafenozide, the active ingredient B is any one of abamectin, emamectin benzoate, spinosad and spinetoram, and the weight ratio of the active ingredient A to the active ingredient B is (1:80)-(80:1); the composition can be in a form of wettable powder, water dispersible granules, a suspending agent, a suspoemulsion, an emulsion in water, a microemulsion, a microcapsule suspending agent or a microcapsule suspending-suspending agent. The composition can be used for controlling pests on rice, wheat, cotton, fruit trees, vegetables, flowers and corn and has a remarkable synergistic effect; the dosage of a pesticide is reduced, and the pesticide composition is safe and harmless to people and livestock and has good environment compatibility; the adhesion force of a preparation is enhanced, and the preparation is resistant to rain wash.
Description
The application is divisional application, and original application is the patent Shen of Shaanxi Welch Crop Protection Co., Ltd.
Please " a kind of ring tebufenozide and the composition pesticide of biogenic substances ", the Application No. of original application:
2012100668220, original application day is 2012.3.14.
Technical field
The invention belongs to technical field of pesticide, relate to the agriculture of a kind of ring tebufenozide and biogenic substances
Drug composition is for preventing and treating the application of crop pest.
Background technology
Ring tebufenozide (chromafenozid), molecular formula: C24H30N2O3, ring tebufenozide is
Bishydrazide insecticide, after pests, suppression feed in several hours, causes insect simultaneously
Cast off a skin in advance and cause death.It is by regulation germling hormone and ecdyson moving obstacle
The molting process of insecticide, causes the death of casting off a skin too early of insecticide.Because it can quickly press down
The feed of insecticide processed, for the similar medicament that other are conventional, can reduce crop
Harm.To noctuid and other caterpillar, no matter in which, ring tebufenozide has in period
The strongest insecticidal activity.
Avilamycin (abamectin), chemical molecular formula:
C48H72O14(B1a)·C47H70O14(B1b).Avilamycin is a kind of macrolide disaccharidase class
Compound.Be from soil microorganism separate natural product, insecticide and demodicid mite class are had tag and
Stomach poison function also has faint fumigation action, without systemic action.But it has the strongest oozing to blade
Effect, can kill subepidermal insect, and the longevity of residure is long thoroughly.Its not ovicidal.Its mechanism of action
Its interference nervous physiology is movable unlike general insecticide, stimulates release r-aminobutyric acid,
And r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if demodicid mite class become demodicid mite and
I.e. there is paralysis symptom after contacting with medicament with larva in insecticide, and inertia does not takes food, 2-4 days
Rear death.Because not causing insecticide rapid dehydration, so its lethal effect is slower.But to predation
Though property and parasite have direct killing effect, but because plant surface residual is few, therefore to benefit
The damage of worm is little.
Emamectin-benzoate (emamectin benzoate), chemical molecular formula:
C49H75NO13·C7H6O2.Emamectin-benzoate be a kind of efficiently, wide spectrum,
The insecticidal/acaricidal agent of longevity of residure length, its mechanism of action is for obstruction pest movements nerve information transmission
Make health paralysis death.Model of action, based on stomach toxicity, also has action of contace poison, to crop without interior
Absorption energy, but effectively penetrate into and use crop epidermal tissue, thus there is the longer longevity of residure.Right
Demodicid mite class, coleoptera and homoptera pest have high activity, soil and in degradable noresidue,
Free from environmental pollution, to beneficial insect and natural enemy, people, animal safety in normal dosage ranges,
Can be with major part combined use of pesticides.
Pleocidin (spinosad), the mechanism of action of pleocidin is the most novel and unique,
Being different from general macrolides compound, it is only that the chemical constitution of its uniqueness determines it
Special insecticidal mechanism.Insecticide is existed by pleocidin quickly to tag and toxicity of ingesting, its tool
Having the distinctive poisoning symptom of never poison, its mechanism of action is the god by stimulating insecticide
Through system, increase its constitutive activity, cause the flesh of non-functional to shrink, exhaustion, and accompany
With trembling and benumbing, demonstrate that nAChR is caused acetyl by sustained activation
Choline extends release reaction.Pleocidin also acts on γ mono-aminobutyric acid receptors simultaneously,
Change the function of GABA gate chloride channel, promote the raising of its insecticidal activity further.
Ethyl pleocidin (spinetoram) chemical molecular formula: C42H69NO10, ethyl
Pleocidin is made up of ethyl pleocidin-J and two kinds of components of ethyl pleocidin-L, makees
For the nervous system of insecticide, to diamondback moth, beet armyworm, Liriomyza, thrips, tiltedly
The prevention effect that Autographa spp, bean-pod borer have had.
In the real process of agricultural production, pest control, evil demodicid mite are easiest to generate the problem that
Drug-fast generation.Different cultivars composition compounds, and is to prevent and treat resistant insect, evil demodicid mite very
Common method.Heterogeneity compounds, and according to practical application effect, judges certain
Compounding be potentiation, add and or antagonism.In most cases, the compounding effect of pesticide
Fruit is all additive effect, really has the compounding little of potentiation, and especially potentiation is non-
Compounding that Chang Mingxian, co-toxicity coefficient are the highest is the most less.Find through inventor's lot of experiments,
Ring tebufenozide and avilamycin, emamectin-benzoate, pleocidin, ethyl are many
After bacteriocidin is compounding, potentiation is notable, and Environmental compatibility is fabulous, considerably reduces pesticide
Dosage.
Summary of the invention
The composition pesticide that the present invention proposes is except bag containing chromafenozide and avilamycin, methylamino
Any one two kinds of activity in abamectin benzoate, pleocidin, ethyl pleocidin
Outside component, also comprise appropriate surfactant and carrier.
A kind of ring tebufenozide and the composition pesticide of biogenic substances, comprise active components A, activity
Composition B, it is characterised in that: active components A is ring tebufenozide, and active component B is A Wei
In rhzomorph, emamectin-benzoate, pleocidin, ethyl pleocidin arbitrarily
One, and the weight ratio of active components A and active component B is 1:80～80:1.
Described composition pesticide, it is characterised in that: active components A and active component B's
Weight ratio is 1:40～60:1.
Described composition pesticide, it is characterised in that: ring tebufenozide and the weight ratio of avilamycin
For 1:5～20:1.
Described composition pesticide, it is characterised in that: ring tebufenozide and Affirm (Merck Co.) benzene
The weight ratio of formates is 1:5～30:1.
Described composition pesticide, it is characterised in that: ring tebufenozide and the weight ratio of pleocidin
For 1:10～20:1.
Described composition pesticide, it is characterised in that: ring tebufenozide and the weight of ethyl pleocidin
Amount ratio is 1:10～20:1.
Described composition pesticide, it is characterised in that: compositions makes wettable powder, moisture
Shot agent, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule hang
Floating-suspending agent.
