CN106857585A - Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof - Google Patents
Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof Download PDFInfo
- Publication number
- CN106857585A CN106857585A CN201710108579.7A CN201710108579A CN106857585A CN 106857585 A CN106857585 A CN 106857585A CN 201710108579 A CN201710108579 A CN 201710108579A CN 106857585 A CN106857585 A CN 106857585A
- Authority
- CN
- China
- Prior art keywords
- ethiprole
- pesticide compositions
- compound pesticide
- ring
- tebufenozide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Compound pesticide compositions the invention discloses a kind of containing chromafenozide and ethiprole and application thereof, the Pesticidal combination with ring tebufenozide and ethiprole as active insecticidal components, wherein, the weight ratio of ring tebufenozide and ethiprole is 50：1~1：50.The Pesticidal combination can produce synergistic function higher, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduces drug cost, and prevention effect is used apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, be used especially for preventing and treating bollworm, snout moth's larva, and its effect is used apparently higher than its single dose.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of desinsection with ring tebufenozide and ethiprole as principle active component
Composition and its application.
Background technology
Ring tebufenozide (Chromafenozide), chemical name：The N- tert-butyl groups-N'- (3- methoxyl group -2- toluyls
Base) -3,5- dimethylbenzohydrazides.It is bishydrazide insecticide, suppresses feed after pests in a few houres, while causing evil
Worm casts off a skin in advance causes death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, and to arthropod class, catch
Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
Ethiprole (Fipronil), molecular formula：C12H4Cl2F6N4OS.Structural formula is：
Ethiprole is a kind of Phenylpyrazole insecticides, insecticidal spectrum wide, to insect based on stomach poison function, have concurrently tag and
Certain systemic action, its mechanism of action is the chloride metabolism for hindering the control of insect GABA, thus to aphid,
The important pests such as leafhopper, plant hopper, lepidopterous larvae, flies and coleoptera have insecticidal activity very high, to crop without poisoning.
Insecticide variety containing single component often existing defects in agricultural chemicals control of insect：It is continuous anti-using easily producing
The property of medicine, insecticidal spectrum is narrow, it is impossible to comprehensively protected for crop provides, and peasant's drug cost is high etc..It is by two kinds or two or more
The combination of various active components can to a certain extent overcome disadvantages mentioned above.Two kinds with synergistic effect or two or more work
Property composition combination mixture, can improve preventive effect, reduce active ingredient ground dosage, it is cost-effective, slow down pest resistance and occur,
And preventing and treating spectrum can be expanded, and play that many worms are simultaneous to be controlled, reduce the use cost of peasant.
The content of the invention
It is an object of the invention to provide a kind of containing chromafenozide and the compound pesticide compositions of ethiprole, the Pesticidal combination
It is the multifunctional insecticide composition for preventing and treating lepidoptera pest.
It is a further object of the present invention to provide the insecticidal materials that the Pesticidal combination prevents and treats resistance lepidoptera pest in preparation
On application, particularly prepare preventing and treating bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is achieved through the following technical solutions：
The compound pesticide compositions of a kind of containing chromafenozide and ethiprole, the compound pesticide compositions are with ring tebufenozide and fluorine
Worm nitrile is principle active component, wherein, the weight ratio of ring tebufenozide and ethiprole is 50：1~1：50.
In this compound pesticide compositions, the weight ratio preferably 20 of ring tebufenozide (A) and ethiprole (B)：1~1：5, enter one
Step is preferably 5：1~1：5, the weight ratio of ring tebufenozide (A) and ethiprole (B) is 50 in some most preferred technical schemes：
Isosorbide-5-Nitrae 0：1,30：1,20：1,10：1,5：1,2：1,1：1,1：5,1：10,1：20,1：30,1：40,1：Carried out in 50 these scopes
Selection.
This compound pesticide compositions can comprise only active component ring tebufenozide and ethiprole, also can in use or preparation to
Other components are added in active component, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In compound pesticide compositions of the present invention, ring tebufenozide and weight of both ethiproles in the compound pesticide compositions
Amount percentage composition is 3%~80%.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention are with ring tebufenozide and ethiprole as active component or principle active component, and agricultural chemicals
Auxiliary agent and excipient are into any one formulation allowed on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wettable powder
Agent, aqueous emulsion, microemulsion or water dispersion granule.
It is foregoing to can be applied to insecticides adjuvant of the invention and be not particularly limited, including but not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., it is foregoing should
Also be not particularly limited for excipient of the invention, including but not limited to solvent naphtha, water, antifreezing agent (such as propane diols),
Deionized water etc..Above auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Compound pesticide compositions of the present invention easily produce various Semipteras and Lepidoptera of resistance to planthopper and snout moth's larva etc.
Insect has good preventive effect；And suppress resistance to the action of a drug product of the insect to unitary agent (ring tebufenozide or ethiprole are any)
It is raw.
