CN1129358C - Pesticide composition containing fipronil - Google Patents
Pesticide composition containing fipronil Download PDFInfo
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- CN1129358C CN1129358C CN99126078A CN99126078A CN1129358C CN 1129358 C CN1129358 C CN 1129358C CN 99126078 A CN99126078 A CN 99126078A CN 99126078 A CN99126078 A CN 99126078A CN 1129358 C CN1129358 C CN 1129358C
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- compound
- cis
- phoxim
- sharp strength
- imidacloprid
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Abstract
The present invention belongs to a pesticide composition which contains a group of compounds prepared from Prince and at least one of imidacloprid, phoxim, thiosultap sodium, sanmite, avermectin and cistron cypermethrin. The pesticide composition can be processed into wettable powder, suspending agents and granules. The pesticide composition provided by the present invention has the advantages of high pesticidal efficiency, effective prevention for crop pests, such as stem borers, plant hoppers, thrips, rice beetles, small diamond black moths, aphids, leafhoppers, lepidopterous larvaes, flies, coleoptera pests, mites, etc., higher prevention effect than that of a single compound and low applying dosage of each active substance.
Description
Technical field:
The present invention relates to have highly active Pesticidal combination.Compound (A) and at least a specific insecticide (B) as the active ingredient representative are wherein arranged.
Technical background:
The chemical name of compound (A) is (±)-5-amino-1-(2,6-two chloro-2,2,2-three chloro-β-tolyls)-4-trifluoromethyl sulfonyl pyrazoles-3-carbonization nitrile.Be a kind of highly active insecticide, can be used for preventing and treating crop pests such as fruit tree, vegetables, grain.In order to enlarge insecticidal spectrum, delaying drug resistance produces, and it can use with other compound, and sharp strength spy belongs to a brand-new compound family for existing insecticide, both at home and abroad also not mentioned it and other compound compositions of patent.
Summary of the invention:
The objective of the invention is the effect that Pesticidal combination showed of compound (A) and some specific compound composition or the stack that activity level has exceeded each composition activity, or enlarged the insecticidal spectrum of one pack system compound.The Pesticidal combination that the present invention is based on this compound (A) and the formation of some specific compound has synergy or enlarges the insecticidal spectrum sphere of action provides one group of Pesticidal combination.
Pesticidal combination provided by the invention is characterised in that to comprise the special and at least a one group of compound (B) that is selected from Imidacloprid (imidacloprid), phoxim (phoxim), desinsection list, pyridaben (pyridaben), acetamiprid (abamecin), cis-, trans-cypermethrin (alphacypermethrin) composition of (A) sharp strength.Their chemical name is respectively:
Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine (imidacloprid B
1);
Phoxim: O, O one diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2);
Desinsection list: 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (B
3)
Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone (pyridaben B
4);
Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1Compound (the abamecfin B that b forms
5).
Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-a-cyano group-(3-benzyloxy phenoxy base)-3 (2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (alphacypermethrinB
6).
Weight ratio between compound in the Pesticidal combination of the present invention (A) and the compound (B) generally is:
For (A) and Imidacloprid (B
1) be 0.4～0.75 to be preferably 0.5～0.6
For (A) and phoxim (B
2) be 1～50 to be preferably 1.5～25
For (A) and desinsection list (B
3) be 1～50 to be preferably 5～25
For (A) and pyridaben (B
4) be 0.75～1 to be preferably 0.9～1
For (A) and acetamiprid (B
5) be 0.1～2 to be preferably 0.5～2
For (A) and cis-, trans-cypermethrin (B
6) be 0.05～0.1 to be preferably 0.05～0.07
The active constituent content of Pesticidal combination of the present invention is 5-90%.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Can be used for preventing and treating the insect such as diamond-back moth, aphid, snout moth's larva, plant hopper, thrips, rice beetle, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of crops such as vegetables, grain, fruit tree.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Preferably suspending agent, granule, also wetting powder.
Adoptable surfactant has anionic surfactant and nonionic surface active agent.It comprises alkylsurfuric acid salt, alkyl sulfonic acid alkali metal salt and amido, dialkyl group succinate sodium sulfonate salt, alkylphenol polyoxyethylene formaldehyde condensation products succinic acid half ester sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol alkylphenol polyoxyethylene sulphate, alkylnaphthalene sulfonate, fatty acid or fatty acid ester sulphate, alkylphenol polyoxyethylene and fatty alcohol-polyoxyethylene ether etc., and that can give an example has farming newborn 8000 series, lignosulfonates, NNO, a dispersing agent MF etc.
