CN105941446A - Compound insecticidal composition containing Lepimectin and chlorfluazuron and application thereof - Google Patents
Compound insecticidal composition containing Lepimectin and chlorfluazuron and application thereof Download PDFInfo
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- CN105941446A CN105941446A CN201610454819.4A CN201610454819A CN105941446A CN 105941446 A CN105941446 A CN 105941446A CN 201610454819 A CN201610454819 A CN 201610454819A CN 105941446 A CN105941446 A CN 105941446A
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- chlorfluazuron
- lepimectin
- pesticide compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The invention discloses a compound insecticidal composition containing Lepimectin and chlorfluazuron and application thereof. In the insecticidal composition, Lepimectin and chlorfluazuron are insecticidal active ingredients, wherein the weight ratio of the Lepimectin to chlorfluazuron is (0.1-80):(0.5-80). The insecticidal composition can generate a relatively strong synergistic effect, overcomes and delays the pest resistance to insecticide, realizes high insecticidal speed and long duration and reduces the application cost while the control effect is obviously better than that of single dosage. The compound insecticidal composition disclosed by the invention can control the lepidoptera pests on crops and particularly can be used for controlling helicoverpa armigera and borer while the effect is obviously better than that of single dosage.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Lepimectin, is the derivant being total to mibemycin (milbemycin) A3/A4 that company finds by Japan three, in
Within 2006, use in Japan's registration.As novel pesticide for the vegetable such as Caulis et Folium Brassicae capitatae, Fructus Lycopersici esculenti, Citrus, Fructus Fragariae Ananssae and Fructus Vitis viniferae and
Fruit, the main preventing and treating insect such as Lepidoptera and Semiptera.This medical instrument has insecticidal activity high, and dosage is few, to person poultry safety,
Free from environmental pollution, specificity is strong, does not injure natural enemy, is not easy to produce the features such as resistance, can take turns with avermectins
Change use, in case avilamycin produces resistance.Therefore it is referred to as the most promising wide spectrum, no interactions efficient, novel at present
One of insecticide of resistance.Its mechanism of action is the permeability that can increase polypide nerve synapse caudacoria to C1-, thus blocks god
Through the transmission of signal, insecticide neural paralysis is finally made to cause insect death.
Chlorfluazuron (Chlorfluazuron), chemical name: 1-(3,5-bis-chloro-4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)
Phenyl)-3-(2,6-difluoro benzoyl) urea, structural formula is:
Chlorfluazuron is a kind of widely used growth regulator, has stomach toxicity, action of contace poison.The mechanism of action is suppression chitin
Matter synthesizes, and hinders insecticide normally to cast off a skin, makes the developmental disorder of the hatching of ovum, larval molting and pupa, and adult eclosion is obstructed.Medicine
Effect height, speed of action is relatively slow, to many Species of Lepidopterous Insect Pests, and Orthoptera, coleoptera, Hymenoptera, Diptera isoreactivity
Height, but invalid to aphid, leafhopper, plant hopper.
Insecticide variety containing single component often existing defects in pesticide Pest control: use easily produces drug resistance continuously
Property, insecticidal spectrum is narrow, it is impossible to provide comprehensively protection for crop, and peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing Lepimectin with the compound pesticide compositions of chlorfluazuron, this Pesticidal combination
It it is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination to prevent and treat on the insecticidal materials of resistance lepidoptera pest in preparation
Application, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing Lepimectin with the compound pesticide compositions of chlorfluazuron, this compound pesticide compositions with Lepimectin and
Chlorfluazuron is principle active component, and wherein, the weight ratio of Lepimectin and chlorfluazuron is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of Lepimectin (A) and chlorfluazuron (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.
In some preferred technical schemes: Lepimectin and chlorfluazuron can 1:30,1:29,1:28,1:27,1:26,
1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、
1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、
8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、
23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、
These ratios of 5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component Lepimectin and chlorfluazuron, it is possible to use or preparation time to
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, Lepimectin and both chlorfluazurons weight in this compound pesticide compositions
Percentage composition is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with Lepimectin and chlorfluazuron as active component or principle active component, and pesticide
Auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettability
Powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to DBSA
Calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned can
The excipient being applied to the present invention is also not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the lepidoptera pest of resistance to planthopper and snout moths larva etc.
There is good preventive effect；And suppress insect that the Drug resistance of unitary agent (Lepimectin or chlorfluazuron are arbitrary) is produced.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially anti-in preparation
Control the application effect on bollworm or snout moths larva insecticidal materials notable.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism lepidoptera pest is such as
Bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) hold concurrently
Have immediate effect and long-acting；(5) with Lepimectin compared with chlorfluazuron single dose, produce and use cost reduces；(6) suppression
The resistance of pesticide is strengthened by lepidoptera pest, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80gLepimectin, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2gLepimectin, 80g chlorfluazuron, lignin 10g, Negel 2g, add to 100g with Kaolin,
Being mixed in super micron mill by above raw material, forming principle active component weight percentage is 82%
Lepimectin chlorfluazuron wettable powder.
Embodiment 3:
Weigh 60gLepimectin, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g,
Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed main effective
Ingredients Weight percentage composition is the Lepimectin 5 percent of hexaflumuron emulsifiable concentrate of 62%.
Embodiment 4:
Weigh 2gLepimectin, 60g chlorfluazuron, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water with water
Dissolving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect,
And continue to shear 10～30 minutes, form the Lepimectin chlorfluazuron water that principle active component weight percentage is 62%
Emulsion.
Embodiment 5:
Weigh 40gLepimectin, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, cosolvent with water
Mix and blend forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight
Amount percentage composition is the Lepimectin chlorfluazuron microemulsion of 42%.
