CN104904743B - Pesticidal combination - Google Patents
Pesticidal combination Download PDFInfo
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- CN104904743B CN104904743B CN201410086887.0A CN201410086887A CN104904743B CN 104904743 B CN104904743 B CN 104904743B CN 201410086887 A CN201410086887 A CN 201410086887A CN 104904743 B CN104904743 B CN 104904743B
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- active component
- etoxazole
- pyridaphethione
- agent
- composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Abstract
The present invention relates to a kind of insecticides, including the first active component etoxazole and the second active component pyridaphethione, more particularly to disinsection method.The weight ratio of a kind of Pesticidal combination of present invention offer, including etoxazole and pyridaphethione, the etoxazole and pyridaphethione is 1:100‑100:1.The first active component etoxazole and the second active component pyridaphethione account for 5% 90% of the composition by weight altogether.The Pesticidal combination has more preferable quick-acting and lasting effect, has the effect of cooperative gain on insecticidal effect, while can reduce production cost and agricultural cost, preferably serves agricultural production.
Description
Technical field
The present invention relates to a kind of insecticides, including the first active component etoxazole and the second active component to rattle away
Piperazine sulphur phosphorus, more particularly to disinsection method.
Background technology
Etoxazole（ Etoxazole）It is a brand-new change with unique texture of SUMITOMO CHEMICAL chemical research exploitation
Compound.Its chemical name is：(RS) -5- the tert-butyl groups -2- [2- (2,6- difluorophenyls) -4,5- dihydro -1,3- oxazole -4- bases] benzene
Ether, its molecular structural formula are formula（I）：
(Formulas I)
Etoxazole is to tetranychid, beginning tetranychid and Panonychus citri, such as Tetranychus urticae, Tetranychus cinnabarinus, citrus red mite, hawthorn, grape
Tetranychid etc. has remarkable preventive effect.Its mode of action includes suppressing normal molting process and ovicidal activity, therefore can effectively prevent
Control the whole juvenile stage of evil mite（Ovum, young mite and deutonymph）.Additionally while etoxazole can not directly kill into mite, but to female into
Mite has infertility effect well.The mite pest that resistance has been produced to existing acaricide can be prevented and treated.Etoxazole has stronger
Rain fastness and longer lasting effect.Lasting period when proper use of on fruit tree can reach more than 50 days, in cotton, vegetables
It can reach more than 30 days with the lasting period on ornamental plant.Up to the present, the examination carried out to etoxazole in greenhouse and field
Test and do not observe poisoning phenomenon as caused by it in concentration.Minimum or even non-hazardous is endangered to many beneficial insects and beneficial mite.
Etoxazole is the important member in integrated pest management system.
Pyridaphethione, chemical name are thio O, O- diethyl-O [2,3- dihydro -3- oxo -2- phenyl -6- pyridazinyls]
Phosphate, its structural formula are formula（II）：
(Formula II)
Pyridaphethione has better effects to a variety of biting mouthpartses and sucking pest.Application method is missible oil pair
Water spray or pulvis dust.This medicament is protruded rice grub drug effect, safer to the natural enemy Predatory Mites of rice grub, to fish
Low toxicity, residual quantity is low in paddy, particularly suitable for rice, can prevent and treat snout moth's larva, leaf-roller, rice plant skipper, plant hopper, leafhopper,
Thrips, pachydiplosis oryzae etc.., can also prevention and control of aphides, cotton boll to significantly inhibiting effect into leech, deutonymph, mite ovum to cotton spider mites special efficacy
Worm, pink bollworm.For the crops such as wheat, coarse cereals, oil plant, vegetables, fruit tree and forest, Zhiduo County's kind biting mouthparts, thorn can be cured
Suction mouthpart insect and tetranychid.Pyridaphethione category low toxicity and low residue broad spectrum activity organic phosphates insecticidal/acaricidal agent, have to insect, evil mite
Have and tag and stomach poison function, and have certain ovicidal action.With good quick-acting, while there is low toxicity, low-residual, be not easy to lure
The features such as sending out pest resistance to insecticide.
Mite class is commonly called as red spider, belongs to arachnoide pest, is that cause harm fruit tree, cotton, Solanaceae, vegetables and ornamental flower etc. is a variety of
One of important pests of crop, common evil mite belong to Acariformes and Acarina more.Mite class mainly causes harm leaf, stem and the flower of plant
Deng thorn inhales the cauline leaf of plant, and there is the yellowish-brown dot of a large amount of needle point size chlorosis in leaf at initial stage front, and anaphase blade is opened from the bottom up
Beginning chlorosis is crispaturaed, even come off.Sometimes take place from blade in the middle part of plant, blade gradually turns yellow, come off.Evil mite occurs from generation to generation
More, fertility is strong, under suitable temperature and humidity conditions, mite population can be doubled and redoubled rapidly within a short period of time, to agriculture
Crop causes very big harm.Evil mite is also easy to produce the resistance to the action of a drug to mite killing medicament, if do not prevented and treated in time in serious occur, aggrieved work
The blade meeting chlorosis of thing is turned white, and is withered and fallen in advance.Under the torrid zone and greenhouse experiment, whole year can all occur.The height of temperature determines
The number of the growth cycle of each worm state of mite class, reproduction speed and egg laying amount.It is big that the weather conditions of extreme arid torrid climate frequently can lead to its
Occur.
Because mite class generating capacity is big, the breeding cycle is short, hidden, and resistance rises fast, it is difficult to prevents and treats, so using chemical pesticide
Preparation is still the main method for preventing and treating mite evil in agricultural production.
Nowadays, pyridaphethione has used as acaricide agriculturally, is used alone and rattles away in mite class early period of origination
Piperazine sulphur phosphorus can effectively suppress the rising of mite class quantity, and quick-acting is preferable, but when mite class largely occurs, rattles away over time
Piperazine sulphur phosphorus just gradually loses control of its quantity so that the lasting period is no more than 20 days, and a drug can only play control generation mite evil
Effect.
