CN107047587A - Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof - Google Patents
Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof Download PDFInfo
- Publication number
- CN107047587A CN107047587A CN201710108581.4A CN201710108581A CN107047587A CN 107047587 A CN107047587 A CN 107047587A CN 201710108581 A CN201710108581 A CN 201710108581A CN 107047587 A CN107047587 A CN 107047587A
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- China
- Prior art keywords
- hexaflumuron
- pesticide compositions
- compound pesticide
- ring tebufenozide
- containing chromafenozide
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses compound pesticide compositions of a kind of containing chromafenozide and HEXAFLUMURON and application thereof, the Pesticidal combination using ring tebufenozide and HEXAFLUMURON as active insecticidal components, wherein, the weight ratio of ring tebufenozide and HEXAFLUMURON is 50：1~1：50.The Pesticidal combination can produce higher synergistic function, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduces drug cost, and prevention effect is used apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, be used especially for preventing and treating bollworm, snout moth's larva, and its effect is used apparently higher than its single dose.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of using ring tebufenozide and HEXAFLUMURON as the desinsection of principle active component
Composition and its application.
Background technology
Ring tebufenozide (Chromafenozide), chemical name：The N- tert-butyl groups-N'- (3- methoxyl group -2- toluyls
Base) -3,5- dimethylbenzohydrazides.For bishydrazide insecticide, suppress feed after pests in a few houres, while causing evil
Worm casts off a skin in advance causes death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, and to arthropod class, catch
Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
HEXAFLUMURON (Hexaflumuron), molecular formula：C16H8Cl2F6N2O3.Structural formula is：
HEXAFLUMURON is new acyl group urea insecticide, and in addition to other acyl group ureas desinsection features, insecticidal spectrum is wider, special
The other insect to genus heliothis has special efficacy, to Noctuidaes such as gypsymoth, tent caterpillar, dysychira abietis, sweet tea Lay noctuid, the real noctuids of paddy
Insect works well, invalid to mite.Knock down power strong, insecticidal effect is rapider than other acylureas, with higher contact ovicidal
Activity, alone can also be used with.
Insecticide variety containing single component often existing defects in agricultural chemicals control of insect：It is continuous anti-using easily producing
The property of medicine, insecticidal spectrum is narrow, it is impossible to provide comprehensive protection, peasant's drug cost height etc. for crop.It is by two kinds or two or more
The combination of various active components can overcome disadvantages mentioned above to a certain extent.Two kinds with synergistic effect or two or more work
Property composition combination mixture, preventive effect can be improved, with reducing active ingredient dosage, it is cost-effective, slow down pest resistance and occur,
And preventing and treating spectrum can be expanded, play that many worms are simultaneous to be controlled, reduce the use cost of peasant.
The content of the invention
It is an object of the invention to provide a kind of containing chromafenozide and the compound pesticide compositions of HEXAFLUMURON, the Pesticidal combination
It is the multifunctional insecticide composition for preventing and treating lepidoptera pest.
It is a further object of the present invention to provide the insecticidal materials that the Pesticidal combination prevents and treats resistance lepidoptera pest in preparation
On application, particularly prepare preventing and treating bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is achieved through the following technical solutions：
The compound pesticide compositions of a kind of containing chromafenozide and HEXAFLUMURON, the compound pesticide compositions are with ring tebufenozide and fluorine
Bell urea is principle active component, wherein, the weight ratio of ring tebufenozide and HEXAFLUMURON is 50：1~1：50.
In this compound pesticide compositions, the weight ratio preferably 5 of ring tebufenozide (A) and HEXAFLUMURON (B)：1~1：20, enter
One step is preferably 5：1~1：5, the weight ratio of ring tebufenozide (A) and HEXAFLUMURON (B) exists in some most preferred technical schemes
50：Isosorbide-5-Nitrae 0：1,30：1,20：1,10：1,5：1,2：1,1：1,1：5,1：10,1：20,1：30,1：40,1：Enter in 50 these scopes
Row selection.
This compound pesticide compositions can comprise only active component ring tebufenozide and HEXAFLUMURON, also can in use or preparation to
Other components are added in active component, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In compound pesticide compositions of the present invention, ring tebufenozide and weight of both HEXAFLUMURONs in the compound pesticide compositions
It is 3%~80% to measure percentage composition.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention are using ring tebufenozide and HEXAFLUMURON as active component or principle active component, and agricultural chemicals
Auxiliary agent and excipient are into any one formulation allowed on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wettable powder
Agent, aqueous emulsion, microemulsion or water dispersion granule.
