CN105379760A - Viral insecticide containing dihalo pyrazole amide - Google Patents
Viral insecticide containing dihalo pyrazole amide Download PDFInfo
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- CN105379760A CN105379760A CN201510688705.1A CN201510688705A CN105379760A CN 105379760 A CN105379760 A CN 105379760A CN 201510688705 A CN201510688705 A CN 201510688705A CN 105379760 A CN105379760 A CN 105379760A
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- Prior art keywords
- pyrazole amide
- dihalo pyrazole
- nuclear polyhedrosis
- polyhedrosis virus
- viral insecticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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Abstract
The invention discloses viral insecticide containing dihalo pyrazole amide. The viral insecticide consists of dihalo pyrazole amide, adjuvants and insect viruses, wherein the adjuvants comprise a carrier, a dispersant, an antifreezer, an antifoamer, a humectant and an ultraviolet protecting agent. According to the viral insecticide disclosed by the invention, dihalo pyrazole amide and the insect viruses serve as effective ingredients and are compounded, so that the insecticidal spectrum is enlarged, the synergistic effect is obvious, the pest killing speed is increased, the insecticidal duration is prolonged, the usage amount of the effective ingredients is reduced, the safety is enhanced, the generation of insecticide resistance of pests is retarded, and thus, the viral insecticide can be extensively applied to the field of agriculture.
Description
Technical field
The present invention relates to pesticide field, specifically a kind of viral insecticide containing dihalo pyrazole amide.
Background technology
Insect is the general designation of the insect to human hazard.Agricultural chemicals refers to the mankind in order to pest control, and the medicament used.Shi Ge large agricultural country of China, the loss that the harm of insect causes China's agricultural production is huge, and according to incomplete statistics, the agricultural losses that the annual because insect of China is caused are up to 20,000,000,000 dollars.In order to prevent and treat pest, use agricultural chemicals up to 10,000,000,000 dollars in China's year.
Due to the chemical insecticide that people's Long-Time Service is single, insect easily produces resistance, in order to reach the effect of control of insect, have to use more highly toxic agricultural chemicals or strengthen the usage amount of agricultural chemicals, so not only increase the financial burden of peasant, have impact on the safety of agricultural product, and the natural enemy causing a large amount of insect is killed, causes insect more rampant.Have a large amount of mixed insecticides in the market, but great majority are the mixture between chemical pesticide, large to the toxicity of people and animals, after using for a long time, also can produce multi-medicament resistance, this exacerbates the difficulty of prevention and cure of insect further.
The viral species of what insect viruses referred to insect is host, popular propagation in its population, has high vigor, and the selectivity of height and host's property, relies on energy and the metabolic system of host completely.Insect viruses untie virion after being eaten by host insect, by breeding in insect host, destroying the histocyte of insect inside, causing insect death.Known to 1600 various insects at present, there are corresponding insect viruses to infect.The insect viruses reported are more than kind more than 1300.Insect viruses have the safety of the host range of high special, can kill off the insect pests and not affect natural enemy, all do not have infectivity and toxicity to fish, bird, mammal, human body simultaneously.The species barrier of infection host makes insect viruses have people, poultry, the outer biological safety of the targets such as animal.Insect viruses viral load in mechanism can increase, and to horizontal longitudinal propagation, therefore lasting effect is good.Meanwhile, insect viruses can not pollute natural environment in production with in using.One that utilizes that insect viruses control agricultural, forestry, sanitary insect pest are control of insect important developing direction.
Insect viruses have natural enemies security due to it, free from environmental pollution, and insect not easily produces resistance and can form epidemic disease and the features such as long-term control insect density in pest population, and making becomes focus in recent years to the use of insect viruses.But up to the present, insect viruses exist several defect, one is that insecticidal spectrum is narrower, and two is that desinsection speed is comparatively slow, and three is by its active obviously decline after Ultraviolet radiation when Field information.
Dihalo pyrazole amide compound is a kind of compound with high insecticidal activity recently found.In public publication " agricultural chemicals " magazine, 53 volumes the 4th phase in 2014, page 242-page 244, " synthesis of dihalo pyrazol acid amide compounds and application thereof " discloses structure, synthetic method and the activity of dihalo pyrazole amide compound.Structure and the synthetic method of this compound is disclosed in patent CN201310043841.6 " a kind of dihalo pyrazol acid amide compounds and application thereof ".Shown under the structure of this compound,
Wherein, R1=CH
3, Cl or Br; Wherein R
2=Cl or Br or CN; Wherein R
3=H, CH
3, CH
2cH
3, pi-allyl, CH (CH
3)
2, or CH
2cH
2cH
3.
