CN1402975A - Pesticide composition containing tebufenozide - Google Patents
Pesticide composition containing tebufenozide Download PDFInfo
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- CN1402975A CN1402975A CN 02146599 CN02146599A CN1402975A CN 1402975 A CN1402975 A CN 1402975A CN 02146599 CN02146599 CN 02146599 CN 02146599 A CN02146599 A CN 02146599A CN 1402975 A CN1402975 A CN 1402975A
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- worm hydrazides
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Abstract
The pesticide composition containing tebufenozide includes tebufenozide as the first active component and one kind of the second active component selected from monosultap, bisultap, triazophos, chlorpyrifos, trichlorfon, phoxim and other five kinds of pesticides. The present invention has reasonable component, low use, cost, and high pesticidal effect higher than the accumulation of its components.
Description
Technical field:
The present invention relates to a kind of insecticide.
Background technology:
As everyone knows, holometabolan grow and metamorphosis process in, the regulating and controlling effect of moulting hormone is very important.The main component of moulting hormone is the 20-hydroxyecdysone.When 20-hydroxyecdysone titre raise, the insect larvae epidermal cell was recombinated, and by combining closely with ecdysone receptor albumen, activated receptor albumen causes protein synthetic in a large number, and constantly secretes new epicuticle and cuticula.Worm hydrazides insecticides promptly is a simulation 20-hydroxyecdysone analog, it by larval feeding after, disturb or destroy original hormonal balance in the insect bodies, make in the old epidermis of larva, constantly form new deformity newly at skin, thereby cause insect growth to grow blocking-up or unusual.Reveal any symptoms only just stopped to get food in 6～8 hours behind the larval feeding worm hydrazides, the crop of no longer causing harm, and polypide dehydration then, shrinkage, dead after 3～4 days, rapider than the effect of the inhibitor of casting off a skin.Get the food medicament on a small quantity, adult of future generation is laid eggs and the incubation rate of ovum reduces.Practical application proves, worm hydrazides (adopted name: tebufenozide) have very strong desinsection, ovicidal activity, Lepidoptera Noctuidae and Pyralidae various pests are had special efficacy.
The worm hydrazides has very high biologically active, but its price is very high, and single time spent economic well-being of workers and staff is less on the various crop at home, and the insecticidal spectrum of single time spent is also limited.The existing conventional insecticide is owing to use for many years, and a lot of pest have produced resistance in various degree to it, and effect descends, and the effect of preventing and treating the snout moth's larva of rice as desinsection list, Hostathion has descended about 1/3; On the other hand, Imidacloprid, Buprofezin etc. can only be prevented eliminating aphis, the plant hopper insect, and is invalid to lepidoptera pest.
Summary of the invention:
The object of the present invention is to provide a kind of component reasonable, good disinsection effect, the Pesticidal combination that contains the worm hydrazides that drug cost is low.
Technical solution of the present invention is:
A kind of Pesticidal combination that contains the worm hydrazides, its feature: comprise as the worm hydrazides of first active ingredient and to be selected from a kind of in desinsection list, dimehypo, Hostathion, chlopyrifos, chlorophos, phoxim, Imidacloprid, Buprofezin, sumicidin, cypermethrin, the decis be second active ingredient.
The weight ratio of first active ingredient and second active ingredient is 1: 0.01～200.Also contain the adjuvant of making suspending agent or the adjuvant of making wetting powder.The adjuvant of making suspending agent comprises dispersant, wetting agent.The adjuvant of making suspending agent comprises that also thickener, suspension stabilizer, defoamer, PH adjust one or more in agent, the antifreezing agent.The adjuvant of making wetting powder comprises dispersant, wetting agent, carrier.The adjuvant of making wetting powder also comprises one or more in bleeding agent, stabilizing agent, spreader-sticker, foam inhibitor, the anticaking agent.
Dispersant and wetting agent that suspending agent adopts have anionic surfactant, nonionic surface active agent comprises lignosulfonates, aliphatic alcohol polyethenoxy base ether, alkylaryl polyoxyethylene groups ether, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, the alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, lignin and derivative sulfonate thereof, the alkylaryl sulfonates of polymerization, Quadrafos, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether phosphate (ester), succinic acid, sulfonated ester, NNO etc.
Thickener and suspension stabilizer mainly contain yellow acid virgin rubber, carboxymethyl cellulose, Sodium Polyacrylate, gaseous state silica and Magnesiumaluminumsilicate etc.