The mixture that contains each active component in the wetting powder, inert carrier and filler and one or more wetting agents, carrier is generally mineral inert carrier such as kaolin, bentonite etc.The wetting powder of the Pesticidal combination of this invention contains the active mixture of 5-90% (weight) (the more excellent 10-80% of being) usually, 1-20% (more excellent is 1-10%) (weight) dispersant, the wetting agent of 1-10% (more excellent is 2-8%) (weight), 1-10% (more excellent is 2-5%) (weight) bleeding agent, inert solid carrier and the filler of 5-70% (weight) (more excellent is 10-80%), the Pesticidal combination of forming jointly by them.
Granule is with active ingredient and fine grainly is dispergated carrier, adds that granulations such as binding agent, colouring agent, dispersant form.It is 1-20% (weight) (the more excellent 1-10% of being) that granule contains effective composition.
The suspending agent of this insecticides is water-soluble relatively poor active component constantly to be stirred in water with emulsifier, dispersant, wetting agent etc. pulverize, make it evenly to disperse and suspend, can suitably add suitable suspending agent such as thickener, antifreezing agent, stabilizing agent, bleeding agent, defoamer as required, comprise the active substance of 1-80% (weight) (the more excellent 5-50% of being).
Pesticidal combination provided by the present invention possesses the insecticide efficiency height, can effectively prevent and treat the insect such as snout moth's larva, plant hopper, thrips, rice beetle, diamond-back moth, aphid, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of the crop of causing harm.Control is significantly higher than the preventive effect of compound alone (A) or compound alone (B), and has reduced the application dosage of every kind of active substance significantly.The present invention simultaneously can replace the insecticide pesticide kind of present high poison, high residue.The present invention not only has ecological significance, also has important environment protection significance simultaneously.
Specific implementation method:
Following examples describe the present invention in detail, and embodiment mainly is for the present invention is described but not is used for limiting the present invention.
Embodiment 1 is the formulation preparation example, and embodiment 2-7 is a biological Examples.
Embodiment 1:
(1) suspending agent:
Active component A with 5% (purity 95%) and 10% active component B
1(purity 93%) and 5% is as 33 of emulsifier
#, 4% NNO, 0.2% thickener xanthans, 3% sodium lignin sulfonate, 0.5% stabilizing agent benzoic acid, 2% antifreeze glycol as wetting agent as dispersant, mix with the proper quantity of defoaming agent n-butanol, in high-speed shearing machine, evenly pulverize and mix.
(2) granule:
Active component A with 1.5% (purity 95%) and 3% active component B
1Produce granule with 2% binding agent, 0.5% colouring agent, 40% potter's clay, 2% dispersant and filler by coating method.
(3) with 3% active component A (purity 95%) and 22% active component B
1(purity 93%) and 5% calcium lignosulfonate as wetting agent, 4% NNO as dispersant, 2% evenly mix through ultramicro grinding as the JFC of bleeding agent etc. and produce.
Embodiment 2: sharp strength is special to be used with the water rice hopper control efficiency with Imidacloprid
Place: Xinyi
Investigation period: 7 day time behind the medicine: 1998
| Medicament | Active ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | 20 | 7.4 | 60 | |
| Sharp strength spy | 25 | 7.6 | 64.2 | |
| Imidacloprid | 10 | 5.0 | 62.8 | |
| Imidacloprid | 15 | 4.8 | 64.8 | |
| Sharp strength spy+Imidacloprid | 20+10 | 6.6 | 89.2 | 85.17 |
| Sharp strength spy+Imidacloprid | 25+10 | 5.2 | 90.1 | 86.7 |
| Sharp strength spy+Imidacloprid | 20+15 | 5.9 | 87.4 | 85.9 |
| Sharp strength spy+Imidacloprid | 25+15 | 8.0 | 93.3 | 87.4 |
Conclusion: sharp strength is special to be used preventive effect with Imidacloprid and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with Imidacloprid.
Embodiment 3: sharp strength is special to be used with snout moth's larva of rice control efficiency with the desinsection list
Place: Xinyi spraying times: once
Control time: 7 day time behind the medicine: 1998
| Medicament | Active ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | 20 | 7.0 | 62.1 | |
| Sharp strength spy | 25 | 9.8 | 63.8 | |
| The desinsection list | 400 | 12 | 60.9 | |
| The desinsection list | 450 | 9.0 | 59.2 | |
| Sharp strength spy+desinsection list | 20+400 | 8.5 | 87.3 | 85.2 |
| Sharp strength spy+desinsection list | 20+450 | 9.6 | 86.7 | 84.5 |
| Sharp strength spy+desinsection list | 25+400 | 7.3 | 89.3 | 85.6 |
| Sharp strength spy+desinsection list | 25+450 | 6.8 | 90.1 | 85.3 |
Conclusion: the special preventive effect of using with the desinsection list of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with the desinsection list.