The characteristics of etoxazole has the lasting period long, so the period of being applicable is wide, but it is to invalid into mite, to mandarin orange mandarin orange, cotton, pears
And the onset time of the red spider on vegetables is that 7-10 talent reaches peak mortality after medicine, to making blade because of the harm of red spider
Chlorosis, but its lasting period was up to 30-45 days.
The activity of the individual compounds is good；However, in low rate of application or they are not when being used for single insect
It is that can meet the high request that insecticide, acaricide or nematicide must are fulfilled for.
Field of pest control occur a typical demand be need reduce prevent and treat active component close rate and
Unfavorable environment or toxicological effects are reduced or avoided, while still allows for the control of insect of effect.Also need to combine and knock down work
Property and extend preventing and treating time, i.e. snap action and long-acting pest control agent.
It is to repeat using another difficulty of insecticide and uniquely uses single Pesticidal compound in many cases
Cause to produce the reactive compound quick selection that is natural or adapting to drug-fast insect.It is therefore desirable to have help prevent
Or overcome drug-fast pest control agent.
Therefore, it is at least one in described problem it is an object of the present invention to provide solving, such as reduce close rate, expand
Big activity profile combines the Pesticidal combination knocked down activity and extend preventing and treating time or resistance to the action of a drug management, delaying drug resistance.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of insecticides, said composition is by by second mite
Azoles and pyridaphethione are combined so that obtained composition has gain effect in prevention effect, and has expanded desinsection
Spectrum, improves the snap action and long-acting of control of insect, has delayed drug-fast generation.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of Pesticidal combination, including
First active component etoxazole,
Second active component pyridaphethione；
The first active component etoxazole and the second active component pyridaphethione are 1 by weight ratio:100-100:1.
As a further improvement on the present invention, the first active component etoxazole and the second active component pyridaphethione are pressed
Weight proportion is 1:50-50:1.
As a further improvement on the present invention, the first active component etoxazole and the second active component pyridaphethione are pressed
Weight proportion is 1:25-25:1.
As a further improvement on the present invention, the first active component etoxazole and the second active component pyridaphethione are pressed
Weight proportion is 1:10-10:1.
A kind of Pesticidal combination, including the first active component etoxazole and the second active component pyridaphethione, described first
Active component etoxazole and the weight of the second active component pyridaphethione account for the 5%-90% of the composition by weight altogether.
A kind of Pesticidal combination, including the first active component etoxazole and the second active component pyridaphethione, described first
Active component etoxazole and the second active component pyridaphethione account for the 10%-80% of the composition by weight altogether.
A kind of Pesticidal combination, including the first active component etoxazole and the second active component pyridaphethione, described first
Active component etoxazole and the second active component pyridaphethione account for the 20%-60% of the composition by weight altogether.
According to the Pesticidal combination of the present invention, also comprising surfactant and/or extender.
According to the Pesticidal combination of the present invention, the Pesticidal combination can be configured to any formulation agriculturally allowed.
According to the Pesticidal combination of the present invention, the formulation of the Pesticidal combination is missible oil, suspending agent, seed coat agent, moisture
Shot agent, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra-low volume liquid
Agent.
On the other hand, it is used to prevent present invention also offers a kind of Pesticidal combination by the present invention or controls harmful organism
Purposes, wherein harmful organism be insect, acarid.
Preferably, the Pesticidal combination is used for the purposes for preventing and treating red spider and aphid.
On the other hand, present invention also offers a kind of method prevented or control harmful organism, by the desinsection group of the present invention
Compound acts on target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.The plant is numerous
It is seedling, rhizome, garden seedling, cutting or seed to grow material.
A kind of cover crop to prevent pest infestation method, including make crop with containing the first active component etoxazole and
Second active component pyridaphethione Pesticidal combination and target useful plant, object noxious livings or the useful plant of its environment, target
The propagating materials contact of thing.
A kind of cover crop to prevent pest infestation method, including separate, sequentially or simultaneously apply the first activearm
Divide etoxazole, the second active component pyridaphethione.
Present invention discover that：First active component etoxazole and the combination of the second active component pyridaphethione can not only be brought pair
Improved in the additive property of insecticidal spectrum, but also realize amazing synergy.
Term " synergy " used herein refers to inventive compound combination insecticidal effect and is more than each active component
Effect sum, in other words, its effect is superadditivity.
The invention provides a kind of desinsection group for including the first active component etoxazole and the second active component pyridaphethione
Compound.
The invention provides a kind of Pesticidal combination, wherein the first active component etoxazole and the second active component pyridazine sulphur
Phosphorus weight ratio is 1:100-100:1, preferably 1:50-50:1, further preferably 1:25-25:1, more preferably 1:10-10:1.
The total amount of active component can be selected according to material elements in the present composition, to realize desired work
With.The factor is for example, formulation, object to be administered, application process etc..First active component etoxazole and the second active component are rattled away
Piperazine sulphur phosphorus accounts for 5% to 90% of the composition by weight, preferably 10% to 80%, more preferably 20% to 60% altogether.
The composition of the present invention optionally includes agronomically acceptable surfactant or extender.
According to the present invention, term " filler ", which refers to, can be combined with active component or combines to make it easier for being administered to pair
As（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the filler is preferably lazy
Property, it is acceptable at least to should be agricultural.The filler can be solid or liquid.
Applicable solid carrier is：Such as phyteral powdery type（Such as soy meal, starch, grain dust, wood powder, bark powder,
Sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, the particle of corncob and tobacco stem, extract residual after plant essence
Slag etc.）, clay class（Such as kaolin, bentonite, acid china clay etc.）, talcum powder class.Silica（Such as diatomite, silica sand, cloud
Female, aqueous silicic acid, calcium silicates）, activated carbon, natural mineral matter class（Float stone, attapulgite and zeolite etc.）, fire diatomite, sand,
Plastics medium etc.（Such as polyethylene, polypropylene, polyvinylidene chloride etc.）, potassium chloride, calcium carbonate, the inorganic mineral of calcium phosphate etc.
