CN107484760A - Dihalo pyrazole amide and ethyl pleocidin complex composition - Google Patents
Dihalo pyrazole amide and ethyl pleocidin complex composition Download PDFInfo
- Publication number
- CN107484760A CN107484760A CN201710875439.2A CN201710875439A CN107484760A CN 107484760 A CN107484760 A CN 107484760A CN 201710875439 A CN201710875439 A CN 201710875439A CN 107484760 A CN107484760 A CN 107484760A
- Authority
- CN
- China
- Prior art keywords
- ethyl pleocidin
- pyrazole amide
- complex composition
- dihalo
- dihalo pyrazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
Abstract
The invention discloses a kind of dihalo pyrazole amide and ethyl pleocidin complex composition, and it contains active ingredient dihalo pyrazole amide and ethyl pleocidin, and both percentage by weights are preferably 1:1~4, and can further increase the auxiliary agent being made up of surfactant, antifreezing agent and thickener, it is watered and aqueous suspension agent is made.The present invention is made up of the active ingredient of different mechanism of action, action site increase, is advantageous to overcome and delays the drug-fast generation of insect pest, and widened insecticidal spectrum, it is especially suitable for preventing and treating the sucking pest of vegetables and fruit, pests with chewing mouthparts, mite class, lepidoptera pest.
Description
Technical field
The invention belongs to technical field of agricultural insecticide, more particularly to a kind of dihalo pyrazole amide and ethyl pleocidin
Complex composition.
Background technology
It is to prevent and treat the maximally efficient means of plant pest using chemical agent in the real process of agricultural production, but
It is easiest to generate the problem that the generation of pest resistance to insecticide by chemical prevention insect.And the administration of long-term continuous high dose is single
One chemical insecticide, a series of problems, such as easily causing residual, the environmental pollution of medicament rational chemical insecticide compounding or
Mixture, which has, expands insecticidal spectrum, improves prevention effect, extends the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, prolong
Delay the positive feature such as insect evil mite drug resistance and drug-fast generation and development, insecticidal/acaricidal agent compounding or mixture are that solution is above-mentioned
One of maximally efficient method of problem.Develop new product insecticide price is constantly soaring, and by contrast, exploitation is high with research
Effect, low toxicity, the compounding of low-residual and mixture has small investment, the lead time is short and is paid attention to both at home and abroad, numerous and confused increasing is developed
Development dynamics.So far it is not yet found that closing the insecticides of dihalo pyrazole amide and ethyl pleocidin.
The content of the invention
In view of this, it is an object of the invention to provide a kind of dihalo pyrazole amide and ethyl pleocidin compounded combination
Thing, it is a kind of efficient, low toxicity, the insecticide of low-residual.
Used technical scheme is：
A kind of dihalo pyrazole amide and ethyl pleocidin complex composition, it contains active ingredient dihalo pyrazoles acyl
Amine and ethyl pleocidin.
Further, the weight of dihalo pyrazole amide and ethyl pleocidin ratio is 1：1~4, such as 1:1,1:2,1:3
With 1:4, preferably 1:3.
Above-mentioned active ingredient dihalo pyrazole amide can pass through various commercial channel or city respectively with ethyl pleocidin
Bought on.
Further, also containing surfactant, antifreezing agent and thickener, and homogeneous phase is watered into, composition is made
Aqueous suspension agent.According to the needs used, add the pesticidal preparations auxiliary of pesticide field surfactant, antifreezing agent and thickener into
Point or auxiliary agent, add water that the composition of auxiliary agent and active ingredient is made into aqueous suspension agent.Auxiliary agent can make suspensibility ＞ 98%, enter one
Step increase soaks and drug effect greatly improved, and the preventive effect time lengthens, and the field rate of active ingredient further declines, and reduces life
Production and use cost, reduce residues of pesticides and environmental pollution.
Further, dihalo pyrazole amide is with the weight percentage in ethyl pleocidin composition：5%~
50%.
Further, the one kind or more of the surfactant in emulsifying agent, dispersant, wetting agent and bleeding agent
Kind.Can surfactant be further preferably nonionic surfactant and the complex preparation of anion surfactant.
Further, the wetting agent is the poly- silicon of the allyl polyether modification for the methoxy group that the degree of polymerization is 4~12
Oxygen alkane, its structural formula represent as follows：
Molecular weight distribution is 350~1000g/mol, and wherein n values are equal to 4~12, and surface tension is 25~30Nm-1。
Further, the surfactant is phenethyl phenol polyoxyethylene poly-oxygen propylene aether phosphate ester polymer, organic
Silicon, the dioctyl Succinate sodium sulfonate that the degree of polymerization is 3~7 or one kind in isooctanol polyethoxylate or two kinds；The benzene
Ethyl phenol polyoxyethylene poly-oxygen propylene aether phosphate ester polymer, its structural formula represent as follows：
Molecular weight distribution is 3000~4000g/mol, wherein value of the value of (a+b) equal to 40~55, m is equal to 15~20.