Described composition pesticide is for preventing and treating the application of crop pests, described crops bag
Include Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, fruit tree, vegetable, Camellia sinensis, flowers, Semen Maydis.
Described application, pest control includes: rice leaf roller, the snout moth's larva of rice, planthopper,
Diamondback moth, Pieris rapae, aphid, thrips, demodicid mite class, scale insect, chafer, weevil, midge
Worm, 2 committees noctuid, citrus fruit flies.
Including at least a kind of surfactant in the composition pesticide of the present invention, when being beneficial to use
Active component dispersion in water.Surface-active contents is the 5%～30% of total formulation weight amount,
Surplus is solid or liquid diluent.Surfactant selected by the composition pesticide of the present invention
It is known in those skilled in the art: dispersant, wetting agent, emulsifying agent can be selected from or disappear
One or more in infusion.
Following constituent content is comprised when making wettable powder: active components A 0.1%～80%,
More than active component B 0.1%～80%, dispersant 3%～15%, wetting agent 2%～10%, filler
Amount.
Compositions includes following constituent content when making water dispersible granules: active components A
0.1%～80%, active component B 0.1%～80%, dispersant 3%～12%, wetting agent 1%～10%,
Disintegrating agent 1%～10%, binding agent 0～8%, filler surplus.
Compositions includes following constituent content when making suspending agent: active components A 0.1%～60%,
Active component B 0.1%～60%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～2%,
Thickening agent 0.05～2%, antifreeze 0～8%, deionized water add to 100%.
Compositions includes following constituent content when making suspension emulsion: active components A 0.1%～60%,
Active component B 0.1%～60%, emulsifying agent 2%～12%, dispersant 2%～10%, defoamer
0.1%～2%, thickening agent 0.05%～2%, antifreeze 0%～8%, stabilizer 0%～5%, molten
Agent 0%～15%, deionized water add to 100%.
Compositions comprises following constituent content when making aqueous emulsion: activity composition A
0.1%～60%, active component B 0.1%～60%, solvent 0%～30%, emulsifying agent 1%～15%,
Antifreeze 0%～10%, thickening agent 0.05%～2%, defoamer 0.01%～2%, deionized water
Supply surplus.
Compositions comprise when making microemulsion following constituent content active components A 0.1%～60%,
Active component B 0.1%～60%, solvent 0%～30%, emulsifying agent 3%～20%, antifreeze
0%～10%, thickening agent 0%～2%, defoamer 0.01%～2%, stabilizer 0%～4%, go
Ionized water surplus.
Compositions is made micro-capsule suspension and is included following constituent content: active components A
0.1%～60%, active component B 0.1%～60%, macromolecule cyst material 1%～12%, table
Face activating agent 2%～10%, organic solvent 1%～15%, emulsifying agent 1%～8%, pH adjusting agent
0.1%～5%, deionized water adds to 100%.
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A
0.1%～60%, active component B 0.1%～60%, macromolecule cyst material 2%～12%, table
Face activating agent 3%～15%, organic solvent 1%～5%, emulsifying agent 1%～6%, defoamer
0.1%～5%, thickening agent 0.05%～2%, pH adjusting agent 0.1%～5%, water add to 100%.
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) ring tebufenozide and avilamycin, emamectin-benzoate, sterilize more
After element, ethyl pleocidin are compounding, there is notable synergistic and lasting effect；
(2) expand preventing and treating spectrum, to Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, fruit tree, vegetable, Camellia sinensis,
Rice leaf roller on Semen Maydis, the snout moth's larva of rice, planthopper, diamondback moth, Pieris rapae, aphid,
Thrips, demodicid mite class, scale insect, chafer, weevil, midge worm, two select committee noctuid, the little reality of Fructus Citri tangerinae
Flies etc. all have greater activity；
(3) decrease the dosage of pesticide, reduce pesticide residual quantity on crop, subtract
Light environmental pollution；
(4) to person poultry safety, Environmental compatibility is good, is not likely to produce Drug resistance.
Detailed description of the invention
Below in conjunction with embodiment, further instruction of the present invention, the percentage ratio in embodiment are
Percentage by weight, but the invention is not limited in this.
Application Example one
Embodiment 1 55% ring tebufenozide avilamycin wettable powder
Ring tebufenozide 50%, avilamycin 5%, alkylnaphthalene sulfonate 5%, dodecyl sulfur
Acid sodium 3%, Kaolin add to 100%, and mixture carries out comminution by gas stream, prepare 55% ring worm
Hydrazides avilamycin wettable powder.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 2 50% ring tebufenozide avilamycin wettable powder
Ring tebufenozide 40%, avilamycin 10%, double (alkyl) naphthalene sulphonate formaldehyde are condensed
Thing 6%, dodecylbenzene sodium sulfonate 4%, attapulgite add to 100%, and mixture carries out gas
Stream is pulverized, and prepares 50% ring tebufenozide avilamycin wettable powder.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 3 32% ring tebufenozide avilamycin water dispersible granules
Ring tebufenozide 30%, avilamycin 2%, naphthalene sulfonic acid-formaldehyde condensation product 6%, pull open powder
BX 5%, sodium bicarbonate 2%, white carbon add to 100%, be mixed to prepare 32% ring tebufenozide Ah
Dimension rhzomorph water dispersible granules.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 4 61% ring tebufenozide avilamycin water dispersible granules
Ring tebufenozide 60%, avilamycin 1%, wetting and penetrating agent F 5%, aryl phenol polyoxy second
Alkene succinate sulfonate 6%, carbamide 2%, Kaolin add to 100%, are mixed to prepare 61%
Ring tebufenozide avilamycin water dispersible granules.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 5 42% ring tebufenozide avilamycin suspending agent
Ring tebufenozide 40%, avilamycin 2%, octylphenol polyethylene oxyethylene group ether sulfate 5%,
Tea seed cake 4%, silicone 0.6%, hydroxymethyl cellulose 0.16%, ethylene glycol 3.8%, deionization
Water adds to 100%, is mixed to prepare 42% ring tebufenozide avilamycin suspending agent.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 6 20% ring tebufenozide avilamycin suspending agent
Ring tebufenozide 15%, avilamycin 5%, polycarboxylate 6%, Fructus Sapindi Mukouossi powder 4%, silicon
Oil 0.7%, arabic gum 0.14%, propylene glycol 0.8%, deionized water add to 100%, mixing
Prepare 20% ring tebufenozide avilamycin suspending agent.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 7 20% ring tebufenozide avilamycin suspension emulsion
