CN107751202A - A kind of Pesticidal combination - Google Patents
A kind of Pesticidal combination Download PDFInfo
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- CN107751202A CN107751202A CN201610673671.3A CN201610673671A CN107751202A CN 107751202 A CN107751202 A CN 107751202A CN 201610673671 A CN201610673671 A CN 201610673671A CN 107751202 A CN107751202 A CN 107751202A
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- Prior art keywords
- pesticidal combination
- plant
- seed
- ethyl pleocidin
- agent
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
Abstract
The present invention relates to a kind of Pesticidal combination, it is characterised in that active component is made up of ethyl pleocidin and suppression food hydrazine, and the weight ratio of the ethyl pleocidin and suppression food hydrazine is 1:1‑1:100.It is used for the purposes for preventing or controlling animal pest the invention further relates to described Pesticidal combination, particularly prevents or control the purposes of rice crops snout moth's larva.Prevent or the method for control animal pest the invention further relates to a kind of, Pesticidal combination of the present invention is applied to the soil of seed, the soil of target useful plant or plant growth or suitable plant growth.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, the Pesticidal combination active component is by ethyl pleocidin and suppression food hydrazine
Composition.It is used for the purposes for preventing or controlling harmful organism the invention further relates to described Pesticidal combination.
Background technology
Chemical prevention is agriculturally to prevent and control an important means for insect.However, it is current, due to the kind of insect etc.
The reasons such as effect caused by class, living nature, living environment etc. is poor, repellence prosperity can not be prevented and kill off effectively sometimes.It is special
It is not for the harmful organism of Insecta, Arachnoidea and Nematoda etc., carrying out prevention and control using conventional dose is just becoming increasingly to be stranded
It is difficult.Therefore, in order to effectively prevent and kill off it is can not possibly preventing and kill off or prevent and kill off difficulty harmful organism and seek a kind of new means and
Method.
Ethyl pleocidin（Spinetoram）It is the macrolide antibiotics insecticide produced by Tao Shi agricultures company.It
It is a newcomer of Spinosyn spinosyn insecticides, is that natural products spinosyns is obtained through chemical modification, belongs to
Biomimetic type agricultural chemicals.In spinosyn insecticides, ethyl pleocidin is a brand-new, unique active ingredient, is one
Efficiently, broad spectrum insecticide.It is mainly used in preventing and treating Lepidoptera and Thysanoptera larva, to diamondback moth, beet armyworm, Liriomyza, Ji
The prevention effect that the vegetable-crop pest-insects such as horse, prodenia litura, bean-pod borer have had, the resistance management wheel for being widely used in vegetable-crop pest-insect are used instead
Medicine kind.Due to the raising of the field crop drug cost such as rice, corn, sugarcane, ethyl pleocidin is also gradually big to these
Promoted the use of in the control of insect of field crop, turn into the medicaments such as Rynaxypyr, fluorobenzene insect amide, metaflumizone, suppression food hydrazine
The rotation kind of resistance management, for squama wings such as striped rice borer, yellow rice borer, rice leaf roller, corn borer, yellow top borer, yellow snout moth's larvas
The preventing and treating medication of mesh insect.
Suppression food hydrazine is a kind of insect growth regulator, IGR, mainly by reducing or suppressing larva and imago feeding ability, is promoted
Insect accelerates decortication, reduces spawning, and hinders insect reproduction to reach insecticidal action.Suppression food hydrazine based on stomach toxicity, also has to insect
There is strong absorbability.Suppression food hydrazine insecticidal spectrum is wide, has good prevention effect to insects such as Lepidoptera, coleoptera, Dipteras.Suppression
It is following formula to eat hydrazine structural formula：
The activity of the individual compounds is good；However, low rate of application or for single insect using when they are not total
The high request that insecticide, acaricide or nematicide must are fulfilled for can be met.
Field of pest control occur a typical demand be need reduce prevent and treat active component close rate and
Unfavorable environment or toxicological effects are reduced or avoided, while still allows for the control of insect of effect.Also need to combine and knock down activity
With the pest control agent for extending the preventing and treating time, i.e. snap action and long-acting.
It is to repeat using another difficulty of insecticide and uniquely uses single Pesticidal compound in many cases
Cause to produce the active component quick selection that is natural or adapting to drug-fast insect.It is therefore desirable to have help preventing and treating or
Overcome drug-fast pest control agent.
Therefore Agricultural pest control field continues the needs for providing pesticide combination be present, and pesticide combination tends to provide improvement
Characteristic, such as biological characteristics, synergism characteristic.
The content of the invention
The present invention seeks to solve above-mentioned at least one problem or its at least one aspect, have especially for effective control
Evil biology.A kind of Pesticidal combination is provided, improve biological characteristics, synergism characteristic is provided, reduces close rate, expand activity profile or
With reference to the Pesticidal combination knocked down activity with extend preventing and treating time or resistance to the action of a drug management, delaying drug resistance.
Through a large amount of biological tests screen, the present inventor it has unexpectedly been discovered that, by ethyl pleocidin and suppression food hydrazine combination
It can effectively prevent or control harmful organism.It is surprising that the work of the combination control harmful organism of reactive compound of the present invention
Property is much higher than single active ingredient physical performance summation.The unexpected effect is real cooperative effect, and not only
Be activity plus and.
Therefore, it is an object of the present invention to provide a kind of Pesticidal combination and its prevention or the use of control harmful organism
On the way.
A kind of Pesticidal combination is to take following technical scheme to realize：
The present invention provides a kind of Pesticidal combination, and active component is made up of ethyl pleocidin and suppression food hydrazine, and the ethyl kills more
The weight ratio of rhzomorph and suppression food hydrazine is 1:1-1:100, preferably 1:1-1:90, preferably 1:1-1:80, more preferred 1:1-1:70, then
It is preferred that 1:1-1:60, further preferably 1:1-1:50, further preferably 1:1-1:40, further preferably 1:1-1:30, further preferably 1:1-1:20, more
Add preferably 1:1-1:10.
The present invention provides a kind of Pesticidal combination, and active component is made up of ethyl pleocidin and suppression food hydrazine, the ethyl
The weight ratio of pleocidin and suppression food hydrazine can also be, for example, 1:1,1:5,1:6,1:7,1:8,1:9, 1:10,1:11,1:12,
1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:25,1:30,1:35,1:40,1:45,1:50,1:55,1:
60,1:65,1:70,1:75,1:80,1:85,1:90,1:95,1:100。
A kind of Pesticidal combination, active component are made up of ethyl pleocidin and suppression food hydrazine, and the ethyl pleocidin and suppression are eaten
The weight of hydrazine accounts for the 1%-90% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-80% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-70% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-60% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-50% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-40% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-30% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for the 1%-20% of the composition by weight altogether.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for 1% of the composition by weight altogether, and 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%,
13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%, 35%,
40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%.
A kind of Pesticidal combination, active component are made up of ethyl pleocidin and suppression food hydrazine, and the Pesticidal combination also wraps
Containing surfactant and/or filler.
The Pesticidal combination of the present invention, formulation is missible oil, at aqueous suspension agent, oil-suspending agent, seed treatment dry powder doses, seed
Manage suspending agent, water dispersible granules, wettable powder, suspension emulsion, smoke agent, coated granule, extrusion granule, aqueous emulsion, micro-
Capsule suspending agent, microcapsule suspension-suspendinagent agent, dry suspending agent, ultra low volume liquids, electrostatic oil agent, gel, soluble powder, granula.
The Pesticidal combination of the present invention is also comprising one or more other active components.
On the other hand, the purposes for preventing or controlling animal pest is used for present invention also offers a kind of Pesticidal combination, its
Middle animal pest is insect, acarid and nematode.
The Pesticidal combination of the present invention can be applied without dilution, and administration can also be diluted with water.