Property powder, ammonium sulfate, ammonium phosphate, urea, chemical fertilizer, the clay fertilizer of greening ammonium etc., these materials can be used alone or 2 kinds
It is mixed above.
Applicable liquid-carrier can select in llowing group of materials, such as water, alcohol type（Such as methanol, ethanol, isopropyl
Alcohol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.）, ethers（Such as
Ether, dioxanes, methylcellulose, tetrahydrofuran etc.）, aliphatic hydrocarbon class（Such as kerosene, mineral oil etc.）, fragrance
Race's hydrocarbon（Such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene etc.）、
Halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal oil etc..
The composition of the present invention can also include additional other components, such as surfactant.Applicable surfactant
There are the emulsifying agent with ion or non-ionic nature, dispersant or wetting agent, or the mixture of these surfactants.These tables
The suitable of face activating agent has AEO, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, poly-
The phosphate of oxygen vinyl alcohol or phenol, the fatty acid ester of polyalcohol, alkylaryl sodium sulfonate, naphthalene sulfonic acid polymer, lignosulfonates,
Branch dress copolymer, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, the fat of macromolecule comb shape
Polyacrylate, the protein hydrolysate such as alcohol and ethylene oxide condensate, alkyltaurate.Suitable oligosaccharide thing or polymerization
Thing, for example, based on single vinyl monomer, acrylic acid, polyoxyethylene or polyoxypropylene or its with for example（It is polynary）Alcohol or（It is more
Member）The combination of amine.When a kind of not soluble in water in one kind in reactive compound and/or inert carrier and when being applied in water
When, it is necessary to surfactant be present.The ratio of surfactant is 5% to 40% weight of the composition of the present invention.
If appropriate, there may also be other addO-on therapies, such as protecting colloid, adhesive, adhesive, thickener, touch
Become agent, bleeding agent, stabilizer, screening agent, sequestering agent, complex-forming agents.Generally, described reactive compound can be with
Any solid or liquid additive conventionally used for preparation purpose combine.
The preparation of the present invention can be entered at least one of the active component and following material by known way
Row mixing：Solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixative, wetting agent, waterproofing agent, if it is desired,
Drier and colouring agent, stabilizer, pigment, defoamer, preservative, thickener, water and other processing aids can also be included.
The Pesticidal combination of the present invention can be used with itself, or can be according to its respective physically and/or chemically property
Used with its dosage form or type of service prepared therefrom, for example, it is aerosol, micro-capsule suspension, harl agent, thermal fog, micro-
Capsule granula, granula subtilis, seed treatment suspending agent, ready to use solution agent, pulvis, missible oil, oil-in-water emulsion, water-in-oil type breast
Agent, big granula, fine granule, oil-dispersing property pulvis, oil suspending agent, finish, foaming agent, paste, seed coat agent, colloidal suspending agent, suspended emulsion,
Aqueous solvent, suspending agent, wettable powder, soluble powder, pulvis and granule, water-soluble granular formulation or tablet, seed treatment
With water solube powder, wettable powder, reactive compound impregnate natural prodcuts and synthetic, polymeric material in kind of an attached bag
Cover the microcapsules in material, and the agent of ultra-low volume harl and hot mist preparation.
Directly carried out or passed through with conventional treatment method with processing of the Pesticidal combination of the present invention to plant and plant part
Act on its environment, habitat or storage areas and carry out, the conventional treatment method for example impregnates, poured, being sprayed, more
Mist, broadcast sowing, dust, mist formation, broadcast sowing, foam, coating, being coated with, drip irrigation；In the case of propagating materials, the feelings especially in seed
Under condition, for dry seedses processing pulvis, seed treatment solution, slurry processing water-soluble powder form, by crust,
Pass through one or more layers coating etc..
The composition of the present invention not only includes can use what suitable device was applied to plant or seed to use composition, and
Including the commercially available concentrate that must be diluted with water before administration.
The composition of the present invention can also be applied with other active ingredient combinations, and other active components are for example antifungal
Agent, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or change
Learn pheromones etc..
The Pesticidal combination of the present invention, has good plant compatibility and favourable homeothermal animal toxicity, suitable for preventing and treating
The harmful organism run into agricultural, forestry, protection Stored Product and material and health field, especially insect and acarid.
They are active for generally sensitive and resistance species, and are respectively provided with activity for all or single stage of development.
Term " harmful organism " used herein means any organism that can be caused damage to the normal condition of plant.Bag
Include：
Lepidoptera pest is included for example：Striped rice borer（chilosuppressalis（walker）, yellow rice borer
（Tryporyzaincertulas（walker））, rice leaf roller（cnaphalocrocismedinalisGuenee）, cabbage heart
Snout moth's larva（hellullaundalis）, dichocrocis punctiferalis（conogethespunctiferlis）, papilio xuthus Linnaeus（papilioxuthus）, it is white
White butterfly（pierisrapaecrucivora）, straight burr rice hesperiidae（parnaraguttata）, tent caterpillar（malacosoma
Neustria testacea）, gypsymoth（lymantriadispar）, fall webworms（hyphantriacunea）, east poison moth
（euproctissubflava）, black line slug moth（scopelodescontracus）, bollworm
（helicoverpaarmigera）, Pectinophora gossypiella（Pink bollworm）, cabbage looper（trichoplusiani）, wild cabbage night
Moth（mamestrabrassicae）, beet armyworm（spodopteraexigua）, prodenia litura（spodopteralitura）、
Tea olethreutid（adoxophyesoranafasciata）, leaf roller（adoxophyeshonmai）, apricot yellow volume moth
（archipsfuscocureanus）, Homonamagnanima（homonamagnanima）, diamondback moth（plutellaxylotella）, cotton
Pink bollworm（pectinophoragossypiella）.