The needs of set of dispense ratio also can add defoamer in the suspending agent, PH adjusts agent and antifreezing agent etc.Defoamer has organosilicon ketone, C
8～C
10Fatty alcohol, C
10～C
20Representative examples of saturated aliphatic carboxylic and ester class thereof, ester-ether type compound etc.PH adjusts agent acetic acid, hydrochloric acid, sodium hydroxide, potassium hydroxide, oxyammonia and amine salt and triethanolamine etc.Antifreezing agent has ethylene glycol, propane diols, glycerine etc.
Each weight percentages of components can be in the related suspending agent of this Pesticidal combination: insecticidal activity mixture 1～80%; Dispersant, wetting agent 0.5～30%; Other adjuvants 0～10%; Water surplus.
Adoptable dispersant of wetting powder and wetting agent have anionic and non-ionic surface active agent, comprise that tea is withered, Chinese honey locust, the lignosulfite dry substance, washing powder, aliphatic alcohol polyethenoxy base ether, alkyl phenol polyoxy ethyl ether, alkylaryl polyoxyethylene groups ether (sodium sulphate), lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, alkylnaphthalene sulfonate, the alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, lignin and derivative sulfonate thereof, Quadrafos, fatty alcohol ethylene oxide adduct phosphate, succinic acid, sulfonated ester, SOPA series, WPA series, NO etc.
The carrier of wetting powder is the mineral inert carriers, as kaolin, bentonite, potter's clay etc.As required, also can add bleeding agent, spreader-sticker, stabilizing agent, foam inhibitor, anticaking agent etc. in the wetting powder.Bleeding agent can be wetting and penetrating agent T, wetting and penetrating agent JFC etc.; Spreader-sticker can be soap, washing powder, enuatrol, polyvinyl alcohol etc.; Foam inhibitor can be silicone, C
8～C
10Fatty alcohol, oxirane etc.; Anticaking agent can be a white carbon black etc.
Various weight percentages of components can be in the wetting powder of this invention insecticides: insecticidal activity mixture 1～90%; Dispersant, wetting agent 1～40%; Other auxiliary agents 0～20% such as bleeding agent, stabilizing agent; The carrier surplus.
Component of the present invention is reasonable, and drug cost is low, good disinsection effect, and its insecticidal effect and activity level have exceeded the stack of each component activity.
Embodiment:
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
Take by weighing 5% worm hydrazides, 50% desinsection list, 3% sodium lignin sulfonate, 3%NNO, 4% propane diols, 0.3% yellow acid virgin rubber, 0.05% silicone defoaming agent, add water to 100% weight portion.The method that above-mentioned raw materials is produced suspending agent routinely drop into successively and fully be mixed into thick dispersion liquid in the high-speed mixer, enter colloid mill carry out fine powder broken, enter the sand milling ultramicro grinding again, promptly make 55% worm hydrazides--desinsection list suspending agent.
The part by weight of worm hydrazides and desinsection list can change between 1: 1～100 (examples 1: 2,1: 8,1: 20,1: 30,1: 50,1: 70,1: 90,1: 100) in the present embodiment, and both total weight items still are 55%, form new embodiment; Also the desinsection list can be replaced to Buprofezin simultaneously, form new embodiment.
Embodiment 2:
Taking by weighing 3% worm hydrazides, 47% dimehypo, 5% lignosulfonates, 4%NO, 2% moistening penetrant t, 10% white carbon black, diatomite fills up to 100% weight portion.The frequent regulation of above-mentioned raw materials is got ultramicro grinding, the blend step of wetting powder and is produced 50% worm hydrazides--dimehypo wetting powder.
The part by weight of worm hydrazides and dimehypo can change between 1: 1～100 (examples 1: 2,1: 8,1: 20,1: 30,1: 50,1: 70,1: 90,1: 100) in the present embodiment, and both total weight items still are 50%, form new embodiment; Dimehypo can also be replaced to phoxim, form new embodiment again.
Embodiment 3:
Take by weighing 5% worm hydrazides, 65% Hostathion, 20% aliphatic alcohol polyethenoxy base ether, 0.2% yellow acid virgin rubber, 0.02% silicone defoaming agent, add water to 100% weight portion.The method that above-mentioned raw materials is produced suspending agent routinely drop into successively and fully be mixed into thick dispersion liquid in the high-speed mixer, enter colloid mill carry out fine powder broken, enter the sand milling ultramicro grinding again, promptly make 70% worm hydrazides--Hostathion suspending agent.