Composition of the present invention unexpectedly presents high in the propagating materials of processing plant, plant parts or plant
Prevention or control animal pest activity.
The Pesticidal combination of the present invention has extensive injurious insect control spectrum and excellent injurious insect control effect under low dosage
Power.
On the other hand, present invention also offers a kind of method prevented or control animal pest, killed of the present invention
Worm composition acts on target useful plant, target animal insect or its environment, the propagating materials of target useful plant.The plant
Thing propagating materials is seedling, rhizome, garden seedling, cutting or seed.
The present invention also provides a kind of method that cover crop attacks to prevent animal pest, by Insecticidal combinations of the present invention
Thing acts on target useful plant, target animal insect or its environment, the propagating materials of target useful plant.
The present invention also provides a kind of method for protecting rice crops to be attacked to prevent snout moth's larva, by Pesticidal combination of the present invention
Act on target useful plant, target animal insect or its environment, the propagating materials of target useful plant.
Prevent or the method for control animal pest present invention also offers a kind of, including by Insecticidal combinations of the present invention
Thing is applied to the soil of seed, the soil of target useful plant or plant growth or suitable plant growth.
On the other hand, present invention also offers a kind of method prevented or control animal pest, killed of the present invention
Worm composition is applied to soil and/or is applied directly to and connect with plant root before germination, after germination or before and after germination
Tactile soil or the soil of suitable plant growth.
Described seed is selected from soybean, wheat, barley, rice, rape, beet, tomato, cowpea, carrot, cotton and jade
Rice seed.
Composition of the present invention is used for the purposes of seed treatment.
Composition of the present invention can be applied to the soil of seed, plant or the fruit of plant or plant growth or be suitable to
The soil of plant growth.
A kind of method prevented or control animal pest, including separate, sequentially or simultaneously apply ethyl pleocidin, suppression food
Hydrazine.
Pesticidal combination of the present invention can be applied in any desired manner, such as seed coating, soil pour
And/or directly ditch spread and/or foliage-spray, and before germination, after germination or germination is front and rear applies.
The present invention provides a kind of Pesticidal combination and ethyl pleocidin and suppression is eaten into hydrazine combination, effectively can prevent or control
Evil biology.The activity of the Insecticidal combinations control harmful organism of the present invention is much higher than single active ingredient physical performance summation.Should
It is unexpected that effect be real cooperative effect, rather than just activity plus and.
Embodiment
Present invention discover that：Ethyl pleocidin and suppression food hydrazine combination can effectively be prevented or control harmful organism.Make us frightened
Strange, the activity of Insecticidal combinations control harmful organism of the invention is much higher than single active ingredient physical performance summation.Should
It is unexpected that effect be real cooperative effect, rather than just activity plus and.
Term " synergy " used herein refers to activating agent combination of the present invention or the insecticidal effect of composition is more than respectively
Activating agent effect sum, in other words, its effect is superadditivity.
The present invention provides a kind of Pesticidal combination, and active component is made up of ethyl pleocidin and suppression food hydrazine, the ethyl
The weight ratio of pleocidin and suppression food hydrazine is 1:1-1:100, preferably 1:1-1:90, preferably 1:1-1:80, more preferred 1:1-1:
70, further preferably 1:1-1:60, further preferably 1:1-1:50, further preferably 1:1-1:40, further preferably 1:1-1:30, further preferably 1:1-1:
20, more preferred 1:1-1:10.
The present invention provides a kind of Pesticidal combination, and active component is made up of ethyl pleocidin and suppression food hydrazine, the ethyl
The weight ratio of pleocidin and suppression food hydrazine can also be, for example, 1:1,1:5,1:6,1:7,1:8,1:9, 1:10,1:11,1:12,
1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:25,1:30,1:35,1:40,1:45,1:50,1:55,1:
60,1:65,1:70,1:75,1:80,1:85,1:90,1:95,1:100。
The total amount of active component can be selected according to material elements in composition of the present invention, the phase to realize
The effect of prestige.The factor is for example, formulation, object to be administered, application process etc..A kind of Pesticidal combination of the present invention, activity
Component is made up of ethyl pleocidin and suppression food hydrazine, and the weight of the ethyl pleocidin and suppression food hydrazine accounts for the composition altogether
1%-90% by weight, preferably 1%-80%, preferably 1%-70%, preferably 1%-60%, preferably 1%-50%, preferably 1%-40%, preferably
1%-30%, preferably 1%-20%.
A kind of Pesticidal combination, active component by ethyl pleocidin and suppression food hydrazine form, the ethyl pleocidin and
The weight of suppression food hydrazine accounts for 1% of the Pesticidal combination by weight altogether, and 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%,
12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%,
35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%.
The composition of the present invention optionally includes agronomically acceptable surfactant or extender.Preferably, institute
It is one kind in dispersant, wetting agent, antifreeze, thickener, defoamer, disintegrant, binding agent, assistant carrier to state auxiliary element
Or mixture.
According to the present invention, term " filler ", which refers to, can be combined with reactive compound or combines to make it easier for being administered to
Object（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the carrier is preferably lazy
Property, at least it should be agronomically acceptable.The filler can be solid or liquid.
The inactive filler that can be used in the present invention can be solid or be liquid, can be used as solid
What filler used has for example：Phyteral powdery type（Such as soy meal, starch, grain dust, wood powder, bark powder, sawdust, walnut
Shell powder, wheat bran, cellulose powder, coconut husk, the particle of corncob and tobacco stem, extract residue after plant essence etc.）, paper
Open, sawdust, crush synthesized polymer body, the clay class of synthetic resin etc.（Such as kaolin, bentonite, acid china clay etc.）, talcum powder
Class.Silica（Such as diatomite, silica sand, mica, aqueous silicic acid, calcium silicates）, activated carbon, natural mineral matter class（Float stone, Lv Po
Thread stone and zeolite etc.）, fire diatomite, sand, plastics medium etc.（Such as polyethylene, polypropylene, polyvinylidene chloride etc.）, chlorination
Chemical fertilizer, the soil of the inorganic mineral powder of potassium, calcium carbonate, calcium phosphate etc., ammonium sulfate, ammonium phosphate, urea, ammonium chloride etc.
Fertilizer, these materials can be used alone or two or more is mixed.
What can be used as liquid filler can select in llowing group of materials, such as water, alcohol type（Such as methanol,
Ethanol, isopropanol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.）, ether
Class（Such as ether, dioxanes, methylcellulose, tetrahydrofuran etc.）, aliphatic hydrocarbon class（Such as kerosene, mineral oil
Deng）, aromatic hydrocarbons class（Such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon,
Chlorobenzene, etc.）, halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal oil etc..
To make the emulsification of active ingredient compound, scattered, solubilized and/or wetting to use surfactant example
AEO, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol can such as be enumerated
Or the branch shape copolymerization of the phosphate of phenol, the fatty acid ester of polyalcohol, naphthalene sulfonic acid polymer, lignosulfonates, macromolecule comb shape
Thing, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate,
Polyacrylate, the protein hydrolysate of alkyltaurate.Suitable oligosaccharide thing or polymer, such as based on single second
Alkene monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or its with for example（It is polynary）Alcohol or（It is polynary）The combination of amine.
To make scattered active ingredient compound, stabilisation, attachment, such as xanthans, aluminium-magnesium silicate, gelatin, shallow lake can be used
Powder, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid（Such as cephalin and lecithin）And synthetic phospholipid,
The adjuvants such as bentonite, sodium lignin sulfonate.
The wherein optional spent glycol of antifreezing agent, propane diols, glycerine, sorbierite.Deflocculant as suspension product
The adjuvant such as naphthalene sulfonic acid polymer, polymeric phosphate can be used.Organic silicon defoamer can be used as defoamer.For
The mobility of solid product is improved, the adjuvant such as paraffin, stearate, alkylphosphonate can be used.
