CN106857520A - Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof - Google Patents
Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof Download PDFInfo
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- CN106857520A CN106857520A CN201710107899.0A CN201710107899A CN106857520A CN 106857520 A CN106857520 A CN 106857520A CN 201710107899 A CN201710107899 A CN 201710107899A CN 106857520 A CN106857520 A CN 106857520A
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- Prior art keywords
- tebufenozide
- pesticide compositions
- ring
- compound pesticide
- containing chromafenozide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Compound pesticide compositions the invention discloses a kind of containing chromafenozide and tebufenozide and application thereof, the Pesticidal combination with ring tebufenozide and tebufenozide as active insecticidal components, wherein, the weight ratio of ring tebufenozide and tebufenozide is 50：1~1：50.The Pesticidal combination can produce synergistic function higher, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduces drug cost, and prevention effect is used apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, be used especially for preventing and treating bollworm, snout moth's larva, and its effect is used apparently higher than its single dose.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of desinsection with ring tebufenozide and tebufenozide as principle active component
Composition and its application.
Background technology
Ring tebufenozide (Chromafenozide), chemical name：The N- tert-butyl groups-N'- (3- methoxyl group -2- toluyls
Base) -3,5- dimethylbenzohydrazides.It is bishydrazide insecticide, suppresses feed after pests in a few houres, while causing evil
Worm casts off a skin in advance causes death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, and to arthropod class, catch
Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
Tebufenozide (Tebufenozide), molecular formula：C22H28N2O2.Structural formula is：
Tebufenozide is on-steroidal Novel insect growth regulator, is the insect hormone insecticides of newest research and development.Tebufenozide
Insecticidal activity is high, and selectivity is strong, effective to all lepidopterous larvaes, antagonism insect bollworm, cabbage caterpillar, diamondback moth, sweet
Dish noctuid etc. has special efficacy.And have extremely strong ovicidal activity, it is safer to non-target organism.Tebufenozide is non-stimulated to eyes and skin
Property, it is fool proof to mammal, birds, natural enemy to higher mammal without teratogenesis, carcinogenic, mutagenesis.
Insecticide variety containing single component often existing defects in agricultural chemicals control of insect：It is continuous anti-using easily producing
The property of medicine, insecticidal spectrum is narrow, it is impossible to comprehensively protected for crop provides, and peasant's drug cost is high etc..It is by two kinds or two or more
The combination of various active components can to a certain extent overcome disadvantages mentioned above.Two kinds with synergistic effect or two or more work
Property composition combination mixture, can improve preventive effect, reduce active ingredient ground dosage, it is cost-effective, slow down pest resistance and occur,
And preventing and treating spectrum can be expanded, and play that many worms are simultaneous to be controlled, reduce the use cost of peasant.
The content of the invention
It is an object of the invention to provide a kind of containing chromafenozide and the compound pesticide compositions of tebufenozide, the Pesticidal combination
It is the multifunctional insecticide composition for preventing and treating lepidoptera pest.
It is a further object of the present invention to provide the insecticidal materials that the Pesticidal combination prevents and treats resistance lepidoptera pest in preparation
On application, particularly prepare preventing and treating bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is achieved through the following technical solutions：
The compound pesticide compositions of a kind of containing chromafenozide and tebufenozide, the compound pesticide compositions are with ring tebufenozide and worm
Hydrazides is principle active component, wherein, the weight ratio of ring tebufenozide and tebufenozide is 50：1~1：50.
In this compound pesticide compositions, the weight ratio preferably 30 of ring tebufenozide (A) and tebufenozide (B)：1~1：10, enter
One step is preferably 30：1~1：5, the weight ratio of ring tebufenozide (A) and tebufenozide (B) exists in some most preferred technical schemes
50：Isosorbide-5-Nitrae 0：1,30：1,20：1,10：1,5：1,2：1,1：1,1：5,1：10,1：20,1：30,1：40,1：Enter in 50 these scopes
Row selection.
This compound pesticide compositions can comprise only active component ring tebufenozide and tebufenozide, also can in use or preparation to
Other components are added in active component, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In compound pesticide compositions of the present invention, ring tebufenozide and weight of both tebufenozides in the compound pesticide compositions
Amount percentage composition is 3%~80%.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention are with ring tebufenozide and tebufenozide as active component or principle active component, and agricultural chemicals
Auxiliary agent and excipient are into any one formulation allowed on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wettable powder
Agent, aqueous emulsion, microemulsion or water dispersion granule.