Ring tebufenozide 10%, avilamycin 10%, lignosulfonates 5%, Fructus Sapindi Mukouossi powder 5%,
Phenyl phenol polyoxyethanyl ether phosphate 6%, butyl ether 10%, C10～20Saturated fat acids is (such as the last of the ten Heavenly stems
Acid) and amide 1%, polyvinylpyrrolidone 0.08%, Polyethylene Glycol 3.8%, deionized water
Add to 100%, be mixed to prepare 20% ring tebufenozide avilamycin suspension emulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 8 15% ring tebufenozide avilamycin suspension emulsion
Ring tebufenozide 10%, avilamycin 5%, alkyl benzene sulfonate calcium salt 5%, spaonin powder 4%,
Triethanolamine salt 6%, Ketohexamethylene 5%, silicone oil 0.8%, phenolic resin 0.15%, propylene glycol
2.1%, deionized water adds to 100%, is mixed to prepare 15% ring tebufenozide avilamycin suspension emulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 9 35% ring tebufenozide avermectin micro-emulsion
Ring tebufenozide 30%, avilamycin 5%, alkylphenol-formaldehyde resin polyoxyethyl ether 7%,
N-ketopyrrolidine 4%, Polyethylene Glycol 1%, polyvinylpyrrolidone 0.18%, C8～10Fat
Alcohols 1.2%, deionized water supplies 100%, is mixed to prepare 35% ring tebufenozide avilamycin
Microemulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 10 12% ring tebufenozide avermectin micro-emulsion
Ring tebufenozide 10%, avilamycin 2%, acetonitrile 6%, polyvinylpyrrolidone 0.2%,
Phenyl phenol polyoxyethyl ether 7%, silicone compound 1.4%, deionized water supplies 100%,
Prepare 12% ring tebufenozide avermectin micro-emulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 11 15% ring tebufenozide abamectin aqueous emulsion
Ring tebufenozide 12%, avilamycin 3%, methanol 4%, ethylene glycol monomethyl ether 5%, epoxy
Oxide-propylene oxide block copolymer 6%, arabic gum 0.18%, silicone 0.8%, go from
Sub-water adds to 100%, is mixed to prepare 15% ring tebufenozide abamectin aqueous emulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 12 16% ring tebufenozide abamectin aqueous emulsion
Ring tebufenozide 15%, avilamycin 1%, acetonitrile 3.5%, N-ketopyrrolidine 5.5%,
Alkylaryl polyoxyethylene polyoxypropylene ether 7%, polyvinylpyrrolidone 0.12%, C10～20Full
With fatty acid 1%, deionized water adds to 100%, blended prepare 16% ring tebufenozide Ah
Dimension rhzomorph aqueous emulsion.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 13 12% ring tebufenozide avermectin microcapsule suspending agent
Ring tebufenozide 2%, avilamycin 10%, deformation lactoprotein 3%, polyisocyanate 2%,
Spaonin powder 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2.8%, propanol 4%, Sorbitan alcohol ester
Fat acid ester polyoxyethylene ether 5%, citric acid 0.4%, sodium hydroxide 0.5%, deionized water add
To 100% weight portion, prepare 12% ring tebufenozide avermectin microcapsule suspending agent.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 14 30% ring tebufenozide avermectin microcapsule suspension-suspending agent
Ring tebufenozide 25%, avilamycin 5%, polyfunctional group acyl halide dihydroxylic alcohols 5%, wheat
Bud sugar 2%, Bombyx mori L. 2.5%, ethyl acetate 7%, alkylphenol-formaldehyde resin polyoxyethyl ether 5%,
Alkylaryl polyoxyethylene polyoxypropylene ether 3%, C8～10Aliphatic alcohols 1.6%, phenolic resin
1.2%, sodium hydroxide 0.4%, citric acid 0.6%, water add to 100% weight portion, prepare 30%
Ring tebufenozide avermectin microcapsule suspension-suspending agent.
Avilamycin is changed to emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 15 30% ring tebufenozide emamectin-benzoate wettable powder
Ring tebufenozide 29%, emamectin-benzoate 1%, ester polyoxyethylene be phonetic 5%,
Fructus Sapindi Mukouossi powder 3%, attapulgite add to 100%, and mixture carries out comminution by gas stream, prepare 30%
Ring tebufenozide emamectin-benzoate wettable powder.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 16 20% ring tebufenozide emamectin-benzoate wettable powder
Ring tebufenozide 18%, emamectin-benzoate 2%, aliphatic acid polyethenoxy
Ester 5%, Bombyx mori L. 5%, Kaolin add to 100%, and mixture carries out comminution by gas stream, prepare 20%
Ring tebufenozide emamectin-benzoate wettable powder.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 17 35% ring tebufenozide emamectin-benzoate water dispersible granules
Ring tebufenozide 30%, emamectin-benzoate 5%, aliphatic amine polyoxyethylene
Phonetic 6%, tea seed cake 5%, aluminum chloride 2.4%, bentonite add to 100%, are mixed to prepare 35%
Ring tebufenozide emamectin-benzoate water dispersible granules.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 18 25% ring tebufenozide emamectin-benzoate water dispersible granules
Ring tebufenozide 20%, emamectin-benzoate 5%, sodium laurylsulfate 5%,
Alkyl benzene sulfonate calcium salt 6%, ammonium sulfate 2%, Kaolin add to 100%, are mixed to prepare 25%
Ring tebufenozide emamectin-benzoate water dispersible granules.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 19 30% ring tebufenozide emamectin benzoate suspending agent
Ring tebufenozide 26%, emamectin-benzoate 4%, alkylphenol-polyethenoxy
Phonetic formaldehyde condensation products sulfate 5%, spaonin powder 4%, C8～10Aliphatic alcohols 1%, Magnesiumaluminumsilicate
0.2%, propylene glycol 4%, deionized water add to 100%, are mixed to prepare 30% ring tebufenozide first
Amino abamectin benzoate suspending agent.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 20 40% ring tebufenozide emamectin benzoate suspending agent
Ring tebufenozide 39.5%, emamectin-benzoate 0.5%, lignin sulfonic acid
Salt 6%, Bombyx mori L. 4%, C8～10Aliphatic alcohols 0.7%, white dextrin 0.14%, 2,2'-ethylenedioxybis(ethanol). 0.8%,
Deionized water adds to 100%, is mixed to prepare 40% ring tebufenozide Affirm (Merck Co.) benzoic acid
Salt suspension agent.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 21 10% ring tebufenozide emamectin-benzoate suspension emulsion
Ring tebufenozide 9.5%, emamectin-benzoate 0.5%, alkylaryl polyoxy
Vinyl Ether 5%, Nekal BX 5%, benzyl dimethyl phenol polyoxyethyl ether 6%, butanol 8%,
C10～20Saturated fat acids 0.1%, polyvinylpyrrolidone 0.06%, Polyethylene Glycol 3.8%,
Deionized water adds to 100%, is mixed to prepare 10% ring tebufenozide Affirm (Merck Co.) benzoic acid
Salt suspension emulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 22 20% ring tebufenozide emamectin-benzoate suspension emulsion
Ring tebufenozide 17.5%, emamectin-benzoate 2.5%, fatty alcohol polyoxy
Vinyl ethers 5%, dodecylbenzene sodium sulfonate 4%, alkyl biphenyl ether disulfonic acid magnesium salt 6%,
N-ketopyrrolidine 5%, silicone 0.8%, phenolic resin 0.15%, propylene glycol 4.1%, go from