The colouring agent that can be used, such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue；And organic pigment/
Dyestuff：Alizarin dyes, azo dyes and metallized phthalocyanine dye；And trace element, such as molysite, manganese salt, boron salt, mantoquita, cobalt
Salt, molybdenum salt and zinc salt.
Optionally, can also include other annexing ingredients, for example, protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent,
Stabilizer, screening agent.
Pesticidal combination of the present invention can be used with itself, or can be respective physically and/or chemically according to its
Property is used with its dosage form or type of service prepared therefrom, such as aerosol, micro-capsule suspension, harl agent, hot mist
Agent, microcapsulated granule, granula subtilis, seed treatment suspending agent, ready to use solution agent, pulvis, missible oil, oil-in-water emulsion, Water-In-Oil
Type emulsion, big granula, fine granule, oil-dispersing property pulvis, oil suspending agent, finish, foaming agent, paste, seed coat agent, colloidal suspending agent, suspension
Emulsion, aqueous solvent, suspending agent, wettable powder, soluble powder, pulvis and granule, water-soluble granular formulation or tablet, seed
In processing water solube powder, wettable powder, the natural prodcuts of activity component impregnation and synthetic, polymeric material with seed
Coat the microcapsules in material, and the agent of ultra-low volume harl and hot mist preparation.
The preferable formulation of Pesticidal combination of the present invention is missible oil, aqueous suspension agent, oil-suspending agent, seed treatment dry powder
Agent, seed treatment suspending agent, water dispersible granules, wettable powder, suspension emulsion, smoke agent, coated granule, extrusion granule,
Aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, dry suspending agent, ultra low volume liquids, electrostatic oil agent, gel, solubility
Pulvis, granula.
Pesticidal combination of the present invention can also be applied with other active ingredient combinations, other active component examples
As fungicide, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener,
Fertilizer or semiochemical etc..
Preparation of the present invention can be mixed the reactive compound to prepare by known way with conventional additives.
For example conventional extender of the conventional additives and solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixative,
Wetting agent, waterproofing agent, if it is desired, drier and colouring agent, stabilizer, pigment, defoamer, preservative, increasing can also be included
Thick dose, water and other processing aids.
The Pesticidal combination of the present invention not only includes can be by suitable equipment as spraying or dusting equipment are applied to immediately
Pending object, and be additionally included in and be applied to the concentration commercial composition that object needs to be diluted before.
The Pesticidal combination of the present invention can be made in the form of the composition of its active compound component suitable for administration
Preparation, it can also be applied in the form of the combination of the commercial preparation of its suitable dosage.
The Pesticidal combination of the present invention, has good plant compatibility and favourable homeothermal animal toxicity, suitable for preventing and treating
The harmful organism run into agricultural, forestry, protection Stored Product and material and health field, especially Insecta
（Insecta）, Arachnoidea (Arachnida), Nematoda（Nematoda）.They have for generally sensitive and resistance species
Activity, and activity is respectively provided with for all or single stage of development, and also realize that prevention or control harmful organism make us frightened
" synergy " effect of happiness.
Present invention also offers the purposes that a kind of Pesticidal combination by the present invention is used to preventing or controlling animal pest.This
Term " animal pest " is used to mean any organism that can be caused damage to the normal condition of plant in text.Including harmful insect
Guiding principle（Insecta）, Arachnoidea (Arachnida), Nematoda（Nematoda）.
Insecta includes Lepidoptera, coleoptera, Diptera, Semiptera, Homoptera, Hymenoptera, Thysanoptera, Isopoda, times
Sufficient mesh, lip foot mesh, comprehensive mesh, Thysanoptera, Collembola, Collembola, Orthoptera, Blattaria, Dermaptera, Isoptera, Anoplura.
Lepidoptera pest, such as：Striped rice borer（chilosuppressalis（walker）, yellow rice borer
（Tryporyzaincertulas（walker））, rice leaf roller（cnaphalocrocismedinalisGuenee）, cabbage heart
Snout moth's larva（hellullaundalis）, dichocrocis punctiferalis（conogethespunctiferlis）, papilio xuthus Linnaeus（papilioxuthus）, it is white
White butterfly（pierisrapaecrucivora）, straight burr rice hesperiidae（parnaraguttata）, tent caterpillar（malacosoma
Neustria testacea）, gypsymoth（lymantriadispar）, fall webworms（hyphantriacunea）, east poison moth
（euproctissubflava）, black line slug moth（scopelodescontracus）, bollworm
（helicoverpaarmigera）, Pectinophora gossypiella（Pink bollworm）, cabbage looper（trichoplusiani）, wild cabbage night
Moth（mamestrabrassicae）, beet armyworm（spodopteraexigua）, prodenia litura（spodopteralitura）、
Tea olethreutid（adoxophyesoranafasciata）, leaf roller（adoxophyeshonmai）, apricot yellow volume moth
（archipsfuscocureanus）, Homonamagnanima（homonamagnanima）, diamondback moth（plutellaxylotella）, cotton
Pink bollworm（pectinophoragossypiella）.
Coleopteran pest, such as：Rice weevil（sitophilusoryzaelinne）, citrus leaf mining first
（PodagricomelanigricollisChe）, sitophilus zea-mais（S.zeamails）, grain weevil（S.granarius）, big daikon leaf beetle
（Cabbageleafbeetle）, daicon leaf beetle（Daikon leaf beele）, flea beetle（fleabeetle）, grape flea beetle
（Alticachalybea）, cabbage flea beetle（phyllotretastriolata）, cucumber flea beetle（Epitrixcucumeris）, cigarette
Careless flea beetle（Ehirtipennis）, eggplant flea beetle（E.fuscula）, aulacophora femoralis（Aulacophoraindica（Gemlin）, leaf mustard
It is chrysomelid（Phaedoncochleariae）Deng.
Diptera pest, such as：Rice leafminer（agromyzaoryzae）, hydrellia griseola（hydrelliagriseola）, it is non-
Continent chrysanthemum liriomyza bryoniae（liriomyzatrifolii）, pea leaf dive fly（chromatomyiahorticola）, Liriomyza brponiae
（liriomyzabryoniae）, delia platura（deliaplatura）, green onion ground Hylemyia Platura Meigen（deliaantiqua）Mediterranean fruitfly
（ceratitiscapiatawiedgman）, Rhagoletis pomonella（Rhagoletispomonella）, cherry fruit fly
（R.cingulata）.
Hemipteran pest, such as：Smelly stinkbug（megacoptapunctatissimum）, cabbage bug（eurydemarugosum）、
Big thorn white star stinkbug（eysarcorislewisi）, white star stinkbug（eysarcorisparvus）, green rice bug（nezaraviridula）、
Si Shi amber stinkbugs（plautiastali）, clerodendron trichotomum stinkbug（halymorphamista）, rice spiny coreid（cletuspunctiger）, in
Magnificent Leptocorisa spp（leptocorisachinensis）, azelea lace bug（stephantispyrioides）, it is red must fleahopper
（trigonotyluscoelestialium）.
Homoptera pest, such as rice green leafhopper（nephotettixcincticeps）, small brown rice planthopper
（laodelphaxstriatellus）, brown plant-hopper（nilaparvatalugens）, white backed planthopper
（sogatellafurcifera）, pear sucker（psyllapyrisuga）, diaphorina citri（diaphorinatabaci）, Bemisia tabaci
（bemisiatabaci）, aphid（homoptera）, apple aphid（eriosomalanigerum）.
Hymenoptera（hymenoptera）Insect, such as yellow-winged cabbage sawfly（athaliarosaeruficornis）, japanese rose leaf
Honeybee（argepagana）, Black Hills ant（formica japonica）, chestnut gall wasp（dryocsmuskuriphilus）Deng.
Thysanoptera, such as thrips（HaplothripsChinensisPriesner）.
