CN1242674C - Tebufenozide pesticide composition - Google Patents
Tebufenozide pesticide composition Download PDFInfo
- Publication number
- CN1242674C CN1242674C CN 01123751 CN01123751A CN1242674C CN 1242674 C CN1242674 C CN 1242674C CN 01123751 CN01123751 CN 01123751 CN 01123751 A CN01123751 A CN 01123751A CN 1242674 C CN1242674 C CN 1242674C
- Authority
- CN
- China
- Prior art keywords
- worm
- rate
- preventive effect
- worm hydrazides
- goes down
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000000575 pesticide Substances 0.000 title abstract description 5
- 239000005937 Tebufenozide Substances 0.000 title description 2
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 title description 2
- 241000238631 Hexapoda Species 0.000 claims abstract description 14
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 45
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 17
- 239000004202 carbamide Substances 0.000 claims description 17
- 239000003630 growth substance Substances 0.000 claims description 11
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 3
- MVPPADPHJFYWMZ-IDEBNGHGSA-N chlorobenzene Chemical group Cl[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 MVPPADPHJFYWMZ-IDEBNGHGSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000007921 spray Substances 0.000 description 34
- 239000003814 drug Substances 0.000 description 32
- 230000003449 preventive effect Effects 0.000 description 32
- 125000002252 acyl group Chemical group 0.000 description 20
- 208000002474 Tinea Diseases 0.000 description 13
- 241000893966 Trichophyton verrucosum Species 0.000 description 13
- 239000002917 insecticide Substances 0.000 description 11
- 239000005893 Diflubenzuron Substances 0.000 description 10
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 10
- 229940019503 diflubenzuron Drugs 0.000 description 10
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 239000000375 suspending agent Substances 0.000 description 9
- 239000005938 Teflubenzuron Substances 0.000 description 7
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 7
- -1 4-chloro-α-cyclopropyl benzal Chemical class 0.000 description 6
- 241000219095 Vitis Species 0.000 description 5
- 235000009754 Vitis X bourquina Nutrition 0.000 description 5
- 235000012333 Vitis X labruscana Nutrition 0.000 description 5
- 235000014787 Vitis vinifera Nutrition 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 241000256247 Spodoptera exigua Species 0.000 description 4
- 241001480238 Steinernema Species 0.000 description 4
- 230000000035 biogenic effect Effects 0.000 description 4
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000005660 Abamectin Substances 0.000 description 3
- 241000985245 Spodoptera litura Species 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 3
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 description 2
- 241000193388 Bacillus thuringiensis Species 0.000 description 2
- 241000012249 Dendrolimus spectabilis Species 0.000 description 2
- 241001441330 Grapholita molesta Species 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 239000005906 Imidacloprid Substances 0.000 description 2
- 239000005917 Methoxyfenozide Substances 0.000 description 2
- 241000255969 Pieris brassicae Species 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 2
- 229940097012 bacillus thuringiensis Drugs 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
- YPSCQJTUAKNUNF-UHFFFAOYSA-N 2-chloro-n-[(4-chlorophenyl)carbamoyl]benzamide Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl YPSCQJTUAKNUNF-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 241000243812 Arenicola marina Species 0.000 description 1
- 239000005887 Chromafenozide Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005903 Gamma-cyhalothrin Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 239000005942 Triflumuron Substances 0.000 description 1
- ZXQYGBMAQZUVMI-UHFFFAOYSA-N [cyano-(3-phenoxyphenyl)methyl] 3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UHFFFAOYSA-N 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- 239000002269 analeptic agent Substances 0.000 description 1
- 230000003555 analeptic effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000006332 fluoro benzoyl group Chemical group 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000000201 insect hormone Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to an insecticidal composition which contains at least one specific insect growth regulating agent, a biological source, neristoxin and/or other pesticides and tebufenzide whose structure formula I is 1-(1, 1-dimethyl ethyl)-1-(4-ethyl benzoyl)-3, 5-dimethyl benzoyl hydrazine.
Description
The present invention relates to desinsection, miticide composition that worm hydrazides and specificity insect growth regulator, IGR, biogenic, nereistoxin and/or other insecticides are formed.
The worm hydrazides is to work with contacting by absorbing, and is a kind of moulting hormone analeptic.Its simulation insect hormone moulting hormone is controlled the process of casting off a skin, and induces fatal precocity to cast off a skin, and causes distortion and influences the insect breeding.If make composition with specificity insect growth regulator, IGR, biogenic, nereistoxin and/or other insecticides, their insecticidal effect can have the increase of surprising degree, they are better to the compatibility of environment, can also alleviate the pesticide resistance of insect simultaneously, reduce farmer's burdens.
