CN108432800A - A kind of compounded pesticides - Google Patents
A kind of compounded pesticides Download PDFInfo
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- CN108432800A CN108432800A CN201810375272.8A CN201810375272A CN108432800A CN 108432800 A CN108432800 A CN 108432800A CN 201810375272 A CN201810375272 A CN 201810375272A CN 108432800 A CN108432800 A CN 108432800A
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- Prior art keywords
- compounded pesticides
- pesticide
- metrifonate
- pyrazole amide
- phosphate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to technical field of agricultural insecticide, more particularly to compounded pesticides, active ingredient is dihalo pyrazole amide and metrifonate, the weight percent 1 of the two:2~4, stabilizer 1%~10%；Binder：1%~3%；Carrier：37%~93%.The present invention is made of the active ingredient of different role mechanism, and action site increases, and is conducive to overcome and delay the generation of insect pest drug resistance, and widened insecticidal spectrum；Increase wetting and drug effect greatly improved, the preventive effect time is long, and the field rate of active ingredient declines, and reduces production and application cost, reduces pesticide residue and environmental pollution.
Description
Technical field
The invention belongs to agricultural fungicides, more particularly to a kind of compound insecticidal including dihalo pyrazole amide and metrifonate
Agent.
Background technology
It is prevention plant pest the most effective means using chemical agent in the real process of agricultural production, but
The problem of being most easily produced by chemical prevention pest is the generation of pest resistance to insecticide.And the application of long-term continuous high dose is single
One chemical insecticide, a series of problems, such as be easy to causeing residual, the environmental pollution of medicament rational chemical insecticide compounding or
Mixture, which has, expands insecticidal spectrum, improves control effect, extends the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, prolong
The positive feature such as the generation of slow pest evil mite drug resistance and drug resistance and development, insecticidal/acaricidal agent compounding or mixture are that solution is above-mentioned
One of maximally efficient method of problem.
Develop new product insecticide price is constantly soaring, and in contrast, exploitation with research efficiently, low toxicity, low-residual, it is low at
This compounding with mixture with small investment, the lead time is short and is paid attention to both at home and abroad, increase developing efforts one after another.So far
Until it is not yet found that close dihalo pyrazole amide and metrifonate insecticides.
Invention content
The present invention be directed to existing insecticide defect, provide a kind of insecticidal spectrum is wide, dosage is few, it is less toxic, have synergistic effect,
The complex insecticidal composition of crops lepidoptera pest can effectively be prevented.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：A kind of compounded pesticides, it is a variety of for preventing
Pest on the cereal and fruit tree such as vegetables, wheat, the active ingredient are dihalo pyrazole amide and metrifonate, the dihalo
The weight ratio of pyrazole amide and metrifonate is 1:2~4.
Preferably, the weight ratio of the dihalo pyrazole amide and metrifonate is 1:3.
Preferably, the active ingredient dihalo pyrazole amide and the weight percentage of metrifonate in the composition：5%
~50%.
Preferably, the compounded pesticides still further comprise pesticidal preparations auxiliary element comprising pesticide stabilizer, agriculture
Medicine binder, pesticide wetting agent, carrier；Pesticide stabilizer 1%~10%；Pesticide binder：1%~3%；Pesticide wetting agent：
1%~10%；Carrier：37%~93%.
Preferably, the pesticide stabilizer is ammonium sulfate, ammonium chloride, methyl oleate, white carbon, talcum powder, styryl
Phenol formaldehyde resin, polyoxyethylene poly-oxygen propylene aether phosphate, ammonium trideceth, ammonium trideceth phosphorus
It is one or more in acid esters, organosilicon, urea；Pesticide binder is starch, dextrin, polyethylene glycol, polyvinyl alcohol, xanthan
It is one or more in glue, gelatin, Shi Que；Carrier be one kind in clay, kaolin, diatomite, gangue, slag, sand or
It is a variety of.The pesticide wetting agent is polystyrene-based phenol formaldehyde resin polyoxyethylene phosphate polymer, methoxy group
It chooses any one kind of them in the polysiloxanes that allyl polyether is modified or a variety of.