Dihalo pyrazole amide is the derivative compound of Rynaxypyr compound, and it belongs to benzamides.Rynaxypyr is the insecticide that E.I.Du Pont Company produces, and starts to use at China's spread at about 2008, and contacted use 7 years at present, some areas have been found that the resistance of insect to it just constantly strengthens.Through our actual biological activity determination, result shows, for the insect Rynaxypyr not being produced to resistance, the activity of dihalo pyrazole amide is higher.But for insect Rynaxypyr being produced to resistance, the activity of dihalo pyrazole amide is undesirable.This may be cause because the precursor structure of dihalo pyrazole amide is similar with Rynaxypyr precursor structure height.Dihalo pyrazol acid amide compounds is not proposed to the resistance solution of insect Rynaxypyr compounds being produced to resistance in patent CN201310043841.6 " a kind of dihalo pyrazol acid amide compounds and application thereof ".
In order to solve these technical problem existed and defects at present.We find dihalo pyrazole amide and insect viruses mixture to make insecticide mixtures, can solve the resistance problem of dihalo pyrazole amide, can solve the slow problem of insect virus insecticide simultaneously.The two mixture has significant synergistic effect, and synergistic factor is more than 80.Meanwhile, utilize biopesticide and chemical pesticide mixture to use, the usage amount of single chemical pesticide can be reduced, reach the object of chemical pesticide decrement.Meanwhile, in mixture preparation, add antiultraviolet auxiliary agent, ultraviolet effectively can be prevented the loss of insect viruses, further increase insecticidal effect.In addition, proposition dihalo pyrazole amide compound and insect viruses carry out the innovative point that the composition and engineering of mixture is also this patent.
Summary of the invention
The object of the present invention is to provide a kind of viral insecticide containing dihalo pyrazole amide, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A viral insecticide containing dihalo pyrazole amide, is made up of by mass fraction following raw material: dihalo pyrazole amide 0.1 ~ 60wt%, auxiliary material 40 ~ 99.9wt%, insect viruses; The content of inclusion body in insecticide of described insect viruses is 1 ~ 30,000,000,000 PIB/ml.
As the further scheme of the present invention: described insect viruses are Nuclear Polyhedrosis Virus of Mamestra Brassicae, laphygma exigua nuclear polyhedrosis virus, students working while studying, prodenia litura nuclear polyhedrosis virus, rice leaf roller nuclear polyhedrosis virus, euproctis pseudoconspersa nuclear polyhedrosis virus, tea geometrid californica nuclear polyhedrosis virus, leucania separara nuclear polyhedrosis virus, heliothis armigera nuclear polyhedrosis virus, hyphantria cunea nuclear polyhedrosis virus, pine caterpillars nuclear polyhedrosis virus, plutella xylostella granulosis virus or carpocapsa pomonella granulosis virus.
As the further scheme of the present invention: described auxiliary material comprises carrier, dispersant, antifreezing agent, defoamer, wetting agent and ultra-violet protecting agent, and the mass fraction of each auxiliary material shared by this insecticide is respectively: carrier 20 ~ 90wt%, dispersant 1 ~ 15wt%, antifreezing agent 0.5 ~ 10wt%, defoamer 0.5 ~ 5wt%, wetting agent 1 ~ 15wt%, ultra-violet protecting agent 0.1 ~ 1%.
As the further scheme of the present invention: described carrier is one or more mixtures in kaolin, diatomite, precipitated calcium carbonate, white carbon, attapulgite, starch, urea, ammonium sulfate, ammonium chloride, potassium chloride, potassium sulfate, potassium dihydrogen phosphate, ammonium hydrogen phosphate, glucose, maltose.
As the further scheme of the present invention: described dispersant is one or more mixtures in NNO, sodium lignin sulfonate, calcium lignosulfonate, Sodium Polyacrylate, di-2-ethylhexylphosphine oxide naphthalene sulfonate, alkyl amino taurate, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products, polyoxyethylene polyoxypropylene block copolymer, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, sodium phosphate trimer, alkylnaphthalene sulfonate.
As the further scheme of the present invention: described antifreezing agent is one or more mixtures in methyl alcohol, ethanol, isopropyl alcohol, ethylene glycol, propane diols, glycerine.
As the further scheme of the present invention: described defoamer is one or more mixtures in silicone oil, higher alcohol, mineral oil, vegetable oil, aliphatic hydrocarbon, polyvinylether.