The specificity insect growth regulator, IGR, biogenic, nereistoxin and/or the other insecticides example that are applicable to composition of the present invention are as follows:
(A) specificity insect growth regulator, IGR insecticide
1, the young urea (Chlorbenzuron) that goes out
2, desinsection grand (triflumuron)
3, Teflubenzuron (teflubenzuron)
4, fluorine bell urea (hexatlumuron)
5, diflubenzuron (diflubenzuron)
6, flucycloxuron (flucycloxuron)
7, ring worm hydrazides (chromafenozide)
8, flufenoxuron (flufenoxurom)
9, methoxyfenozide (methoxyfenozide)
(B) biological source insecticide
1, bacillus thuringiensis,Bt (Bacullus thuringiensis)
2, Avermectin (abamectin)
3, emamection benaoate (emamectin benzoate)
(C) nereistoxin insecticide
1, desinsection list
2, dimehypo (dimthypo)
(D) other insecticides
1, chlorfenapyr (chlorfenapyr)
2, Imidacloprid (imidacloprid)
3, beta-cypermethrin
4, gamma cyhalothrin (iambda-cyhalothrin)
The common name that provides in A, B, C and the D group compound of representing to have following IUPAC title in the above:
(A) specificity insect growth regulator, IGR
(1) adjacent chlorobenzene formacyl-3-(4-chlorphenyl) urea of 1-;
(2) 1-2 (2-chlorobenzene formacyl)-3-(4-Trifluoromethoxyphen-l) urea;
(3) 1-(3,5-two chloro-2,4-difluorophenyl)-3-(2, the 6-difluoro benzoyl) urea;
(4) 1-[3,5-two chloro-4-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-(2, the 6-difluoro benzoyl) urea;
(5) 1-(4-chlorphenyl)-3-(2, the 6-difluoro benzoyl) urea;
(6) 1-[α-(the amino oxygen of 4-chloro-α-cyclopropyl benzal) is right-tolyl]-3-(2, the 6-difluoro benzoyl) urea;
(7) 2 '-tert-butyl groups-5-methyl-2 '-(3, the 5-dimethylbenzoyl) chroman-6-formylhydrazine;
(8) 1-[4-(α-three fluoro-is to toloxyl for 2-chloro-α, α)-2 fluorophenyls]-3-(2,6-two fluorobenzoyl) urea;
(9) the N-tert-butyl group-N '-(3-methyl-2-toluyl groups)-3,5-dimethyl benzene formylhydrazine.
(B) biological source insecticide
(1) bacillus thuringiensis,Bt;
(2) Avermectin;
(3) 4 " methylamino-4 "-deoxidation Avermectin B1 benzoates.
(C) sandworm toxin insecticide
(1) 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate;
(2) 2-N, N dimethylamine base-1, two (the thiosulfonic acid sodium base) propane of 3-.
(D) other insecticides
(1) 4-bromo-2-(4-chlorphenyl)-1-ethoxyl methyl-5-trifluoromethyl pyrpole-3-nitrile;
(2) 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine;
(3) 2,2-dimethyl-3-(2, the 2-dichloroethylene) cyclopropane-carboxylic acid-alpha-cyano-(3-phenoxy group)-benzyl ester;
(4) 3-(2-chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl cyclopropane carboxylic acid-alpha-cyano-3-phenoxybenzyl ester.
For composition of the present invention, preferablely in the above listed specificity insect growth regulator, IGR be young urea, Teflubenzuron, diflubenzuron, the flufenoxuron of going out.
Composition of the present invention can be two combinations, also can be the composition that aforesaid compound forms more than three kinds.
The mechanism of action difference of the various compositions of composition of the present invention, mutually synergy between them, the pesticide resistance of insect, evil mite reduces, thus the insecticidal effect of composition apparently higher than each component insecticidal effect of single time spent, and insecticidal spectrum is wider.
Composition of the present invention can be used for various crop and prevent and treat various pests, evil mite, and the lepidoptera pest in fruit tree, grape, vegetables and the forestry is had special efficacy.As oriental fruit moth, grape steinernema, beet armyworm, diamond-back moth, prodenia litura, cabbage caterpillar, pine caterpillars, cotton bollworm etc.
The ratio of worm hydrazides and specificity insect growth regulator, IGR, biogenic, nereistoxin and/or other insecticides is 1: 160～80: 1 based on the parts by weight of active constituent in the present composition, and the best is 1: 40～40: 1.
