CN102113516B - Insect killing compound containing chlorantraniliprole - Google Patents
Insect killing compound containing chlorantraniliprole Download PDFInfo
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- CN102113516B CN102113516B CN2010100038439A CN201010003843A CN102113516B CN 102113516 B CN102113516 B CN 102113516B CN 2010100038439 A CN2010100038439 A CN 2010100038439A CN 201010003843 A CN201010003843 A CN 201010003843A CN 102113516 B CN102113516 B CN 102113516B
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- CN
- China
- Prior art keywords
- rynaxypyr
- mass
- chlorantraniliprole
- pesticidal combination
- mobucin
- Prior art date
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- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 106
- 239000005886 Chlorantraniliprole Substances 0.000 title claims abstract description 24
- 241000238631 Hexapoda Species 0.000 title abstract description 14
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000004615 ingredient Substances 0.000 claims abstract description 16
- 230000000361 pesticidal effect Effects 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 24
- 238000009736 wetting Methods 0.000 claims description 23
- 239000000375 suspending agent Substances 0.000 claims description 21
- 238000009825 accumulation Methods 0.000 claims description 19
- 239000004562 water dispersible granule Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 239000004530 micro-emulsion Substances 0.000 claims description 15
- -1 pleocidin Chemical compound 0.000 abstract description 20
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 abstract description 11
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 abstract description 9
- 239000005875 Acetamiprid Substances 0.000 abstract description 9
- 239000005663 Pyridaben Substances 0.000 abstract description 9
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 abstract description 9
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 abstract description 9
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 abstract description 7
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 abstract description 7
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 abstract description 7
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 abstract description 7
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 5
- 235000009566 rice Nutrition 0.000 abstract description 5
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 241000238876 Acari Species 0.000 abstract description 2
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003111 delayed effect Effects 0.000 abstract description 2
- 239000005946 Cypermethrin Substances 0.000 abstract 2
- 229960005424 cypermethrin Drugs 0.000 abstract 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000005937 Tebufenozide Substances 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 abstract 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 18
- 239000003814 drug Substances 0.000 description 17
- 230000008569 process Effects 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 8
- 239000005995 Aluminium silicate Substances 0.000 description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 7
- 241000500437 Plutella xylostella Species 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 6
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 6
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 6
- 229960001952 metrifonate Drugs 0.000 description 6
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 241000255777 Lepidoptera Species 0.000 description 5
- 238000003556 assay Methods 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 5
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 206010033799 Paralysis Diseases 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 241001486250 Etiella zinckenella Species 0.000 description 2
- 241000256247 Spodoptera exigua Species 0.000 description 2
- 241000985245 Spodoptera litura Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 210000004894 snout Anatomy 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- ZXQYGBMAQZUVMI-XDHOZWIPSA-N [cyano-(3-phenoxyphenyl)methyl] 3-[(e)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(\C=C(\Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-XDHOZWIPSA-N 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000007905 drug manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 230000003387 muscular Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insect killing compound containing chlorantraniliprole, which is prepared by two effective ingredients A and B. The ingredient A is chlorantraniliprole, the ingredient B is one of high-efficiency cypermethrin, trifluoro-cypermethrin, dursban, profenofos, dipterex, diafenthiuron, chlorfenapyr, emamectin benzoate, pleocidin, tebufenozide, hexaf lumuron, chlorfenapyr, pyridaben, acetamiprid, isoprocarb, dimehypo and cartap, and the composed mass ratio of the effective ingredient A to the ingredient B is 1:60-60:1. The accumulated mass percent of the two ingredients A and B accounts 1%-85% of the total mass of the compound. In the invention, the blending of the two active ingredients is utilized, so that the effect is improved obviously, the dosage of effective ingredients is reduced, and the drug resistance of insects and mites on the chlorantraniliprole is delayed. The insect killing compound can be used controlling various insects on rice, cotton, vegetables, fruit trees and the like.