Further, one or more of the antifreezing agent in ethylene glycol, propane diols, glycerine and urea.
Further, the thickener is selected from gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, Sodium Polyacrylate, changed
One or more in property starch, xanthans, bentonite, silica and Magnesiumaluminumsilicate.
Further, the suspensibility of the aqueous suspension agent is more than 98%, can be allowed to form transparent homogeneous phase, preferably send out
Wave drug effect.
The beneficial effects of the present invention are：
1st, the present invention is made up of the active ingredient of different mechanism of action, action site increase, is advantageous to overcome and delay worm
The drug-fast generation of evil, and insecticidal spectrum has been widened, it is especially suitable for preventing and treating sucking pest, the nozzle of vegetables and fruit
Chew formula mouthpart insect, mite class, lepidoptera pest.
2nd, compared with using one-component insecticide, produce the risk of poisoning reduces the present invention；It is compatible to person poultry safety, environment
Property is good.
3rd, the present invention is made up of two kinds of different active ingredients of the mechanism of action, is advantageous to avoid drug-fast generation and is delayed
The drug-fast generation speed of germ.
4th, present invention can be mainly used for preventing and treating various vegetables, the diamondback moth on the cereal and fruit tree such as wheat, cabbage caterpillar, beet
The various pests such as noctuid, prodenia litura, Oeobia undalis, vegetable aphid, liriomyza bryoniae, thrips, rust mite.
Embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these exemplary embodiments and
Purpose is only used for enumerating the present invention, not forms any type of any restriction to the real protection scope of the present invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Experiment one
Co-toxicity bioassay test after being compounded first using dihalo pyrazole amide with ethyl pleocidin suspending agent,
To prove that drug effect strengthens after both compoundings.
First, test method
For trying target：Diamondback moth
Test medicine：96% dihalo pyrazole amide active compound, produced by Zibo elder generation Long Da agricultural chemicals Co., Ltd；Ethyl kills more
Rhzomorph active compound, Shaanxi Hui Cheng bio tech ltd；Dihalo pyrazole amide is with ethyl pleocidin with different weight than multiple
With mixture.
Test method：By appropriate dihalo pyrazole amide and ethyl pleocidin with different weight ratio (1:6,1:5,1:
4,1:3,1:2,1:1) aqueous suspension agent composition is made into, then is made into 10000 μ g/ml mother liquors, it is stand-by in 4 DEG C of preservations.
On the basis of pilot study, with above method respectively to single dose dihalo pyrazole amide and ethyl pleocidin poison
Power determines, and the two EC50 value is respectively 0.53mg/l and 2.27mg/l.
Using the first leaching leaf method that is followed by worm, by not in contact with the cabbage leaves of the same size of excessively any medicament respectively with
Taken out after soaking 5s in good decoction, naturally dry is put into insect box, and access is raised, often for examination larva under the conditions of 25 DEG C
3 repetitions are handled, it is 30 often to repeat test worm number used, while sets blank control, and dead borer population was checked in 72 hours, is calculated dead
Rate and corrected mortality, try to achieve virulence regression equation and calculate LC50 values.If compareing the death rate is more than 10%, it is considered as invalid examination
Test.Calculation formula is as follows：
Borer population × 100% living before the death rate (%)=(borer population living after borer population-dispenser living before dispenser)/dispenser
Corrected mortality (%)=(the treatment group death rate-control group death rate)/(the 1- control groups death rate) × 100%
Probit value (y) will be converted into for examination insect corrected mortality, concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with
Least square method draws virulence regression equation, and thus calculates the value of every kind of medicament.Calculated altogether according to the abundant equations of Sun Yun
Malicious coefficient CTC.Calculation formula is as follows：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) * 100
A percentage composition (%)+B toxicity index in theoretical toxicity index (TTI)=A toxicity index ATI* mixtures
Percentage composition (%) in ATI* mixtures
Co-toxicity coefficient (CTC)=(ATI/TTI) * 100
If co-toxicity coefficient is big by 120, show there is synergistic effect；If being significantly lower than 100 (less than 80), it is shown to be short of money
Anti- effect；Between 100~120, summation action is shown to be.
Result of the test is as shown in table 1, and A represents dihalo pyrazole amide in table, and B represents ethyl pleocidin.
Toxicity measurement result of the table 1 to 1~2 age diamondback moth
As known from Table 1, dihalo pyrazole amide kills more with ethyl is preventing and treating the proportioning of 1~2 age diamondback moth 1：When 1~4
Co-toxicity coefficient is higher than 120, has synergistic effect, especially 1:When 3, synergistic effect is most obvious.Prove dihalo- provided by the invention
It is obvious for pyrazole amide and the effect of ethyl pleocidin mixture synergism.
