CN106857521A - Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof - Google Patents
Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof Download PDFInfo
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- CN106857521A CN106857521A CN201710108565.5A CN201710108565A CN106857521A CN 106857521 A CN106857521 A CN 106857521A CN 201710108565 A CN201710108565 A CN 201710108565A CN 106857521 A CN106857521 A CN 106857521A
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- Prior art keywords
- fenvalerate
- pesticide compositions
- compound pesticide
- ring
- containing chromafenozide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Compound pesticide compositions the invention discloses a kind of containing chromafenozide and fenvalerate and application thereof, the Pesticidal combination with ring tebufenozide and fenvalerate as active insecticidal components, wherein, the weight ratio of ring tebufenozide and fenvalerate is 50：1~1：50.The Pesticidal combination can produce synergistic function higher, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduces drug cost, and prevention effect is used apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, be used especially for preventing and treating bollworm, snout moth's larva, and its effect is used apparently higher than its single dose.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of killing with ring tebufenozide and fenvalerate as principle active component
Worm composition and its application.
Background technology
Ring tebufenozide (Chromafenozide), chemical name：The N- tert-butyl groups-N'- (3- methoxyl group -2- toluyls
Base) -3,5- dimethylbenzohydrazides.It is bishydrazide insecticide, suppresses feed after pests in a few houres, while causing evil
Worm casts off a skin in advance causes death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, and to arthropod class, catch
Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
Fenvalerate (Phenvalerate), molecular formula：C25H22ClNO3.Structural formula is：
Fenvalerate is a kind of wide spectrum, efficient, quick pyrethroid.With tag with stomach poison function based on, without it is interior inhale make
With, it is invalid to mite class, for preventing and treating cotton aphid, leaf to lepidopterous larvae, Orthoptera, Semiptera, Diptera pest effectively
Cicada, stinkbug, leaf folder, cabbage caterpillar, eating-core bean worm, wheat armyworm, pink bollworm, bollworm, phyllocnistis citrella stainton larva.
Insecticide variety containing single component often existing defects in agricultural chemicals control of insect：It is continuous anti-using easily producing
The property of medicine, insecticidal spectrum is narrow, it is impossible to comprehensively protected for crop provides, and peasant's drug cost is high etc..It is by two kinds or two or more
The combination of various active components can to a certain extent overcome disadvantages mentioned above.Two kinds with synergistic effect or two or more work
Property composition combination mixture, can improve preventive effect, reduce active ingredient ground dosage, it is cost-effective, slow down pest resistance and occur,
And preventing and treating spectrum can be expanded, and play that many worms are simultaneous to be controlled, reduce the use cost of peasant.
The content of the invention
It is an object of the invention to provide a kind of containing chromafenozide and the compound pesticide compositions of fenvalerate, the Insecticidal combinations
Thing is the multifunctional insecticide composition for preventing and treating lepidoptera pest.
It is a further object of the present invention to provide the insecticidal materials that the Pesticidal combination prevents and treats resistance lepidoptera pest in preparation
On application, particularly prepare preventing and treating bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is achieved through the following technical solutions：
A kind of compound pesticide compositions of containing chromafenozide and fenvalerate, the compound pesticide compositions with ring tebufenozide and
Fenvalerate is principle active component, wherein, the weight ratio of ring tebufenozide and fenvalerate is 50：1~1：50.
In this compound pesticide compositions, the weight ratio preferably 10 of ring tebufenozide (A) and fenvalerate (B)：1~1：10,
More preferably 10：1~1：1, the weight of ring tebufenozide (A) and fenvalerate (B) in some most preferred technical schemes
Than 50：Isosorbide-5-Nitrae 0：1,30：1,20：1,10：1,5：1,2：1,1：1,1：5,1：10,1：20,1：30,1：40,1：50 these scopes
In selected.
This compound pesticide compositions can comprise only active component ring tebufenozide and fenvalerate, also can be in use or preparation
To other components are added in active component, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In compound pesticide compositions of the present invention, ring tebufenozide is with both fenvalerates in the compound pesticide compositions
Weight percentage is 3%~80%.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention are with ring tebufenozide and fenvalerate as active component or principle active component, and agriculture
Medicine auxiliary agent and excipient are into any one formulation allowed on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wettable
Pulvis, aqueous emulsion, microemulsion or water dispersion granule.
It is foregoing to can be applied to insecticides adjuvant of the invention and be not particularly limited, including but not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., it is foregoing should
Also be not particularly limited for excipient of the invention, including but not limited to solvent naphtha, water, antifreezing agent (such as propane diols),
Deionized water etc..Above auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Compound pesticide compositions of the present invention easily produce various Semipteras and Lepidoptera of resistance to planthopper and snout moth's larva etc.