Isopoda（Isopoda）, for example, Cape jasmine beach louse（Oniscusasellus）, pillworm
（Armadilliudiumvulgare）, ball pillworm（Porcellioscaber）.
Sufficient mesh insect again, for example, Blaniulusguttulatus.
Lip foot mesh insect, for example, ground Scolopendra (GeophiluscarpophagusScutigera spp.).
Comprehensive mesh insect, for example, kahikatea worm (Scutigerellaimmaculata).
Thysanoptera insect, for example, silverfish (Lepismasaccharina).
Collembola insect, for example, arms Onychiurus arcticus (Onychiurusarmatus).
Orthoptera pest, for example, family Xi (Achetadomesticus), mqb category category kind of (Gryllotalpa spp.
), Asiatic migratory locust (Locustamigratoriamigratorioides), black locust category kind of (a Melanopluss pp.), desert
Locust (Schistocercagregaria).
Blattaria insect, for example, oriental cockroach (Blattaorientalis), American cockroach
(Periplanetaamericana), leucophaea maderae (Leucophaeamaderae), Groton bug (
Blattellagermanica) 。
Dermaptera insect, for example, European earwig (Forficulaauricularia).
Isoptera insect, for example, Reticulitermes kind (Reticulitermes spp.).
Anoplura (Anoplura, Phthiraptera), such as Damalinia (Damalinia spp.), Haematopinus
(Haematopinus spp.), Linognathus (Linognathus spp.), Pediculus (Pediculus spp.), Trichodectes
(Trichodectes spp. )。
Arachnoidea（Arachnida）Insect.Such as panonychus citri（panonychuscitri）, Tetranychus cinnabarinus
（Tetranychuscinnabarinus）, panonychus ulmi（panonychusulmi）, Tetranychus urticae
（tetranychusurticae）, tetranychus viennensis（tetranychusviennensis）, oligonychus ununguis
（oligonychusununguis）Citrus beginning tetranychid（eotetranychuskankitus）, purplish red short hairs mite
（brevipalpusphoenicis）, Bryobia praetiosa（bryobiapraetiosa）, wheat leaf roll mite（aceriatulipae）、
Grape erineum mite (Eriophyes vitis)（colomerusvitis）, tealeaves goitre mite（calacaruscarinatus）, yellow tea mite
（polyphagotarsonemuslatus）, long hair root mite（rhizoglyphusrostochiensis）, Acarus siro
（Acarussiro）, citrus aceria（Aceriasheldoni）, steinman pin thorn goitre mite（Aculusschlechtendali）, leaf
Mite category（Tetranychus spp.）, Panonychus citri category（Panonychus spp.）, wrinkle Genus Phyllocoptess（Phyllocoptruta
spp.）, short whisker Acarapis（Brevipalpus spp.）Deng.
Nematoda（(Nematoda)）Representative biology have selected from Meloidogyne（Meloidogyne spp.）, different skin
Turbatrix（Heterodera spp.）, ball Heterodera（Globodera spp.）, perforation line Eimeria（Radopholus
spp.）, Pratylenchus（Pratylenchus spp.）, minute hand Turbatrix（Longidorus spp.）Deng.It is preferred that lower alignment
The soybean cyst nematode Heterodera glycines of worm（Heterodera）, globodera rostochiensis（golboderarostochiensis）, Root Knot line
Worm（meloidogyne incognita）Deng.
More preferred, Pesticidal combination of the invention is suitable for preventing and treating pear sucker, aphid, diamondback moth, cnaphalocrocis
Snout moth's larva, striped rice borer, Bemisia tabaci, planthopper.
The Pesticidal combination of the present invention is for combating animal pests, such as insect, immature insect, insect at initial stage and elder brother
Worm's ovum is environment that is effective and being applied directly to insect or their existence.Controlled according to the Pesticidal combination of the present invention
Insect include agricultural/horticultural insect, health insect pest, storage insect insect, clothes insect and furniture insect.
According to the present invention it is possible to handle each several part of all plants and plant.Plant is understood to mean that all herein
Plant and plant population as desired and undesirable wild plant or crop (crop for including spontaneous growth).Crop can be with
It is the plant obtained by conventional breeding and optimum seeking method, or passes through biotechnology and genetic engineering method or the group of these methods
Close the plant obtained, including genetically modified plants and the Plant cultivars including that can or can not be protected by plant breeder's certificate.
Plant parts are understood to mean that all part and plant organ such as seedling, leaf, Hua Hegen above and below the ground, the reality that can be mentioned that
Example is leaf, pin, stem, dry, flower, fructification, fruit and seed and root, stem tuber and rhizome.After the part of plant also includes harvest
Plant and vegetative propagation and case of propagation material, such as seedling, stem tuber, rhizome, transplant and seed.
As described above, all plants and its part can be handled according to the present invention.In preferred embodiments, open country has been handled
Plant kind and Plant cultivars or by standard biologic breeding method as hybridization or protoplast fusion obtain
Plant variety and its part.In a more preferred embodiment, handled by genetic engineering (if necessary with reference to conventional method
The genetically modified plants and Plant cultivars and its part that (Genetically Modified Organisms) is obtained.
According to the present invention, particularly preferably handle be commercially available in all cases or use in plant plant
Train the plant of kind.
It is emphasized that the Pesticidal combination of the present invention is used for effect particularly advantageous during such as following plant：Cereal
Such as wheat, oat, barley, spelt (spelt), triticale and rye, and it is corn, jowar He Li, rice, sweet
Sugarcane, soybean, sunflower, potato, cotton, rape (oil seed rape), canola (canola), tobacco, sweet tea
Dish, fodder beet, asparagus, hops and fruit bearing plant (including the operatic circle such as apple and pears, drupe for example peach, honey peach, cherry, plum,
Apricot, cedra fruits such as orange, grape cypress, bitter orange, cumquat, citrus and Sa Mo tangerines, nut such as pistachio, almond, walnut
And pecan, tropical fruit (tree) such as mango, papaya, pineapple, nipa palm and banana, and grape) and vegetables (including leaf vegetables is such as
Hare's-lettuce, corn salad, fennel, Leaf lettuce, celery lettuce, Swiss chard, spinach and salad are with witloof, wild cabbage such as cauliflower, blue and white
(wrinkle leaf is sweet by cabbage, Chinese leaf, Brassica oleracea (L.) convar. acephalavar. sabellicaL.
Blue, collard), kohlrabi, brussels sprout, red cabbage, white cabbage and savoy, fruit vegetables for example eggplant, cucumber,
Capsicum, edible squash, tomato, bush pumpkin and corn, root vegetables for example celeriac, rape, carrot include yellow cultivars,
Wild radish class includes Raphanussativus var. niger and Raphanussativusvar.radicula, beet, celery
Dish, legume such as pea and soybean, and allium vegetables such as leek and onion).
The present invention Pesticidal combination be particularly suitable for use in rice crops preventing and treating snout moth's larva invasion and attack.
On the other hand, present invention also offers a kind of method prevented or control animal pest, by the desinsection group of the present invention
Compound acts on target useful plant, target animal insect or its environment, the propagating materials of target useful plant.The plant is numerous
It is seedling, rhizome, garden seedling, cutting or seed to grow material.
The present invention Pesticidal combination there is good plant compatibility, suitable for control insect, particularly insect, acarid,
Nematode, and fungi, rodent, microorganism etc., it is preferably adapted for leaf processing, soil treatment and seed, rice shoot is handled
Composition.
The present invention also provides a kind of method for protecting target useful plant to prevent pest infestation, including makes the present invention's
Pesticidal combination and target useful plant or its environment, object noxious livings or its environment, the propagating materials of target useful plant
Contact.