Description
Technical field
The present invention relates to a kind of agricultural insecticidal medicament, especially relate to the Pesticidal combination and the application thereof that contain Rynaxypyr.
Background technology
On January 1st, 2007, the contour malicious agricultural chemicals of acephatemet is forbidden comprehensively, and ethiprole becomes one of replace of hypertoxic insecticides product of national agrotechnical center emphasis popularization simultaneously, has been the principal item of domestic rice district control rice leaf roller, snout moth's larva so far.Yet, on February 1st, 2009, general office of the Ministry of Agriculture sends about printing and distributing the notice of " the 8th national agriculture chemical registration evaluation committee fourth plenary session summary ", from 1 day July in 2009,, stop within the border selling and use pesticidal preparations for otherwise containing fipronil composition in China with, part dry land coating agent for seed except health.Stopping using of ethiprole, mainly contain the factor of three aspects:: at first, ethiprole is very large to aquatile toxicity, and is unfriendly to environment; Secondly, 2008 a lot of local at home, and rice leaf roller, snout moth's larva etc. resistance occurs to ethiprole, and the ethiprole successful reduces than before; The superseded paces of ethiprole have been accelerated in the Rynaxypyr listing of the 3rd, 2008 year Du Pont.
Rynaxypyr (chlorantraniliprole), efficient, interior suction, good penetrability, the lasting period is long, little poison.Can be used for preventing and treating nearly all lepidoptera pests such as diamond-back moth, rice leaf roller, striped rice borer, paddy stem borer, prodenia litura, beet armyworm, lima bean pod borer, corn borer.Its mechanism of action is by activating the ryanodine receptor in insect muscle, causing the unconfined release of internal calcium ion, stops contraction of muscle, thereby makes insect stop rapidly taking food, and occurs that muscular paralysis, vigor disappear, paralyse until dead.Insect stops causing harm from taking food paralysis, only needs the time of a few minutes.And this composition is to the not injury substantially such as the aquatiles such as fish, shrimp, honeybee, Predatory Mites.Can prevent and treat multiple lepidoptera pest.
But contain a kind of insecticide of active constituent to agricultural insect management, often because using continuously, insect easily develops immunity to drugs, and medication often, causes the pollution grows worse of environment etc.Advantage of the present invention and good effect are to carry out the agricultural chemicals of two kinds of different structures, the mechanism of action composite, be the control resistant insect, enlarge insecticidal spectrum and improve the effective way of drug effect, the more important thing is and avoid or delay the generation of insect to new composition Rynaxypyr resistance.
Summary of the invention
The object of the invention is to: provide the Pesticidal combination that contains Rynaxypyr of a kind of efficient, wide spectrum, low toxicity, with cause harm multiple lepidoptera pest on paddy rice, cotton, vegetables, fruit tree etc. of control.
to achieve these goals, technical scheme of the present invention is: the Pesticidal combination that a kind of containing chlorantraniliprole is provided, wherein, formed by two kinds of effective ingredient A and B, the A composition is Rynaxypyr, the B composition is beta-cypermethrin, Cyhalothrin, chlopyrifos, Profenofos, chlorophos, diafenthiuron, chlorfenapyr, emamection benaoate, pleocidin, the worm hydrazides, HEXAFLUMURON, chlorfenapyr, pyridaben, Acetamiprid, isopropyl becomes, dimehypo, a kind of in cartap, it is 1: 60～60: 1 that described two kinds of effective ingredient A and B form mass ratio.
Preferably, described two kinds of effective ingredient A and B composition mass ratio are 1: 50～5: 1.
Preferably, the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 1%～85% of gross mass.
Preferably, the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 0.6%～82% of gross mass.
Preferably, the described Pesticidal combination that contains Rynaxypyr can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules, microemulsion or suspending agent.