Coleopteran pest is included for example：Rice weevil（sitophilusoryzaelinne）, citrus leaf mining first
（Podagricomela nigricollis Che）, sitophilus zea-mais（S.zeamails）, grain weevil（S.granarius）, big daikon leaf beetle
（Cabbageleafbeetle）, daicon leaf beetle（Daikon leaf beele）, flea beetle（fleabeetle）, grape flea beetle
（Alticachalybea）, cabbage flea beetle（phyllotretastriolata）, cucumber flea beetle（Epitrixcucumeris）, cigarette
Careless flea beetle（Ehirtipennis）, eggplant flea beetle（E.fuscula）, aulacophora femoralis（Aulacophoraindica（Gemlin）, leaf mustard
It is chrysomelid（Phaedon cochleariae）Deng.
Diptera pest is included for example：Rice leafminer（agromyzaoryzae）, hydrellia griseola
（hydrelliagriseola）, African Chrysanthemum liriomyza bryoniae（liriomyzatrifolii）, pea leaf dive fly
（chromatomyiahorticola）, Liriomyza brponiae（liriomyzabryoniae）, delia platura（deliaplatura）、
Green onion ground Hylemyia Platura Meigen（deliaantiqua）Mediterranean fruitfly（ceratitiscapiatawiedgman）, Rhagoletis pomonella
（Rhagoletispomonella）, cherry fruit fly（R.cingulata）.
Hemipteran pest is included for example：Smelly stinkbug（megacoptapunctatissimum）, cabbage bug
（eurydemarugosum）, big thorn white star stinkbug（eysarcorislewisi）, white star stinkbug（eysarcorisparvus）, rice it is green
Stinkbug（nezaraviridula）, Si Shi amber stinkbugs（plautiastali）, clerodendron trichotomum stinkbug（halymorphamista）, rice spiny coreid
（cletuspunctiger）, Chinese Leptocorisa spp（leptocorisachinensis）, azelea lace bug
（stephantispyrioides）, it is red must fleahopper（trigonotyluscoelestialium）.
Homoptera pest includes such as rice green leafhopper（nephotettixcincticeps）, small brown rice planthopper
（laodelphaxstriatellus）, brown plant-hopper（nilaparvatalugens）, white backed planthopper
（sogatellafurcifera）, pear sucker（psyllapyrisuga）, diaphorina citri（diaphorinatabaci）, Bemisia tabaci
（bemisiatabaci）, aphid（homoptera）, apple aphid（eriosomalanigerum）.
Hymenoptera（hymenoptera）In have, yellow-winged cabbage sawfly（athaliarosaeruficornis）, rose sawfly
（argepagana）, Black Hills ant（formica japonica）, chestnut gall wasp（dryocsmuskuriphilus）Deng.
Thysanoptera, such as thrips（HaplothripsChinensisPriesner）.
Arachnoidea（Arachnida）Insect.Such as panonychus citri（panonychus citri）, Tetranychus cinnabarinus
（Tetranychus cinnabarinus）, panonychus ulmi（panonychus ulmi）, T.urticae Koch（tetranychus
urticae）, tetranychus viennensis（tetranychus viennensis）, oligonychus ununguis（oligonychus ununguis）Mandarin orange
Tangerine beginning tetranychid（eotetranychus kankitus）, purplish red short hairs mite（brevipalpus phoenicis）, Bryobia praetiosa
（bryobiapraetiosa）, wheat leaf roll mite（aceria tulipae）, grape erineum mite (Eriophyes vitis)（colomerus vitis）, tealeaves
Goitre mite（calacarus carinatus）, yellow tea mite（polyphagotarsonemus latus）, long hair root mite
（rhizoglyphus rostochiensis）Deng.
Anoplura (Anoplura, Phthiraptera), such as Damalinia (Damalinia spp.), Haematopinus
(Haematopinus spp.), Linognathus (Linognathus spp.), Pediculus (Pediculus spp.), Trichodectes
(Trichodectes spp. )。
Isopoda（Isopoda）, for example, Cape jasmine beach louse（Oniscus asellus）, pillworm（Armadilliudium
vulgare）, ball pillworm（Porcellio scaber）.
Sufficient mesh (Diplopoda) again, for example, Blaniulus guttulatus.
Lip foot mesh (Chi lopoda), for example, ground Scolopendra (Geophilus carpophagusScutigera
spp.) 。
Comprehensive mesh (Symphyla), for example, kahikatea worm (Scutigerella immaculata).
Thysanoptera (Thysanura), for example, silverfish (Lepisma saccharina).
Collembola (Collembola), for example, arms Onychiurus arcticus (Onychiurus armatus).
Orthoptera (Orthoptera), for example, family Xi (Acheta domesticus), mqb category category kind
(Gryllotalpa spp.), Asiatic migratory locust (Locusta migratoriamigrator ioides), black locust category kind (
Melanopluss pp.), desert locust (Schistocercagregaria).
Blattaria (Blattaria), for example, oriental cockroach (Blattaorientalis), American cockroach
(Periplaneta americana), leucophaea maderae (Leucophaea maderae), Groton bug (Blattella
germanica) 。
Dermaptera (Dermaptera), for example, European earwig (Forficula auricularia).
Isoptera (lsoptera), for example, Reticulitermes kind (Reticulitermes spp.).
Nematoda（(Nematoda)）Representative biology have and form nematode, stem eelworm and leaf selected from root-knot nematode, cyst
The nematode of nematode.It is preferred that the soybean cyst nematode Heterodera glycines of following nematode（Heterodera）, globodera rostochiensis（golbodera
rostochiensis）, Meloidogyne incognita（meloidogyne incognita）Deng, lance line mesh（dorylaimida）In have,
Minute hand Turbatrix（longidorus sp.）Deng.
The Pesticidal combination of the present invention has prominent effect for anti-eliminate aphis with red spider.
