CN101755819A - Insecticidal composition having chlorantraniliprole - Google Patents
Insecticidal composition having chlorantraniliprole Download PDFInfo
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- CN101755819A CN101755819A CN200910035235A CN200910035235A CN101755819A CN 101755819 A CN101755819 A CN 101755819A CN 200910035235 A CN200910035235 A CN 200910035235A CN 200910035235 A CN200910035235 A CN 200910035235A CN 101755819 A CN101755819 A CN 101755819A
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- cypermethrin
- rynaxypyr
- compound
- insecticidal composition
- preventive effect
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Abstract
The invention provides an insecticidal composition having chlorantraniliprole and a preparation method and application thereof. The insecticidal composition is characterized by comprising a compound (A), namely chlorantraniliprole, and a mixture formed by a group of compounds (B) formed by at least one selected from alpha-cypermethrin, etofenprox, cypermethrin, beta-cypermethrin and cyhalothrin. The weight ratio of the compound (A) to the compounds (B) is generally 1-50:1-50. The insecticidal composition can be prepared into frequently-used wettable powder, soluble powder, emulsifiable concentrates, water dispersible powder, granules and emulsion in water according to the needs. The insecticidal composition has the characteristic of wide insecticidal spectrum and can effectively control various crop pests and the like. The control effect of the insecticidal composition is obviously superior to that of the single compound (A) or compound (B), and the application dosage of various bioactive substances can be reduced.
Description
Technical field:
The present invention relates to have the agricultural insecticidal composite of synergism performance.
Background technology
The Rynaxypyr general by name of compound (A), chemical name are Rynaxypyr, and chemical name is 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide is a kind of insecticide.This insecticide can be used for preventing and treating mythimna separata (subtropics mythimna separata, the meadow mythimna separata, yellow bar mythimna separata, western yellow bar mythimna separata), cotton bollworm, the moth-eaten moth of tomato, the tomato Grapholita spp, hawkmoth, garden webworm, potato tuberworm, diamond-back moth, cabbage looper, noctuid, beet armyworm, codling moth, peach fruit borer, oriental fruit moth, rose slanted bar leaf roller, the apple olethreutid, spot curtain leaf miner, apple leaf miner, rice-stem borer, paddy stem borer, pink rice borer, rice leaf roller, cabbage caterpillar, European corn borer, Asiatic corn borer, melon worm, melon thin,tough silk snout moth's larva, the wild snout moth's larva of melon, various pests such as oriental tobacco budworm.Domestic and international using with of also not mentioned it and alpha-cypermethrin of patent, ether chrysanthemum ester, cypermethrin, beta-cypermethrin, cyhalothrin in addition.Therefore the immixture of Nitenpyram and alpha-cypermethrin, ether chrysanthemum ester, cypermethrin, beta-cypermethrin, cyhalothrin is unforeseen.
Summary of the invention
Pesticidal combination provided by the invention is characterized in that comprising compound (A) Rynaxypyr and at least aly is selected from one group of compound compound (B) that alpha-cypermethrin, ether chrysanthemum ester, cypermethrin, beta-cypermethrin, cyhalothrin are formed.They are respectively:
Compound (A):
Rynaxypyr: benzene 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl)]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide
Structural formula is:
Compound (B):
(B1): alpha-cypermethrin
(B2): ether chrysanthemum ester
(B3) cypermethrin
(B4) beta-cypermethrin
(B5) cyhalothrin
Weight ratio between compound in insecticides of the present invention (A) and the compound (B) generally is:
(A) Rynaxypyr is 1-50: 1-50 with (B1) alpha-cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B2) ether chrysanthemum ester
(A) Rynaxypyr is 1-50: 1-50 with (B3) cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B4) beta-cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B5) cyhalothrin
Pesticidal combination provided by the present invention possesses characteristic of wide insecticidal spectrum, effectively control various crop pests etc.Preventive effect is significantly higher than the preventive effect of compound alone (A) or compound (B), and can reduce the application dosage of each bioactivator.
The present invention is used for control various crop pests etc.Do spraying at the insect pest initial stage of origination and handle, the method for processing can be by adding the good composition of formula or before use that the different activities component is mixed and handled.