The foregoing insecticides adjuvant that can be applied to the present invention is not particularly limited, including but not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., it is foregoing should
For the present invention excipient be also not particularly limited, including but not limited to solvent naphtha, water, antifreezing agent (such as propane diols),
Deionized water etc..Above auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Compound pesticide compositions of the present invention easily produce a variety of Semipteras and Lepidoptera of resistance to planthopper and snout moth's larva etc.
Insect has good preventive effect；And suppress resistance to the action of a drug production of the insect to unitary agent (ring tebufenozide or HEXAFLUMURON are any)
It is raw.
Above-mentioned compound pesticide compositions prevent and treat the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system
Application effect on standby preventing and treating bollworm or snout moth's larva insecticidal materials is notable.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism lepidoptera pest
Such as bollworm, snout moth's larva have obvious synergistic function, overcome and have delayed pest resistance to insecticide, expand preventing and treating spectrum, desinsection speed
It hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With it is long-acting；(5) with ring tebufenozide compared with HEXAFLUMURON single dose, production and use cost reduction；(6) lepidoptera pest is suppressed to agriculture
The resistance enhancing of medicine, its effect is used apparently higher than its single dose.
Embodiment
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Embodiment 1：
Weigh ring tebufenozide and HEXAFLUMURON common 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, plant
Thing is oily to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, be configured to principle active component
Weight percentage is 30% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.The specific ratio of wherein ring tebufenozide and HEXAFLUMURON is shown in Table 1
With 2.
Indoor synergy biologicall test is carried out using feed plus malicious method, selection resistant bollworm is target pest, often handles weight
Multiple 3 times, 60 are handled per concentration, with niqueMin method calculate each medicament antagonism bollworm toxicity regression equation and it is lethal in it is dense
Spend LC50, use LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun, the results are shown in Table 1：
The ring tebufenozide of table 1 and hexaflumuron compounded and single dose antagonism bollworm toxicity test
As shown in Table 1, ring tebufenozide and hexaflumuron compounded, co-toxicity coefficient is all higher than 120, shows good Synergistic
Effect.
The toxicity test of the ring tebufenozide of table 2 and hexaflumuron compounded and single dose to striped rice borer
Table 2 understands, ring tebufenozide and hexaflumuron compounded, and co-toxicity coefficient is all higher than 120, shows good Synergistic and makees
With.
The preventing and treating bollworm test of pesticide effectiveness is carried out to embodiment 3,4,5, comparison medicament is 20% HEXAFLUMURON SC and 5% ring worm acyl
Hydrazine SC, is diluted according to the extension rate in form 3, is looked into after medicine 3 days, 7 days, the result of 14 days, result was shown in Table 3：
Table 3：The field test results of ring tebufenozide-hexaflumuron compounded antagonism bollworm
Field efficacy result shows that ring tebufenozide HEXAFLUMURON composition antagonism bollworm has excellent preventing and treating effect
Really, prevention effect is better than the effect that single dose kind is directly acted on.
Table 4：Ring tebufenozide-hexaflumuron compounded the field test results to green vegetables cabbage caterpillar
Field efficacy result shows that ring tebufenozide HEXAFLUMURON composition has excellent preventing and treating effect to green vegetables cabbage caterpillar
Really, prevention effect is better than the effect that single dose kind is directly acted on.
Embodiment 1：
50g ring tebufenozides, 1g HEXAFLUMURONs, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g are weighed, is gathered
Vinyl alcohol 5g, borax 2g, kaolin 13g, by weight of the above raw material by water dispersible granular agent method formation principle active component
Percentage composition is 51% ring tebufenozide hexaflumuron water dispersible granule.
Embodiment 2：
Weigh 5g ring tebufenozides, 50g HEXAFLUMURONs, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, 600#1g,
150# solvent naphtha 13g, add water to 100g.The method input mixing kettle high speed that above raw material is routinely prepared into aqueous emulsion is mixed
Close, form the ring tebufenozide HEXAFLUMURON aqueous emulsion that principle active component weight percentage is 55%.
Embodiment 3：
Weigh 2g ring tebufenozides, 18g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.Above raw material is routinely prepared to the method input of microemulsion
Mixed in mixing kettle, form the ring tebufenozide HEXAFLUMURON microemulsion that principle active component weight percentage is 20%.