Embodiment 6:
Weigh 2gLepimectin, 40g chlorfluazuron, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The Lepimectin 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20gLepimectin, 2g chlorfluazuron, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof
4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect lower form the Lepimectin chlorfluazuron suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2gLepimectin, 20g chlorfluazuron, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 22%.
Embodiment 9:
Weigh 10gLepimectin, 5g chlorfluazuron, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, form main effectively one-tenth by above raw material by the method for water dispersion granule
The Lepimectin chlorfluazuron water dispersible granules dividing weight percentage to be 15%.
Embodiment 10:
Weigh 10gLepimectin, 2g chlorfluazuron, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 12%.
Embodiment 11:
Weigh 10gLepimectin, 10g chlorfluazuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh Lepimectin and chlorfluazuron 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the Lepimectin 5 percent of hexaflumuron emulsifiable concentrate of 30%.Wherein Lepimectin and chlorfluazuron specifically than
Example is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes repetition 3
Secondary, every concentration process 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1Lepimectin, chlorfluazuron and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after Lepimectin and chlorfluazuron mixture, antagonism bollworm are had potentiation, listed in table
Proportioning co-toxicity coefficient be both greater than 120, therefore Lepimectin and chlorfluazuron mixture have significant synergies.
Weigh Lepimectin, chlorfluazuron uses conventional formulation method to be configured to principle active component weight percent by different proportion
Content is the Lepimectin 5 percent of hexaflumuron emulsifiable concentrate of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes repetition
3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50
Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2Lepimectin, chlorfluazuron and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation after Lepimectin and chlorfluazuron mixture to rice-stem borer, listed by table
Proportioning co-toxicity coefficient is all much larger than 120, and therefore Lepimectin and chlorfluazuron mixture have significant synergies.
2, field control effectiveness test
Use embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament be 5% chlorfluazuron EC and
10%LepimectinEC (cream), is diluted according to the extension rate in form 3, looks into 3 days after medicine, 7 days, and 14
It result, result is shown in Table 3:
Table 3 Lepimectin-chlorfluazuron compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: with chlorfluazuron built agent, bollworm and rice-stem borer are had aobvious by Lepimectin
The synergistic insecticidal action write；Field control effectiveness test also indicates that all of built agent of the present invention is the most aobvious to bollworm insecticidal effect equally
Write the effect higher than corresponding single dose pesticide.
Claims (10)
1. containing Lepimectin and a compound pesticide compositions for chlorfluazuron, it is characterized in that this compound pesticide compositions with
Lepimectin and chlorfluazuron are active insecticidal components, and wherein, the weight ratio of Lepimectin and chlorfluazuron is 0.1～80:
0.5～80.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that described
Lepimectin and the weight ratio of chlorfluazuron be 1～60:1～60.
The most according to claim 2 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that described
Lepimectin and the weight ratio of chlorfluazuron be 1～40:1～40.
The most according to claim 3 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that described
Lepimectin and the weight ratio of chlorfluazuron be 1～30:1～30.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that
Lepimectin and both chlorfluazurons weight percentage in this compound pesticide compositions are 3%～80%.
The most according to claim 5 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that
Lepimectin and both chlorfluazurons weight percentage in this compound pesticide compositions are 5%～55%.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that this is multiple
As active insecticidal components and insecticides adjuvant is configured on pesticide the agent of permission with chlorfluazuron with Lepimectin to close Pesticidal combination
Type.
The most according to claim 7 containing Lepimectin with the compound pesticide compositions of chlorfluazuron, it is characterized in that described
Dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing Lepimectin and chlorfluazuron described in claim 1 prevents and treats resistance squama wing in preparation
Application on the insecticidal materials of mesh insect.
Compound pesticide compositions containing Lepimectin and chlorfluazuron the most according to claim 9 is in preparation preventing and treating cotton
Application on the insecticidal materials of earworm or snout moths larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454819.4A CN105941446A (en) | 2016-06-21 | 2016-06-21 | Compound insecticidal composition containing Lepimectin and chlorfluazuron and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610454819.4A CN105941446A (en) | 2016-06-21 | 2016-06-21 | Compound insecticidal composition containing Lepimectin and chlorfluazuron and application thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528140A (en) * | 2003-10-10 | 2004-09-15 | 江苏省农业科学院 | Efficient low-toxicity compound insecticide acaricide |
| CN1860881A (en) * | 2006-06-19 | 2006-11-15 | 江苏省农业科学院 | Composite pesticide contg. abamectin and chlorfluazuron |
| CN102550581A (en) * | 2012-01-13 | 2012-07-11 | 河南金田地农化有限责任公司 | Ultralow-volume concentrate containing chlorfluazuron |
| US20150150246A1 (en) * | 2013-12-03 | 2015-06-04 | Mclaughlin Gormley King Company | Use of insect growth regulators in cockroach control |
-
2016
- 2016-06-21 CN CN201610454819.4A patent/CN105941446A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528140A (en) * | 2003-10-10 | 2004-09-15 | 江苏省农业科学院 | Efficient low-toxicity compound insecticide acaricide |
| CN1860881A (en) * | 2006-06-19 | 2006-11-15 | 江苏省农业科学院 | Composite pesticide contg. abamectin and chlorfluazuron |
| CN102550581A (en) * | 2012-01-13 | 2012-07-11 | 河南金田地农化有限责任公司 | Ultralow-volume concentrate containing chlorfluazuron |
| US20150150246A1 (en) * | 2013-12-03 | 2015-06-04 | Mclaughlin Gormley King Company | Use of insect growth regulators in cockroach control |
Non-Patent Citations (1)
| Title |
|---|
| 胡萍 等: "生物杀虫剂—lepimectin", 《世界农药》 * |
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Application publication date: 20160921 |