Adoptable surfactant has anionic surfactant and nonionic surface active agent.The aliphatic alcohol sulfate that comprises Sulfates, alkylol polyoxyethylene groups ether sodium sulfate etc., the sodium alkyl sulfonate of Sulfonates, alkylbenzenesulfonate, alkylnaphthalene sulfonate, dialkyl succinylsuccinate sulfonate, monoalkyl phenyl polyoxyethylene groups ether succinic acid sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, fatty alcohol epoxy vinyl ether, alkylphenol-polyethenoxy base ether, the anhydrous sorbitol fatty acid ester, anhydrous sorbitol aliphatic acid polyethenoxy base ether, alkylphenol formaldehyde condensation product polyoxyethylene groups ether, sulfonation castor-oil plant alkoxide, quaternary ammonium salt derivative, the condensation product of oxirane and nonyl or octyl phenol is the main product or the alkalies and alkaline earth salt of sulfuric ester and sulfonic acid, as sulphonyl amber ester octyl group sodium in two ninth of the ten Heavenly Stems and such as the alkali of the macromolecule sulfonic acid derivative of sodium lignin sulfonate and calcium and the carboxylate of the anhydrous sorbierite that the alkali salt condensation forms etc.That can give an example has farming breast No. 2000 series, petroleum sodium sulfonate, dodecyl sodium sulfates, draws back powder, ethoxylated dodecyl alcohol sodium sulfonate, tween series, dispersing agent MF, NNO etc.
Missible oil of the present invention is that the mixture with each active component is dissolved in the solvent toluene, adds suitable emulsifier allotment and forms.Can optionally add auxiliary agents such as suitable stabilizing agent, bleeding agent.The content of active principle is 1-40% (weight) (the more excellent 5-30% of being) in the missible oil.
Wetting powder of the present invention is with the mixture of active component, inert carrier and filler and one or more wetting agents, dispersant, bleeding agent, obtains wetting powder by ultramicro grinding.
The preparation of granule of the present invention is that active ingredient is sprayed at particulate inert material surface with absorption property or active ingredient is adhered to carrier mass surface or particulate inert material surfaces such as sand, kaolin with adhesives such as polyvinyl alcohol, Sodium Polyacrylate or mineral oil, also can the active ingredient that some is suitable be processed into granule with the method for common manufacturing granular fertilizer.Its active constituent content of dispersible granules agent (weight) between 5-90% in the water spreads fertilizer over the fields active constituent content (weight) between 1-50% in the granule, between the preferred 1-25%.
Pesticidal combination provided by the invention possesses the insecticide efficiency height, can effectively prevent and treat the insect of harm various crop.Preventive effect is significantly higher than the preventive effect of compound alone (A) or compound alone (B), and has significantly reduced the application dosage of every kind of active substance, and the present invention simultaneously can replace high poison, high residue and insecticide pesticide kind.The present invention not only has ecological significance, also has important environment protection significance simultaneously.
Following examples describe the present invention in detail, and embodiment mainly is for the present invention is described but not is used for limiting the present invention.
Embodiment 1 is the formulation preparation example, and embodiment 2-6 is a biological Examples.
Embodiment 1: the formulation preparation example
(a) missible oil
Active component with 10% (A) and 1% active component (B1) and 10% emulsifier (available emulsifier has agricultural newborn series etc.), an amount of stabilizing agent and solvent toluene mixing form.
(b) wetting powder
Active principle with 15% (A) and 2% active component (B1) and 2% sodium lauryl sulfate as wetting agent, 4% NNO as dispersant, but and other inert filler fully mix together and obtain wet-milling through ultramicro grinding.
Embodiment 2 Rynaxypyrs and alpha-cypermethrin are used the control efficiency to cabbage caterpillar with
The place: period is investigated in the Xinyi: the 3 day time behind the medicine: 2009
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr | ??10 | ??8.6 | ??61.5 | |
| Rynaxypyr | ??15 | ??7.9 | ??74.3 | |
| Rynaxypyr | ??20 | ??8.4 | ??82.3 | |
| Alpha-cypermethrin | ??15 | ??5.8 | ??69.7 | |
| Rynaxypyr+alpha-cypermethrin | ??10+15 | ??8.9 | ??79.2 | ??70.6 |
| Rynaxypyr+alpha-cypermethrin | ??15+15 | ??7.8 | ??88.4 | ??81.5 |
| Rynaxypyr+alpha-cypermethrin | ??20+15 | ??7.7 | ??97.5 | ??86.3 |
Conclusion: Rynaxypyr and alpha-cypermethrin are used preventive effect with and are higher than its expectancy theory preventive effect, illustrate that Rynaxypyr and alpha-cypermethrin used synergistic effect with.
Embodiment 3 Rynaxypyrs and ether chrysanthemum ester are used the control efficiency to rice-stem borer with
The place: period is investigated in the Xinyi: the 3 day time behind the medicine: 2009
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr | ??10 | ??9.5 | ??65.4 | |
| Rynaxypyr | ??15 | ??8.4 | ??70.9 | |
| Rynaxypyr | ??20 | ??7.9 | ??80.4 | |
| Ether chrysanthemum ester | ??15 | ??8.5 | ??70.5 | |
| Rynaxypyr+ether chrysanthemum ester | ??10+15 | ??9.5 | ??79.7 | ??70.7 |
| Rynaxypyr+ether chrysanthemum ester | ??15+15 | ??7.7 | ??88.6 | ??81.4 |
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr+ether chrysanthemum ester | ??20+15 | ??5.6 | ??95.3 | ??88.4 |
Conclusion: Rynaxypyr and ether chrysanthemum ester are used preventive effect with and are higher than its expectancy theory preventive effect, illustrate that Rynaxypyr and ether chrysanthemum ester used synergistic effect with.