It is foregoing to can be applied to insecticides adjuvant of the invention and be not particularly limited, including but not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., it is foregoing should
Also be not particularly limited for excipient of the invention, including but not limited to solvent naphtha, water, antifreezing agent (such as propane diols),
Deionized water etc..Above auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Compound pesticide compositions of the present invention easily produce various Semipteras and Lepidoptera of resistance to planthopper and snout moth's larva etc.
Insect has good preventive effect；And suppress resistance to the action of a drug product of the insect to unitary agent (ring tebufenozide or tebufenozide are any)
It is raw.
Above-mentioned compound pesticide compositions are preparing the application prevented and treated on resistance lepidoptera pest insecticidal materials, especially in system
Application effect on standby preventing and treating bollworm or snout moth's larva insecticidal materials is notable.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism lepidoptera pest
Such as bollworm, snout moth's larva have obvious synergistic function, overcome and delayed pest resistance to insecticide, expand preventing and treating spectrum, desinsection speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With it is long-acting；(5) with ring tebufenozide compared with tebufenozide single dose, production and use cost are reduced；(6) lepidoptera pest is suppressed to agriculture
The resistance enhancing of medicine, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Indoor biometricses are tested：
Indoor synergy biologicall test is carried out using feed plus malicious method, selection resistant bollworm and green vegetables cabbage caterpillar are target evil
Worm, often treatment is repeated 3 times, and 60 are processed per concentration, and each medicament antagonism bollworm and rice-stem borer are calculated with niqueMin method
Toxicity regression equation and lethal concentration of 50 LC50, use LC50Value is pressed the abundant methods of Sun Yun and calculates co-toxicity coefficient, and specific method is as follows：
A certain single dose (generally selects LC50 juniors) as standard agent with mixture, is calculated：
Single dose toxicity index=standard agent LC50/ single doses LC50 × 100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey LC50 value × 100 of the LC50 values/mixture of toxicity index=standard single dose
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
The results are shown in Table 1,2：
The ring tebufenozide of table 1 and the toxicity test of tebufenozide compounding and single dose antagonism bollworm
As shown in Table 1, ring tebufenozide and tebufenozide are compounded, and co-toxicity coefficient is all higher than 120, shows good Synergistic
Effect.
The ring tebufenozide of table 2 and tebufenozide compounding and single dose are to the toxicity test of cabbage caterpillar
Table 2 understands that ring tebufenozide and tebufenozide are compounded, and co-toxicity coefficient is all higher than 120, shows good Synergistic and makees
With.
Field control effectiveness test：
Listed embodiment 1-12 is carried out to prevent and treat bollworm and the green vegetables cabbage caterpillar test of pesticide effectiveness, comparison medicament is 20% worm acyl
Hydrazine SC and 5% ring tebufenozide SC, is diluted according to the extension rate in form 3 and form 4, looks into 3 days after medicine, 7 days, 14 days
As a result, result is shown in Table 3 and 4：
Table 3：Ring tebufenozide-tebufenozide compounds the field test results of antagonism bollworm
Field efficacy result shows, ring tebufenozide tebufenozide composition antagonism bollworm and cabbage caterpillar have excellent
Prevention effect, prevention effect is better than the effect of single dose kind direct effect.
Table 4：Field test results of the ring tebufenozide-tebufenozide compounding to green vegetables cabbage caterpillar
Field efficacy result shows that there is ring tebufenozide tebufenozide composition excellent preventing and treating to imitate to green vegetables cabbage caterpillar
Really, prevention effect is better than the effect of single dose kind direct effect.
Embodiment 1：
50g ring tebufenozides, 1g Bassas, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g are weighed, is gathered
Vinyl alcohol 5g, borax 2g, kaolin 13g, the weight that water dispersible granular agent method forms principle active component is pressed by above raw material
Percentage composition is 51% ring tebufenozide Bassa water dispersible granules.
Embodiment 2：
Weigh 30g ring tebufenozides, 1g tebufenozides, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, 600#1g,
200# solvent naphtha 13g, add water to 100g.The method input mixing kettle high speed that above raw material routinely prepares aqueous emulsion is mixed
Close, form the ring tebufenozide tebufenozide aqueous emulsion that principle active component weight percentage is 31%.