All plants and plant parts can all be handled according to the present invention.The implication of plant herein is interpreted as all plants
Thing and plant population, if desired for unwanted wild plant or crop plants (including naturally occurring crop plants).Crop
Plant is that by conventional breeding and method for optimizing or by biotechnology and genetic engineering method or can pass through these methods
The plant that obtains of combination, the plant includes genetically modified plants, also including that can be weighed (plant by plant breeder
Breeders'rights) the plant variety protected or be not protected by it.It is complete that the implication of plant parts is interpreted as the plant
Portion part above and below the ground and organ, such as branch, leaf, Hua Hegen, the example that can be mentioned that is leaf, pin, leaf, stem, dry, flower, son
Entity, fruit and seed, Yi Jigen, stem tuber and rhizome.The plant parts also include harvested material and asexual and generative propagation
Thing, such as transplant, stem tuber, rhizome, sprout and seed.
It is emphasized that the Pesticidal combination of the present invention is used for effect particularly advantageous during such as following plant：Cereal is planted
Thing such as wheat, oat, barley, spelt (spelt), triticale and rye, and it is corn, jowar He Li, rice, sweet
Sugarcane, soybean, sunflower, potato, cotton, rape (oil seed rape), canola (canola), tobacco, sweet tea
Dish, fodder beet, asparagus, hops and fruit bearing plant (including the operatic circle such as apple and pears, drupe for example peach, honey peach, cherry, plum,
Apricot, cedra fruits for example orange, grape cypress, bitter orange, twist Lu, cumquat, citrus and Sa Mo tangerines, nut for example pistachio, almond,
Walnut and pecan, tropical fruit (tree) such as mango, papaya, pineapple, nipa palm and banana, and grape) and vegetables (including leaf vegetables
Class such as hare's-lettuce, corn salad, fennel, Leaf lettuce, celery lettuce, Swiss chard, spinach and salad with witloof, wild cabbage such as cauliflower,
Broccoli, Chinese leaf, Brassica oleracea (L.) convar. acephalavar. sabellicaL. (wrinkle leaves
Wild cabbage, collard), kohlrabi, brussels sprout, red cabbage, white cabbage and savoy, fruit vegetables such as eggplant, Huang
Melon, capsicum, edible squash, tomato, bush pumpkin and corn, root vegetables such as celeriac, rape, carrot include yellow product
Kind, wild radish class include Raphanus sativus var. niger and Raphanus sativus var.radicula,
Beet, celery, legume such as pea and soybean, and allium vegetables such as leek and onion).
According to processing of the Pesticidal combination of the present invention to plant and plant parts, directly carried out by conventional treatment method
Or handle its environment, habitat or storage area to carry out, the conventional treatment method for example immersion liquid, spraying, evaporation, atomizing,
Broadcast sowing, smear.
Plant site is soaked with fluid composition or the effective of solid form is handled into mesh into the method for the present invention
Useful organisms, or the compositions-treated object noxious livings with the present invention are marked, can directly be carried out by usual processing method,
Or carried out by acting on its environment, habitat or storage areas, the generally processing method such as passes through pouring（Dipping）, drop
Fill, spray, evaporating, being atomized, broadcasting sowing, dusting, foaming, the mode such as coating are applied to the blade of plant（Foliage applying）, can adjust
The frequency and dosage applied are saved, is adapted it to by the degree of the harmful organism infestation.
The soil of described plant or cultivation medium are to refer to make farming when being implemented by the application method of the present invention
The supporter that thing is taken root, grown, such as：Soil, water etc., specific raw material can use such as sand, float stone, vermiculite, silicon
Diatomaceous earth, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc..
The method of medicament is applied into soil, such as liquid preparation is diluted in water or do not diluted and is directly applied to plant
The methods of in the root of body or the rice seedling bed of seedling, side granule being disseminated in the root of plant or the rice seedling bed of seedling
Method has the method that pulvis, water dispersible granules etc. are sprayed in soil prior to seeding and integrally mixed with soil, before sowing or plants
It will be sprayed on before kind plant after pulvis, water-dispersible grain dilution agent in implantation hole, seed furrow, in method sowed etc..
The present invention composition be also suitable for protect plant propagating materials such as seed, fruit, stem tuber or kernel or
Plant cutting is not encroached on by harmful organism particularly insect and acarid.Can before administration with the compositions-treated propagating materials,
Such as dress seed prior to seeding.Also by soaking kernel in fluid composition or kernel can be coated with solid composite, by activity
Composition is applied in benevolence（Coating）., also can will when propagating materials is applied into for example seed is broadcast in ditch in seeding process
Said composition is applied to application site.These processing methods to plant propagation material and the plant propagation material that is processed as are all
It is further subject matter of the present invention.
On the other hand, processing of the invention can also produce following super additive effect：Improve plant growth, improve to high temperature
Or low temperature tolerance, improve to arid or to the tolerance of water or soil salt content, improve Flowering quality, make harvesting simpler
Just, accelerate ripe, raising harvesting yield, improve the quality of harvested products and/or improve its nutritive value, improve harvested products
Bin stability and/or its processing characteristics.
It is common and favourable that the Pesticidal combination of the present invention is generally applied with following dosage：
- for leaf portion processing：0.1-10000 g/ha, preferably 10-1000 g/ha, more preferably 20-300 g/ha；For
For dipping or administration of instiling, the dosage can also even reduce, particularly when using inert base such as asbestos or perlite
Shi Shi；
- for seed treatment：2-200g/100kg seeds, preferably 3-150g/100kg seeds；
- for soil treatment：0.1-10000 g/ha, preferably 1-5000 g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to actual feelings when reality is applied
Condition and needs, rate of application is adjusted especially in accordance with the property and insect pest situation of pending plant or crop.
The Pesticidal combination of the present invention includes separating, sequentially or simultaneously applies the first active component etoxazole and the second activity
Composition.
It should be pointed out that the present invention any embodiment or embodiment any technical characteristic can independently with this
Any other embodiment of invention is combined with each other.That is, one or more technologies of any embodiment of the present invention
Feature can all reconfigure with any other technical characteristic.Thus the technical characteristic that technical characteristic is reconfigured and formed is disclosed in
Herein, as especially being recorded herein it.