Term " plant propagation material " is interpreted as referring to all plant parts for having fertility, such as seed, and it can be used
In breeding the latter, and vegetable matter such as cuttage bar or stem tuber（Such as potato）.Therefore, plant used herein
Part includes plant propagation material.It is mentioned that such as seed, root, fruit, stem tuber, bulb, rhizome and plant part.Treat
The germination plant and effective plant suppressed after being germinateed from soil or after emergence.Young plant can be before transplantation by being impregnated into
Row whole or Local treatment are protected.Plant propagation material preferred seed.
Prevent or the method for control harmful organism present invention also offers a kind of, including by Insecticidal combinations of the present invention
Thing is applied to the soil of seed, the soil of target useful plant or plant growth or suitable plant growth.
The present invention also provides a kind of protection useful plant to prevent the method for pest infestation, and it is included in the useful plant of target
Thing or its environment, object noxious livings or its environment, target useful plant propagating materials on wished serially or simultaneously with any
Apply the combination comprising ethyl pleocidin and suppression food hydrazine in ground.
Directly carried out with conventional treatment method with processing of the Pesticidal combination of the present invention to useful plant, at the routine
Reason method for example impregnates, poured, being sprayed, atomizing, broadcasts sowing, dusts, and mist formation, broadcasts sowing, foams, coating, being coated with, drip irrigation；
In the case of propagating materials, especially in the case of seed, for the pulvis of dry seedses processing, seed treatment solution, slurry
Expect processing water-soluble powder form, by crust, pass through one or more layers coating etc..
The Pesticidal combination of the present invention can be used to protect useful plant or their propagating materials.Therefore, it is of the invention to kill
Worm composition can in a usual manner, for example foliar spray is applied to useful plant.
The Pesticidal combination of the present invention not only include can use suitable device be applied to plant or plant propagation material i.e.
With composition, and the commercially available concentrate including that must be diluted with water before administration.
The Pesticidal combination of the present invention can be applied without dilution, and administration can also be diluted with water.
The present invention also provides a kind of method prevented or control animal pest, including separates, sequentially or simultaneously applies ethyl
Pleocidin, suppression food hydrazine.
Pesticidal combination of the present invention can be applied to seed, plant or the fruit of plant or plant growth soil or
Soil suitable for plant growth.
Pesticidal combination of the present invention can be applied in any desired manner, such as seed coating, soil pour
And/or directly ditch spread and/or foliage-spray, and before germination, after germination or germination is front and rear applies.
The present invention also provides a kind of protection seed to prevent soil insect and protection seedling root and branch to prevent soil and blade face
The method of insect, it is included in before sowing and/or makes the Insecticidal combinations of the invention of seed and insecticidal effective dose after vernalization
Thing contacts.
Therefore, the present invention provides a kind of method for protecting seed, seedling root and branch to be attacked to prevent soil and foliar insect,
It is included in before sowing and/or contacts seed and the Pesticidal combination of effective dose of the present invention after vernalization.
The present invention also provides one kind in plant propagation material and in growing plants organ, plant part and/or plant afterwards
The method that harmful organism is prevented and treated or prevented in thing, including the Pesticidal combination of the present invention is applied to plant propagation material or its ring
On border.Plant propagation material preferred seed.
Most of infringement as caused by insect to crop plants is early in seed, and during storage and seed is sown into soil
After earth and during plant germination or after germination, when being invaded and harassed just there occurs.This stage is particularly critical, because just in growing plant
Root and seedling it is especially sensitive, even small infringement may also lead to the death of whole plant.Therefore, by using suitable group
Compound come protect seed and germination plant be of specific interest.
It is known for a long time come pest control and is the theme updated by handles vegetable seeds.However,
It is not that can find to solve the problems, such as in a satisfactory manner that processing seed, which is also brought a series of,.Therefore, it is necessary to develop guarantor
The method for protecting seed and the plant that germinates, it can exempt after planting or additionally apply crop protection products again after plant germination.Separately
Outside, it is also necessary to the amount of reactive compound used in optimization, so as to provide best protection to seed and germination plant, to prevent insect
Invasion and attack, and reactive compound used will not damage plant in itself.Especially, the method for handling seed also contemplates for transgenosis plant
The intrinsic insecticidal property of thing with using minimum crop protection products reach to seed and germination plant best protection.
Therefore, the present invention relate particularly to it is a kind of by using the present invention Pesticidal combination handle seed and protect seed and
Method of the germination plant from pest attacks.Present invention protection seed and the plant that germinates include simultaneously from the method for pest attacks
The method for handling the seed with ethyl pleocidin and suppression food hydrazine.It also includes one kind ethyl pleocidin and suppression food hydrazine exists
The method of the different time processing seed.
It is used to handle seed the invention further relates to the Pesticidal combination of the present invention to protect the seed and be grown by it
Purposes of the plant from pest attacks.
Moreover, it relates to the Pesticidal combination through the present invention is handled is protected from the kinds of pest attacks so as to obtain
Son.
The invention further relates to the seed that ethyl pleocidin and suppression food hydrazine are handled simultaneously.The invention further relates to killed through ethyl more
The seed that rhzomorph and suppression food hydrazine are handled in different time.For the kind handled through ethyl pleocidin and suppression food hydrazine in different time
Son, each reactive compound of Pesticidal combination of the present invention can exist in the different layers on the seed.Wherein, containing ethyl
The layer of pleocidin and suppression food hydrazine can be separated optionally by an intermediate layer.The invention further relates to wherein by ethyl pleocidin and
The seed that suppression food hydrazine is applied as coating ingredients or as one or more layers extra play outside coating.
The Pesticidal combination of the present invention can be applied to the seed of any physiological status.Preferred seed is in durable enough
State, so as to without damage in processing procedure.Usually, seed can be harvested from field, remove from plant, be isolated from appointing
What cob, stem, crust and the pulp of surrounding or seed of other non-seed vegetable materials.Seed can also be preferably biological steady
Fixed, to reach the degree that processing will not cause biological damage to seed.Can seed harvest and seed sowing between or
Any time processing during seeding process is applied to seed.Seed can also vernalization before and after treatments.
The seed that Pesticidal combination by the present invention is handled can be stored, manage, sowing and farming.
Seed treatment can be by wishing sequentially or simultaneously to apply it ethyl pleocidin and suppression food hydrazine with any.
Seed treatment occurs on unseeded seed, term " unseeded seed " be intended to include in seed harvest and
The seed in any period between seed is in plant germination and grows purpose sowing in soil.Preferably, handle and broadcast in seed
Occur before kind, so as to which the sowing seed is pretreated with the combination.Especially, seed pelleting or pellet seeds are at this
It is preferable to invent in the processing of combination.After processing, the composition in each combination is attached on seed and therefore available for insect pest
Preventing and treating.
Described seed is selected from soybean, wheat, barley, rice, rape, beet, tomato, cowpea, carrot, cotton and jade
Rice seed.
Pesticidal combination of the present invention is used for the purposes of seed treatment.
The present invention also provides a kind of method for protecting useful plant to prevent pest infestation, including the desinsection by the present invention
Composition is applied to environment, habitat or the storage areas of useful plant growth.The environment of plant growth, habitat are to refer to make agriculture
The supporter that crop takes root, grown, such as：Soil, water etc., specific raw material can use for example sand, float stone, vermiculite,
Diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc..It is preferred that soil.
On the other hand, present invention also offers a kind of method prevented or control animal pest, killed of the present invention
Worm composition is applied to soil and/or is applied directly to and connect with plant root before germination, after germination or before and after germination
Tactile soil or the soil of suitable plant growth.
The method of medicament is applied into soil, such as liquid preparation is diluted in water or do not diluted and is directly applied to plant
The methods of in the root of body or the rice seedling bed of seedling, side granule being disseminated in the root of plant or the rice seedling bed of seedling
Method has the method that pulvis, water dispersible granules etc. are sprayed in soil prior to seeding and integrally mixed with soil, before sowing or plants
It will be sprayed on before kind plant after pulvis, water-dispersible grain dilution agent in implantation hole, seed furrow, then method sowed etc..