Sub-water adds to 100%, is mixed to prepare 20% ring tebufenozide emamectin-benzoate and hangs
Emulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 23 24% ring tebufenozide emamectin benzoate microemulsion
Ring tebufenozide 21%, emamectin-benzoate 3%, phenyl phenol polyoxyethanyl
Ether 7%, Ketohexamethylene 4%, arabic gum 1%, crospolyvinylpyrrolidone 0.18%, the last of the ten Heavenly stems
Acid 1.2%, deionized water supplies 100%, is mixed to prepare 24% ring tebufenozide methylamino A Wei
Rhzomorph benzoate microemulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 24 30% ring tebufenozide emamectin benzoate microemulsion
Ring tebufenozide 20%, emamectin-benzoate 10%, ethyl acetate 6%,
Methylcellulose 0.2%, phenethyl fluosite polyoxyethyl ether 7%, C8～10Aliphatic alcohols
0.4%, deionized water supplies 100%, prepares 30% ring tebufenozide Affirm (Merck Co.) benzene first
Hydrochlorate microemulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 25 20% ring tebufenozide emamectin-benzoate aqueous emulsion
Ring tebufenozide 16%, emamectin-benzoate 4%, toluene 4%, front three
Cyclohexene ketone 5%, phenethyl phenol polyoxyethanyl polypropylene-base ether 6%, Magnesiumaluminumsilicate 0.18%,
Silicone 0.8%, deionized water adds to 100%, is mixed to prepare 20% ring tebufenozide methylamino
Abamectin benzoate aqueous emulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 26 30% ring tebufenozide emamectin-benzoate aqueous emulsion
Ring tebufenozide 29.5%, emamectin-benzoate 0.5%, acetonitrile 3.5%,
N-ketopyrrolidine 5.5%, ethylene oxide-propylene oxide block copolymer 7%, phenolic resin
0.12%, silicone oil 1%, deionized water adds to 100%, blended prepared 30% ring tebufenozide first
Amino abamectin benzoate aqueous emulsion.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 27 30% ring tebufenozide emamectin-benzoate micro-capsule suspension
Ring tebufenozide 25%, emamectin-benzoate 5%, polyfunctional group acyl halide
Dihydroxylic alcohols 3%, sodium alginate 2%, sodium laurylsulfate 5%, lignosulfonates 5%,
N-ketopyrrolidine 4%, ethylene oxide-propylene oxide block copolymer 5%, citric acid 0.4%,
Sodium hydroxide 0.5%, deionized water add to 100% weight portion, prepare 30% ring tebufenozide first
Amino abamectin benzoate micro-capsule suspension.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 28 14% ring tebufenozide emamectin benzoate microcapsule suspension-suspending agent
Ring tebufenozide 12%, emamectin-benzoate 2%, carbamide 5%, formaldehyde
3%, tea seed cake 2.5%, butyl ether 7%, phenethyl phenol polyoxyethanyl polypropylene-base ether 5%, fat
Polyoxyethylenated alcohol 3%, silicone 1.6%, sodium tripolyphosphate 1.2%, sodium hydroxide 0.4%,
Citric acid 0.6%, water add to 100% weight portion, prepare 14% ring tebufenozide methylamino A Wei
Rhzomorph benzoate microcapsule suspension-suspendinagent agent.
Emamectin-benzoate is changed to avilamycin, pleocidin, the many sterilizations of ethyl
Element can form new embodiment.
Embodiment 29 81% ring tebufenozide pleocidin wettable powder
Ring tebufenozide 1%, pleocidin 80%, lignosulfonates 6%, dodecyl sulfur
Acid sodium 5%, attapulgite add to 100%, and mixture carries out comminution by gas stream, prepare 81% ring
Tebufenozide pleocidin wettable powder.
Effective active composition pleocidin is changed to emamectin-benzoate, Avermectin
Element, ethyl pleocidin form new embodiment.
Embodiment 30 50% ring tebufenozide pleocidin wettable powder
Ring tebufenozide 40%, pleocidin 10%, aliphatic alcohol polyethenoxy base ether 6%, pull open
Powder BX 5%, Kaolin add to 100%, and mixture carries out comminution by gas stream, prepare 50% ring worm
Hydrazides pleocidin wettable powder.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 31 61% ring tebufenozide pleocidin water dispersible granules
Ring tebufenozide 1%, pleocidin 60%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm
Sand 6%, glucose 2.6%, bentonite add to 100%, are mixed to prepare 61% ring tebufenozide many
Bacteriocidin water dispersible granules.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 32 60% ring tebufenozide pleocidin water dispersible granules
Ring tebufenozide 40%, pleocidin 20%, dodecylbenzene sodium sulfonate 5%, octyl phenol
Polyoxyethylene groups ether sulfate 6%, ammonium sulfate 2%, Kaolin add to 100%, are mixed to prepare
60% ring tebufenozide pleocidin water dispersible granules.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 33 42% ring tebufenozide pleocidin suspension
Ring tebufenozide 40%, pleocidin 2%, alkyl benzene sulfonate calcium salt 5%, dodecyl
Sodium sulfate 4%, silicone oil 1%, sodium tripolyphosphate 0.2%, glycerol 4%, deionized water add to
100%, it is mixed to prepare 42% ring tebufenozide pleocidin suspension.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 34 30% ring tebufenozide pleocidin suspension
Ring tebufenozide 20%, pleocidin 10%, polycarboxylate 6%, tea seed cake 4%, silicone
Class 0.7%, xanthan gum 0.14%, glycerol 0.8%, deionized water add to 100%, mixing system
Obtain 30% ring tebufenozide pleocidin suspension.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 35 25% ring tebufenozide pleocidin suspension emulsion
Ring tebufenozide 20%, pleocidin 5%, alkyl benzene sulfonate calcium salt 6%, moistening infiltration
Agent F 4%, alkylphenol-formaldehyde resin polyoxyethyl ether 6%, ethylene glycol monomethyl ether 5%, C10～20
Saturated fat acids 1%, polyvinyl alcohol 0.12%, Polyethylene Glycol 1.5%, deionized water add to
100%, it is mixed to prepare 25% ring tebufenozide pleocidin suspension emulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 36 15% ring tebufenozide pleocidin suspension emulsion
Ring tebufenozide 10%, pleocidin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, the moon
Lauryl sulfate 6%, phenethyl fluosite polyoxyethyl ether 6%, ethyl acetate 4%,
C8～10Aliphatic alcohols 1%, methylcellulose 0.15%, glycerol 4%, deionized water add to 100%,
It is mixed to prepare 15% ring tebufenozide pleocidin suspension emulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 37 24% ring tebufenozide pleocidin microemulsion
Ring tebufenozide 16%, pleocidin 8%, propanol 6%, phenolic resin 0.2%, alkyl
Aryl polyoxyethylene poly-oxygen propylene aether 7%, silicone 1.4%, deionized water supplies 100%,
Prepare 24% ring tebufenozide pleocidin microemulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 38 35% ring tebufenozide pleocidin microemulsion
Ring tebufenozide 25%, pleocidin 10%, Ketohexamethylene 6%, sodium acrylate 0.2%, mountain
Pears alcohol acid anhydride monostearate 7%, C8～10Aliphatic alcohols 1.4%, 2,2'-ethylenedioxybis(ethanol). 3.8%, deionization
