CN107006471B - The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide - Google Patents

The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide Download PDF

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Publication number
CN107006471B
CN107006471B CN201710107922.6A CN201710107922A CN107006471B CN 107006471 B CN107006471 B CN 107006471B CN 201710107922 A CN201710107922 A CN 201710107922A CN 107006471 B CN107006471 B CN 107006471B
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Prior art keywords
methoxyfenozide
pesticide compositions
compound pesticide
ring
ring tebufenozide
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CN201710107922.6A
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CN107006471A (en
Inventor
高瑞花
邢刚
石振龙
程清云
孙会杰
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system

Abstract

The invention discloses the compound pesticide compositions and application thereof of a kind of containing chromafenozide and methoxyfenozide, and the Pesticidal combination is using ring tebufenozide and methoxyfenozide as active insecticidal components, wherein ring tebufenozide and the weight ratio of methoxyfenozide are 50:1~1:50.The Pesticidal combination can generate higher synergistic function, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduce drug cost, and control effect is apparently higher than the use of its single dose.The present invention can prevent the lepidoptera pest occurred on crops, be used especially for prevention bollworm, snout moth's larva, with obvious effects to be used higher than its single dose.

Description

The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide
Technical field
The invention belongs to pesticide fields, and in particular to a kind of using ring tebufenozide and methoxyfenozide as principle active component Pesticidal combination and its application.
Background technology
Ring tebufenozide (Chromafenozide), chemical name:N- tertiary butyls-N'- (3- methoxyl group -2- toluyls Base) -3,5- dimethylbenzohydrazides.For bishydrazide insecticide, inhibit feed after pests in a few houres, while causing to do harm to Worm casts off a skin in advance leads to death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, but also to arthropod class, catch Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
Methoxyfenozide (Methoxyfenozide), molecular formula:C22H28N2O3.Structural formula is:
Methoxyfenozide is 2nd generation bishydrazide insect growth regulator, IGR, has height selection desinsection to lepidoptera pest Activity mainly causes to imitate without osmosis and bast systemic activity by stomach poison function, at the same also have it is certain tag and Ovicidal activity.As other bishydrazide insecticides such as ring tebufenozide, chlorine tebufenozide and tebufenozide, methoxyfenozide is also to slough off Skin Hormone agonists, it causes lepidopterous larvae to stop feeding, accelerates husking process, makes pest before maturation due to casting off a skin ahead of time It is lethal.
Insecticide variety containing single component often existing defects in pesticide control of insect:Continuous use easy tos produce anti- Pharmacological property, insecticidal spectrum is narrow, and comprehensive protection, peasant's drug cost height etc. cannot be provided for crop.It is by two kinds or two or more The combination of various active constituents can overcome disadvantages mentioned above to a certain extent.Two kinds with synergistic effect or two or more work Property ingredient combination mixture, preventive effect can be improved, with reducing active ingredient dosage, it is cost-effective, slow down pest resistance occur, And prevention spectrum can be expanded, it plays that more worms are simultaneous to be controlled, reduces the use cost of peasant.
Invention content
The object of the present invention is to provide the compound pesticide compositions of a kind of containing chromafenozide and methoxyfenozide, the desinsection groups It is the multifunctional insecticide composition for preventing lepidoptera pest to close object.
It is a further object of the present invention to provide the Pesticidal combinations in the insecticidal materials for preparing prevention resistance lepidoptera pest On application, especially prepare prevention bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of compound pesticide compositions of containing chromafenozide and methoxyfenozide, the compound pesticide compositions are with ring tebufenozide It is principle active component with methoxyfenozide, wherein ring tebufenozide and the weight ratio of methoxyfenozide are 50:1~1:50.
In this compound pesticide compositions, the weight ratio of ring tebufenozide (A) and methoxyfenozide (B) is preferably 20:1~1: 30, further preferably 5:1~1:5, ring tebufenozide (A) and methoxyfenozide (B) in some most preferred technical solutions Weight ratio is 50:Isosorbide-5-Nitrae 0:1,30:1,20:1,10:1,5:1,2:1,1:1,1:5,1:10,1:20,1:30,1:40,1:50 these It is selected in range.
This compound pesticide compositions can contain only active constituent ring tebufenozide and methoxyfenozide, can also use or prepare When other components are added into active constituent, the effective ingredient in the Pesticidal combination can be present in combination with enhancing effective amount In object.
In compound pesticide compositions of the present invention, both ring tebufenozide and methoxyfenozide are in the compound pesticide compositions Weight percentage be 3%~80%.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention using ring tebufenozide and methoxyfenozide as active constituent or principle active component, and Insecticides adjuvant and excipient are the preferred missible oil of the dosage form, suspending agent, wettable at any one dosage form allowed on pesticide Property pulvis, aqueous emulsion, microemulsion or water dispersion granule.
The aforementioned insecticides adjuvant that can be applied to the present invention is not particularly limited, including but not limited to detergent alkylate Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), nonylphenol polyoxyethylene ether etc., it is aforementioned to answer For the present invention excipient be also not particularly limited, including but not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol), Deionized water etc..The above auxiliary agent, excipient and other auxiliary materials can be applied alone or be used in combination.
Compound pesticide compositions of the present invention easy to produce planthopper and snout moth's larva etc. a variety of Semipteras and Lepidoptera of resistance Pest has good preventive effect;And inhibit drug resistance of the pest to single formulation (ring tebufenozide or methoxyfenozide are any) It generates.
Application of the above-mentioned compound pesticide compositions on preparing prevention resistance lepidoptera pest insecticidal materials, is especially making Application effect on standby prevention bollworm or snout moth's larva insecticidal materials is notable.