Embodiment 4 Rynaxypyrs and cypermethrin are used the control efficiency to cabbage caterpillar with
The place: period is investigated in the Xinyi: the 3 day time behind the medicine: 2009
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr | ??10 | ??6.7 | ??62.4 | |
| Rynaxypyr | ??15 | ??7.8 | ??75.6 | |
| Rynaxypyr | ??20 | ??8.5 | ??83.4 | |
| Cypermethrin | ??15 | ??6.7 | ??68.9 | |
| Rynaxypyr+cypermethrin | ??10+15 | ??7.2 | ??78.6 | ??69.8 |
| Rynaxypyr+cypermethrin | ??15+15 | ??8.4 | ??89.5 | ??82.3 |
| Rynaxypyr+cypermethrin | ??20+15 | ??8.1 | ??95.3 | ??88.4 |
Conclusion: Rynaxypyr and cypermethrin are used preventive effect with and are higher than its expectancy theory preventive effect, illustrate that Rynaxypyr and cypermethrin used synergistic effect with.
Embodiment 5 Rynaxypyrs and cypermethrin are used the control efficiency to cabbage caterpillar with
The place: period is investigated in the Xinyi: the 3 day time behind the medicine: 2009
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr | ??10 | ??8.9 | ??60.5 | |
| Rynaxypyr | ??15 | ??8.5 | ??70.5 | |
| Rynaxypyr | ??20 | ??8.4 | ??81.3 | |
| Beta-cypermethrin | ??15 | ??8.9 | ??70.6 |
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr+beta-cypermethrin | ??10+15 | ??7.5 | ??75.5 | ??70.9 |
| Rynaxypyr+beta-cypermethrin | ??15+15 | ??7.9 | ??89.5 | ??81.4 |
| Rynaxypyr+beta-cypermethrin | ??20+15 | ??9.2 | ??96.4 | ??87.5 |
Conclusion: Rynaxypyr and beta-cypermethrin are used preventive effect with and are higher than its expectancy theory preventive effect, illustrate that Rynaxypyr and beta-cypermethrin used synergistic effect with.
Embodiment 6 Rynaxypyrs and cyhalothrin are used the control efficiency to cabbage caterpillar with
The place: period is investigated in the Xinyi: the 3 day time behind the medicine: 2009
| Medicament | Effective ingredient (ai/hm 2) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (%) |
| Rynaxypyr | ??10 | ??8.2 | ??61.3 | |
| Rynaxypyr | ??15 | ??8.5 | ??71.6 | |
| Rynaxypyr | ??20 | ??8.7 | ??80.5 | |
| Cyhalothrin | ??15 | ??9.7 | ??74.3 | |
| Rynaxypyr+cyhalothrin | ??10+15 | ??8.6 | ??79.6 | ??69.8 |
| Rynaxypyr+cyhalothrin | ??15+15 | ??8.4 | ??91.3 | ??83.5 |
| Rynaxypyr+cyhalothrin | ??20+15 | ??9.2 | ??97.5 | ??90.6 |
Conclusion: Rynaxypyr and cyhalothrin are used preventive effect with and are higher than its expectancy theory preventive effect, illustrate that Rynaxypyr and cyhalothrin used synergistic effect with.
Claims (3)
1. the Pesticidal combination that contains Rynaxypyr is characterized in that comprising compound (A) 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide.
The structural formula of compd A is:
Compd B is:
(B1): alpha-cypermethrin
(B2): ether chrysanthemum ester
(B3): cypermethrin
(B4): beta-cypermethrin
(B5): cyhalothrin.
2. Pesticidal combination according to claim 1 is characterized in that the weight ratio between compound in the Pesticidal combination (A) and the compound (B) is:
(A) Rynaxypyr is 1-50: 1-50 with (B1) alpha-cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B2) ether chrysanthemum ester
(A) Rynaxypyr is 1-50: 1-50 with (B3) cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B4) beta-cypermethrin
(A) Rynaxypyr is 1-50: 1-50 with (B5) cyhalothrin.