The benefit that the present invention is compounded by both has at following 5 points：
A, the insecticidal activity exceedes active sum when described two reactive compounds are each applied；This to optimize institute
It is possibly realized with the amount of reactive compound；
B, both are mixed, solve the problems, such as lasting period and quick-acting, so as to reduce times for spraying, reduce manually into
This；
C, the generation of resistance has been delayed：Both mechanisms of action and the mode of action are entirely different, have after combination tag, stomach
Poison, ovicidal and the effect for reducing spawning rate and incubation rate, so that insect is more easy to be killed, so as to delay the generation of resistance；
D, the preventing and treating spectrum of the first active component etoxazole has been expanded, the second active component pyridaphethione is to the fruit tree mites same period
The aphid of generation has preferable prevention effect, after the first active ingredient combinations, is endangered while effectively preventing and treating red spider, aphid
Evil；
E, it is short to solve the pyridaphethione lasting period, is also easy to produce drug-fast problem.
Embodiment
Below with reference to embodiment, the invention will be further elaborated：
Example of formulations
The missible oil of embodiment 1
Said components are mixed to the liquid of transparent and homogeneous, that is, obtain the cream preparation of the present invention.
The wettable powder of embodiment 2
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention
The aqueous emulsion of embodiment 3
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare
Aqueous phase；Under high velocity agitation, it is oil phase is mixed with water, the aqueous emulsion of the present invention is made.
The water dispersible granules of embodiment 4
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow powder
Wettable powder is broken into, adds a certain amount of water mixing extruder grain.The water-dispersible grain of the present invention is obtained after drying and sieving
Agent.
The microemulsion of embodiment 5
Said components are mixed to the liquid of transparent and homogeneous, that is, obtain the microemulsion of the present invention.
The wettable powder of embodiment 6
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention.
The suspension emulsion of embodiment 7
Second active component pyridaphethione is dissolved in SOLVESSO TMIn 200, ethoxylated castor oil is added, obtains breast
Oil；By the first active component, AEO sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans,
The above-mentioned each component such as bentonite, glycerine, water mixes in proportion, and through being sanded, is prepared into suspending agent.The first activity will be contained
The oil phase of composition etoxazole is added in the suspending agent containing the second active component pyridaphethione, obtains suspension emulsion.
The aqueous emulsion of embodiment 8
Oil phase：
Aqueous phase：
First active component etoxazole and the second active component pyridaphethione are dissolved in methyl oleate, add polyphenyl second
Alkene obtains oil phase；Aqueous phase is obtained according to the component in formula is well mixed；Oil phase addition aqueous phase is obtained into aqueous emulsion under agitation.
The wettable powder of embodiment 9
Combinations thereof is mixed in proportion, and ground, crushes, is prepared into wettable powder.
The coated granule of embodiment 10
In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol.In this way
Dust-free coated granules agent can be obtained.
The wettable powder of embodiment 11
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
Embodiment 12 extrudes granule
Active component is mixed and ground with auxiliary agent, mixture is moistened with water.The mixture is extruded, then in air stream
Middle drying.
The suspension emulsion of embodiment 13
Second active component pyridaphethione is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, obtains breast
Oil；By the first active component etoxazole, AEO sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE,
The above-mentioned each component such as xanthans, bentonite, glycerine, water mixes in proportion, and through being sanded, is prepared into suspending agent.It will contain
The oil phase of second active component pyridaphethione is added in the suspending agent containing the first active component etoxazole, obtains suspension emulsion.
The suspension emulsion of embodiment 14
Second active component pyridaphethione is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, is contained
Second active component pyridaphethione missible oil；By the first active component etoxazole, AEO sulfosuccinic acid monoesters
The above-mentioned each component such as disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, water mixes in proportion, and passes through
It is sanded, is prepared into suspending agent.Oil phase containing the second active component pyridaphethione is added to containing the first active component etoxazole
In suspending agent, suspension emulsion is obtained.
The suspension emulsion of embodiment 15
Second active component pyridaphethione is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, is contained
Second active component missible oil；First active component etoxazole, AEO sulfosuccinic acid monoesters disodium is modified
The above-mentioned each component such as calcium lignosulfonate, xanthans, bentonite, glycerine, water mixes in proportion, and through being sanded, prepares
Into suspending agent.
Oil phase containing the second active component pyridaphethione is added in the suspending agent containing the first active component etoxazole, obtained
To suspended emulsion.
The missible oil of embodiment 16
Said components are mixed to the liquid of transparent and homogeneous, that is, obtain the missible oil of the present invention.
The microcapsule suspension-suspendinagent agent of embodiment 17
By poly methylene poly phenyl poly isocyanate（PAPI）, the second active component pyridaphethione and SOLVESSOTM200
The oil phase of formation, which adds, contains ATLOXTMIn 4913 aqueous solution, emulsion is formed.Then heat and be incubated 50oAdd and urge under C
Agent is reacted 2 hours.The microcapsules containing the second active component pyridaphethione is obtained after cooling.
ATLOX TM4913, dispersant LFH, defoamer, urea, the first active component etoxazole and water mix in proportion
Uniformly, and through being sanded, it is prepared into suspending agent.
The obtained microcapsules containing the second active component pyridaphethione is added to the aqueous suspension of the first active component etoxazole
In agent, the microcapsule suspension-suspendinagent agent of the present invention is uniformly mixing to obtain.
The suspension seed-coating agent of embodiment 18
Second active component pyridaphethione is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, is contained
The missible oil of second active component pyridaphethione；By the first active component etoxazole, AEO sulfosuccinic acid list
The above-mentioned each component such as ester disodium, MODIFIED LIGNOSULPHONATE, xanthans, glycerine, polyvinylpyrrolidone, water mixes in proportion
Uniformly, and through being sanded, it is prepared into suspending agent.
Oil phase containing the second active component pyridaphethione is added to the suspension seed-coating agent containing the first active component etoxazole
In, obtain the suspension seed-coating agent of the present invention.