Experiment two
Field efficacy plot experiment method is used below, further proves that dihalo pyrazole amide hangs with ethyl pleocidin
Floating agent compounding is applied in crop field synergistic effect to desinsection, and can be used in crop field.
First, experimental condition
1st, subjects and trial crops
Subjects：Diamondback moth
Trial crops：Wild cabbage
2nd, environmental condition
Field test is being arranged in the progress of Guangdong Province Baiyun District base, and the field gesture is flat, and wild cabbage growing way is basically identical.
2nd, experimental design
1st, medicament
1.1st, test medicine
From medicament made from example 1 below~3.
1.2nd, comparison medicament
The medicament of comparative example 1：10% dihalo pyrazole amide aqueous suspension agent
The medicament of comparative example 2：6% ethyl pleocidin aqueous suspension agent
1.3rd, blank control
If without using the blank control of any medicament
2nd, cell arrangement：Test medicine, comparison medicament and the processing of the cell of blank control are arranged using random district's groups, are used
Fixed point investigation, 5 plants are pinpointed per cell.
Number of repetition：Each processing is repeated 4 times.
3rd, control time and number
Radix is investigated：Dispenser before processing
Second of investigation：After dispenser processing 1d
Third time is investigated：After dispenser processing 3d
4th investigation：After dispenser processing 7d
3.3rd, drug effect computational methods
Drug effect calculates as follows
Borer population × 100% living before the insect population death rate (%)=(borer population living after borer population-dispenser living before dispenser)/dispenser
Corrected mortality (%)=(the treatment group death rate-control group death rate)/(the 1- control groups death rate) × 100%
4th, to the influence of crop
4.1st, chemical injury of crops is influenceed
By chemicals treatment district compared with blank district, whether continuous 7d range estimations medicament has medicine to crop after dispenser
Evil, evaluate poisoning：Plant growth is normal, is influenceed substantially without poisoning.
4.2nd, other biological is influenceed
It is actually nontoxic to its mouse oral substantially without influence, Oral toxicity experiment on ambient water, soil, air etc..
5th, result
Significance test is carried out by DMRT (the new multipoles of Deng Kenshi are poor) method, evaluates preventive effect.
Percentage is weight percentage in following examples, and the treatment dosage of field efficacy is effective ingredient consumption.
Embodiment 1
(wherein 20% is active ingredient dihalo pyrazoles to 20% dihalo pyrazole amide ethyl pleocidin aqueous suspension agent
The content sum of acid amides and ethyl pleocidin), it is made up of following component and content：
Embodiment 2
(wherein 12% is active ingredient dihalo pyrazoles to 12% dihalo pyrazole amide ethyl pleocidin aqueous suspension agent
The content sum of acid amides and ethyl pleocidin), it is made up of following component and content：
Embodiment 3
(wherein 12% is active ingredient dihalo pyrazoles to 12% dihalo pyrazole amide ethyl pleocidin aqueous suspension agent
The content sum of acid amides and ethyl pleocidin), it is made up of following component and content：
Above-described embodiment 1-3 preparation method is：By the embodiment 1-3 components provided and its percentage by weight, by two
Halo-pyrazole acid amides is sequentially placed into reactor with ethyl pleocidin, surfactant and other functional aids, adds water to mix
Close uniform, in high speed shear dispersion emulsifying machine, 20min is disperseed under 3000r/min rotating speeds, then through rotating speed be 1500r/min
Sand mill be sanded 2.5h, screening obtain particle diameter be 0.5~5 μm.
Diamondback moth, which is prevented and treated, using embodiment 1~3 and comparative example 1~2 carries out field control effectiveness test such as table 2.
The embodiment 1~3 of table 2 prevents and treats the field control effectiveness test result of diamondback moth with comparative example 1~2
It can be seen that by the result of the test of table 2：Embodiment is less than or equal to single dose in the mu dosage of complex agent type active ingredient
In the case of, dihalo pyrazole amide and ethyl pleocidin suspending agent built composition for preventing and controlling diamondback moth drug effect of the present invention is excellent
Good, drug effect is substantially better than corresponding the dihalo pyrazole amide of single dose 10% and 6% ethyl pleocidin suspending agent, illustrates the present invention two
Halo-pyrazole acid amides and ethyl pleocidin suspending agent complex composition have obvious synergistic effect.Field is seen during experiment
Examine, embodiment 1-3 medicaments respectively handle decoction to plant growth without influence, and to the safety of beneficial organism around, being compatible with the environment property is good.
As can be seen here, dihalo pyrazole amide and ethyl pleocidin compounding are a preferable insecticide mixtures.