3. Pesticidal combination according to claim 1 is characterized in that Pesticidal combination can be prepared into wetting powder commonly used, soluble powder, missible oil, water dispersible granule, granule, aqueous emulsion etc. as required.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910035235A CN101755819A (en) | 2009-09-24 | 2009-09-24 | Insecticidal composition having chlorantraniliprole |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910035235A CN101755819A (en) | 2009-09-24 | 2009-09-24 | Insecticidal composition having chlorantraniliprole |
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| Publication Number | Publication Date |
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| CN101755819A true CN101755819A (en) | 2010-06-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910035235A Pending CN101755819A (en) | 2009-09-24 | 2009-09-24 | Insecticidal composition having chlorantraniliprole |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101961027A (en) * | 2010-10-09 | 2011-02-02 | 广东省农业科学院植物保护研究所 | Pesticidal suspending agent or missible oil containing chlorantraniliprole and high-efficiency cypermethrin and preparation method thereof |
| CN102037977A (en) * | 2011-01-18 | 2011-05-04 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing thiacloprid amide and synthetic pyrethroid insecticide |
| CN102077838A (en) * | 2011-01-24 | 2011-06-01 | 青岛海利尔药业有限公司 | Insecticidal composition containing clothianidine and pyrethroid compound |
| CN102113516B (en) * | 2010-01-05 | 2013-11-20 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN105580836A (en) * | 2014-10-24 | 2016-05-18 | 陕西美邦农药有限公司 | High-effective insecticidal composition containing ZJ3757 |
| CN105613563A (en) * | 2014-10-25 | 2016-06-01 | 陕西美邦农药有限公司 | ZJ3757-containing pesticide composition |
| CN105638675A (en) * | 2013-01-07 | 2016-06-08 | 陕西汤普森生物科技有限公司 | Insecticide composition with tetra-chlorantraniliprole and synthetic pyrethroid |
| CN107494585A (en) * | 2017-09-07 | 2017-12-22 | 广东省农业科学院植物保护研究所 | A kind of Pesticidal combination containing effective cypermethrin and Rynaxypyr |
| CN107873703A (en) * | 2017-10-11 | 2018-04-06 | 江苏明德立达作物科技有限公司 | A kind of granule of containing chlorantraniliprole and gamma cyhalothrin and preparation method and application |
| CN108184859A (en) * | 2017-12-29 | 2018-06-22 | 广东真格生物科技有限公司 | One kind contains fourth chlorantraniliprole and pyrethroid Pesticidal combination and its application |
| CN115281199A (en) * | 2022-06-28 | 2022-11-04 | 陕西美邦药业集团股份有限公司 | Insecticidal composition for preventing and treating spinach plutella xylostella |
-
2009
- 2009-09-24 CN CN200910035235A patent/CN101755819A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113516B (en) * | 2010-01-05 | 2013-11-20 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN101961027A (en) * | 2010-10-09 | 2011-02-02 | 广东省农业科学院植物保护研究所 | Pesticidal suspending agent or missible oil containing chlorantraniliprole and high-efficiency cypermethrin and preparation method thereof |
| CN102037977A (en) * | 2011-01-18 | 2011-05-04 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing thiacloprid amide and synthetic pyrethroid insecticide |
| CN102037977B (en) * | 2011-01-18 | 2013-06-26 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing thiacloprid amide and synthetic pyrethroid insecticide |
| CN102077838A (en) * | 2011-01-24 | 2011-06-01 | 青岛海利尔药业有限公司 | Insecticidal composition containing clothianidine and pyrethroid compound |
| CN105638675A (en) * | 2013-01-07 | 2016-06-08 | 陕西汤普森生物科技有限公司 | Insecticide composition with tetra-chlorantraniliprole and synthetic pyrethroid |
| CN105580836A (en) * | 2014-10-24 | 2016-05-18 | 陕西美邦农药有限公司 | High-effective insecticidal composition containing ZJ3757 |
| CN105613563A (en) * | 2014-10-25 | 2016-06-01 | 陕西美邦农药有限公司 | ZJ3757-containing pesticide composition |
| CN107494585A (en) * | 2017-09-07 | 2017-12-22 | 广东省农业科学院植物保护研究所 | A kind of Pesticidal combination containing effective cypermethrin and Rynaxypyr |
| CN107873703A (en) * | 2017-10-11 | 2018-04-06 | 江苏明德立达作物科技有限公司 | A kind of granule of containing chlorantraniliprole and gamma cyhalothrin and preparation method and application |
| CN108184859A (en) * | 2017-12-29 | 2018-06-22 | 广东真格生物科技有限公司 | One kind contains fourth chlorantraniliprole and pyrethroid Pesticidal combination and its application |
| CN115281199A (en) * | 2022-06-28 | 2022-11-04 | 陕西美邦药业集团股份有限公司 | Insecticidal composition for preventing and treating spinach plutella xylostella |
| CN115281199B (en) * | 2022-06-28 | 2024-02-27 | 陕西美邦药业集团股份有限公司 | Insecticidal composition for preventing and controlling spinach plutella xylostella |
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Application publication date: 20100630 |