Preferably, the pesticide wetting agent is polystyrene-based phenol formaldehyde resin polyoxyethylene phosphate polymer,
Account for the proportioning of compounded pesticides：1%~10%, structural formula indicates as follows：
Molecular weight distribution be 3000~4000g/mol, wherein the value of (n1+n2) equal to 40~55, m value be equal to 15~
20。
Preferably, the wetting agent is the polysiloxanes of the allyl polyether modification of methoxy group, and it is multiple to account for desinsection
Proportioning with combination：1%~10%, the degree of polymerization is 4~15, and structural formula indicates as follows：
Molecular weight distribution is 350~1222g/mol, wherein：N values are equal to 5~15, and surface tension is 25~30Nm-1.
Compared with prior art, in compounded pesticides of the present invention, active ingredient dihalo pyrazole amide and metrifonate, dihalo-
It is notable to pest controling effects such as striped rice borer, rice leaf roller, diamondback moth, bollworm, cabbage caterpillar, nocturnal moth classes for pyrazole amide.
Metrifonate is the organophosphorus insecticide that a kind of toxicity is low, insecticidal spectrum is wide, has stronger stomach poison function to pest, has work of tagging concurrently
With to plant with permeability, but without uptake and translocation effect.Suitable for prevention rice, wheat, vegetables, tea tree, fruit tree, mulberry tree,
Pests with chewing mouthparts and animal parasite and sanitary insect pest on the crops such as cotton etc..The present invention is by different role mechanism
Active ingredient composition, action site increase, be conducive to overcome and delay the generation of insect pest drug resistance, and widened desinsection
Spectrum is especially adapted for prevention vegetables and the sucking pest of fruit, pests with chewing mouthparts, mite class, Lepidoptera evil
Worm.Also, in application, settleability is good.Drift small environmental pollution is light, and the longevity of residure is long, using convenient, solid pharmaceutical preparation
The big raising of stability；It is good to safety of human and livestock, Environmental compatibility.On compounding synergy, had by two kinds of mechanisms of action are different
It imitates into and is grouped as, compound synergic is apparent, is conducive to the generation for avoiding drug resistance and delays the generation speed of germ drug resistance.
Specific implementation mode
The present invention provides a kind of compounded pesticides, for preventing the pest on the cereal and fruit tree such as various vegetables, wheat,
Wherein, the active ingredient is dihalo pyrazole amide and metrifonate, the weight ratio of the dihalo pyrazole amide and metrifonate
It is 1:2~4, it is preferable that the weight ratio of the dihalo pyrazole amide and metrifonate is 1:3.The active ingredient dihalo pyrrole
Azoles amide and the weight percentage of metrifonate in the composition：5%~50%.
Wherein, dihalo pyrazole amide is the wide derivative of health, belongs to 3- halo ethyoxyl pyrazol acid amide compounds, can be efficiently
The ryanodine receptor in insect cell is activated, it is in combination, cause the improper long-time in this receptor channel to open, to excessively release
Intracellular calcium ion is put, insect muscular paralysis is caused, finally, paralysis is dead.Its structure is as shown in general formula I：In formula：R1It is selected from
CH3, ClOr Br；R2Selected from ClOr Br；R3Selected from CH3, CH (CH3)2, CH2C≡CH.Field efficacy discovery, dihalo pyrazole amide
It is notable to pest controling effects such as striped rice borer, rice leaf roller, diamondback moth, bollworm, cabbage caterpillar, nocturnal moth classes.