Water supplies 100%, prepares 35% ring tebufenozide pleocidin microemulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 39 25% ring tebufenozide pleocidin aqueous emulsion
Ring tebufenozide 15%, pleocidin 10%, acetonitrile 5%, toluene 5%, alkyl biphenyl
Ether disulfonic acid magnesium salt 6%, xanthan gum 0.18%, silicone compound 0.8%, ethylene glycol 4%,
Deionized water adds to 100%, is mixed to prepare 25% ring tebufenozide pleocidin aqueous emulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 40 20% ring tebufenozide pleocidin aqueous emulsion
Ring tebufenozide 15%, pleocidin 5%, DMF 5%, N are pungent
Base ketopyrrolidine 5%, alkylphenol-formaldehyde resin polyoxyethyl ether 6%, xanthan gum 0.18%,
C8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, is mixed to prepare 20% ring tebufenozide many
Bacteriocidin aqueous emulsion.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 41 45% ring tebufenozide spinosad microcapsule suspending agent
Ring tebufenozide 30%, pleocidin 15%, carbamide 3%, sodium alginate 3%, Laurel
Alcohol sodium sulfate 5%, alkylphenol-polyethenoxy are phonetic 2.8%, vegetable oil 6%, styrene polyoxy second
Alkene ether ammonium sulfate salt 5%, citric acid 0.4%, sodium hydroxide 0.6%, deionized water add to 100%
Weight portion, prepares 45% ring tebufenozide spinosad microcapsule suspending agent.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 42 18% ring tebufenozide pleocidin microcapsule suspension-suspendinagent agent
Ring tebufenozide 12%, pleocidin 6%, gelatin 5%, arabic gum 2%, dodecane
Base sodium sulfate 2.5%, vegetable oil 6%, phenethyl fluosite polyoxyethyl ether 5%, castor
Oleum Sesami polyoxyethylene ether 3%, silicone compound 0.6%, polyvinylpyrrolidone 1.2%,
Sodium hydroxide 0.4%, citric acid 0.5%, water add to 100% weight portion, prepare 18% ring worm
Hydrazides pleocidin microcapsule suspension-suspendinagent agent.
Effective active composition pleocidin is changed to avilamycin, Affirm (Merck Co.) benzoic acid
Salt, ethyl pleocidin form new embodiment.
Embodiment 43 55% ring tebufenozide ethyl pleocidin wettable powder
Ring tebufenozide 5%, ethyl pleocidin 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%,
Dodecylbenzene sodium sulfonate 5%, kieselguhr add to 100%, and mixture carries out comminution by gas stream,
Prepare 55% ring tebufenozide ethyl pleocidin wettable powder.
Effective active composition ethyl pleocidin is changed to emamectin-benzoate, Ah
Dimension rhzomorph, pleocidin form new embodiment.
Embodiment 44 60% ring tebufenozide ethyl pleocidin wettable powder
Ring tebufenozide 45%, ethyl pleocidin 15%, the phonetic formaldehyde of alkylphenol-polyethenoxy contract
Compound sulfate 6%, spaonin powder 5%, Kaolin add to 100%, and mixture carries out air-flow powder
Broken, prepare 60% ring tebufenozide ethyl pleocidin wettable powder.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 45 42% ring tebufenozide ethyl pleocidin water dispersible granules
Ring tebufenozide 40%, ethyl pleocidin 2%, alkylphenol-polyethenoxy are phonetic 6%, tea
Withered 4%, aluminum chloride 3%, precipitated calcium carbonate add to 100%, are mixed to prepare 42% ring tebufenozide second
Quito bacteriocidin water dispersible granules.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 46 60% ring tebufenozide ethyl pleocidin water dispersible granules
Ring tebufenozide 30%, ethyl pleocidin 30%, sodium laurylsulfate 5%, alkyl phenol
Polyoxyethylene phonetic formaldehyde condensation products sulfate 6%, sodium carbonate 2%, Kaolin add to 100%,
It is mixed to prepare 60% ring tebufenozide ethyl pleocidin water dispersible granules.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 47 30% ring tebufenozide ethyl pleocidin suspending agent
Ring tebufenozide 20%, ethyl pleocidin 10%, polycarboxylate 5%, detergent alkylate
Sodium sulfonate 4%, silicone 1%, phenolic resin 0.2%, glycerol 4%, deionized water add to
100%, it is mixed to prepare 30% ring tebufenozide ethyl pleocidin suspending agent.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 48 25% ring tebufenozide ethyl pleocidin suspending agent
Ring tebufenozide 20%, ethyl pleocidin 5%, the phonetic formaldehyde condensation of alkylphenol-polyethenoxy
Thing sulfate 6%, sodium laurylsulfate 4%, C8～10Aliphatic alcohols 0.7%, guar gum 0.14%,
Diethylene glycol 3%, deionized water add to 100%, are mixed to prepare 25% ring tebufenozide ethyl and kill more
Rhzomorph suspending agent.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 49 30% ring tebufenozide ethyl pleocidin suspension emulsion
Ring tebufenozide 10%, ethyl pleocidin 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%,
Tea seed cake 4%, phenethyl fluosite polyoxyethyl ether 6%, butyl ether 5%, silicone oil 1%,
White dextrin 0.12%, diethylene glycol 3.5%, deionized water add to 100%, are mixed to prepare 30% ring
Tebufenozide ethyl pleocidin suspension emulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 50 20% ring tebufenozide ethyl pleocidin suspension emulsion
Ring tebufenozide 10%, ethyl pleocidin 10%, alkylphenol-polyethenoxy phonetic 7%, ten
Sodium dialkyl sulfate 6%, thermally coupled distillation columns 6%, N-ketopyrrolidine 4%,
C10～20Saturated fat acids (such as capric acid) and amide 1%, hydroxymethyl cellulose 0.15%, second
Glycol 4%, deionized water add to 100%, are mixed to prepare the 20% ring many sterilizations of tebufenozide ethyl
Element suspension emulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 51 25% ring tebufenozide ethyl pleocidin microemulsion
Ring tebufenozide 19%, ethyl pleocidin 6%, Ketohexamethylene 6%, xanthan gum 0.2%,
Sorbitan monostearate 7%, C8～10Aliphatic alcohols 1.4%, deionized water supplies 100%,
Prepare 25% ring tebufenozide ethyl pleocidin microemulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 52 15% ring tebufenozide ethyl pleocidin microemulsion
Ring tebufenozide 10%, ethyl pleocidin 5%, acetone 6%, sodium tripolyphosphate 0.2%,
Fatty alcohol-polyoxyethylene ether 7%, silicone 1.4%, ethylene glycol 3.8%, deionized water is supplied
100%, prepare 15% ring tebufenozide ethyl pleocidin microemulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 53 30% ring tebufenozide ethyl pleocidin aqueous emulsion
Ring tebufenozide 25%, ethyl pleocidin 5%, N-ketopyrrolidine 5%, N, N-diformazan
Base Methanamide 5%, styrene polyoxyethylene ether ammonium sulfate salt salt 6%, arabic gum 0.1%,
Silicone 0.8%, 2,2'-ethylenedioxybis(ethanol). 4%, deionized water adds to 100%, is mixed to prepare 30% ring worm
Hydrazides ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 54 20% ring tebufenozide ethyl pleocidin aqueous emulsion