Embodiment 4：
Weigh 1g ring tebufenozides, 5g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, 150#
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form principle active component
Weight percentage is 6% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 5：
Weigh 50g ring tebufenozides, 20g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form main effective
Ingredients Weight percentage composition is 70% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 6：
Weigh 2g ring tebufenozides, 40g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150#
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form principle active component
Weight percentage is 42% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 7：
Weigh 0.2g ring tebufenozides, 50g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form main effective
Ingredients Weight percentage composition is 50.2% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 8：
Weigh 5g ring tebufenozides, 0.5g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form main effective
Ingredients Weight percentage composition is 5.5% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 9：
Weigh 5g ring tebufenozides, 30g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150#
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, formed system it is main effectively into
Divide the ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate that weight percentage is 35%.
Embodiment 10：
Weigh 20g ring tebufenozides, 5g HEXAFLUMURONs, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, 150#
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, form preparation mainly effective
Ingredients Weight percentage composition is 25% ring tebufenozide 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 11：
Weigh 30g ring tebufenozides, 12g HEXAFLUMURONs, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
The weight percentage that principle active component is formed under effect is 42% ring tebufenozide HEXAFLUMURON suspending agent.
Embodiment 12：
Weigh 2g ring tebufenozides, 5g HEXAFLUMURONs, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 21g, by weight hundred of the above raw material by water dispersible granular agent method formation principle active component
Divide the ring tebufenozide HEXAFLUMURON water dispersion granule that content is 7%.
Claims (9)
1. the compound pesticide compositions of a kind of containing chromafenozide and HEXAFLUMURON, it is characterized in that the compound pesticide compositions are with ring worm acyl
Hydrazine and HEXAFLUMURON are active insecticidal components, wherein, the weight ratio of ring tebufenozide and HEXAFLUMURON is 50：1~1：50.
2. the compound pesticide compositions of containing chromafenozide according to claim 1 and HEXAFLUMURON, it is characterized in that described ring
Tebufenozide and the weight of HEXAFLUMURON ratio are 5：1~1：20.
3. the compound pesticide compositions of containing chromafenozide according to claim 2 and HEXAFLUMURON, it is characterized in that described ring
Tebufenozide and the weight of HEXAFLUMURON ratio are 5：1~1：5.
4. the compound pesticide compositions of containing chromafenozide according to claim 1 and HEXAFLUMURON, it is characterized in that ring tebufenozide
It is 3%~80% with weight percentage of both HEXAFLUMURONs in the compound pesticide compositions.
5. the compound pesticide compositions of containing chromafenozide according to claim 4 and HEXAFLUMURON, it is characterized in that ring tebufenozide
It is 5%~55% with weight percentage of both HEXAFLUMURONs in the compound pesticide compositions.
6. the compound pesticide compositions of containing chromafenozide according to claim 1 and HEXAFLUMURON, are killed it is characterized in that this is combined
Worm composition using ring tebufenozide and HEXAFLUMURON be that active insecticidal components and insecticides adjuvant and excipients are configured to what is allowed on agricultural chemicals
Formulation.
7. the compound pesticide compositions of containing chromafenozide according to claim 6 and HEXAFLUMURON, it is characterized in that the formulation
It is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of containing chromafenozide according to claim 1 and HEXAFLUMURON prevent and treat resistance squama wing in preparation
Application on the insecticidal materials of mesh insect.
9. the compound pesticide compositions of containing chromafenozide according to claim 8 and HEXAFLUMURON prepare preventing and treating bollworm or
Application on the insecticidal materials of snout moth's larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108581.4A CN107047587A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108581.4A CN107047587A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107047587A true CN107047587A (en) | 2017-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710108581.4A Pending CN107047587A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and HEXAFLUMURON and application thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06256111A (en) * | 1993-03-05 | 1994-09-13 | Nippon Kayaku Co Ltd | Insecticidal composition containing hydrazine compound and benzoylphenylurea compound |
| CN101647434A (en) * | 2009-07-06 | 2010-02-17 | 东莞市瑞德丰生物科技有限公司 | Pesticide composition having synergistic function and application thereof |
| CN102246785A (en) * | 2011-05-20 | 2011-11-23 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing inhibitor synthesized by using fufenozide and chitin |
-
2017
- 2017-02-27 CN CN201710108581.4A patent/CN107047587A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06256111A (en) * | 1993-03-05 | 1994-09-13 | Nippon Kayaku Co Ltd | Insecticidal composition containing hydrazine compound and benzoylphenylurea compound |
| CN101647434A (en) * | 2009-07-06 | 2010-02-17 | 东莞市瑞德丰生物科技有限公司 | Pesticide composition having synergistic function and application thereof |
| CN102246785A (en) * | 2011-05-20 | 2011-11-23 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing inhibitor synthesized by using fufenozide and chitin |
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