Embodiment 4: sharp strength is special to be used with flower Ji, paddy rice rice plant skipper control efficiency with phoxim
Place: Xinyi spraying times: once
Control time: 7 day time behind the medicine: 1998
| Medicament | Active ingredient | Worm refers to | Preventive effect | The expection preventive effect |
| (ai/hm) | (％) | (％) | (coby method) | |
| Sharp strength spy | 20 | 7.7 | 59.2 | |
| Sharp strength spy | 25 | 8.2 | 63.1 | |
| Phoxim | 1500 | 10.3 | 63.4 | |
| Phoxim | 2000 | 9.8 | 64.2 | |
| Sharp strength spy+phoxim | 20+1500 | 6.5 | 87.2 | 85.1 |
| Sharp strength spy+phoxim | 20+2000 | 5.4 | 88.7 | 85.4 |
| Sharp strength spy+phoxim | 25+1500 | 9.8 | 89.2 | 86.0 |
| Sharp strength spy+phoxim | 25+2000 | 10.2 | 90.4 | 86.8 |
Conclusion: the special preventive effect of using with phoxim of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with phoxim.
Embodiment 5: sharp strength is special to be used with the cotton aphid control efficiency with pyridaben
Place: Pei County, Jiangsu spraying times: secondary
Investigation period: 7 day time behind the medicine for the second time: 1998
| Medicament | Active ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | 1000 | 8.9 | 64.3 | |
| Sharp strength spy | 1500 | 9.0 | 62.5 | |
| Pyridaben | 1000 | 7.3 | 60.1 | |
| Pyridaben | 1500 | 8.4 | 63.4 | |
| Sharp strength spy+pyridaben | 1000+1000 | 9.2 | 88.1 | 85.8 |
| Sharp strength spy+pyridaben | 1500+1500 | 10.8 | 89.4 | 86.3 |
Conclusion: sharp strength is special to be used preventive effect with pyridaben and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with pyridaben.
Embodiment 6: sharp strength is special to be used with Chinese cabbage diamond-back moth control efficiency with acetamiprid
Place: Shouguang, Shandong dispenser period: larva stage of invasion
Spraying times: once investigate period: 7 day time behind the medicine: 1998
| Medicament | Active ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | 20 | 7.6 | 60 | |
| Sharp strength spy | 25 | 6.3 | 62.1 | |
| Acetamiprid | 15 | 5.2 | 55.0 | |
| Acetamiprid | 20 | 4.8 | 60.0 | |
| Sharp strength spy+acetamiprid | 20+15 | 8.4 | 87.3 | 85.0 |
| Sharp strength spy+acetamiprid | 25+20 | 7.9 | 87.4 | 86.0 |
| Sharp strength spy+acetamiprid | 25+15 | 10.2 | 84.5 | 82.3 |
| Sharp strength spy+acetamiprid | 25+20 | 9.8 | 89.7 | 84.5 |
Conclusion: sharp strength is special to be used preventive effect with acetamiprid and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with acetamiprid.
Embodiment 7: sharp strength is special to be used with the colorado potato beetle control efficiency with cis-, trans-cypermethrin
Place: Guangdong dispenser period: larval phase
Spraying times: once investigate period: 7 day time behind the medicine: 1998
| Medicament | Active ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | 15 | 10.2 | 59.3 | |
| Sharp strength spy | 20 | 9.8 | 62.4 | |
| Cis-, trans-cypermethrin | 1 | 7.8 | 56.7 | |
| Cis-, trans-cypermethrin | 1.5 | 7.3 | 58.3 | |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1 | 8.3 | 83.7 | 82.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1.5 | 8.4 | 85.1 | 83.0 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1 | 5.6 | 86.3 | 83.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1.5 | 6.0 | 88.7 | 84.3 |
Conclusion: sharp strength is special to be used preventive effect with cis-, trans-cypermethrin and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with cis-, trans-cypermethrin.