As the further scheme of the present invention: described wetting agent is one or more mixtures in neopelex, lauryl sodium sulfate, Negel, fatty alcohol polyglycol ether sulphate, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, Span APEO.
As the further scheme of the present invention: described ultra-violet protecting agent is benzophenone, dimethoxy-benzophenone, octyl methoxycinnamate, octyl salicylate, one or more mixtures in tryptophan.
As the present invention's further scheme: the formulation of this viral insecticide is wetting powder, suspending agent, granule or water dispersible granules.
Compared with prior art, the invention has the beneficial effects as follows: viral insecticide of the present invention is using dihalo pyrazole amide and insect viruses as active ingredient, both are composite, and expand insecticidal spectrum, synergistic effect is obvious, improve the lethal speed of insect, extend the duration of desinsection, decrease the usage amount of active ingredient, add safety, delay the drug-fast generation of insect, can agriculture field be widely used in.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Dihalo pyrazole amide compound is
Biological activity determination selects 2 instar larvaes of indoor feeding, bouncing.Adopt dip method, test worm is put into steel wire, takes out flood 10s in liquid after, be placed on filter paper and creep, after it dries naturally, put into the culture dish that feed is housed, in the artificial illumination climater case of intelligence, design temperature 25 ± 1 DEG C, relative moisture 60%, illumination L:D is 16h:8h.
Through indoor biological determination of activity, Nuclear Polyhedrosis Virus of Mamestra Brassicae and the virulence LC50 of dihalo pyrazole amide to tomato moth are respectively 0.02mg/L, 9500PIB/ml.And mixture 0.01mg/L dihalo pyrazole amide, 4750PIB/ml Nuclear Polyhedrosis Virus of Mamestra Brassicae is 92% to the lethality of tomato moth, in table 1.The malicious factor altogether=(actual measurement lethality-expected mortality)/expected mortality=84, the two mixture has significant synergy benefit.
The toxicity measurement result of table 1 mixture
| Test medicine | Lethality/% |
| 0.02mg/L dihalo pyrazole amide | 50 |
| 9500PIB/ml Nuclear Polyhedrosis Virus of Mamestra Brassicae | 50 |
| 0.01mg/L dihalo pyrazole amide, 4750PIB/ml Nuclear Polyhedrosis Virus of Mamestra Brassicae | 92 |
By Nuclear Polyhedrosis Virus of Mamestra Brassicae mother liquor 20,000,000,000 PIB/ml5kg, dihalo pyrazole amide (95% content) female medicine 2.63kg, polyoxyethylene nonylphenol ether 2kg, polyvinylpyrrolidone 5.5kg, benzophenone 0.2kg, mix with precipitated calcium carbonate polishing 100kg, after pulverizing, be prepared as Nuclear Polyhedrosis Virus of Mamestra Brassicae 1,000,000,000 PIB/g, the wetting powder of 2.5% dihalo pyrazole amide.
Adopt the preparation contrast wetting powder medicament 2,000,000,000 PIB/g Nuclear Polyhedrosis Virus of Mamestra Brassicae that uses the same method, and 5% dihalo pyrazole amide medicament in contrast.Choose tomato moth resistance area, be watered 1000 times and evenly spray.Result of the test is in table 2.The two mixture antagonism tomato moth has significant insect protected synergistic effect, can solve to prevent and treat problem to the tomato moth of dihalo pyrazole amide resistance.
The field test results of table 2 mixture
Embodiment 2
Dihalo pyrazole amide compound is
Biological activity determination selects 2 instar larvaes of indoor feeding, bouncing.Adopt dip method, test worm is put into steel wire, takes out flood 10s in liquid after, be placed on filter paper and creep, after it dries naturally, put into the culture dish that feed is housed, in the artificial illumination climater case of intelligence, design temperature 25 ± 1 DEG C, relative moisture 60%, illumination L:D is 16h:8h.
Through indoor biological determination of activity, heliothis armigera nuclear polyhedrosis virus and the virulence LC50 of dihalo pyrazole amide to cotton bollworm are respectively 0.04mg/L, 15000PIB/ml.And mixture 0.02mg/L dihalo pyrazole amide, 7500PIB/ml heliothis armigera nuclear polyhedrosis virus is 95% to the lethality of cotton bollworm, in table 3.The malicious factor altogether=(actual measurement lethality-expected mortality)/expected mortality=90, the two mixture has significant synergy benefit.