Ring tebufenozide 15%, ethyl pleocidin 5%, 3-methyl cyclohexanol ketenes 5%, propanol
5%, phenethyl fluosite polyoxyethyl ether 6%, sodium tripolyphosphate 0.18%, C10～20
Saturated fat acids (such as capric acid) and amide 0.8%, deionized water adds to 100%, mixing system
Obtain 20% ring tebufenozide ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 55 30% ring tebufenozide ethyl pleocidin micro-capsule suspension
Ring tebufenozide 15%, ethyl pleocidin 15%, polyisocyanate 4%, formaldehyde 3%,
Sodium lauryl sulphate 5%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate 2.8%, second
Nitrile 6%, alkyl biphenyl ether disulfonic acid magnesium salt 5%, sorbic acid 0.4%, sodium hydroxide 0.6%,
Deionized water adds to 100% weight portion, prepares 30% ring tebufenozide ethyl pleocidin microcapsule
Suspending agent.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
Embodiment 56 20% ring tebufenozide ethyl pleocidin microcapsule suspension-suspendinagent agent
Ring tebufenozide 14%, ethyl pleocidin 6%, deformation lactoprotein 5%, polyvinyl alcohol
2%, dodecylbenzene sodium sulfonate 2.5%, ethyl acetate 6%, epoxy ethane-epoxy propane is embedding
Section copolymer 5%, NPE 3%, silicone compound 0.6%, crosslinking gather
Vinylpyrrolidone 1.2%, sodium hydroxide 0.4%, citric acid 0.5%, water add to 100% weight
Amount part, prepares 20% ring tebufenozide ethyl pleocidin microcapsule suspension-suspendinagent agent.
Effective active composition ethyl pleocidin is changed to avilamycin, Affirm (Merck Co.) benzene
Formates, pleocidin form new embodiment.
The embodiment of the present invention is the method using Toxicity Determination and field test to combine.First
Co-toxicity coefficient by Toxicity Determination, after clear and definite two kinds of medicaments are compounding by a certain percentage
(CTC), CTC ＜ 80 is antagonism, and 80≤CTC≤120 are summation action, CTC ＞
120 is potentiation, on this basis, then carries out field test.
Test method: respectively the mother solution of each mixed agent is diluted to during test five series concentration,
It is respectively placed in beaker standby.Use the method that first leaching leaf is followed by worm, will be not in contact with any medicament
Blade of the same size in the medicinal liquid configured, soak 5s after take out, naturally dry, put
Enter in insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3 times
Repeating, often repeating examination borer population used is 50, sets blank simultaneously, checks in 72h dead
Borer population, calculates mortality rate and corrected mortality, tries to achieve virulence regression equation and calculate LC50Value.
If comparison mortality rate is more than 10%, then it is considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), draws virulence regression equation with method of least square, and thus calculates every kind of medicine
The value of agent.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (with
Ring tebufenozide is standard agent, and its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=ring tebufenozide of MRing tebufenozide+ active component B
TI × PActive component B
In formula: M is the mixture of different ratio；
PActive component BFor the ratio that active component B is shared in the composition；
PRing tebufenozideFor the ratio that ring tebufenozide is shared in the composition.
Note: active component B is avilamycin, emamectin-benzoate, sterilizes more
Arbitrary one in element, ethyl pleocidin.
Application Example two:
For examination insect: cotten aphid.
EXPERIMENTAL DESIGN: through pilot study determine the former medicine of ring tebufenozide, avilamycin and the two not
Effective lethasl concentration scope with proportioning mixture.
Toxicity test result one
Table 1 ring tebufenozide and the avilamycin different ratio toxicity test to cotten aphid
As shown in Table 1, ring tebufenozide and abamectin compounded prevention and control of aphides fit over 80:1 extremely
During 1:80, co-toxicity coefficient is all higher than 120, and both mixtures in the range of 80:1 to 1:80 are described
All show potentiation, especially obtain proportioning at 20:1 extremely when ring tebufenozide and avilamycin
During 1:5, potentiation becomes apparent from highlighting, wherein when ring tebufenozide and avilamycin weight ratio
Maximum for co-toxicity coefficient during 5:1, potentiation is the most obvious.Find simultaneously, ring tebufenozide with
Avilamycin proportioning 20:1,19:1,18:1,17:1,16:1,15:1,14:1,13:1,
12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、
1:3,1:4,1:5 recurrence of disease at the same time next year pairing rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, dish
Kattapillar, aphid, thrips, demodicid mite class, scale insect, chafer, weevil, midge worm, 2 committees
The insect such as noctuid, citrus fruit fly also has preferable potentiation, and co-toxicity coefficient is all higher than 120.
Application Example three:
For examination insect: rice leaf roller.
EXPERIMENTAL DESIGN: determine ring tebufenozide, Affirm (Merck Co.) benzoic acid through pilot study
The former medicine of salt and effective lethasl concentration scope of the two different ratio mixture.
Toxicity test result two
Table 2 ring tebufenozide and the emamectin-benzoate different ratio toxicity test to rice leaf roller
As shown in Table 2, ring tebufenozide is indulged with emamectin-benzoate compounding preventing and treating rice
The proportioning of leaf roll snout moth's larva is when 80:1 to 1:80, and co-toxicity coefficient is all higher than 120, illustrate both
In the range of 80:1 to 1:80, mixture all shows potentiation, especially when ring tebufenozide and first
The proportioning of amino abamectin benzoate is when 30:1 to 1:5, and potentiation becomes apparent from dashing forward
Go out, wherein the most malicious when ring tebufenozide and emamectin-benzoate weight ratio are 6:1
Coefficient is maximum, and potentiation is the most obvious, finds simultaneously, ring tebufenozide and methylamino Avermectin
Element benzoate proportioning 30:1,29:1,28:1,27:1,26:1,25:1,24:1,23:1,
22:1、21:1、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、
11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、
1:4,1:5 recurrence of disease at the same time next year pairing rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, Pieris rapae,
Aphid, thrips, demodicid mite class, scale insect, chafer, weevil, midge worm, 2 committee noctuid,
The insects such as citrus fruit fly also have preferable potentiation, and co-toxicity coefficient is all higher than 120.