Above-mentioned compound pesticide compositions are preparing the application prevented and treated on resistance lepidoptera pest insecticidal materials, especially in system
Application effect on standby preventing and treating bollworm or snout moth's larva insecticidal materials is notable.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism lepidoptera pest
Such as bollworm, snout moth's larva have obvious synergistic function, overcome and delayed pest resistance to insecticide, expand preventing and treating spectrum, desinsection speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With it is long-acting；(5) with ring tebufenozide compared with ethiprole single dose, production and use cost are reduced；(6) lepidoptera pest is suppressed to agriculture
The resistance enhancing of medicine, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Indoor biometricses are tested：
Indoor synergy biologicall test is carried out using feed plus malicious method, selection resistant bollworm and diamondback moth are target pest,
Often treatment is repeated 3 times, and 60 are processed per concentration, and the toxicity for calculating each medicament antagonism bollworm and diamondback moth with niqueMin method is returned
Return equation and lethal concentration of 50 LC50, use LC50Value is pressed the abundant methods of Sun Yun and calculates co-toxicity coefficient, and specific method is as follows：
A certain single dose (generally selects LC50 juniors) as standard agent with mixture, is calculated：
Single dose toxicity index=standard agent LC50/ single doses LC50 × 100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey LC50 value × 100 of the LC50 values/mixture of toxicity index=standard single dose
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
The results are shown in Table 1,2：
The ring tebufenozide of table 1 and Firponil compounded and single dose antagonism bollworm toxicity test
As shown in Table 1, ring tebufenozide and Firponil compounded, co-toxicity coefficient is all higher than 120, shows good Synergistic
Effect.
The toxicity test of the ring tebufenozide of table 2 and Firponil compounded and single dose to diamondback moth
Table 2 understands, ring tebufenozide and Firponil compounded, and co-toxicity coefficient is all higher than 120, shows good Synergistic and makees
With.
Field control effectiveness test：
Listed embodiment 1-12 is carried out to prevent and treat bollworm and the diamondback moth test of pesticide effectiveness, comparison medicament is 5% ethiprole SC
With 5% ring tebufenozide SC, it is diluted according to the extension rate in form 3,4, is looked into after medicine 3 days, 7 days, the result of 14 days, treatment
The results are shown in Table 3,4：
Table 3：The field test results of ring tebufenozide-Firponil compounded antagonism bollworm
Field efficacy result shows that there is ring tebufenozide composition containing fipronil antagonism bollworm excellent preventing and treating to imitate
Really, prevention effect is better than the effect of single dose kind direct effect.
Table 4：Ring tebufenozide-Firponil compounded the field test results to diamondback moth
Field efficacy result shows that there is ring tebufenozide composition containing fipronil excellent preventing and treating to imitate to green vegetables diamondback moth
Really, prevention effect is better than the effect of single dose kind direct effect.
Embodiment 1：
Weigh 50g ring tebufenozides, 1g ethiproles, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 51% ring tebufenozide ethiprole missible oil.
Embodiment 2：
Weigh 30g ring tebufenozides, 10g ethiproles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、600#
1g, 150# solvent naphtha 13g, add water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing kettle high speed
Mixing, forms the ring tebufenozide ethiprole aqueous emulsion that principle active component weight percentage is 31%.
Embodiment 3：
Weigh 20g ring tebufenozides, 1g ethiproles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.Above raw material is routinely prepared the method input of microemulsion
Mix in mixing kettle, form the ring tebufenozide ethiprole microemulsion that principle active component weight percentage is 21%.
Embodiment 4：
Weigh 10g ring tebufenozides, 1g ethiproles, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, 200#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 11% ring tebufenozide ethiprole missible oil.
Embodiment 5：
Weigh 20g ring tebufenozides, 4g ethiproles, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, 200#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 24% ring tebufenozide ethiprole missible oil.
Embodiment 6：
Weigh 20g ring tebufenozides, 10g ethiproles, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
200# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 30% ring tebufenozide ethiprole missible oil.
Embodiment 7：
Weigh 10g ring tebufenozides, 10g ethiproles, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g,
200# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 20% ring tebufenozide ethiprole missible oil.
Embodiment 8：
Weigh 4g ring tebufenozides, 20g ethiproles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 200#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 24% ring tebufenozide ethiprole missible oil.
Embodiment 9：
Weigh 2g ring tebufenozides, 20g ethiproles, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 200#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, formed system it is main effectively into
Divide the ring tebufenozide ethiprole missible oil that weight percentage is 22%.
Embodiment 10：
Weigh 1g ring tebufenozides, 20g ethiproles, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, 200#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form preparation mainly effective
Ingredients Weight percentage composition is 21% ring tebufenozide ethiprole missible oil.