The toxicity measurement result of table 3 mixture
| Test medicine | Lethality/% |
| 0.04mg/L dihalo pyrazole amide | 50 |
| 15000PIB/ml heliothis armigera nuclear polyhedrosis virus | 50 |
| 0.02mg/L dihalo pyrazole amide, 7500PIB/ml heliothis armigera nuclear polyhedrosis virus | 95 |
By heliothis armigera nuclear polyhedrosis virus mother liquor 20,000,000,000 PIB/ml5kg, dihalo pyrazole amide (95% content) female medicine 2.63kg, sodium lignin sulfonate 3kg, Dodecyl Polyoxyethylene Ether 5.5kg, tryptophan 0.2kg, glycerine 3kg, Sodium Polyacrylate 5kg, moisturizing is to 100kg.Above-mentioned raw materials is loaded in sand mill, start sand mill and grind, when sand milling to particle size is less than 3 μm, mixture is dropped into after processing in homogenizer, pour into again in airtight container, prepare heliothis armigera nuclear polyhedrosis virus 1,000,000,000 PIB/ml, the suspending agent of 2.5% dihalo pyrazole amide.
Adopt the preparation contrast suspending agent medicament 2,000,000,000 PIB/ gram of heliothis armigera nuclear polyhedrosis virus that use the same method, and 5% dihalo pyrazole amide medicament in contrast.Choose cotton bollworm high drug-resistance area, be watered 1000 times and evenly spray.Result of the test is in table 4.The two mixture antagonism cotton bollworm has significant insect protected synergistic effect, can solve the cotton bollworm of resistance produces to dihalo pyrazole amide prevent and treat problem.
The field test results of table 4 mixture
Embodiment 3
Dihalo pyrazole amide compound is
Biological activity determination selects 2 instar larvaes of indoor feeding, bouncing.Adopt dip method, test worm is put into steel wire, takes out flood 10s in liquid after, be placed on filter paper and creep, after it dries naturally, put into the culture dish that feed is housed, in the artificial illumination climater case of intelligence, design temperature 25 ± 1 DEG C, relative moisture 60%, illumination L:D is 16h:8h.
Through indoor biological determination of activity, prodenia litura nuclear polyhedrosis virus and the virulence LC50 of dihalo pyrazole amide to prodenia litura are respectively 0.06mg/L, 10000PIB/ml.And mixture 0.03mg/L dihalo pyrazole amide, 5000PIB/ml prodenia litura nuclear polyhedrosis virus is 94% to the lethality of prodenia litura, in table 5.The malicious factor altogether=(actual measurement lethality-expected mortality)/expected mortality=88, the two mixture has significant synergy benefit.
The toxicity measurement result of table 5 mixture
By prodenia litura nuclear polyhedrosis virus mother liquor 20,000,000,000 PIB/ml5kg, dihalo pyrazole amide (95% content) female medicine 2.63kg, lauryl sodium sulfate 2kg, di-2-ethylhexylphosphine oxide naphthalene sulfonate 5.5kg, polyvinyl alcohol 1kg, dimethoxy-benzophenone 0.2kg, mix with kaolin polishing 100kg, certain water gaging mixing extruder grain is added after pulverizing, 1,00k,g10 hundred million PIB/g prodenia litura nuclear polyhedrosis virus is prepared, the water dispersible granules of 2.5% dihalo pyrazole amide after drying screening.
Adopt the preparation contrast water dispersible granules medicament 2,000,000,000 PIB/g prodenia litura nuclear polyhedrosis virus that uses the same method, and 5% dihalo pyrazole amide medicament in contrast.Choose prodenia litura high drug-resistance area, be watered 1000 times and evenly spray.Result of the test is in table 6.The two mixture antagonism prodenia litura has significant insect protected synergistic effect, can solve the control of prodenia litura dihalo pyrazole amide single dose being produced to resistance.
The field test results of table 6 mixture
Test shows, insecticide of the present invention effectively can prevent and kill off the lepidoptera pests such as tomato moth, beet armyworm, prodenia litura, cotton bollworm, be used alone with dihalo pyrazole amide or insect viruses compared with there is obvious synergistic effect.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
Claims (10)
1. the viral insecticide containing dihalo pyrazole amide, is characterized in that, be made up of following raw material by mass fraction: dihalo pyrazole amide 0.1 ~ 60wt%, auxiliary material 40 ~ 99.9wt%, insect viruses; The content of inclusion body in insecticide of described insect viruses is 1 ~ 30,000,000,000 PIB/ml.