Metrifonate (Trichlorfon), chemical name 0,0- dimethyl-(2,2,2- tri- chloro- 1- hydroxyethyls) phosphonic acids
Ester.Molecular formula C4H8Cll3O4P, molecule formula weight 257.45.Other entitled poison despot, trichlorine pines.Metrifonate sterling slightly band aroma
The white crystalline powder of body, dissolves in a variety of organic solvents such as benzene, ethyl alcohol, chloroform, methanol, at 25 DEG C, solubility in water
For 154g/L, stablize under room temperature；Its aqueous solution places change acidity for a long time, and hydrolyzed under acidic conditions demethylating generates nontoxic
Demethyl metrifonate；Hydrolyzed under basic conditions sloughs the DDVP that an one's share of expenses for a joint undertaking hydrogen chloride generates toxicity bigger, has corrosion to metal.
Metrifonate toxicity is low toxicity, and male white rat LD50 of passing through mouth is 630mg/kg, and female is 560mg/kg, is that a kind of toxicity is low, kills
Worm composes wide organophosphorus insecticide, has stronger stomach poison function to pest, has action of contace poison concurrently, has permeability to plant, but
Without uptake and translocation effect.Suitable for preventing the chewing type mouth on the crops such as rice, wheat, vegetables, tea tree, fruit tree, mulberry tree, cotton
Device pest and animal parasite and sanitary insect pest etc..
The compounded pesticides still further comprise pesticidal preparations auxiliary element comprising pesticide stabilizer, pesticide bond
Agent, pesticide wetting agent；Carrier；Stabilizer 1%~10%；Pesticide wetting agent：1%~10%；Binder：1%~3%；Carrier：
37%~93%.
Wherein, the pesticide stabilizer is ammonium sulfate, ammonium chloride, methyl oleate, white carbon, talcum powder, styryl benzene
Fluosite, polyoxyethylene poly-oxygen propylene aether phosphate, ammonium trideceth, ammonium trideceth phosphoric acid
It is one or more in ester, organosilicon, urea；Pesticide binder be starch, dextrin, polyethylene glycol, polyvinyl alcohol, xanthans,
It is one or more in gelatin, Shi Que；Carrier is one kind or more in clay, kaolin, diatomite, gangue, slag, sand
Kind.
The wetting agent is polystyrene-based phenol formaldehyde resin polyoxyethylene phosphate polymer, accounts for disinsection compound group
The proportioning of conjunction：1%~10%, structural formula indicates as follows：
Molecular weight distribution is 3000~4000g/mol, wherein (n1+n2) value equal to 40~55, m value be equal to 15~
20。
The wetting agent is the polysiloxanes that the allyl polyether of methoxy group is modified, and accounts for matching for disinsection compound combination
Than：1%~10%, the degree of polymerization is 4~15, and structural formula indicates as follows：
Molecular weight distribution is 350~1222g/mol, wherein：N values are equal to 5~15, and surface tension is 25~30Nm-1.
Following embodiment sketches the application proportioning of compounded pesticides, and the treatment dosage of field efficacy is that active ingredient is used
Amount, percentage are weight percentage.
Embodiment one
20% compounded pesticides
Formula：Dihalo pyrazole amide 4kg, metrifonate 16kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate
6kg, organosilicon 2kg, starch 1.5kg, diatomite complement to 100kg.
Embodiment two
16% compounded pesticides
Formula：Dihalo pyrazole amide 4kg, metrifonate 12kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate
5kg, organosilicon 2kg, starch 2kg, diatomite complement to 100kg.
Embodiment three
12% compounded pesticides
Formula：Dihalo pyrazole amide 4kg, metrifonate 8kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate
5kg, organosilicon 2kg, starch 3kg, diatomite complement to 100kg.