The part by weight of worm hydrazides and Hostathion can change between 1: 1～50 (examples 1: 2,1: 8,1: 20,1: 30,1: 50) in the present embodiment, and both total weight items still are 70%, form new embodiment and criticize; Simultaneously Hostathion can be replaced to chlopyrifos, form new
Embodiment.
Embodiment 4:
Take by weighing 10% worm hydrazides, 1% cypermethrin, 10% lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, 8% carboxymethyl cellulose, 0.05%C
8The fatty alcohol defoamer adds water to 100% weight portion.The method that above-mentioned raw materials is produced suspending agent routinely drop into successively and fully be mixed into thick dispersion liquid in the high-speed mixer, enter colloid mill carry out fine powder broken, enter the sand milling ultramicro grinding again, promptly make 11% worm hydrazides--desinsection list suspending agent.
The part by weight of worm hydrazides and cypermethrin can change between 1: 0.05～10 (examples 1: 0.05,1: 1,1: 2,1: 3,1: 5,1: 7,1: 10) in the present embodiment, and both total weight items still are 11%, form new embodiment; Also cypermethrin can be replaced to decis simultaneously, form new embodiment.
Embodiment 5:
Take by weighing that 5% worm hydrazides, 80% chlorophos, 5% tea are withered, 1% moistening penetrating agent JFC, 1% white carbon black, kaolin fill up to 100% weight portion.The frequent regulation of above-mentioned raw materials is got ultramicro grinding, the blend step of wetting powder and is produced 85% worm hydrazides--chlorophos wetting powder.
The part by weight of worm hydrazides and chlorophos can change between 1: 5～200 (examples 1: 5,1: 20,1: 50,1: 90,1: 130,1: 170,1: 200) in the present embodiment, and both total weight items still are 85%, form new embodiment.
Embodiment 6: take by weighing 7% worm hydrazides, 1% pyrrole worm phosphorus, 35% alkyl phenol polyoxy ethyl ether, 10% moistening penetrant t, 10% white carbon black, kaolin and fill up to 100% weight portion.The frequent regulation of above-mentioned raw materials is got ultramicro grinding, the blend step of wetting powder and is produced 8% worm hydrazides--pyrrole worm phosphorus wetting powder.
The part by weight of worm hydrazides and pyrrole worm phosphorus can change between 1: 0.01～25 (examples 1: 0.01,1: 2,1: 5,1: 10,1: 15,1: 20,1: 25) in the present embodiment, and both total weight items still are 8%, form new embodiment.
Embodiment 7:
Take by weighing 1% worm hydrazides, 1% sumicidin, 3% lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, add water to 100% weight portion.The method that above-mentioned raw materials is produced suspending agent routinely drop into successively and fully be mixed into thick dispersion liquid in the high-speed mixer, enter colloid mill carry out fine powder broken, enter the sand milling ultramicro grinding again, promptly make 2% worm hydrazides--sumicidin suspending agent.
The part by weight of worm hydrazides and sumicidin can change between 1: 0.5～20 (examples 1: 0.5,1: 2,1: 5,1: 10,1: 15,1: 20) in the present embodiment, and both total weight items still are 2%, form new embodiment.
Claims (7)
1, a kind of Pesticidal combination that contains the worm hydrazides is characterized in that: comprise as the worm hydrazides of first active ingredient and be selected from desinsection list, dimehypo, Hostathion, chlopyrifos, so a kind of in hundred worms, phoxim, Imidacloprid, Buprofezin, sumicidin, cypermethrin, decis is second active ingredient.
2, the Pesticidal combination that contains the worm hydrazides according to claim 1 is characterized in that: the weight ratio of first active ingredient and second active ingredient is 1: 0.01～200.
3, the Pesticidal combination that contains the worm hydrazides according to claim 1 and 2 is characterized in that: also contain the adjuvant of making suspending agent or the adjuvant of making wetting powder.
4, the Pesticidal combination that contains the worm hydrazides according to claim 3 is characterized in that: the adjuvant of making suspending agent comprises dispersant, wetting agent.
5, the Pesticidal combination that contains the worm hydrazides according to claim 4 is characterized in that: the adjuvant of making suspending agent comprises that also thickener, suspension stabilizer, defoamer, PH adjust one or more in agent, the antifreezing agent.
6, the Pesticidal combination that contains the worm hydrazides according to claim 3 is characterized in that: the adjuvant of making wetting powder comprises dispersant, wetting agent, carrier.