It should be appreciated that these embodiments and the purposes of experiment are merely to illustrate the present invention and are not intended to the guarantor of the limitation present invention
Protect scope.In addition, it should also be understood that, after the technology contents of the present invention have been read, those skilled in the art can be to the present invention
Make various change, modification and/or variation, all these equivalent form of values equally fall within the application appended claims and limited
Protection domain within.
Claims (10)
1. a kind of dihalo pyrazole amide and ethyl pleocidin complex composition, it is characterised in that it contains active ingredient two
Halo-pyrazole acid amides and ethyl pleocidin.
2. dihalo pyrazole amide according to claim 1 and ethyl pleocidin complex composition, it is characterised in that two
The weight of halo-pyrazole acid amides and ethyl pleocidin ratio is 1:1~4.
3. dihalo pyrazole amide according to claim 1 and ethyl pleocidin complex composition, it is characterised in that also
Containing surfactant, antifreezing agent and thickener, and homogeneous phase is watered into, aqueous suspension agent is made in composition.
4. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that two
Halo-pyrazole acid amides is with the weight percentage in ethyl pleocidin composition：5%~50%.
5. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that institute
State one or more of the surfactant in emulsifying agent, dispersant, wetting agent and bleeding agent.
6. dihalo pyrazole amide according to claim 5 and ethyl pleocidin complex composition, it is characterised in that institute
The polysiloxanes that the allyl polyether that wetting agent is the methoxy group that the degree of polymerization is 4~12 is modified is stated, its structural formula represents such as
Under：
Molecular weight distribution is 350~1000g/mol, and wherein n values are equal to 4~12, and surface tension is 25~30Nm-1。
7. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that institute
It is phenethyl phenol polyoxyethylene poly-oxygen propylene aether phosphate ester polymer, organosilicon, two that the degree of polymerization is 3~7 to state surfactant
One kind in octyl group Succinate sodium sulfonate or isooctanol polyethoxylate or two kinds；The phenethyl phenol polyoxyethylene polyoxy third
Alkene ether phosphate polymer, its structural formula represent as follows：
Molecular weight distribution is 3000~4000g/mol, wherein value of the value of (a+b) equal to 40~55, m is equal to 15~20.
8. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that institute
State one or more of the antifreezing agent in ethylene glycol, propane diols, glycerine and urea.
9. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that institute
State thickener and be selected from gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, Sodium Polyacrylate, modified starch, xanthans, swelling
One or more in soil, silica and Magnesiumaluminumsilicate.
10. dihalo pyrazole amide according to claim 3 and ethyl pleocidin complex composition, it is characterised in that
The suspensibility of the aqueous suspension agent is more than 98%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710875439.2A CN107484760A (en) | 2017-09-25 | 2017-09-25 | Dihalo pyrazole amide and ethyl pleocidin complex composition |
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| CN201710875439.2A CN107484760A (en) | 2017-09-25 | 2017-09-25 | Dihalo pyrazole amide and ethyl pleocidin complex composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108432800A (en) * | 2018-04-24 | 2018-08-24 | 广东省工业技术成果转化推广中心 | A kind of compounded pesticides |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101184747A (en) * | 2005-04-20 | 2008-05-21 | 先正达参股股份有限公司 | Cyano anthranilamide insecticides |
| CN102599167A (en) * | 2012-01-18 | 2012-07-25 | 华南理工大学 | Chlorantraniliprole and Spinetoram compound suspending agent and preparation method thereof |
| CN103232431A (en) * | 2013-01-25 | 2013-08-07 | 青岛科技大学 | Dihalogenated pyrazole amide compound and its use |
| CN105379760A (en) * | 2015-10-21 | 2016-03-09 | 江西新龙生物科技股份有限公司 | Viral insecticide containing dihalo pyrazole amide |
-
2017
- 2017-09-25 CN CN201710875439.2A patent/CN107484760A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101184747A (en) * | 2005-04-20 | 2008-05-21 | 先正达参股股份有限公司 | Cyano anthranilamide insecticides |
| CN102599167A (en) * | 2012-01-18 | 2012-07-25 | 华南理工大学 | Chlorantraniliprole and Spinetoram compound suspending agent and preparation method thereof |
| CN103232431A (en) * | 2013-01-25 | 2013-08-07 | 青岛科技大学 | Dihalogenated pyrazole amide compound and its use |
| CN105379760A (en) * | 2015-10-21 | 2016-03-09 | 江西新龙生物科技股份有限公司 | Viral insecticide containing dihalo pyrazole amide |
Non-Patent Citations (2)
| Title |
|---|
| 吴浩杰等: ""聚醚接枝硅氧烷类表面活性剂的制备"", 《皮革与化工》 * |
| 耿丙新等: ""二卤代吡唑酰胺类化合物的合成及其应用"", 《农药》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108432800A (en) * | 2018-04-24 | 2018-08-24 | 广东省工业技术成果转化推广中心 | A kind of compounded pesticides |
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