Composition of the present invention can also comprise emulsifier, solvent, auxiliary agent or filler, and the parts by weight of its shared composition are 0.5%～95%.
Composition of the present invention can wiring solution-forming, emulsion, wetting powder, suspending agent, pulvis, dust agent, paste, soluble powder, granula, microemulsion, missible oil, aerosol, fumicants and sustained release agent.
Composition of the present invention also will add surface reactive materials such as emulsifier, dispersant, wetting agent, to increase stability, wetability, the permeability of composition.
The product that the present invention describes can be the finished product preparation form, and promptly material mixes in the product.Yet the composition of composition also can provide with preparation separately, directly mixes in jar before use.
Composition of the present invention also can contain other active constituent, and for example other has the compound of weeding, desinsection or bactericidal property, also can mix with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Composition of the present invention can use by common method, as pouring into a mould, spray, spray, dust or putting cigarette.
The present composition can illustrate with following embodiment:
The preparation of embodiment 1 20% suspending agent
Worm hydrazides 10% (weight)
Young urea 10% (weight) goes out
Auxiliary agent 11% (weight)
Filler 27% (weight)
Water 42% (weight)
Various components are mixed, in sand mill, be ground to the active ingredient particle diameter less than 3 μ m.
The preparation of embodiment 2 wetting powders
Worm hydrazides 17% (weight)
UC 62644 3% (weight)
Auxiliary agent 9% (weight)
Filler 71% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed, be crushed to certain fineness.
The preparation of embodiment 3 granulas
Worm hydrazides 15% (weight)
Diflubenzuron 15% (weight)
Bentonite 29% (weight)
Talcum 40% (weight)
Sulphur ammonium 1% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed, through kneading, dissolving, drying, size degradation, granulation success.
The embodiment 4 20% worm acyls control efficiency of suspending agent of going out to beet armyworm
Place: Shanghai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| The 10% worm hydrazides+10% young urea that goes out | 96.75 | 96.70 | 98.72 | 98.70 | a | A |
| 20% worm hydrazides SC | 93.21 | 93.11 | 94.31 | 94.22 | b | B |
| The 20% young urea SC that goes out | 92.56 | 92.46 | 94.20 | 94.11 | b | B |
| CK | 1.310 | —— | 1.50 | —— | c | C |
Embodiment 5 20% worm acyl bisultap powders are to the control efficiency of cotton bollworm
Place: Binzhou
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 10% worm hydrazides+10% dimehypo | 93.75 | 93.60 | 94.00 | 93.91 | a | A |
| 20% worm hydrazides SC | 85.21 | 84.86 | 85.63 | 85.41 | b | B |
| 18% dimehypo water solution | 84.56 | 84.19 | 86.00 | 85.78 | b | B |
| CK | 2.34 | —— | 1.52 | —— | c | C |
The embodiment 6 18% worm acyls control efficiency of suspending agent of going out to apple skin worm
The place; Northwest Agricultural University
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| The 10% worm hydrazides+8% young urea that goes out | 9175 | 91.68 | 94.74 | 94.73 | a | A |
| 20% worm hydrazides SC | 88.21 | 88.10 | 90.63 | 90.52 | b | B |
| The 20% young urea SC that goes out | 8856 | 88.46 | 90.11 | 85.78 | b | B |
| CK | 0.90 | —— | 1.11 | —— | c | C |
Embodiment 7 20% worm acyls are decided the control efficiency of worm wetting powder to prodenia litura
Place: Laiyang
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 17% worm hydrazides+3% UC 62644 | 96.55 | 96.44 | 98.65 | 98.61 | a | A |
| 20% worm hydrazides SC | 9023 | 89.92 | 92.31 | 92.04 | b | B |
| 5% UC 62644 (pressing down hooligan) EC | 89.05 | 88.70 | 91.89 | 91.60 | b | B |
| CK | 3.10 | —— | 3.45 | —— | c | C |
Embodiment 8 15% worm acyls are decided the control efficiency of worm wetting powder to apple skin worm
Test site: Yantai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 12% worm hydrazides+3% UC 62644 | 89.11 | 88.98 | 92.31 | 92.12 | a | A |