Application Example four:
For examination insect: diamondback moth.
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, ethyl pleocidin and two through pilot study
Effective lethasl concentration scope of person's different ratio mixture.
Toxicity test result three
Table 3 ring tebufenozide and the ethyl pleocidin different ratio toxicity test to diamondback moth
As shown in Table 3, ring tebufenozide and ethyl pleocidin compound the proportioning of preventing and treating diamondback moth and exist
During 80:1 to 1:80, co-toxicity coefficient is all higher than 120, illustrates that both are in 80:1 to 1:80 scope
Interior mixture all shows potentiation, especially when the proportioning of ring tebufenozide Yu ethyl pleocidin
When 20:1 to 1:10, potentiation becomes apparent from highlighting, wherein when ring tebufenozide and ethyl
When pleocidin weight ratio is 2:1, co-toxicity coefficient is maximum, and potentiation is the most obvious, sends out simultaneously
Existing, ring tebufenozide and ethyl pleocidin proportioning 20:1,19:1,18:1,17:1,16:1,
15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、
3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, recurrence of disease at the same time next year
Pairing rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, Pieris rapae, aphid, thrips,
Demodicid mite class, scale insect, chafer, weevil, midge worm, 2 committee's evils such as noctuid, citrus fruit fly
Worm also has preferable potentiation, and co-toxicity coefficient is all higher than 120.
Application Example five:
For examination insect: citrus fruit fly.
EXPERIMENTAL DESIGN: through pilot study determine the former medicine of ring tebufenozide, pleocidin and the two not
Effective lethasl concentration scope with proportioning mixture.
Toxicity test result four
Table 4 ring tebufenozide and the pleocidin different ratio toxicity test to citrus fruit fly
As shown in Table 3, ring tebufenozide exists with the proportioning of pleocidin compound preventing and treating citrus fruit fly
During 80:1 to 1:80, co-toxicity coefficient is all higher than 120, illustrates that both are in 80:1 to 1:80 scope
Interior mixture all shows potentiation, especially exists when the proportioning of ring tebufenozide Yu pleocidin
During 20:1 to 1:10, potentiation becomes apparent from highlighting, wherein when ring tebufenozide and many sterilizations
When element weight ratio is 2:1, co-toxicity coefficient is maximum, and potentiation is the most obvious, finds, ring simultaneously
Tebufenozide and pleocidin proportioning 20:1,19:1,18:1,17:1,16:1,15:1,14:1,
13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、
Pairing rice is indulged for 1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, recurrence of disease at the same time next year
Leaf roll snout moth's larva, the snout moth's larva of rice, planthopper, diamondback moth, Pieris rapae, aphid, thrips, demodicid mite class,
Scale insect, chafer, weevil, midge worm, 2 committee insects such as noctuid, citrus fruit fly also have
Having preferable potentiation, co-toxicity coefficient is all higher than 120.
Application Example six ring tebufenozide and avilamycin and the effect of compounding preventing and treating Caulis et Folium Brassicae capitatae diamondback moth thereof
Test
This experimental establishment is in Qishan County of Baoji, Shaanxi province city, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 2% A Wei
Rhzomorph cream (commercial).
Test uses conventional nebulization, investigates Caulis et Folium Brassicae capitatae diamondback moth insect pest index, send out in insect pest before medicine
Raw initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Real
Test result as follows:
Table 5 ring tebufenozide, avilamycin and the compounding preventing and treating Caulis et Folium Brassicae capitatae diamondback moth test of pesticide effectiveness thereof
As can be seen from Table 5, ring tebufenozide with abamectin compounded after effectively to prevent and treat Caulis et Folium Brassicae capitatae little
Diamond-back moth, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.At test scope of medication
In target crop is had no adverse effects.
Application Example seven ring tebufenozide and avilamycin and the medicine of compounding preventing and treating rice-stem borer thereof
Effect test
This experimental establishment is in Pingchang County, Bazhong City, Sichuan Province, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 2% A Wei
Rhzomorph cream (commercial).
Test uses conventional nebulization, investigates rice-stem borer insect pest index, send out in insect pest before medicine
Raw initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.Real
Test result as follows:
Table 6 ring tebufenozide, avilamycin and the compounding preventing and treating rice-stem borer test of pesticide effectiveness thereof
As can be seen from Table 6, ring tebufenozide can effectively prevent and treat Oryza sativa L. two after abamectin compounded
Changing snout moth's larva, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.At test scope of medication
In target crop is had no adverse effects.
Application Example eight ring tebufenozide and emamectin-benzoate and compounding preventing and treating thereof
The test of pesticide effectiveness of cabbage pieris
This experimental establishment is in Changan District, Xi'an City, Shanxi Province, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 2% first ammonia
Base abamectin benzoate cream (commercial).
Test uses conventional nebulization, investigates cabbage pieris insect pest index, send out in insect pest before medicine
Raw initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.Real
Test result as follows:
Table 7 ring tebufenozide, emamectin-benzoate and the compounding preventing and treating cabbage pieris test of pesticide effectiveness thereof
As can be seen from Table 7, energy after ring tebufenozide is compounding with emamectin-benzoate
Effectively preventing and treating cabbage pieris, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.
In test scope of medication, target crop is had no adverse effects.
Application Example nine ring tebufenozide and emamectin-benzoate and compounding preventing and treating thereof
The cotton boll worm test of pesticide effectiveness
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 2% first ammonia
Base abamectin benzoate cream (commercial).
Test uses conventional nebulization, investigates cotton boll pests index, send out in insect pest before medicine
Raw initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.Real
Test result as follows:
Table 8 ring tebufenozide, emamectin-benzoate and the compounding preventing and treating cotton boll worm test of pesticide effectiveness thereof
As can be seen from Table 8, energy after ring tebufenozide is compounding with emamectin-benzoate
Effectively preventing and treating cotton boll worm, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.
In test scope of medication, target crop is had no adverse effects.
Application Example bull's eye tebufenozide and pleocidin and the drug effect of compounding preventing and treating Fructus Solani melongenae thrips thereof
Test
This experimental establishment is in Yangling District, Shaanxi Province, and test medicine is had by Shaanxi Wei Erqi crop protection
Limit company provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 10% pleocidin
Suspending agent (autogamy).