7, the Pesticidal combination that contains the worm hydrazides according to claim 6 is characterized in that: the adjuvant of making wetting powder also comprises one or more in bleeding agent, spreader-sticker, foam inhibitor, the anticaking agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146599 CN1402975A (en) | 2002-10-28 | 2002-10-28 | Pesticide composition containing tebufenozide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146599 CN1402975A (en) | 2002-10-28 | 2002-10-28 | Pesticide composition containing tebufenozide |
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| Publication Number | Publication Date |
|---|---|
| CN1402975A true CN1402975A (en) | 2003-03-19 |
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|---|---|---|---|
| CN 02146599 Pending CN1402975A (en) | 2002-10-28 | 2002-10-28 | Pesticide composition containing tebufenozide |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103222472A (en) * | 2013-05-06 | 2013-07-31 | 南通金陵农化有限公司 | Compound pesticide |
| CN103222467A (en) * | 2013-04-26 | 2013-07-31 | 南通金陵农化有限公司 | Complex pesticide of pymetrozine and tebufenozide |
| CN103300028A (en) * | 2012-03-13 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide |
| CN103300002A (en) * | 2012-03-16 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and nereistoxins |
| CN103300044A (en) * | 2012-03-16 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and neonicotinoids |
| CN103763926A (en) * | 2011-08-25 | 2014-04-30 | 住友化学株式会社 | Arthropod pest control composition, and arthropod pest control method |
| CN104982454A (en) * | 2015-07-28 | 2015-10-21 | 扬州大学 | Pesticide preparation for prevention and control of sylepta derogata |
| CN105145554A (en) * | 2015-08-13 | 2015-12-16 | 广东中迅农科股份有限公司 | Wettable powder containing low-melting technical material and preparation method of wettable powder |
| CN105638699A (en) * | 2012-03-13 | 2016-06-08 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide |
| CN106857521A (en) * | 2017-02-27 | 2017-06-20 | 南京华洲药业有限公司 | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof |
| CN107114398A (en) * | 2017-06-29 | 2017-09-01 | 山东大农药业有限公司 | A kind of dimehypo and phoxim compound Pesticidal combination |
-
2002
- 2002-10-28 CN CN 02146599 patent/CN1402975A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103763926A (en) * | 2011-08-25 | 2014-04-30 | 住友化学株式会社 | Arthropod pest control composition, and arthropod pest control method |
| CN103763926B (en) * | 2011-08-25 | 2015-06-17 | 住友化学株式会社 | Arthropod pest control composition, and arthropod pest control method |
| CN103300028B (en) * | 2012-03-13 | 2016-03-30 | 陕西韦尔奇作物保护有限公司 | A kind of Pesticidal combination containing ring worm hydrazides |
| CN103300028A (en) * | 2012-03-13 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide |
| CN105638699A (en) * | 2012-03-13 | 2016-06-08 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide |
| CN103300002A (en) * | 2012-03-16 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and nereistoxins |
| CN103300044A (en) * | 2012-03-16 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and neonicotinoids |
| CN103300044B (en) * | 2012-03-16 | 2016-08-10 | 陕西韦尔奇作物保护有限公司 | A kind of containing chromafenozide and the Pesticidal combination of anabasine |
| CN103222467A (en) * | 2013-04-26 | 2013-07-31 | 南通金陵农化有限公司 | Complex pesticide of pymetrozine and tebufenozide |
| CN103222472A (en) * | 2013-05-06 | 2013-07-31 | 南通金陵农化有限公司 | Compound pesticide |
| CN104982454A (en) * | 2015-07-28 | 2015-10-21 | 扬州大学 | Pesticide preparation for prevention and control of sylepta derogata |
| CN104982454B (en) * | 2015-07-28 | 2017-04-05 | 扬州大学 | The pesticidal preparations of preventing and treating cotton leafroller |
| CN105145554A (en) * | 2015-08-13 | 2015-12-16 | 广东中迅农科股份有限公司 | Wettable powder containing low-melting technical material and preparation method of wettable powder |
| CN106857521A (en) * | 2017-02-27 | 2017-06-20 | 南京华洲药业有限公司 | Compound pesticide compositions of containing chromafenozide and fenvalerate and application thereof |
| CN107114398A (en) * | 2017-06-29 | 2017-09-01 | 山东大农药业有限公司 | A kind of dimehypo and phoxim compound Pesticidal combination |
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