The invention has the advantages that: the present invention utilizes two kinds of active constituents to be mixed, and has obvious synergistic effect, can reduce the effective ingredient dosage, delays insect evil mite to the drug-fast generation of new medicament chlorine worm benzoyl.The present invention can be used for preventing and treating the various pests on paddy rice, cotton, vegetables, fruit tree etc.
Embodiment
The invention will be further described below in conjunction with preferred embodiment, but the present invention never is limited to following embodiment.In following examples, each component percentage composition all by quality ratio.
Embodiment one
10.2% Rynaxypyr diafenthiuron, namely both mass ratioes are the wetting powder of 1: 50
Common process forms, wherein
Rynaxypyr 0.2%
Diafenthiuron 10%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and diafenthiuron accounts for 10.2% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, then pulverize, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment two
3% Rynaxypyr Cyhalothrin, namely both mass ratioes are the microemulsion of 1: 5
Common process forms, wherein
Rynaxypyr 0.5%
Cyhalothrin 2.5%
DMF 6%
Glycerine 8%
Calcium dodecyl benzene sulfonate 4%
Tween 80 12%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and Cyhalothrin accounts for 3% of gross mass.
Embodiment three
20.5% Rynaxypyr and dursban, namely both mass ratioes are the suspending agent of 1: 40
Common process forms, wherein
Rynaxypyr 0.5%
Chlopyrifos 20%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Glycerine 3%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and chlopyrifos accounts for 20.5% of gross mass.
Embodiment four
12% Rynaxypyr Profenofos, namely both mass ratioes are the water dispersible granules of 5: 1
Common process forms, wherein
Rynaxypyr 10%
Profenofos 2%
Fatty alcohol 6%
Ammonium sulfate 5%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and Profenofos accounts for 12% of gross mass.
Embodiment five
82% Rynaxypyr chlorophos, namely both mass ratioes are the soluble powder of 1: 40
Common process forms, wherein
Rynaxypyr 2%
Chlorophos 80%
Lauryl sodium sulfate is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and chlorophos accounts for 82% of gross mass.
Embodiment six
6% Rynaxypyr beta-cypermethrin, namely both mass ratioes are the suspending agent of 1: 3
Common process forms, wherein
Rynaxypyr 1.5%
Beta-cypermethrin 4.5%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and beta-cypermethrin accounts for 6% of gross mass.
Embodiment seven
0.6% Rynaxypyr emamection benaoate, namely both mass ratioes are the microemulsion of 1: 5
Common process forms, wherein
Rynaxypyr 0.1%
Methyl abamectin benzoate 0.5%
DMF 4%
Glycerine 2.5%
Calcium dodecyl benzene sulfonate 5%
Tween 80 16%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and emamection benaoate accounts for 0.6% of gross mass.
Embodiment eight
5% Rynaxypyr pleocidin, namely both mass ratioes are the suspending agent of 1: 1
Common process forms, wherein
Rynaxypyr 2.5%
Pleocidin 2.5%
Polyoxyethylene alkyl ether 12%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and pleocidin accounts for 5% of gross mass.
Embodiment nine
4% Rynaxypyr worm hydrazides, namely both mass ratioes are the suspending agent of 1: 1
Common process forms, wherein
Rynaxypyr 2%
Worm hydrazides 2%
Polyoxyethylene alkyl ether 1.5%
Polyoxyethylene nonylphenol ether 1.5%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Glycerine 3%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and worm hydrazides accounts for 4% of gross mass.
Embodiment ten
6% Rynaxypyr and hexaflumuron, namely both mass ratioes are the wetting powder of 1: 5
Common process forms, wherein
Rynaxypyr 1%
HEXAFLUMURON 5%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and HEXAFLUMURON accounts for 6% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, then pulverize, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 11
12% Rynaxypyr chlorfenapyr, namely both mass ratioes are the suspending agent of 1: 5
Common process forms, wherein
Rynaxypyr 2%
Chlorfenapyr 10%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and chlorfenapyr accounts for 12% of gross mass.