Test uses conventional nebulization, investigates Fructus Solani melongenae thrips insect pest index, occur in insect pest before medicine
Initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.Experiment
Result is as follows:
Table 9 ring tebufenozide, pleocidin and the compounding preventing and treating Fructus Solani melongenae thrips test of pesticide effectiveness thereof
As can be seen from Table 9, Fructus Solani melongenae Ji can effectively be prevented and treated after ring tebufenozide and pleocidin compound
Horse, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.In test scope of medication
Target crop is had no adverse effects.
Application Example 11 ring tebufenozide is entrusted night with pleocidin and compounding preventing and treating Semen Maydis 2 thereof
The moth test of pesticide effectiveness
This experimental establishment is in Jiande City, Zhejiang Province, and test medicine is had by Shaanxi Wei Erqi crop protection
Limit company provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 10% pleocidin
Suspending agent.
Test uses conventional nebulization, investigates Semen Maydis 2 committee noctuid insect pest index, in worm before medicine
Evil early period of origination dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.
Experimental result is as follows:
Table 10 ring tebufenozide, pleocidin and compounding preventing and treating Semen Maydis 2 the committee noctuid test of pesticide effectiveness thereof
As can be seen from Table 10, Semen Maydis can effectively be prevented and treated after ring tebufenozide and pleocidin compound
2 committee noctuids, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example ten bicyclo-tebufenozide is changed with ethyl pleocidin and compounding preventing and treating Oryza sativa L. three thereof
The test of pesticide effectiveness of snout moth's larva
This experimental establishment is in XiaoShan, HangZhou City, Zhejiang Province district, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 60 grams/
Rise ethyl pleocidin suspending agent (autogamy).
Test uses conventional nebulization, investigates Yellow Rice Borer insect pest index, send out in insect pest before medicine
Raw initial stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 5 days, 7 days.Real
Test result as follows:
Table 11 ring tebufenozide, ethyl pleocidin and the compounding preventing and treating Yellow Rice Borer test of pesticide effectiveness thereof
As can be seen from Table 11, can effectively prevent and treat after ring tebufenozide is compounding with ethyl pleocidin
Yellow Rice Borer, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example 13 ring tebufenozide is indulged with ethyl pleocidin and compounding preventing and treating Oryza sativa L. rice thereof
The leaf roll snout moth's larva test of pesticide effectiveness
This experimental establishment is in Shangrao City Shangrao County, Jiangxi Province, and test medicine is by Shaanxi Wei Erqi crop
Protection company limited provides, comparison medicament 10% chromafenozide suspending agent (autogamy), 60 grams/
Rise ethyl pleocidin suspending agent.
Test uses conventional nebulization, investigates Oryza sativa L. rice leaf roller medicine insect pest index before medicine, in
Insect pest early period of origination dispenser, after dispenser, 1 day, 5 days, 7 days investigation insect pest indexes calculating are anti-
Effect.Experimental result is as follows:
Table 12 ring tebufenozide, ethyl pleocidin and the compounding preventing and treating Oryza sativa L. rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 12, can effectively prevent and treat after ring tebufenozide is compounding with ethyl pleocidin
Oryza sativa L. rice leaf roller, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.In examination
In testing scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, ring tebufenozide and avilamycin,
Emamectin-benzoate, ethyl pleocidin, pleocidin compound make wettability
Powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent,
After microcapsule suspension-suspendinagent agent to the rice leaf roller of all kinds of crops, the snout moth's larva of rice, planthopper,
Diamondback moth, Pieris rapae, aphid, thrips, demodicid mite class, scale insect, chafer, weevil, midge
Worm, 2 committee the common insect pests such as noctuid, citrus fruit fly preventive effect all more than 95%, be better than list
Agent preventive effect, potentiation is obvious.
Claims (7)
1. a composition pesticide for ring tebufenozide and biogenic substances, comprise active components A,
Active component B, it is characterised in that: active components A is ring tebufenozide, and active component B is
In pleocidin, ethyl pleocidin arbitrary a kind of, and active components A and active component B
Weight ratio 1:80～80:1.
Composition pesticide the most according to claim 1, it is characterised in that: active component
The weight ratio of A and active component B is 1:40～60:1.
Composition pesticide the most according to claim 2, it is characterised in that: ring tebufenozide
It is 1:10～20:1 with the weight ratio of pleocidin.
Composition pesticide the most according to claim 2, it is characterised in that: ring tebufenozide
It is 1:10～20:1 with the weight ratio of ethyl pleocidin.
5., according to the composition pesticide described in any one in Claims 1 to 4, its feature exists
In: compositions make wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion,
Microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.
Composition pesticide the most according to claim 5 is for preventing and treating answering of crop pests
With.
Application the most according to claim 6, it is characterised in that institute's pest control includes:
Rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, Pieris rapae, aphid, thrips, demodicid mite
Class, scale insect, chafer, weevil, midge worm, 2 committees noctuid, citrus fruit flies.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328834.4A CN105994275B (en) | 2012-03-14 | 2012-03-14 | A kind of composition pesticide of ring tebufenozide and biogenic substances |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328834.4A CN105994275B (en) | 2012-03-14 | 2012-03-14 | A kind of composition pesticide of ring tebufenozide and biogenic substances |
| CN201210066822.0A CN103300021B (en) | 2012-03-14 | 2012-03-14 | A kind of ring tebufenozide and the composition pesticide of biogenic substances |
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| CN201210066822.0A Division CN103300021B (en) | 2012-03-14 | 2012-03-14 | A kind of ring tebufenozide and the composition pesticide of biogenic substances |
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| Publication Number | Publication Date |
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| CN104430316A (en) * | 2014-11-11 | 2015-03-25 | 济南新起点医药科技有限公司 | Water dispersible granules with active ingredients of chromafenozide and allicin |
| CN107751202A (en) * | 2016-08-16 | 2018-03-06 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN115530173A (en) * | 2021-08-31 | 2022-12-30 | 广西壮族自治区农业科学院 | Synergistic pesticide for preventing and treating sugarcane borers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| WO2007101540A1 (en) * | 2006-03-06 | 2007-09-13 | Bayer Cropscience Ag | Combinations of active ingredients with insecticidal properties |
| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
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| CN1274219C (en) * | 2001-07-31 | 2006-09-13 | 马韵升 | Methlaminoabamectin benzoate pesticide and miticide composite |
| JP5026645B2 (en) * | 2001-08-23 | 2012-09-12 | 日本化薬株式会社 | Ogawa pesticide formulation |
| TWI444140B (en) * | 2005-11-18 | 2014-07-11 | Cheminova As | Oil-in-water formulation of avermectins |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| WO2007101540A1 (en) * | 2006-03-06 | 2007-09-13 | Bayer Cropscience Ag | Combinations of active ingredients with insecticidal properties |
| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
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| CN103300021B (en) | 2016-08-17 |
| CN105994275B (en) | 2019-01-01 |
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