Beneficial effects of the present invention compared with prior art:(1) compared with single dose, the composition antagonism lepidoptera pest Such as bollworm, snout moth's larva have apparent synergistic function, overcome and delayed pest resistance to insecticide, expand prevention spectrum, desinsection speed Soon, hence it is evident that improve control effect;(2) prevention recruitment, drug cost are reduced;(3) alternative high-toxic pesticide;(4) it has concurrently quick-acting With it is long-acting;(5) with ring tebufenozide compared with methoxyfenozide single dose, production and application cost reduces;(6) inhibit lepidoptera pest Resistance enhancing to pesticide, it is with obvious effects to be used higher than its single dose.
Specific implementation mode
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Indoor test is tested:
Indoor synergy bioassay is carried out using feed plus malicious method, resistant bollworm and rice-stem borer is selected to be done harm to for target Worm, often processing are repeated 3 times, and 60 are handled per concentration, and each medicament antagonism bollworm and rice-stem borer are calculated with niqueMin method Toxicity regression equation and lethal concentration of 50 LC50, use LC50Value calculates co-toxicity coefficient by Sun Yunpei's Method, and the specific method is as follows:
Using a certain single dose in mixture as standard agent (generally selecting LC50 juniors), calculated:
Single dose toxicity index=standard agent LC50/ single doses LC50 × 100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture × B single doses proportion in mixture
Value × 100 LC50 of LC50 values/mixture of survey toxicity index=standard single dose
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified:It is antagonism when being less than 80 that mixture, which has synergetic, CTC, when CTC is more than 120, and CTC exists It is summation action between 80-120.
It the results are shown in Table 1,2:
1 ring tebufenozide of table and methoxyfenozide compounding and the toxicity test of single dose antagonism bollworm
As shown in Table 1, ring tebufenozide and methoxyfenozide compounding, co-toxicity coefficient are all higher than 120, show to cooperate with well Synergistic effect.
2 ring tebufenozide of table and methoxyfenozide compounding and single dose are to the toxicity test of striped rice borer
For table 2 it is found that ring tebufenozide and methoxyfenozide compound, co-toxicity coefficient is all higher than 120, shows to cooperate with increasing well Effect acts on.
Field control effectiveness test:
Prevention bollworm and the rice-stem borer test of pesticide effectiveness are carried out to the embodiment 1-12, comparison medicament is 24% methoxy Tebufenozide SC and 5% ring tebufenozide SC, is diluted according to the extension rate in table 3 and 4, looks into 3 days after medicine, 7 days, 14 days As a result, handling result is shown in Table 3 and 4:
Table 3:The field test results of ring tebufenozide-methoxyfenozide compounding antagonism bollworm
Table 4:Field test results of the ring tebufenozide-methoxyfenozide compounding to rice-stem borer
Field efficacy the result shows that, ring tebufenozide methoxyfenozide composition has bollworm and rice-stem borer excellent Good control effect, control effect are better than the effect that single dose kind directly acts on.
Embodiment 1:
Weigh 50g ring tebufenozides, 1g methoxyfenozides, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、 600#1g, 150# solvent naphtha 13g, add water to 100g.In the method input mixing kettle that the above raw material is routinely prepared to aqueous emulsion Mixed at high speed forms the ring tebufenozide methoxyfenozide aqueous emulsion that principle active component weight percentage is 51%.
Embodiment 2:
Weigh 30g ring tebufenozides, 1g methoxyfenozides, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、 600#1g, 150# solvent naphtha 13g, add water to 100g.In the method input mixing kettle that the above raw material is routinely prepared to aqueous emulsion Mixed at high speed forms the ring tebufenozide methoxyfenozide aqueous emulsion that principle active component weight percentage is 31%.
Embodiment 3:
Weigh 20g ring tebufenozides, 1g methoxyfenozides, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.The method that the above raw material is routinely prepared into microemulsion It is mixed in input mixing kettle, forms the ring tebufenozide methoxyfenozide micro emulsion that principle active component weight percentage is 21% Agent.
Embodiment 4:
Weigh 10g ring tebufenozides, 1g methoxyfenozides, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, 150# solvent naphthas are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective The ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 11%.
Embodiment 5:
Weigh 20g ring tebufenozides, 4g methoxyfenozides, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, 150# solvent naphthas are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective The ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 24%.
Embodiment 6:
Weigh 20g ring tebufenozides, 10g methoxyfenozides, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# solvent naphtha are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, formation mainly has Imitate the ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 30%.
Embodiment 7:
Weigh 10g ring tebufenozides, 10g methoxyfenozides, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, 150# solvent naphtha are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, formation mainly has Imitate the ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 20%.
Embodiment 8:
Weigh 4g ring tebufenozides, 20g methoxyfenozides, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# solvent naphthas are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective The ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 24%.
Embodiment 9:
Weigh 1g ring tebufenozides, 10g methoxyfenozides, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# solvent naphthas are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forming system mainly has Imitate the ring tebufenozide methoxyfenozide missible oil that Ingredients Weight percentage composition is 11%.
Embodiment 10:
Weigh 1g ring tebufenozides, 20g methoxyfenozides, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, 150# solvent naphthas are to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, it is main to form preparation The ring tebufenozide methoxyfenozide missible oil that active ingredient weight percentage is 21%.
Embodiment 11:
Weigh 1g ring tebufenozides, 30g methoxyfenozides, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulphur Hydrochlorate 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, are being sanded The ring tebufenozide methoxyfenozide suspending agent that the weight percentage of principle active component is 31% is formed under the action of machine.
Embodiment 12:
Weigh 1g ring tebufenozides, 50g methoxyfenozides, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate The above raw material is formed principle active component by 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g by water dispersible granular agent method The ring tebufenozide methoxyfenozide water dispersion granule that weight percentage is 51%.