Illustrate the preparation method of compounded pesticides below：
Carrier diatomaceous earth is sent into jaw crusher and will be crushed by step 1), and granularity control is broken in 0.5-3cm
Carrier is dried to moisture in 100-180 DEG C and is less than 3%,
Step 2) then, by carrier is sent into warehouse cooled to room temperature, spare；
Step 3) send dihalo pyrazole amide and metrifonate, surfactant and other functional aids successively in proportion
It is just mixed to enter the interior progress of premixer, then, is crushed in the material feeding ultrafine crusher after just mixing, the material after crushing
It is again introduced into mixing machine and is uniformly mixed；
Step 4) is added binder and is mediated, and the material after kneading is sent into comminutor, particle is made, Control granularity
For 100-200 mesh, the solia particle agent of column or approximate sphericity is obtained through drying, screening.
Diamondback moth, which is prevented, using Examples 1 to 3 and comparative example 1~2 carries out field control effectiveness test such as table 1.
1 Examples 1 to 3 of table prevents the field control effectiveness test result of diamondback moth with comparative example 1~2
It can be seen that by 1 test result of table：Embodiment is less than or equal to single dose in the mu dosage of complex agent type active ingredient
In the case of, compounded pesticides prevention diamondback moth drug effect of the present invention is excellent, and drug effect is substantially better than 10% dihalo pyrrole of corresponding single dose
Azoles amide and 6% metrifonate granule illustrate that dihalo pyrazole amide of the present invention mixes granula with metrifonate and mutually mixes in specific proportions
With apparent synergistic effect.Field observation during experiment, embodiment medicament respectively handle liquid to plant growth without influence, to week
Beneficial organism safety is enclosed, being compatible with the environment property is good.It can be seen that dihalo pyrazole amide is that an ideal is killed with metrifonate compounding
Worm agent mixture.
Technical scheme of the present invention and advantageous effect are described further by the following examples.
First, the two compounding is proved with hundred granule co-toxicity bioassay tests of enemy using dihalo pyrazole amide
Drug effect enhances afterwards.
One, test method
For trying target：Cabbage caterpillar
Test medicament：96% dihalo pyrazole amide active compound (is produced) by Zibo elder generation Long Da pesticides Co., Ltd；Metrifonate is former
Medicine (Jiangshan Pesticides ＆ Chemical Co., Ltd., Nantong)；Dihalo pyrazole amide is with metrifonate with different weight than compounding mixture.
Test method：By suitable dihalo pyrazole amide and metrifonate with different weight ratio (1:6,1:5,1:4,1:3,
1:2,1:1) mixing is made into binary built agent as No. 1-mixture of mixture 4, by mixture dihalo pyrazole amide and metrifonate two
No. 1-mixture of kind single dose and mixture 4 is diluted to 10ppm.On the basis of pilot study, with above method respectively to single dose
Dihalo pyrazole amide and metrifonate toxicity test, the two EC50 values are respectively 49.89mg/l and 294.43mg/l.
Using the first leaching leaf method that is followed by worm, by not in contact with the cabbage leaves of the same size of excessively any medicament respectively with
It is taken out after impregnating 5s in good liquid, naturally dry is put into insect box, and access is raised, often for trying larva under the conditions of 25 DEG C
3 repetitions are handled, it is 30 often to repeat test worm number used, while setting blank control, and dead borer population was checked in 72 hours, is calculated dead
Rate and corrected mortality acquire virulence regression equation and calculate LC50 values.If compareing the death rate is more than 10%, it is considered as invalid examination
It tests.
Calculation formula is as follows：
Borer population × 100% living before the death rate (%)=(borer population living after borer population-dispenser of living before dispenser)/dispenser
Corrected mortality (%)=(the processing group death rate-control group death rate)/(the 1- control groups death rate) × 100%
It will be converted into probit value (y) for examination insect corrected mortality, concentration for the treatment of (μ g/ml) is converted into logarithm (x), with
Least square method obtains virulence regression equation, and thus calculates the value of each medicament.It is calculated altogether according to the abundant equations of Sun Yun
Malicious coefficient CTC.