2. the viral insecticide containing dihalo pyrazole amide according to claim 1, it is characterized in that, described insect viruses are Nuclear Polyhedrosis Virus of Mamestra Brassicae, laphygma exigua nuclear polyhedrosis virus, students working while studying, prodenia litura nuclear polyhedrosis virus, rice leaf roller nuclear polyhedrosis virus, euproctis pseudoconspersa nuclear polyhedrosis virus, tea geometrid californica nuclear polyhedrosis virus, leucania separara nuclear polyhedrosis virus, heliothis armigera nuclear polyhedrosis virus, hyphantria cunea nuclear polyhedrosis virus, pine caterpillars nuclear polyhedrosis virus, plutella xylostella granulosis virus or carpocapsa pomonella granulosis virus.
3. the viral insecticide containing dihalo pyrazole amide according to claim 1, it is characterized in that, described auxiliary material comprises carrier, dispersant, antifreezing agent, defoamer, wetting agent and ultra-violet protecting agent, and the mass fraction of each auxiliary material shared by this insecticide is respectively: carrier 20 ~ 90wt%, dispersant 1 ~ 15wt%, antifreezing agent 0.5 ~ 10wt%, defoamer 0.5 ~ 5wt%, wetting agent 1 ~ 15wt%, ultra-violet protecting agent 0.1 ~ 1%.
4. the viral insecticide containing dihalo pyrazole amide according to claim 3, it is characterized in that, described carrier is one or more mixtures in kaolin, diatomite, precipitated calcium carbonate, white carbon, attapulgite, starch, urea, ammonium sulfate, ammonium chloride, potassium chloride, potassium sulfate, potassium dihydrogen phosphate, ammonium hydrogen phosphate, glucose, maltose.
5. the viral insecticide containing dihalo pyrazole amide according to claim 3; it is characterized in that, described dispersant is one or more mixtures in NNO, sodium lignin sulfonate, calcium lignosulfonate, Sodium Polyacrylate, di-2-ethylhexylphosphine oxide naphthalene sulfonate, alkyl amino taurate, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products, polyoxyethylene polyoxypropylene block copolymer, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, sodium phosphate trimer, alkylnaphthalene sulfonate.
6. the viral insecticide containing dihalo pyrazole amide according to claim 3, it is characterized in that, described antifreezing agent is one or more mixtures in methyl alcohol, ethanol, isopropyl alcohol, ethylene glycol, propane diols, glycerine.
7. the viral insecticide containing dihalo pyrazole amide according to claim 3, it is characterized in that, described defoamer is one or more mixtures in silicone oil, higher alcohol, mineral oil, vegetable oil, aliphatic hydrocarbon, polyvinylether.
8. the viral insecticide containing dihalo pyrazole amide according to claim 3, it is characterized in that, described wetting agent is one or more mixtures in neopelex, lauryl sodium sulfate, Negel, fatty alcohol polyglycol ether sulphate, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, Span APEO.
9. according to the viral insecticide containing dihalo pyrazole amide according to claim 3, it is characterized in that, described ultra-violet protecting agent is benzophenone, dimethoxy-benzophenone, octyl methoxycinnamate, octyl salicylate, one or more mixtures in tryptophan.
10., according to the viral insecticide containing dihalo pyrazole amide according to claim 1, it is characterized in that, the formulation of this viral insecticide is wetting powder, suspending agent, granule or water dispersible granules.
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| CN106417378A (en) * | 2016-08-10 | 2017-02-22 | 中国科学院武汉病毒研究所 | Broad-spectrum baculovirus biopesticide for preventing and treating snout moth's larvae and preparation method |
| CN107484760A (en) * | 2017-09-25 | 2017-12-19 | 广东省工业技术成果转化推广中心 | Dihalo pyrazole amide and ethyl pleocidin complex composition |
| CN107637591A (en) * | 2016-07-22 | 2018-01-30 | 中国林业科学研究院森林生态环境与保护研究所 | A kind of hyphantria cunea nuclear polyhedrosis virus water dispersible granules and its preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107637591A (en) * | 2016-07-22 | 2018-01-30 | 中国林业科学研究院森林生态环境与保护研究所 | A kind of hyphantria cunea nuclear polyhedrosis virus water dispersible granules and its preparation method and application |
| CN106417378A (en) * | 2016-08-10 | 2017-02-22 | 中国科学院武汉病毒研究所 | Broad-spectrum baculovirus biopesticide for preventing and treating snout moth's larvae and preparation method |
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