Embodiment 11：
Weigh 1g ring tebufenozides, 30g ethiproles, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
The weight percentage that principle active component is formed under effect is 31% ring tebufenozide ethiprole suspending agent.
Embodiment 12：
1g ring tebufenozides, 50g ethiproles are weighed, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 21g, the weight that water dispersible granular agent method forms principle active component is pressed by above raw material
Percentage composition is 51% ring tebufenozide fipronil water dispersible granule.
Claims (9)
1. compound pesticide compositions of a kind of containing chromafenozide and ethiprole, it is characterized in that the compound pesticide compositions are with ring worm acyl
Hydrazine and ethiprole are active insecticidal components, wherein, the weight ratio of ring tebufenozide and ethiprole is 50：1~1：50.
2. compound pesticide compositions of containing chromafenozide according to claim 1 and ethiprole, it is characterized in that described ring
The weight ratio of tebufenozide and ethiprole is 20：1~1：5.
3. compound pesticide compositions of containing chromafenozide according to claim 2 and ethiprole, it is characterized in that described ring
The weight ratio of tebufenozide and ethiprole is 5：1~1：5.
4. compound pesticide compositions of containing chromafenozide according to claim 1 and ethiprole, it is characterized in that ring tebufenozide
It is 3%~80% with weight percentage of both ethiproles in the compound pesticide compositions.
5. compound pesticide compositions of containing chromafenozide according to claim 4 and ethiprole, it is characterized in that ring tebufenozide
It is 5%~55% with weight percentage of both ethiproles in the compound pesticide compositions.
6. compound pesticide compositions of containing chromafenozide according to claim 1 and ethiprole, it is characterized in that this compound is killed
Worm composition is with ring tebufenozide and ethiprole as active insecticidal components and insecticides adjuvant is configured to the formulation of permission on agricultural chemicals.
7. compound pesticide compositions of containing chromafenozide according to claim 6 and ethiprole, it is characterized in that the formulation
It is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. containing chromafenozide and the compound pesticide compositions of ethiprole described in claim 1 prevents and treats resistance Lepidoptera evil in preparation
Application on the insecticidal materials of worm.
9. the compound pesticide compositions of containing chromafenozide according to claim 8 and ethiprole prepare preventing and treating bollworm or
Application on the insecticidal materials of snout moth's larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108579.7A CN106857585A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108579.7A CN106857585A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106857585A true CN106857585A (en) | 2017-06-20 |
Family
ID=59167972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710108579.7A Pending CN106857585A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106857585A (en) |
-
2017
- 2017-02-27 CN CN201710108579.7A patent/CN106857585A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102415398A (en) | Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof | |
| CN106857585A (en) | Compound pesticide compositions of containing chromafenozide and ethiprole and application thereof | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN103039456B (en) | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof | |
| CN103053594A (en) | Synergistic insecticidal composition containing tolfenpyrad and theta-cypermethrin and its application | |
| CN107006471B (en) | The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide | |
| CN106889067B (en) | A kind of containing chromafenozide and the compound pesticide compositions of chlorine tebufenozide and application thereof | |
| CN105475339B (en) | A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin | |
| CN104642363B (en) | A kind of containing metaflumizone and the Pesticidal combination of ethyl pleocidin and application | |
| CN106857643B (en) | Containing chromafenozide and the compound pesticide compositions of silafluofene and application thereof | |
| CN104738038A (en) | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof | |
| CN106857520A (en) | Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof | |
| CN106857521A (en) | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof | |
| CN106973925A (en) | Compound pesticide compositions of containing chromafenozide and Bassa and application thereof | |
| CN106973935A (en) | Compound pesticide compositions of containing chromafenozide and acrinathrin and application thereof | |
| CN106857525A (en) | Compound pesticide compositions of containing chromafenozide and chlorfenapyr and application thereof | |
| CN107047587A (en) | Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof | |
| CN107347886A (en) | A kind of field bucket for Control Insect Pests In Rice Field mixes agricultural chemicals | |
| CN106417344A (en) | Synergistic insecticidal composition containing cyantraniliprole and acetamiprid and application of synergistic insecticidal composition | |
| CN105638667B (en) | A kind of Synergistic insecticidal compositions and its application containing propargite and ethyl spinosad | |
| CN104738058A (en) | Compound insecticidal composition containing pyridalyl and matrine, and application thereof | |
| CN104738043A (en) | Composite insecticidal composition containing pyridalyl and fufenozide and application thereof | |
| CN104642315A (en) | A composite pesticidal composition comprising pyriproxyfen and spinetoram and applications thereof | |
| CN104642364A (en) | A composite pesticidal composition comprising chlorfluazuron and spinetoram and applications thereof | |
| CN107996603A (en) | A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170620 |
|
| WD01 | Invention patent application deemed withdrawn after publication |