The Pesticidal combination of the present invention can also be applied with other active ingredient combinations, and other active components for example kill
Epiphyte pharmaceutical, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer
Or semiochemical etc..
The present invention also provides a kind of method for protecting useful crop attack to prevent animal pest, including combine, it is separated or according to
Secondary administration of active ingredients ethyl pleocidin and suppression food hydrazine.In the case of separate administration, order is generally to the knot of prophylactico-therapeutic measures
Fruit does not influence.
The present invention provides a kind of method prevented or control animal pest, and the Pesticidal combination of the present invention is acted on into target
Useful plant or its environment, object noxious livings, the propagating materials of target useful plant, other agricultural chemicals can be more in administration ethyl
Bacteriocidin and suppression food hydrazine before, with ethyl pleocidin and suppression food hydrazine simultaneously or apply ethyl pleocidin and press down eat hydrazine it
Apply independently of each other afterwards, and in the case of ethyl pleocidin and suppression food hydrazine separate administration, each other agricultural chemicals can applied
With ethyl pleocidin and suppression food hydrazine before, with apply ethyl pleocidin and suppression food hydrazine simultaneously, administration ethyl more sterilize
Applied independently of each other between element and suppression food hydrazine or after ethyl pleocidin and suppression food hydrazine is applied.
On the other hand, processing of the invention can also produce following super additive effect：Improve plant growth, improve to high temperature
Or low temperature tolerance, improve to arid or to the tolerance of water or soil salt content, improve Flowering quality, make harvesting simpler
Just, accelerate ripe, raising harvesting yield, improve the quality of harvested products and/or improve its nutritive value, improve harvested products
Bin stability and/or its processing characteristics.
It is common and favourable that the Pesticidal combination of the present invention is generally applied with following dosage：
- for leaf portion processing：0.1-10000 g/ha, preferably 10-1000g/ha, more preferably 50-300g/ha, more preferably
50-200g/ha；
- for seed treatment：2-200 g/100kg seeds, preferably 3-150g/100kg seeds；
- for soil treatment：0.1-10000g/ha, preferably 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to actual conditions when reality is applied
And needs, adjust rate of application especially in accordance with the property and insect pest situation of pending plant or crop.
The Pesticidal combination of the present invention is also applied for preventing and treating the animal pest of closing space, particularly insect, spider and mite
Worm, the closing space such as house, factory floor, office, cabin etc..They can be used for preventing and treating this in domestic insecticide products
A little insects, they to sensitivity and the kind of resistance and active to all stages of development.These insects include:
Scorpionida, such as pincers scorpion (Buthusoccitanus).
Acarina, for example, adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family food sweet tea mite, tampan tick,
Brown dog tick, trombiculid (Trombiculaalfreddugesi), Neutrombiculaautumnalis, dermatophagoides pteronyssinus, dust
Mite
Araneida, such as cockle spider section, Yuan Zhu sections
Opiliones, such as plan scorpion class (Pseudoscorpioneschelifer), Pseudoscorpionescheiridium,
Opilionesphalangium。
Isopoda, such as damp worm, pillworm.
Sufficient mesh again, such as tool zebra land, mountain cricket Eimeria.
Lip foot mesh, for example, Scolopendra.
Zygentoma mesh, such as comb silverfish category, Lepisma saccarina, Lepismodesinquilinus.
Blattaria, such as oriental cockroach, Groton bug, Blatella (BlattellaCaudell), leucophaea maderae, angle abdomen
Lian category, wooden Lian category, Australian cockroach, American cockroach, Periplanetabrunnea, Peroplaneta fluligginosa, long hair blattaria.
Saltatoria, such as family Shuai.
Dermaptera, such as European earwig.
Isoptera, such as kalotermitid category, Reticulitermes.
Worm mesh, such as Lepinatus category, powder asthma Eimeria
Coleoptera, such as Anthrenus, the moth-eaten category of fur, khapra beetle category, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, paddy
As, rice weevil, sitophilus zea-mais, Stegobium paniceum.
Diptera, such as Aedes aegypti, aedes albopictus, Aedestaeniorhynchus, Anopheles, calliphora erythrocephala, great number
Sarcophagid, Culex quinquefasciatus, northern house, Culextarsalis, stay fly category, Fannia canicularis, housefly, Bai Ling category, sarcophagid
(Sarcophagacarnaria), Simulium, male servant chela fly, daddy-longlegs (Tipulapaludosa).
Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, Tineolabisselliella.
Siphonaptera, such as dog comb head lices, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, such as hunchbacked ant is blazoned, bright hair ant, black wool ant, Lasiusumbratus, MonomoriumMayr,
Paravespula belongs to, Pavement Ant.
Anoplura, such as head louse, body louse, crab louse.
Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus, invade and harass vertebra and hunt stinkbug.
The Pesticidal combination of the present invention can be used as aerosol, no pressure spray product such as pump spraying and atomizer spray, oneself
Dynamic mist formation system, aerosol producer, foam, gel, evaporator product, the liquid with evaporating plate made of cellulose or polymer
Evacuator body device, gel and film evaporator, propeller driving evaporator, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch
Moth bag and insect-catching glue, agent or pulvis are drawn as, in the bait formulation of sprinkling or bait formulation position.
It should be pointed out that the present invention any embodiment or embodiment any technical characteristic can independently with this
Any other embodiment of invention is combined with each other.That is, one or more technologies of any embodiment of the present invention
Feature can all reconfigure with any other technical characteristic.Thus the technical characteristic that technical characteristic is reconfigured and formed is disclosed in
Herein, as especially being recorded herein it.
Example of formulations
Embodiment 1：3% ethyl pleocidin+30% suppression food hydrazine suspending agent
Ethyl pleocidin 3%
Suppression food hydrazine 30%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/or high
3% ethyl pleocidin+30% suppression food hydrazine suspending agent is obtained after speed shearing.
The ethyl pleocidin+54.5% of embodiment 2 5.5% suppression food hydrazine wettable powder
Ethyl pleocidin 5.5%
Suppression food hydrazine 54.5%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, that is, obtained
5.5% ethyl pleocidin+54.5% suppression food hydrazine wettable powder.
The ethyl pleocidin+19.7% of embodiment 3 0.3% suppression food hydrazine aqueous emulsion
Ethyl pleocidin 0.3%
Suppression food hydrazine 19.7%
1-METHYLPYRROLIDONE 15%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 5%
Water complements to 100%
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare aqueous phase；
Under high velocity agitation, it is oil phase is mixed with water, 0.3% ethyl pleocidin+19.7% suppression food hydrazine aqueous emulsion is made.
The ethyl pleocidin+40% of embodiment 4 2% suppression food hydrazine water dispersible granules
Ethyl pleocidin 2%
Suppression food hydrazine 40%
Sodium lignin sulfonate 4%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow crushing into
Wettable powder, add a certain amount of water mixing extruding and make material.The suppression of 2% ethyl pleocidin+40% is obtained after drying and sieving
Eat hydrazine water dispersible granules.
The ethyl pleocidin+7.5% of embodiment 5 0.6% suppression food hydrazine suspending agent
Ethyl pleocidin 0.6%
Suppression food hydrazine 7.5%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/or high
0.6% ethyl pleocidin+7.5% suppression food hydrazine suspending agent is obtained after speed shearing.
The ethyl pleocidin+25% of embodiment 6 2.5% suppression food hydrazine suspending agent
Ethyl pleocidin 2.5%
Suppression food hydrazine 25%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/or high
2.5% ethyl pleocidin+25% suppression food hydrazine suspending agent is obtained after speed shearing.