Claims (5)
1, the Pesticidal combination that contains sharp strength spy is characterized in that comprising compound (A) (sharp strength spy) and at least a specific following one group of compound (B);
The structural formula of A is:
Compd B is respectively: Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine (imidaclopridB
1); Phoxim: o, o one diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2); Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone (pyridabenB
4); Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1Compound (the abamecfin B that b forms
5); Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-a-cyano group-(3-benzyloxy phenoxy base)-3 (2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (alphacypermethrin B
6);
Weight ratio between compound in the composition (A) and the compound (B) is:
For (A) and Imidacloprid (B
1) be 0.4～0.75
For (A) and phoxim (B
2) be 1～50
For (A) and pyridaben (B
4) be 0.75～1
For (A) and acetamiprid (B
5) be 0.1～2
For (A) and cis-, trans-cypermethrin (B
6) be 0.05～0.1
2, Pesticidal combination according to claim 1 is characterized in that the preferable range of weight ratio between compound in the composition (A) and the composition (B):
For (A) and Imidacloprid (B
1) be 0.5～0.6
For (A) and phoxim (B
2) be 1.5～25
For (A) and pyridaben (B
4) be 0.9～1
For (A) and acetamiprid (B
5) be 0.5～2
For (A) and cis-, trans-cypermethrin (B
6) be 0.05～0.07
3, Pesticidal combination according to claim 1, the effective component content that it is characterized in that composition is 5-90%.
4, according to one or the multinomial a kind of preparation of compositions method of claim 1-2, it is characterized in that, medicament can be processed into wetting powder, suspending agent and granule.
5, according to the Pesticidal combination described in the claim 1-2, can be used for preventing and treating the multiple kinds of crops insect pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1265268A CN1265268A (en) | 2000-09-06 |
| CN1129358C true CN1129358C (en) | 2003-12-03 |
Family
ID=5284315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99126078A Expired - Fee Related CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1129358C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101204155A (en) * | 2007-12-12 | 2008-06-25 | 海南利蒙特生物农药有限公司 | Fipronil and monosultap compound pesticide |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340169C (en) * | 2005-08-11 | 2007-10-03 | 徐克华 | Compound pesticide of fipronil and pridaphenthione |
| CN100364979C (en) * | 2006-02-28 | 2008-01-30 | 浙江大学 | Aryl pyrazole inulin acidamide compound and use thereof |
| JP5931322B2 (en) * | 2006-11-10 | 2016-06-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Crystal modification of fipronil |
| BRPI0718634A2 (en) * | 2006-11-17 | 2013-11-26 | Basf Se | METHOD FOR INCREASING ATMOSPHERE CARBON DIOXIDE SEQUEST BY A PLANT, AND USE OF AN INSECTICIDE. |
| CN100433979C (en) * | 2007-01-18 | 2008-11-19 | 江苏太湖地区农业科学研究所 | Compound insecticide containing fipronil and Etrofolan |
| WO2011154419A1 (en) | 2010-06-09 | 2011-12-15 | Basf Se | Method for cultivating sugar cane |
| AU2011269037B2 (en) | 2010-06-23 | 2014-08-07 | Basf Agro B.V., Arnhem (Nl)- Wadenswil Branch | Nematicidal mixtures for use in sugar cane |
| CN102726435A (en) * | 2011-04-09 | 2012-10-17 | 浙江森得保生物制品有限公司 | Specifically effective formula for controlling Pleonomus canaliculatus Faldemann |
| BR112014006421A2 (en) | 2011-09-23 | 2017-04-11 | Basf Se | sugarcane cultivation methods |
| CN102771503B (en) * | 2012-08-03 | 2014-01-08 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN104522006B (en) * | 2014-12-19 | 2016-10-05 | 湖南化工研究院有限公司 | A kind of preventing and treating Lepidoptera and homoptera pest compositions |
| CN105686963A (en) * | 2016-03-19 | 2016-06-22 | 上海申亚动物保健品阜阳有限公司 | Insectifuge pet shampoo |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206333A (en) * | 1995-12-27 | 1999-01-27 | 拜尔公司 | Synergistic insecticidal composition |
| CN1231120A (en) * | 1998-07-08 | 1999-10-13 | 胡国文 | Firponil compounded pesticide |
-
1999
- 1999-12-15 CN CN99126078A patent/CN1129358C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206333A (en) * | 1995-12-27 | 1999-01-27 | 拜尔公司 | Synergistic insecticidal composition |
| CN1231120A (en) * | 1998-07-08 | 1999-10-13 | 胡国文 | Firponil compounded pesticide |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101204155A (en) * | 2007-12-12 | 2008-06-25 | 海南利蒙特生物农药有限公司 | Fipronil and monosultap compound pesticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1265268A (en) | 2000-09-06 |
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