Claims (9)

1. the compound pesticide compositions of a kind of containing chromafenozide and methoxyfenozide, it is characterized in that the compound pesticide compositions are with ring Tebufenozide and methoxyfenozide are active insecticidal components, wherein ring tebufenozide and the weight ratio of methoxyfenozide are 50:1~1:5 0。
2. the compound pesticide compositions of containing chromafenozide according to claim 1 and methoxyfenozide, it is characterized in that described Ring tebufenozide and methoxyfenozide weight ratio be 20:1~1:3 0.
3. the compound pesticide compositions of containing chromafenozide according to claim 2 and methoxyfenozide, it is characterized in that described Ring tebufenozide and methoxyfenozide weight ratio be 5:1~1:5 .
4. the compound pesticide compositions of containing chromafenozide according to claim 1 and methoxyfenozide, it is characterized in that ring worm The weight percentage of both hydrazides and methoxyfenozide in the compound pesticide compositions is 3% ~ 80%.
5. the compound pesticide compositions of containing chromafenozide according to claim 4 and methoxyfenozide, it is characterized in that ring worm The weight percentage of both hydrazides and methoxyfenozide in the compound pesticide compositions is 5% ~ 55%.
6. the compound pesticide compositions of containing chromafenozide according to claim 1 and methoxyfenozide, it is characterized in that this is multiple Close what Pesticidal combination was configured to allow on pesticide using ring tebufenozide and methoxyfenozide as active insecticidal components and insecticides adjuvant Dosage form.
7. the compound pesticide compositions of containing chromafenozide according to claim 6 and methoxyfenozide, it is characterized in that described Dosage form is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of containing chromafenozide described in claim 1 and methoxyfenozide are preparing prevention resistance squama wing Application on the insecticidal materials of mesh pest.
9. application according to claim 8, it is characterised in that:The compound pesticide compositions are preparing prevention bollworm Or the application on the insecticidal materials of snout moth's larva.
CN201710107922.6A 2017-02-27 2017-02-27 The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide Active CN107006471B (en)

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IL100643A (en) * 1991-01-25 1996-10-31 Nippon Kayaku Kk Hydrazine derivatives and pesticidal compositions comprising such derivatives as effective component
JP4603679B2 (en) * 1999-12-14 2010-12-22 日本化薬株式会社 Pest control agent
CN1242674C (en) * 2001-07-31 2006-02-22 马韵升 Tebufenozide pesticide composition

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