Calculation formula is as follows：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) * 100
The toxicity index of percentage composition (%)+B of A in the toxicity index ATI* mixtures of theoretical toxicity index (TTI)=A
Percentage composition (%) in ATI* mixtures
Co-toxicity coefficient (CTC)=(ATI/TTI) * 100
If co-toxicity coefficient is big by 120, show there is synergistic effect；If being significantly lower than 100 (80 or less), it is shown to be antagonism；
Between 100~120, it is shown to be summation action.
Test result is as shown in table 1, and A represents dihalo pyrazole amide in table, and B represents metrifonate.
Toxicity measurement result of the table 2 to 1~2 age diamondback moth
As known from Table 2, dihalo pyrazole amide is preventing the proportioning of 1~2 age diamondback moth 1 with metrifonate：It is total to when 1~4
Malicious coefficient is higher than 120, has synergistic effect, especially 1:When 3, synergistic effect is most apparent.Prove dihalo provided by the invention
Pyrazole amide and metrifonate mixture compounded pesticides synergistic effect are apparent.
Field efficacy plot experiment method is used below, further proves that compounded pesticides of the present invention are applied in crop field to killing
Worm has synergistic effect, and can be used in crop field.
One, experimental condition
1, subjects and trial crops
Subjects：Diamondback moth
Trial crops：Wild cabbage
2, environmental condition
Field trial is being arranged in the progress of Guangdong Province Baiyun District base, and the field gesture is flat, and wild cabbage growing way is almost the same.
Two, experimental design
1, medicament
1.1, test medicine
Select medicament made from following example 1~3.
1.2, comparison medicament
1 medicament of comparative example：10% dihalo pyrazole amide granule
2 medicament of comparative example：6% metrifonate granule
1.3, blank control
If without using the blank control of any medicament
2, cell arrangement：Test medicine, comparison medicament and the processing of the cell of blank control are arranged using random district's groups, are used
Fixed point investigation, 5 plants are pinpointed per cell.
Number of repetition：Each processing is repeated 4 times.
3, control time and number
Radix is investigated：Before dispenser processing
Second of investigation：After dispenser handles 1d
Third time is investigated：After dispenser handles 3d
4th investigation：After dispenser handles 7d
3.3, drug effect computational methods
Drug effect calculates as follows
Borer population × 100% living before the insect population death rate (%)=(borer population living after borer population-dispenser of living before dispenser)/dispenser
Corrected mortality (%)=(the processing group death rate-control group death rate)/(the 1- control groups death rate) × 100%
4, to the influence of crop
4.1, chemical injury of crops is influenced
Chemicals treatment district is compared with blank district, whether continuous 7d range estimations medicament has medicine to crop after dispenser
Evil evaluates poisoning：Plant growth is normal, is influenced substantially without poisoning.
4.2, other biological is influenced
On water around, soil, air etc. substantially without influence, Oral toxicity experiment is actually nontoxic to mouse oral.
5, result
Significance test is carried out by DMRT (the new multipoles of Deng Kenshi are poor) method, evaluates preventive effect.
The present invention contains the compounded pesticides of dihalo pyrazole amide and metrifonate granule, is mainly used for preventing a variety of vegetables
Diamondback moth, cabbage caterpillar, beet armyworm, prodenia litura, Oeobia undalis, vegetable aphid, liriomyza bryoniae, thrips on the cereal and fruit tree such as dish, wheat,
The various pests such as rust mite.
The present invention is described in detail above, described above, only the preferred embodiments of the invention, when cannot
Limit the scope of the present invention, i.e., it is all according to the made equivalent changes and modifications of the application range, it all should still belong to covering scope of the present invention
It is interior.
Claims (10)
1. a kind of compounded pesticides, for preventing the pest on the cereal and fruit tree such as various vegetables, wheat, it is characterised in that：Institute
Active ingredient is stated as dihalo pyrazole amide and metrifonate, the weight ratio of the dihalo pyrazole amide and metrifonate is 1:2~
4。
2. compounded pesticides according to claim 1, it is characterised in that：The weight of the dihalo pyrazole amide and metrifonate
Amount is than being 1:3.