Embodiment 12
15% Rynaxypyr pyridaben, namely both mass ratioes are the wetting powder of 2: 13
Common process forms, wherein
Rynaxypyr 2%
Pyridaben 13%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and pyridaben accounts for 15% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, then pulverize, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 13
6% Rynaxypyr Acetamiprid, namely both mass ratioes are the water dispersible granules of 1: 1
Common process forms, wherein
Rynaxypyr 3%
Acetamiprid 3%
Lauryl sodium sulfate 5%
Calcium lignosulfonate 8%
Sucrose 2%
Sodium methylene bis-naphthalene sulfonate 5%
Polyvinylpyrrolidone 10%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and Acetamiprid accounts for 6% of gross mass.
Embodiment 14
10% Rynaxypyr Mobucin, namely both mass ratioes are the wetting powder of 1: 4
Common process forms, wherein
Rynaxypyr 2%
Mobucin 8%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage that described Rynaxypyr becomes with isopropyl accounts for 10% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, then pulverize, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 15
20% Rynaxypyr dimehypo, namely both mass ratioes are the suspending agent of 1: 1
Common process forms, wherein
Rynaxypyr 10%
Dimehypo 10%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and dimehypo accounts for 20% of gross mass.
Embodiment 16
82% Rynaxypyr cartap, namely both mass ratioes are the wetting powder of 1: 40
Common process forms, wherein
Rynaxypyr 2%
Cartap 80%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described containing chlorantraniliprole also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and cartap accounts for 82% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, then pulverize, after the assay was approved, wetting powder can carry out the packing of product.
Biological Examples one:
The examination worm is adopted the indoor diamond-back moth that connects the generation raising, and concrete grammar is:
Medicament preparation: test former medicine and provide former medicine for producer, made the preparation that needs by I company's product development center Drug Manufacturing Room.Before test, according to different mix proportion schemes, be mixed with different concentration gradients, 6 concentration of every proportioning.
Connect worm: put into 3, cabbage leaves dish of the same size in the 9cm culture dish, select 3 instar larvaes of neat uniformity in culture dish, every ware connects 30 of worms.
Spraying: spray under 50PSI pressure with the POTT spray tower, spray 2 milliliters of medicines at every turn.Leaf dish positive and negative is all sprayed.Spraying is from low concentration, and blank sprays the equivalent clear water.Each proportioning arranges 6 concentration gradients, three wares of every concentration spray.Put into after having sprayed insectary (25 ± 1 ℃, 12H/12H) in.
Investigation statistics: process after 48 hours and check dead borer population, with Abbott formula calculation correction lethality.The appliance computer program is obtained each for examination single dose lethal concentration of 50 LC50, and method abundant according to Sun Yun calculated the co-toxicity coefficient (CTC value) of mixed medicament, CTC value greater than 100 be synergistic effect, equaling 100 is addition, less than 100, is antagonism.Circular is as follows:
Setting a kind of single dose (A) is the standard single dose, and specifying its toxicity index (TI) is 100:
The percentage of TI * single dose in mixture of the theoretical toxicity index (TTI) of mixture=each single dose of ∑
Result of the test in Table 1, table 2.