Embodiment 3：
Weigh 20g ring tebufenozides, 1g tebufenozides, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.Above raw material is routinely prepared the method input of microemulsion
Mix in mixing kettle, form the ring tebufenozide tebufenozide microemulsion that principle active component weight percentage is 21%.
Embodiment 4：
Weigh 10g ring tebufenozides, 1g tebufenozides, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 11% ring tebufenozide tebufenozide missible oil.
Embodiment 5：
Weigh 20g ring tebufenozides, 4g tebufenozides, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 24% ring tebufenozide tebufenozide missible oil.
Embodiment 6：
Weigh 20g ring tebufenozides, 10g tebufenozides, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 30% ring tebufenozide tebufenozide missible oil.
Embodiment 7：
Weigh 10g ring tebufenozides, 10g tebufenozides, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 20% ring tebufenozide tebufenozide missible oil.
Embodiment 8：
Weigh 4g ring tebufenozides, 20g tebufenozides, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form principle active component
Weight percentage is 24% ring tebufenozide tebufenozide missible oil.
Embodiment 9：
Weigh 1g ring tebufenozides, 10g tebufenozides, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, formed system it is main effectively into
Divide the ring tebufenozide tebufenozide missible oil that weight percentage is 11%.
Embodiment 10：
Weigh 1g ring tebufenozides, 20g tebufenozides, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, 150#
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form preparation mainly effective
Ingredients Weight percentage composition is 21% ring tebufenozide tebufenozide missible oil.
Embodiment 11：
Weigh 1g ring tebufenozides, 30g tebufenozides, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
The weight percentage that principle active component is formed under effect is 31% ring tebufenozide Tebufenozide suspending agent.
Embodiment 12：
1g ring tebufenozides, 50g tebufenozides are weighed, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 21g, the weight that water dispersible granular agent method forms principle active component is pressed by above raw material
Percentage composition is 51% ring tebufenozide tebufenozide water dispersion granule.
Claims (9)
1. compound pesticide compositions of a kind of containing chromafenozide and tebufenozide, it is characterized in that the compound pesticide compositions are with ring worm acyl
Hydrazine and tebufenozide are active insecticidal components, wherein, the weight ratio of ring tebufenozide and tebufenozide is 50：1~1：50.
2. compound pesticide compositions of containing chromafenozide according to claim 1 and tebufenozide, it is characterized in that described ring
The weight ratio of tebufenozide and tebufenozide is 30：1~1：10.
3. compound pesticide compositions of containing chromafenozide according to claim 2 and tebufenozide, it is characterized in that described ring
The weight ratio of tebufenozide and tebufenozide is 30：1~1：5.
4. compound pesticide compositions of containing chromafenozide according to claim 1 and tebufenozide, it is characterized in that ring tebufenozide
It is 3%~80% with weight percentage of both tebufenozides in the compound pesticide compositions.
5. compound pesticide compositions of containing chromafenozide according to claim 4 and tebufenozide, it is characterized in that ring tebufenozide
It is 5%~55% with weight percentage of both tebufenozides in the compound pesticide compositions.
6. compound pesticide compositions of containing chromafenozide according to claim 1 and tebufenozide, it is characterized in that this compound is killed
Worm composition is with ring tebufenozide and tebufenozide as active insecticidal components and insecticides adjuvant is configured to the formulation of permission on agricultural chemicals.
7. compound pesticide compositions of containing chromafenozide according to claim 6 and tebufenozide, it is characterized in that the formulation
It is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. containing chromafenozide and the compound pesticide compositions of tebufenozide described in claim 1 prevents and treats resistance Lepidoptera evil in preparation
Application on the insecticidal materials of worm.
9. the compound pesticide compositions of containing chromafenozide according to claim 8 and tebufenozide prepare preventing and treating bollworm or
Application on the insecticidal materials of snout moth's larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710107899.0A CN106857520A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710107899.0A CN106857520A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106857520A true CN106857520A (en) | 2017-06-20 |
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ID=59168007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710107899.0A Pending CN106857520A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and tebufenozide and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106857520A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN104738038A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof |
-
2017
- 2017-02-27 CN CN201710107899.0A patent/CN106857520A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN104738038A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 林文彩 等: "不同杀虫剂对甘蓝上菜青虫和小菜蛾的防治效果", 《浙江农业科学》 * |
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Application publication date: 20170620 |