The smoke agent of embodiment 19
First by antifreezing agent propane diols, diluent SOLVESSOTM100 mixing, stir the first active component second of lower addition
Mite azoles and the second active component pyridaphethione；Surfactant is added thereto, passes through a disintegrating apparatus colloid under agitation
Mill is crushed, by by the suspension after colloid mill, then by a micronizer.Move in circles to solids
Untill particle diameter≤2um.
The wettable powder of embodiment 20
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention.
The active ingredient combination of embodiment 21
First active component etoxazole and the second active component pyridaphethione are uniformly mixed according to a ratio.
Proportioning in above example is weight per distribution ratio.
Embodiment
Crop protection products are made in different combination of active principles, be develop and develop at present new crop protection products with
And prevent and treat a kind of effective and quick way of agriculturally resistant insect.After the pestsides synthesis of different cultivars, three are typically exhibited
Kind type of action：Summation action, synergistic effect and antagonism.But it is specially which kind of effect, it is unpredictable, only by a large amount of
Experiment just can know that.Compound synergic is formulated well, due to significantly improving actual prevention effect, reduces the use of agricultural chemicals
Amount, it is the important means of integrated control disease so as to greatly delay the generation speed of pest resistance to insecticide.
Inventor by substantial amounts of screening test, the different ratio of etoxazole and pyridaphethione has been carried out lot of experiments with
And effectiveness analysis, finding in certain ratio range, resulting Pesticidal combination has gain effect, rather than just
The simple addition of two kinds of medicaments, is specifically illustrated with implementation below.
In embodiments of the present invention by the way of Toxicity Determination and insecticidal test are combined, pass through interior first
Toxicity test, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient（CTC）, CTC<80 be to resist effect short of money, 80≤CTC
≤ 120 be summation action, and CTC ＞ 120 are synergistic effect, carry out insecticidal test again on this basis.
Calculation formula is as follows：
Borer population * 100 living before the death rate (%)=(borer population living after borer population-medicine living before medicine)/medicine
Corrected mortality (%)=(the treatment group death rate-control group death rate)/(the 100- control groups death rate) * 100
Probit value (y) will be converted into for examination insect corrected mortality, concentration for the treatment of (μ g/ml) is converted into logarithm value (x),
Concentration LC in suppressing is calculated with least square method50, then according to the abundant method calculating co-toxicity coefficients (CTC) of Sun Yun.Calculation formula it is following (with
Spirodiclofen is standard agent, 100) its toxicity index is：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
In theoretical toxicity index (TTI)=A medicaments ATI × mixture in A percentage composition+B medicaments ATI × mixture B hundred
Divide content
Co-toxicity coefficient (CTC)=(mixture ATI/ mixture TTI) × 100
Experiment 1：To the Toxicity Determination of Tetranychus urticae
Experiment is with reference to pesticide indoor bioassay test rule（Agricultural industry criteria NY/T1154.7-2006）With
Formulate pesticide bioactivity evaluation SOP（Insecticide is rolled up）, using infusion process.Kidney bean leaf blade band handle is cut, inserted in
The peace of water is added to cut open in bottle.Connect a number of into mite.After 24h is laid eggs into mite, mite is removed into, by the leaf with enough ovum
Piece is dipped in 10s in decoction, sucks unnecessary decoction with blotting paper rapidly, and blade is replaced in into peace cuts open in bottle, naturally dry.It is placed in
Cultivated in observation ward.Experiment is repeated 4 times, and sets blank control, is investigated after all hatchings are compareed.Can not incubate during investigation
The young mite that changes and can not normally creep is considered as dead worm.
Table 1：
As known from Table 1, the proportioning of preventing and treating Tetranychus urticae, etoxazole and pyridaphethione is 1:100-100:When in 1 scope,
Co-toxicity coefficient is all higher than 120, illustrates that both show as gain effect, the especially ratio when both at mixture in the range of this
Example is 1:When 5, gain effect is especially prominent.
Experiment 2：To the Toxicity Determination result of panonychus citri
Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the decoction prepared
Take out, naturally dry, be put into insect box after middle immersion 5s, then connect for examination larva, raise under the conditions of 25 DEG C, often handle
3 repetitions, it is 20 often to repeat test worm number used, while sets blank control, checks dead borer population in 72h, calculates the death rate and school
The positive death rate, try to achieve virulence regression equation and calculate LC50 values.If compareing the death rate is more than 10%, it is considered as invalid experiment.
Table 2：
As known from Table 2, the proportioning of preventing and treating panonychus citri, etoxazole and pyridaphethione is 1:100-100:In 1 scope
When, co-toxicity coefficient is all higher than 120, illustrates that both show as gain effect at mixture in the range of this, especially when both
Ratio 1:When 10, gain effect is especially prominent.
Experiment 3：
When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is administered alone, deposit
In the desinsection and acaricidal action of collaboration.So-called " Colby can be used in the predictive role of the particular combination of two kinds of reactive compounds
Formula " is (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of
Herbicide Combinations ", Weeds 1967,15,20-22) it is calculated as below:If
X is when the use of dosage being m g/ha or kill rate during reactive compound A that concentration is m ppm, is expressed as accounting for
The percentage of untreated control,
Y is when the use of dosage being n g/ha or kill rate during reactive compound B that concentration is nppm, is expressed as accounting for not
The percentage of control is handled,
E is when the use of dosage being m and n g/ha or kill during reactive compound A and B that concentration is m and n ppm
Rate, it is expressed as accounting for the percentage of untreated control,
So
If actual desinsection fatal rate exceedes calculated value, the lethal effect of composition is super plus sum, that is, association be present
Same-action.In this case, the kill rate actually observed must be over the expection kill rate value calculated using above-mentioned formula
(E) value.