The ethyl pleocidin+20% of embodiment 7 4% suppression food hydrazine wettable powder
Ethyl pleocidin 4%
Suppression food hydrazine 20%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The ethyl pleocidin+15% of embodiment 8 1% suppression food hydrazine suspending agent
Ethyl pleocidin 1%
Suppression food hydrazine 15%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/or high
1% ethyl pleocidin+15% suppression food hydrazine suspending agent is obtained after speed shearing.
The ethyl pleocidin+40% of embodiment 9 2% suppression food hydrazine aqueous emulsion
Oil phase：
Ethyl pleocidin 2%
Suppression food hydrazine 40%
Methyl oleate 40%
Polystyrene 3.7%
Aqueous phase：
Xanthans 0.07%
The sodium salt 1% of naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Bactericide 0.2%
Water complements to 100%
Ethyl pleocidin and suppression food hydrazine are dissolved in methyl oleate, polystyrene is added and obtains oil phase；According in formula
Component is well mixed to obtain aqueous phase；Oil phase addition aqueous phase is obtained into aqueous emulsion under agitation.
The ethyl pleocidin+48% of embodiment 10 6% suppression food hydrazine wettable powder
Ethyl pleocidin 6%
Suppression food hydrazine 48%
Sodium lignin sulfonate 4%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The ethyl pleocidin+25% of embodiment 11 1% suppression food hydrazine coated granule
Ethyl pleocidin 1%
Suppression food hydrazine 25%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol.It can obtain in this way
Obtain dust-free coated granules agent.
The ethyl pleocidin+40% of embodiment 12 1% suppression food hydrazine wettable powder
Ethyl pleocidin 1%
Suppression food hydrazine 40%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The ethyl pleocidin+50% of embodiment 13 1% suppression food hydrazine extrusion granule
Ethyl pleocidin 1%
Suppression food hydrazine 50%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, then done in the air stream
It is dry.
The ethyl pleocidin+60% of embodiment 14 5% suppression food hydrazine suspending agent
Ethyl pleocidin 5%
Suppression food hydrazine 60%
AEO sulfosuccinic acid monoesters disodium 5%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/or high
5% ethyl pleocidin+60% suppression food hydrazine suspending agent is obtained after speed shearing.
The ethyl pleocidin+12.4% of embodiment 15 0.6% suppression food hydrazine ZC
ATLOXTM4913 4%
Citric acid 0.05%
Catalyst 0.1%
Water 10%
Ethyl pleocidin 0.6%
PAPI 1.35%
SOLVESSOTM200 5%
ATLOXTM4913 10%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 4.4%
Suppression food hydrazine 12.4%
Water complements to 100%
By poly methylene poly phenyl poly isocyanate（PAPI）, ethyl pleocidin and SOLVESSO TM200 oil phases formed add
Enter to contain ATLOXTMIn 4913 aqueous solution, emulsion is formed.Then heat and be incubated 50oIt is small that catalyst reaction 2 is added under C
When.The microcapsules of ethyl pleocidin is obtained after cooling.
ATLOXTM4913, dispersant LFH, defoamer, urea, suppression food hydrazine and water mix in proportion, and through being sanded,
It is prepared into the suspending agent of the hydrazine of food containing suppression.
The microcapsules of obtained ethyl pleocidin is added in the aqueous suspension agent of suppression food hydrazine, be uniformly mixing to obtain 0.6% second
The suppression food hydrazine of Quito bacteriocidin+12.4% ZC.
The ethyl pleocidin+50% of embodiment 16 5% suppression food hydrazine suspended emulsion
Ethyl pleocidin 5%
Suppression food hydrazine 50%
SOLVESSOTM200 10%
Ethoxylated castor oil 4%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ethyl pleocidin is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, obtains ethyl pleocidin
Missible oil；
Hydrazine is eaten into suppression, AEO sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion, and passes through
It is sanded, is prepared into suspending agent.
Oil phase containing ethyl pleocidin is added in the suspending agent of the hydrazine of food containing suppression, obtains suspended emulsion.
The ethyl pleocidin+20% of embodiment 17 1% suppression food hydrazine missible oil
Ethyl pleocidin 1%
Suppression food hydrazine 20%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
SOLVESSOTM200 complement to 100%
Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.
The ethyl pleocidin+5% of embodiment 18 0.5% suppression food hydrazine dashing agent
Ethyl pleocidin 0.5%
Suppression food hydrazine 5%
1-METHYLPYRROLIDONE complements to 100%
Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.
The ethyl pleocidin+10% of embodiment 19 0.5% suppression food hydrazine suspension seed-coating agent
Ethyl pleocidin 0.5%
Suppression food hydrazine 10%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspension seed-coating agent.
The dry suspending agent of embodiment 20
| Ethyl pleocidin | 1.5% |
| Suppression food hydrazine | 22.5% |
| Alkyl dimethyl benzyl ammonium | 10% |
| Trisiloxanes APEO | 8% |
| Polyvinyl alcohol | 4% |
| Propane diols | 5% |
| Silicone | 5% |
| Kaolin | Complement to 100% |
Active component and various auxiliary agents are mixed with water, after high speed shear is scattered, sand mill is sanded, form high dispersive, steady
Fixed suspension system, suspending agent is made, obtained suspension is obtained into the dry suspending agent of the present invention by fluidized bed drying.
The ultra low volume liquids of embodiment 21
Ethyl pleocidin 0.05%
Suppression food hydrazine 0.5%
Ethoxylated castor oil 3%
Methyl oleate complements to 100%
Mentioned component is proportionally prepared, is uniformly mixing to obtain phase.Obtained composition is directly applied without dilution
Proportioning is weight per distribution ratio in above example.
Embodiment
Crop protection products are made in different combination of active principles, are to develop and develop at present new crop protection products and prevent
Control a kind of effective and quick way of agriculturally resistant insect.After the pestsides synthesis of different cultivars, three kinds of works are typically exhibited
Use type：Summation action, synergistic effect and antagonism.But it is specially which kind of effect, it is unpredictable, only pass through many experiments
Just it can know that.Compound synergic is formulated well, due to significantly improving actual prevention effect, reduces the usage amount of agricultural chemicals, from
And greatly delayed the generation speed of pest resistance to insecticide, it is the important means of integrated control disease.
For inventor by substantial amounts of screening test, the different ratio that hydrazine is eaten to ethyl pleocidin and suppression has carried out a large amount of examinations
To test and effectiveness is analyzed, find in certain ratio range, resulting Pesticidal combination has gain effect, and not only
Only it is the simple addition of two kinds of medicaments, is specifically illustrated with implementation below.
Tested with reference to the People's Republic of China (PRC) agricultural industry criteria (NY/T154.7-2009) farm-chemical indoor determination
The synergy measure of the part mixture of criterion insecticide the 7th, according to survey data, calculate the corrected mortality of each processing, and root
The co-toxicity coefficient of mixture is calculated according to the abundant methods of Sun Yun（CTC values）.
Clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient（CTC）, CTC<80 be to resist effect short of money, 80≤CTC
≤ 120 be summation action, and CTC ＞ 120 are synergistic effect.
Calculation formula is as follows：
Borer population * 100 living before the death rate (%)=(borer population living after borer population-medicine living before medicine)/medicine
Corrected mortality (%)=(the treatment group death rate-control group death rate)/(the 100- control groups death rate) * 100
Probit value (y) will be converted into for examination insect corrected mortality, concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with most
Small square law calculates concentration LC in suppression50, then according to the abundant method calculating co-toxicity coefficients (CTC) of Sun Yun.Calculation formula is following (with ethyl
Pleocidin is standard agent, 100) its toxicity index is：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
B percentage contains in A percentage composition+B medicaments ATI × mixture in theoretical toxicity index (TTI)=A medicaments ATI × mixture
Amount
Co-toxicity coefficient (CTC)=(mixture ATI/ mixture TTI) × 100
CTC<80 show as resisting effect short of money, and 80≤CTC≤120 show as summation action, and CTC ＞ 120 show as synergistic effect
Experiment 1：To the Toxicity Determination result of wild cabbage diamondback moth
Experiment determines ethyl pleocidin, suppression food hydrazine and the two different proportion with reference to NY/T1154.14-2009 leaf dipping methods
Combine the indoor biological activity to test worm.
Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the decoction prepared
Take out, naturally dry, be put into insect box after middle immersion 5s, then connect for examination larva, raise under the conditions of 25 DEG C, often handle
3 repetitions, it is 20 often to repeat test worm number used, while sets blank control, checks dead borer population in 72h, calculates the death rate and school
The positive death rate, try to achieve virulence regression equation and calculate LC50 values.If compareing the death rate is more than 10%, it is considered as invalid experiment.
Table 1：
As known from Table 1, wild cabbage diamondback moth is prevented and treated, ethyl pleocidin eats the proportioning of hydrazine 1 with suppression:1-1:When in 100 scope,
Co-toxicity coefficient is all higher than 120, illustrates that both show as gain effect at mixture in the range of this.
Experiment 2：To the Toxicity Determination result of rice-stem borer
Experiment determines ethyl pleocidin, suppression food hydrazine and the two different proportion with reference to NY/T1154.14-2009 leaf dipping methods
Combine the indoor biological activity to test worm.
Using the method that first leaching leaf is followed by worm, will be soaked not in contact with the blade of the same size of any medicament in the decoction prepared
Take out, naturally dry, be put into insect box after bubble 5s, then connect for examination larva, raised under the conditions of 25 DEG C, often handled 3 times
Repeat, it is 20 often to repeat test worm number used, while sets blank control, and dead borer population is checked in 72h, calculates the death rate and correction is dead
Rate is died, virulence regression equation is tried to achieve and calculates LC50 values.If compareing the death rate is more than 10%, it is considered as invalid experiment.
Table 2：
As known from Table 2, rice-stem borer is prevented and treated, ethyl pleocidin eats the proportioning of hydrazine 1 with suppression:1-1:When in 100 scope,
Co-toxicity coefficient is all higher than 120, illustrates that both show as gain effect at mixture in the range of this.
Biological test example
When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is administered alone, association be present
Same desinsection and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can be used so-called " Colby formula "
(referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of
Herbicide Combinations ", Weeds 1967,15,20-22) it is calculated as below:If
X is when the use of dosage being m g/ha or kill rate during reactive compound A that concentration is m ppm, is expressed as accounting for and does not locate
The percentage of control is managed,
Y is when the use of dosage being n g/ha or kill rate during reactive compound B that concentration is nppm, is expressed as accounting for untreated
The percentage of control,
E be when the use of dosage being m and n g/ha or kill rate during reactive compound A and B that concentration is m and n ppm,
It is expressed as accounting for the percentage of untreated control,
So
If actual desinsection fatal rate exceedes calculated value, the lethal effect of composition is super plus sum, that is, collaboration be present and make
With.In this case, the kill rate actually observed must be over the expection kill rate value (E) calculated using above-mentioned formula
Value.
The diamondback moth of biological test example 1 tests sensitive strain
The parts by weight dimethylformamide of solvent 7
The parts by weight alkaryl polyglycol ether of emulsifying agent 2
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
Cabbage leaves are impregnated into the active agent preparations for wish concentration and it handled and when blade is still moist
Use diamondback moth（Sensitive strain）Caterpillar is infected.
After the desired time, killing rate % is determined.100% represents that all caterpillars are killed；0% represents the leaf through processing
The quantity of caterpillar is suitable with the caterpillar quantity of unprocessed control group on piece.The killing rate of measure is counted using Colby formula
Calculate.
In this test, Pesticidal combination of the invention is demonstrated by collaboration enhancing work compared with reactive compound is administered alone
Property, and the Pesticidal combination of the present invention increases significantly compared to prior art tool.
Diamondback moth is tested, sensitive strain
It was found that *=discovery activity
The * * of calculating=be applicable the activity that Colby formula calculate
The experiment of the striped rice borer of biological test example 2
The parts by weight dimethylformamide of solvent 7
The parts by weight alkaryl polyglycol ether of emulsifying agent 2
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It is handled by being impregnated into by the rice leaf of striped rice borer severe infections in the active agent preparations for wish concentration.
After the desired time, killing rate % is determined.100% represents that all striped rice borer have been killed；0% represents through processing
Blade on striped rice borer quantity it is suitable with the striped rice borer quantity of unprocessed control group.The killing rate of measure is public using Colby
Formula is calculated.
In this test, Pesticidal combination of the invention is demonstrated by collaboration enhancing work compared with reactive compound is administered alone
Property, and the Pesticidal combination of the present invention increases significantly compared to prior art tool.
Striped rice borer is tested
It was found that *=discovery activity
The * * of calculating=be applicable the activity that Colby formula calculate.
Claims (10)
1. a kind of Pesticidal combination, it is characterised in that active component is made up of ethyl pleocidin and suppression food hydrazine, and the ethyl is more
The weight ratio of bacteriocidin and suppression food hydrazine is 1:1-1:100, preferably 1:1-1:90, preferably 1:1-1:80, more preferred 1:1-1:70,
Further preferably 1:1-1:60, further preferably 1:1-1:50, further preferably 1:1-1:40, further preferably 1:1-1:30, further preferably 1:1-1:20,
More preferred 1:1-1:10.
2. Pesticidal combination according to claim 1, it is characterised in that the weight of the ethyl pleocidin and suppression food hydrazine
The composition 1%-90% by weight, more preferably preferably 1%-80%, more preferably 1%-70%, 1%-60% are accounted for altogether, more preferably
1%-50%, more preferably 1%-40%, more preferably 1%-30%, more preferably 1%-20%.
3. Pesticidal combination according to claim 1, it is characterised in that also comprising surfactant and/or filler.
4. Pesticidal combination according to claim 1, it is characterised in that the Pesticidal combination formulation is missible oil, water hangs
Floating agent, oil-suspending agent, seed treatment dry powder doses, seed treatment suspending agent, water dispersible granules, wettable powder, suspension emulsion, smog
Agent, coated granule, extrusion granule, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, dry suspending agent, ultra-low volume
Liquor, electrostatic oil agent, gel, soluble powder, granula.
5. the Pesticidal combination described in claim 1 is used for the purposes for preventing or controlling animal pest.
6. the Pesticidal combination described in claim 1 is used for the purposes for preventing or controlling rice crops snout moth's larva.
A kind of 7. method prevented or control animal pest, it is characterised in that the Pesticidal combination of claim 1 is used for target
Useful plant, target animal insect or its environment, the propagating materials of target useful plant.
A kind of 8. method prevented or control animal pest, it is characterised in that apply the Pesticidal combination described in claim 1
To the soil of seed, the soil of target useful plant or plant growth or suitable plant growth.
A kind of 9. method prevented or control animal pest, it is characterised in that planting the Pesticidal combination described in claim 1
Son germination before, germination after or germination before and after be applied to soil and/or be applied directly to soil contact with plant root or fit
Close the soil of plant growth.
10. a kind of protect seed to prevent soil insect and protect the method for seedling root and branch to prevent soil and foliar insect, its
It is characterised by, the Pesticidal combination described in the claim 1 of seed and insecticidal effective dose is made before sowing and/or after vernalization
Contact.
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| CN110150293A (en) * | 2018-02-13 | 2019-08-23 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN115488985A (en) * | 2022-09-21 | 2022-12-20 | 上海康拜环保设备有限公司 | Method for manufacturing formaldehyde-free artificial board made of eucalyptus bark |
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| CN115488985A (en) * | 2022-09-21 | 2022-12-20 | 上海康拜环保设备有限公司 | Method for manufacturing formaldehyde-free artificial board made of eucalyptus bark |
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