| 20% worm hydrazides SC | 80.45 | 80.22 | 86.31 | 85.97 | b | B |
| 5% UC 62644 (pressing down hooligan) EC | 81.12 | 80.90 | 86.89 | 86.57 | b | B |
| CK | 1.15 | —— | 2.45 | —— | c | C |
Embodiment 9 15% worm acyl ring worm acyl suspending agents are to the control efficiency of apple skin worm
Test site: Yantai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 10% worm hydrazides+5 ring worm acyl % | 91.75 | 91.59 | 95.74 | 95.69 | a | A |
| 20% worm hydrazides SC | 85.21 | 84.92 | 91.63 | 91.54 | b | B |
| 10% ring worm hydrazides SC | 86.56 | 86.29 | 90.91 | 90.81 | b | B |
| CK | 1.90 | —— | 1.11 | —— | c | C |
Embodiment 10 20% worm acyls volt worm missible oil is to the control efficiency of beet armyworm
Test site: Shanghai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 17% worm hydrazides+3% Teflubenzuron | 94.11 | 93.97 | 96.58 | 96.56 | a | A |
| 20% worm hydrazides SC | 90.35 | 90.12 | 93.28 | 93.25 | b | B |
| 5% Teflubenzuron EC | 89.94 | 89.71 | 92.69 | 92.65 | b | B |
| CK | 2.25 | —— | 0.50 | —— | c | C |
Embodiment 11 22% worm acyl chlorfenapyr granulas are to the control efficiency of cabbage caterpillar
Test site: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 17% worm hydrazides+5% chlorfenapyr | 88.63 | 88.51 | 91.66 | 91.49 | a | A |
| 20% worm hydrazides | 84.35 | 84.19 | 87.68 | 87.43 | b | B |
| 10% chlorfenapyr SC | 83.99 | 83.83 | 86.89 | 86.62 | b | B |
| CK | 1.01 | —— | 2.00 | —— | c | C |
Embodiment 12 15% worm acyls volt worm soluble powder is to the control efficiency of grape steinernema
Test site: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 12% worm hydrazides+3% Teflubenzuron | 86.33 | 86.16 | 93.22 | 92.83 | a | A |
| 20% worm hydrazides SC | 81.21 | 80.97 | 88.30 | 87.63 | b | B |
| 5% Teflubenzuron EC | 82.20 | 81.98 | 86.98 | 86.23 | b | B |
| CK | 1.24 | —— | 5.44 | —— | c | C |
Embodiment 13 30% worm acyl deinsectization soluble powders are to the control efficiency of pine caterpillars
Test site: Liaoning
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+15% diflubenzuron | 92.33 | 92.23 | 96.88 | 96.81 | a | A |
| 20% worm hydrazides SC | 88.21 | 88.06 | 91.32 | 91.14 | b | B |
| 25% diflubenzuron (enemy go out spirit) WP | 87.20 | 81.98 | 89.99 | 89.78 | b | B |
| CK | 1.24 | —— | 2.05 | —— | c | C |
Embodiment 14 30% worm acyl deinsectization suspending agents are to the control efficiency of oriental fruit moth
Test site; Laiyang
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+15% diflubenzuron | 88.33 | 88.29 | 93.85 | 93.77 | a | A |
| 20% worm hydrazides SC | 84.21 | 84.16 | 89.78 | 89.65 | b | B |
| 25% diflubenzuron (enemy go out spirit) WP | 83.20 | 83.15 | 87.94 | 87.79 | b | B |
| CK | 0.30 | —— | 1.25 | —— | c | C |
Embodiment 15 25% worm acyl deinsectization wetting powders are to the control efficiency of grape steinernema
Test site: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+10% diflubenzuron | 90.34 | 90.30 | 95.38 | 95.28 | a | A |
| 20% worm hydrazides SC | 88.21 | 88.16 | 91.30 | 91.12 | b | B |
| 25% diflubenzuron WP | 87.60 | 87.55 | 90.54 | 90.34 | b | B |
| CK | 0.41 | —— | 2.03 | —— | c | C |
Embodiment 16 15.2% worm acyl methylamino A Wei suspending agents are to the control efficiency of diamond-back moth
Test site: Binzhou
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+0.2% emamection benaoate | 92.33 | 92.23 | 96.88 | 96.81 | a | A |
| 20% worm hydrazides SC | 88.21 | 88.06 | 91.32 | 91.14 | b | B |
| 1% emamection benaoate EC | 87.20 | 81.98 | 89.99 | 89.78 | b | B |
| CK | 1.24 | —— | 2.05 | —— | c | C |
Embodiment 17 21% worm acyl ring worm acyl water dispersible granules are to the control efficiency of beet armyworm
Test site: Shanghai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+6% ring worm acyl | 88.33 | 88.29 | 93.85 | 93.77 | a | A |
| 20% worm hydrazides SC | 84.21 | 84.16 | 89.78 | 89.65 | b | B |
| 10% ring worm hydrazides SC | 83.20 | 83.15 | 87.94 | 87.79 | b | B |
| CK | 0.30 | —— | 1.25 | —— | c | C |