Insect has good preventive effect；And suppress resistance to the action of a drug product of the insect to unitary agent (ring tebufenozide or fenvalerate are any)
It is raw.
Above-mentioned compound pesticide compositions are preparing the application prevented and treated on resistance lepidoptera pest insecticidal materials, especially in system
Application effect on standby preventing and treating bollworm or snout moth's larva insecticidal materials is notable.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism lepidoptera pest
Such as bollworm, snout moth's larva have obvious synergistic function, overcome and delayed pest resistance to insecticide, expand preventing and treating spectrum, desinsection speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With it is long-acting；(5) with ring tebufenozide compared with fenvalerate single dose, production and use cost are reduced；(6) lepidoptera pest pair is suppressed
The resistance enhancing of agricultural chemicals, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Indoor biometricses are tested：
Indoor synergy biologicall test is carried out using feed plus malicious method, selection resistant bollworm and rice-stem borer are target evil
Worm, often treatment is repeated 3 times, and 60 are processed per concentration, and each medicament antagonism bollworm and rice-stem borer are calculated with niqueMin method
Toxicity regression equation and lethal concentration of 50 LC50, use LC50Value is pressed the abundant methods of Sun Yun and calculates co-toxicity coefficient, and specific method is as follows：
A certain single dose (generally selects LC50 juniors) as standard agent with mixture, is calculated：
Single dose toxicity index=standard agent LC50/ single doses LC50 × 100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey LC50 value × 100 of the LC50 values/mixture of toxicity index=standard single dose
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
The results are shown in Table 1,2：
The ring tebufenozide of table 1 and the toxicity test of fenvalerate built and single dose antagonism bollworm
As shown in Table 1, ring tebufenozide and fenvalerate built, co-toxicity coefficient are all higher than 120, show collaboration well and increase
Effect is acted on.
The toxicity test of the ring tebufenozide of table 2 and fenvalerate built and single dose to striped rice borer
Table 2 understands that ring tebufenozide and fenvalerate built, co-toxicity coefficient are all higher than 120, show good Synergistic
Effect.
Field control effectiveness test：
Listed embodiment is carried out to prevent and treat bollworm and the rice-stem borer test of pesticide effectiveness, comparison medicament is 20% fenvalerate
EC and 5% ring tebufenozide SC, is diluted according to the extension rate in form 3,4, is looked into after medicine 3 days, 7 days, the result of 14 days, place
Reason the results are shown in Table 3,4：
Table 3：The field test results of ring tebufenozide-fenvalerate built antagonism bollworm
Field efficacy result shows that there is ring tebufenozide fenvalerate composition antagonism bollworm excellent preventing and treating to imitate
Really, prevention effect is better than the effect of single dose kind direct effect.
Table 4：Field test results of the ring tebufenozide-fenvalerate built to rice-stem borer
Field efficacy result shows that there is ring tebufenozide fenvalerate composition excellent preventing and treating to imitate to rice-stem borer
Really, prevention effect is better than the effect of single dose kind direct effect.
Embodiment 1：
Weigh 50g ring tebufenozides, 1g fenvalerates, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 51% ring tebufenozide fenvalerate missible oil.
Embodiment 2：
Weigh 30g ring tebufenozides, 1g fenvalerates, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、600#
1g, 150# solvent naphtha 13g, add water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing kettle high speed
Mixing, forms the ring tebufenozide fenvalerate aqueous emulsion that principle active component weight percentage is 31%.
Embodiment 3：
Weigh 20g ring tebufenozides, 1g fenvalerates, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.The method that above raw material routinely prepares microemulsion is thrown
Enter mixing in mixing kettle, form the ring tebufenozide fenvalerate microemulsion that principle active component weight percentage is 21%.
Embodiment 4：
Weigh 10g ring tebufenozides, 1g fenvalerates, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 11% ring tebufenozide fenvalerate missible oil.
Embodiment 5：
Weigh 20g ring tebufenozides, 4g fenvalerates, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 24% ring tebufenozide fenvalerate missible oil.
Embodiment 6：
Weigh 20g ring tebufenozides, 10g fenvalerates, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 30% ring tebufenozide fenvalerate missible oil.
Embodiment 7：
Weigh 10g ring tebufenozides, 10g fenvalerates, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g,
200# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 20% ring tebufenozide fenvalerate missible oil.