Prevent and treat the test of pesticide effectiveness of panonychus citri
Experiment is carried out as follows：Test site is Zhejiang Jiaxing, and the time is at the beginning of 5 months.Tested using potted plant citrus, seedling age 3
Year.Every plant of inoculation Panonychus citri is female into mite 200 before spray.Spray processing in 2 days after inoculation.It is defined by squirting leave dual sides, often
3 plants of citrus seedlings of individual processing.25 blades are adopted within 3 days, 10 days, 20 days and 30 days after medicine in the indoor binocular investigation blade of experiment
On into mite number, calculate Revision insect recluced rate and prevention effect, formula be as follows：
Specific test method and data are as follows：
Mite mouth decline rate（%）=（Borer population living after borer population-treatment region medicine living before treatment region medicine）Borer population * living before/treatment region medicine
100
Prevention effect（%）=（Treatment region mite mouth decline rate ± check plot mite mouth decline rate）/（100 ± check plot mite mouth subtracts
Move back rate）*100
Table 3：
In terms of the result of the test of table 3, the preventive effect observed after the compounding of etoxazole and pyridaphethione is anti-apparently higher than calculating
Effect, shows obvious synergistic effect.Etoxazole and pyridaphethione compounding, which combine, knocks down activity and extends the preventing and treating time, reaches
The effect of snap action and long-acting.
Experiment two：Prevent and treat the test of pesticide effectiveness of citrus cotten aphid
Experiment is carried out as follows：Test site is Zhejiang Jiaxing, and the time is at the beginning of 3 months.Tested using potted plant citrus, seedling age 3
Year.Every plant of inoculation cotten aphid adult 200 before spray.Spray processing in 2 days after inoculation.It is defined by squirting leave dual sides, each place
Manage 3 plants of citrus seedlings.6 days after medicine, adopt 25 blades in test on indoor binocular investigation blade into borer population, calculate insect population
Decline rate and prevention effect, formula are as follows：
Specific test method and data are as follows：
Revision insect recluced rate（%）=（Borer population living after borer population-treatment region medicine living before treatment region medicine）Borer population * living before/treatment region medicine
100
Prevention effect（%）=（Treatment region Revision insect recluced rate ± check plot Revision insect recluced rate）/（100 ± check plot insect population subtracts
Move back rate）*100
Table 4：
In terms of the result of the test of table 4, the preventive effect observed after the compounding of etoxazole and pyridaphethione is anti-apparently higher than calculating
Effect, shows obvious synergistic effect.
Claims (13)
- A kind of 1. method prevented or control harmful organism, it is characterised in that：A kind of Pesticidal combination is used for the useful plant of target Thing, object noxious livings or its environment, the propagating materials of target useful plant, the Pesticidal combination active component are lived by first Property composition etoxazole and the second active component pyridaphethione composition, the first active component etoxazole and the second active component are rattled away The weight proportion of piperazine sulphur phosphorus is 1:100 to 100:1, the harmful organism is Tetranychus urticae, panonychus citri, cotten aphid.
- 2. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component The weight proportion of pyridaphethione is 1:50 to 50:1.
- 3. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component The weight proportion of pyridaphethione is 1:25 to 25:1.
- 4. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component The weight proportion of pyridaphethione is 1:10 to 10:1.
- 5. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component Pyridaphethione accounts for the 5%-90% of the composition by weight altogether.
- 6. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component Pyridaphethione accounts for the 10%-80% of the composition by weight altogether.
- 7. according to the method for claim 1, it is characterised in that：The first active component etoxazole and the second active component Pyridaphethione accounts for the 20%-60% of the composition by weight altogether.
- 8. according to the method for claim 1, it is characterised in that：The Pesticidal combination also comprising surfactant and/or Extender.
- 9. according to the method for claim 1, it is characterised in that：The Pesticidal combination, formulation are missible oil, suspending agent, kind Clothing agent, water dispersible granules, wettable powder, suspension emulsion, extrusion granule, coated granule, smoke agent, aqueous emulsion, micro-capsule hang Floating agent, ultra low volume liquids, microcapsule suspension-suspendinagent agent.
- 10. according to the method for claim 1, it is characterised in that：The plant propagation material be seedling, rhizome, garden seedling, Cutting or seed.
- 11. according to the method for claim 1, it is characterised in that：Including separating, sequentially or simultaneously applying the first active component Etoxazole, the second active component pyridaphethione.
- 12. according to the method for claim 1, it is characterised in that：Wherein described first active component etoxazole and second is lived Property composition pyridaphethione is individually the form of formulated composition.
- 13. according to the method for claim 1, it is characterised in that：Including make the useful crop of target, object noxious livings or its Environment, the propagating materials of target useful plant contact with the Pesticidal combination described in claim 1.
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| CN103271078A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-profenofos pesticide composition |
| CN103271081A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-triazophos pesticide composition |
| CN103651544A (en) * | 2012-09-19 | 2014-03-26 | 青岛星牌作物科学有限公司 | Acaricidal composition of profenofos and etoxazole and formula instance |
| CN104106593A (en) * | 2014-06-12 | 2014-10-22 | 广东中迅农科股份有限公司 | Insecticide acaricidal composition containing xiaochongthion and etoxazole |
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| WO2005053407A1 (en) * | 2003-12-01 | 2005-06-16 | Syngenta Participations Ag | Pesticidally active combinations |
| CN101779661B (en) * | 2009-12-18 | 2012-11-07 | 陕西美邦农资贸易有限公司 | Compound insecticide prepared from emamectin benzoate and pyridaphethione |
| CN103461376B (en) * | 2013-09-05 | 2015-08-12 | 江苏龙灯化学有限公司 | A kind of agricultural insecticide composition containing fipronil bisamide and pyridaphethione |
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| CN103651544A (en) * | 2012-09-19 | 2014-03-26 | 青岛星牌作物科学有限公司 | Acaricidal composition of profenofos and etoxazole and formula instance |
| CN103271078A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-profenofos pesticide composition |
| CN103271081A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-triazophos pesticide composition |
| CN104106593A (en) * | 2014-06-12 | 2014-10-22 | 广东中迅农科股份有限公司 | Insecticide acaricidal composition containing xiaochongthion and etoxazole |
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