Embodiment 18 21% worm acyl ring worm acyl suspending agents are to the control efficiency of prodenia litura
Test site: Northwest Agricultural University
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+6% ring worm acyl | 90.34 | 90.30 | 95.38 | 95.28 | a | A |
| 20% worm hydrazides SC | 88.21 | 88.16 | 91.30 | 91.12 | b | B |
| 10% ring worm hydrazides SC | 87.60 | 87.55 | 90.54 | 90.34 | b | B |
| CK | 0.41 | —— | 2.03 | —— | c | C |
Embodiment 19 21% worm acyl ring worm acyl suspending agents are to the control efficiency of grape steinernema
Test site: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | 0.05 | 0.01 | |
| 15% worm hydrazides+6% ring worm hydrazides | 93.34 | 93.31 | 95.11 | 94.93 | a | A |
| 20% worm hydrazides SC | 89.21 | 89.16 | 92.33 | 91.95 | b | B |
| 10% ring worm hydrazides SC | 88.60 | 88.55 | 91.80 | 91.49 | b | B |
| CK | 0.44 | —— | 3.55 | —— | c | C |
Claims (2)
1. Pesticidal combination, it contains the N-tertiary butyl-N-(4-ethylamino benzonitrile acidic group)-3 of a species specificity insect growth regulator, IGR and following I structure, 5-dimethyl benzene formylhydrazine---worm hydrazides, wherein the ratio of structural formula I and specificity insect growth regulator, IGR is 1: 160 to 80: 1 based on the parts by weight of active component.
2. according to the composition of claim 1, wherein the specificity insect growth regulator, IGR is adjacent chlorobenzene formacyl-3-(4-chlorphenyl) urea of 1-, 1-(4-chlorphenyl)-3-(2, the 6-difluoro benzoyl) urea.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01123751 CN1242674C (en) | 2001-07-31 | 2001-07-31 | Tebufenozide pesticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01123751 CN1242674C (en) | 2001-07-31 | 2001-07-31 | Tebufenozide pesticide composition |
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| CN1399876A CN1399876A (en) | 2003-03-05 |
| CN1242674C true CN1242674C (en) | 2006-02-22 |
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| CN 01123751 Expired - Fee Related CN1242674C (en) | 2001-07-31 | 2001-07-31 | Tebufenozide pesticide composition |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY142815A (en) * | 2004-02-19 | 2011-01-14 | Univ Florida | Use of molt-accelerating compounds, ecdysteroids, analogs thereof, and chitin synthesis inhibitors for controlling termites. |
| CN101796949B (en) * | 2009-12-31 | 2013-10-09 | 青岛星牌作物科学有限公司 | Plant insecticidal protective agent and application thereof |
| CN101878766B (en) * | 2010-07-02 | 2013-06-26 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing methoxyfenozide and biogenic pesticide |
| CN103766364A (en) * | 2011-12-05 | 2014-05-07 | 江西正邦生物化工股份有限公司 | Pesticide suspension containing chlorfluazuron and tebufenozide and preparation method of pesticide suspension |
| CN102578114A (en) * | 2012-01-20 | 2012-07-18 | 山东潍坊双星农药有限公司 | Pesticide composite containing emamectin benzoate and tebufenozide |
| CN105994275B (en) * | 2012-03-14 | 2019-01-01 | 陕西韦尔奇作物保护有限公司 | A kind of composition pesticide of ring tebufenozide and biogenic substances |
| CN105941451A (en) * | 2012-03-16 | 2016-09-21 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing chromafenozide and neonicotinoid |
| CN103300002A (en) * | 2012-03-16 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and nereistoxins |
| CN103563953A (en) * | 2012-08-05 | 2014-02-12 | 南京华洲药业有限公司 | Composite insecticidal composition containing methoxyfenozide and chlorfluazuron and application thereof |
| CN103210909B (en) * | 2013-03-24 | 2016-04-27 | 广东中迅农科股份有限公司 | Ring worm hydrazides aqueous emulsion and preparation method thereof |
| CN106857520A (en) * | 2017-02-27 | 2017-06-20 | 南京华洲药业有限公司 | Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof |
| CN107006471B (en) * | 2017-02-27 | 2018-07-17 | 南京华洲药业有限公司 | The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide |
| CN106857525A (en) * | 2017-02-27 | 2017-06-20 | 南京华洲药业有限公司 | Compound pesticide compositions of containing chromafenozide and chlorfenapyr and application thereof |
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