3. compounded pesticides according to claim 1, it is characterised in that：The active ingredient dihalo pyrazole amide and enemy
The weight percentage of hundred worms in the composition：5%~50%.
4. compounded pesticides according to claim 1, it is characterised in that：The compounded pesticides still further comprise pesticide
Preparation auxiliary element comprising pesticide stabilizer, pesticide binder, pesticide wetting agent, carrier；Pesticide stabilizer 1%~10%；
Pesticide binder：1%~3%；Pesticide wetting agent 1%~10%；Carrier：37%~93%.
5. compounded pesticides according to claim 1, it is characterised in that：The pesticide stabilizer be ammonium sulfate, ammonium chloride,
Methyl oleate, white carbon, talcum powder, styrylphenol formaldehyde resin, polyoxyethylene poly-oxygen propylene aether phosphate, tridecanol
It is one or more in polyoxyethylene ether, ammonium trideceth phosphate, organosilicon, urea；Pesticide binder is to form sediment
It is one or more in powder, dextrin, polyethylene glycol, polyvinyl alcohol, xanthans, gelatin, Shi Que；Carrier is clay, kaolin, silicon
It is one or more in diatomaceous earth, gangue, slag, sand；The pesticide wetting agent is polystyrene-based phenol formaldehyde resin polyoxy
Ethylene phosphate ester polymer.
6. compounded pesticides according to claim 1, it is characterised in that：The pesticide wetting agent is polystyrene-based phenol
Formaldehyde resin polyoxyethylene phosphate polymer, accounts for the proportioning of compounded pesticides：1%~10%, structural formula indicates as follows：
Molecular weight distribution is 3000~4000g/mol, wherein value of the value of (n1+n2) equal to 40~55, m is equal to 15~20.
7. compounded pesticides according to claim 1, it is characterised in that：The wetting agent is the allyl of methoxy group
The polyether-modified polysiloxanes of base, accounts for the proportioning of compounded pesticides：1%~10%, the degree of polymerization is 4~15, structural formula table
Show as follows：
Molecular weight distribution is 350~1222g/mol, and wherein n values are equal to 5~15, and surface tension is 25~30Nm-1.
8. compounded pesticides according to claim 1, it is characterised in that：Each group distribution ratio in the compounded pesticides：Two
Halo-pyrazole amide 4kg, metrifonate 16kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate 6kg, organosilicon 2kg form sediment
Powder 1.5kg, diatomite complement to 100kg.
9. compounded pesticides according to claim 1, it is characterised in that：Each group distribution ratio in the compounded pesticides：Two
Halo-pyrazole amide 4kg, metrifonate 12kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate 5kg, organosilicon 2kg form sediment
Powder 2kg, diatomite complement to 100kg.
10. compounded pesticides according to claim 1, it is characterised in that：Each group distribution ratio in the compounded pesticides：Two
Halo-pyrazole amide 4kg, metrifonate 8kg, phenethyl phenol polyethenoxy ether polyoxypropylene ether phosphate 5kg, organosilicon 2kg form sediment
Powder 3kg, diatomite complement to 100kg.
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| CN201810375272.8A CN108432800A (en) | 2018-04-24 | 2018-04-24 | A kind of compounded pesticides |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN107484760A (en) * | 2017-09-25 | 2017-12-19 | 广东省工业技术成果转化推广中心 | Dihalo pyrazole amide and ethyl pleocidin complex composition |
-
2018
- 2018-04-24 CN CN201810375272.8A patent/CN108432800A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN107484760A (en) * | 2017-09-25 | 2017-12-19 | 广东省工业技术成果转化推广中心 | Dihalo pyrazole amide and ethyl pleocidin complex composition |
Non-Patent Citations (1)
| Title |
|---|
| 耿丙新 等: "二卤代吡唑酰胺类化合物的合成及其应用", 《农药》 * |
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