The virulence of each reagent agent of table 1 to diamond-back moth
| Medicament | LC50(ppm) |
| Rynaxypyr | 4.46 |
| Beta-cypermethrin | 223.02 |
| Cyhalothrin | 218.24 |
| Chlopyrifos | 273.40 |
| Profenofos | 272.46 |
| Chlorophos | 284.43 |
| Diafenthiuron | 59.50 |
| Emamection benaoate | 0.40 |
| Pleocidin | 15.65 |
| The worm hydrazides | 78.90 |
| HEXAFLUMURON | 10.26 |
| Chlorfenapyr | 8.22 |
| Pyridaben | 340.25 |
| Acetamiprid | 380.76 |
| Mobucin | 270.11 |
| Dimehypo | 340.37 |
| Cartap | 355.41 |
The composite effect of the composition of table 2 containing chlorantraniliprole to diamond-back moth
| Composition | Ratio | LC50 (ppm) | CTC |
| Rynaxypyr+beta-cypermethrin | 1∶3 | 12.34 | 136.38 |
| Rynaxypyr+Cyhalothrin | 1∶5 | 18.25 | 133.04 |
| Rynaxypyr+chlopyrifos | 1∶40 | 69.68 | 159.81 |
| Rynaxypyr+Profenofos | 5∶1 | 4.48 | 119.06 |
| Rynaxypyr+chlorophos | 1∶40 | 85.49 | 131.49 |
| Rynaxypyr+diafenthiuron | 1∶50 | 33.13 | 144.58 |
| Rynaxypyr+emamection benaoate | 1∶5 | 0.31 | 152.11 |
| Rynaxypyr+pleocidin | 1∶1 | 5.5 | 126.21 |
| Rynaxypyr+worm hydrazides | 1∶1 | 6.38 | 132.31 |
| Rynaxypyr+HEXAFLUMURON | 1∶5 | 6.75 | 124.92 |
| Rynaxypyr+chlorfenapyr | 1∶5 | 5.53 | 130.33 |
| Rynaxypyr+pyridaben | 1∶6.5 | 28.46 | 120.91 |
| Rynaxypyr+Acetamiprid | 1∶1 | 7.51 | 117.39 |
| Rynaxypyr+Mobucin | 1∶4 | 16.34 | 128.00 |
| Rynaxypyr+dimehypo | 1∶1 | 6.37 | 138.2 |
| Rynaxypyr+cartap | 1∶40 | 109.32 | 111.20 |
As can be seen from Table 1 and Table 2, with composite each composition of Rynaxypyr to the co-toxicity coefficient (CTC) of diamond-back moth all greater than 100, show, each composite effect all has synergistic effect to diamond-back moth.Each complex composition is processed into suitable formulation, but the effectively preventing rice leaf roller,, the multiple lepidoptera pest such as diamond-back moth, cotton bollworm, beet armyworm, prodenia litura, lima bean pod borer, leaf roller.Because diafenthiuron, chlorfenapyr and pyridaben have acaricidal activity, Acetamiprid and Mobucin, flea beetle, aleyrodid, plant hopper etc. there is good activity, so the built agent of the built agent of the built agent of Rynaxypyr and diafenthiuron or chlorfenapyr or pyridaben, Rynaxypyr and Acetamiprid, Rynaxypyr and Mobucin is except effective control lepidoptera pest, other insect also there is certain effect, enlarge insecticidal spectrum, reduced the medication number of times of agricultural chemicals.For the new medicament Rynaxypyr, delayed the generation of pest resistance to insecticide, can be used for preventing and treating the various pests that paddy rice, cotton, vegetables, fruit tree etc. occur.
Claims (4)
1. contain the Pesticidal combination of Rynaxypyr and Mobucin, it is characterized in that: the composition mass ratio of described two kinds of effective ingredient Rynaxypyrs and Mobucin is 1: 60～60: 1.
2. the Pesticidal combination that contains Rynaxypyr and Mobucin as claimed in claim 1 is characterized in that: it is 1: 50～5: 1 that described two kinds of effective ingredient Rynaxypyrs and Mobucin form mass ratio.
3. the Pesticidal combination that contains Rynaxypyr and Mobucin as claimed in claim 1, it is characterized in that: the mass accumulation percentage of described two kinds of effective ingredients accounts for 1%～85% of gross mass.
4. the Pesticidal combination that contains Rynaxypyr and Mobucin as claimed in claim 1, it is characterized in that: the Pesticidal combination of described containing chlorantraniliprole and Mobucin is made wetting powder, soluble liquid, water dispersible granules, microemulsion or suspending agent.
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