Embodiment 8：
Weigh 4g ring tebufenozides, 20g fenvalerates, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form main effective
Ingredients Weight percentage composition is 24% ring tebufenozide fenvalerate missible oil.
Embodiment 9：
Weigh 2g ring tebufenozides, 20g fenvalerates, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, forming system mainly has
Effect Ingredients Weight percentage composition is 22% ring tebufenozide fenvalerate missible oil.
Embodiment 10：
Weigh 1g ring tebufenozides, 20g fenvalerates, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g,
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, form preparation main
Active ingredient weight percentage is 21% ring tebufenozide fenvalerate missible oil.
Embodiment 11：
Weigh 1g ring tebufenozides, 30g fenvalerates, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulfuric acid
Salt 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
In the presence of formed principle active component weight percentage be 31% ring tebufenozide fenvalerate suspending agent.
Embodiment 12：
Weigh 1g ring tebufenozides, 50g fenvalerates, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, diatomite 21g, the weight that water dispersible granular agent method forms principle active component is pressed by above raw material
Amount percentage composition is 51% ring tebufenozide fenvalerate water dispersion granule.
Claims (9)
1. compound pesticide compositions of a kind of containing chromafenozide and fenvalerate, it is characterized in that the compound pesticide compositions are with ring worm
Hydrazides and fenvalerate are active insecticidal components, wherein, the weight ratio of ring tebufenozide and fenvalerate is 50：1~1：50.
2. compound pesticide compositions of containing chromafenozide according to claim 1 and fenvalerate, it is characterized in that described
The weight ratio of ring tebufenozide and fenvalerate is 10：1~1：10.
3. compound pesticide compositions of containing chromafenozide according to claim 2 and fenvalerate, it is characterized in that described
The weight ratio of ring tebufenozide and fenvalerate is 10：1~1：1.
4. compound pesticide compositions of containing chromafenozide according to claim 1 and fenvalerate, it is characterized in that ring worm acyl
Hydrazine is 3%~80% with weight percentage of both fenvalerates in the compound pesticide compositions.
5. compound pesticide compositions of containing chromafenozide according to claim 4 and fenvalerate, it is characterized in that ring worm acyl
Hydrazine is 5%~55% with weight percentage of both fenvalerates in the compound pesticide compositions.
6. compound pesticide compositions of containing chromafenozide according to claim 1 and fenvalerate, it is characterized in that this is compound
Pesticidal combination is with ring tebufenozide and fenvalerate as active insecticidal components and insecticides adjuvant is configured to the formulation of permission on agricultural chemicals.
7. compound pesticide compositions of containing chromafenozide according to claim 6 and fenvalerate, it is characterized in that described dose
Type is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. containing chromafenozide and the compound pesticide compositions of fenvalerate described in claim 1 prevents and treats resistance Lepidoptera in preparation
Application on the insecticidal materials of insect.
9. the compound pesticide compositions of containing chromafenozide according to claim 8 and fenvalerate are preparing preventing and treating bollworm
Or the application on the insecticidal materials of snout moth's larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108565.5A CN106857521A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710108565.5A CN106857521A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106857521A true CN106857521A (en) | 2017-06-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710108565.5A Pending CN106857521A (en) | 2017-02-27 | 2017-02-27 | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06263604A (en) * | 1993-03-15 | 1994-09-20 | Nippon Kayaku Co Ltd | Insecticidal composition comprising hydrazine-based compound and pyrethroid-based compound |
| CN1402975A (en) * | 2002-10-28 | 2003-03-19 | 通州正大农药厂 | Pesticide composition containing tebufenozide |
| WO2006008109A2 (en) * | 2004-07-20 | 2006-01-26 | Bayer Cropscience Ag | Insecticidal agents based on selected insecticides and safeners |
| CN103314987A (en) * | 2012-03-19 | 2013-09-25 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and pyrethroids |
-
2017
- 2017-02-27 CN CN201710108565.5A patent/CN106857521A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06263604A (en) * | 1993-03-15 | 1994-09-20 | Nippon Kayaku Co Ltd | Insecticidal composition comprising hydrazine-based compound and pyrethroid-based compound |
| CN1402975A (en) * | 2002-10-28 | 2003-03-19 | 通州正大农药厂 | Pesticide composition containing tebufenozide |
| WO2006008109A2 (en) * | 2004-07-20 | 2006-01-26 | Bayer Cropscience Ag | Insecticidal agents based on selected insecticides and safeners |
| CN103314987A (en) * | 2012-03-19 | 2013-09-25 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and pyrethroids |
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