CN109329287A - A kind of Pesticidal combination and preparation method thereof - Google Patents
A kind of Pesticidal combination and preparation method thereof Download PDFInfo
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- CN109329287A CN109329287A CN201811548524.9A CN201811548524A CN109329287A CN 109329287 A CN109329287 A CN 109329287A CN 201811548524 A CN201811548524 A CN 201811548524A CN 109329287 A CN109329287 A CN 109329287A
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- Prior art keywords
- capillary
- agent
- pesticidal combination
- thickener
- preservative
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- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000002270 dispersing agent Substances 0.000 claims abstract description 27
- 239000003755 preservative agent Substances 0.000 claims abstract description 27
- 230000002335 preservative effect Effects 0.000 claims abstract description 27
- 239000002562 thickening agent Substances 0.000 claims abstract description 27
- 238000009736 wetting Methods 0.000 claims abstract description 27
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- 239000011365 complex material Substances 0.000 claims abstract description 17
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000005498 polishing Methods 0.000 claims abstract description 14
- 239000003814 drug Substances 0.000 claims description 32
- 238000013329 compounding Methods 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 19
- -1 alkyl phenol Chemical compound 0.000 claims description 17
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 15
- 239000000460 chlorine Substances 0.000 claims description 15
- 229910052801 chlorine Inorganic materials 0.000 claims description 15
- 239000004576 sand Substances 0.000 claims description 14
- 229920000858 Cyclodextrin Polymers 0.000 claims description 13
- 239000001202 beta-cyclodextrine Substances 0.000 claims description 13
- BTIJJDXEELBZFS-QDUVMHSLSA-K hemin Chemical group CC1=C(CCC(O)=O)C(C=C2C(CCC(O)=O)=C(C)\C(N2[Fe](Cl)N23)=C\4)=N\C1=C/C2=C(C)C(C=C)=C3\C=C/1C(C)=C(C=C)C/4=N\1 BTIJJDXEELBZFS-QDUVMHSLSA-K 0.000 claims description 13
- 229940025294 hemin Drugs 0.000 claims description 13
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 11
- 230000036961 partial effect Effects 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000007859 condensation product Substances 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 229940009868 aluminum magnesium silicate Drugs 0.000 claims description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000021003 saturated fats Nutrition 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 241001272567 Hominoidea Species 0.000 claims 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 239000000375 suspending agent Substances 0.000 abstract description 15
- 231100000674 Phytotoxicity Toxicity 0.000 abstract description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 12
- 244000241257 Cucumis melo Species 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 150000001408 amides Chemical class 0.000 description 7
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 6
- 240000001980 Cucurbita pepo Species 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 6
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 235000009852 Cucurbita pepo Nutrition 0.000 description 5
- 230000000749 insecticidal effect Effects 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000500437 Plutella xylostella Species 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 235000021384 green leafy vegetables Nutrition 0.000 description 4
- 238000009781 safety test method Methods 0.000 description 4
- 231100000041 toxicology testing Toxicity 0.000 description 4
- 238000012271 agricultural production Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 244000221633 Brassica rapa subsp chinensis Species 0.000 description 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 2
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 2
- 244000302544 Luffa aegyptiaca Species 0.000 description 2
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 2
- 235000011430 Malus pumila Nutrition 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- 235000015103 Malus silvestris Nutrition 0.000 description 2
- 235000009811 Momordica charantia Nutrition 0.000 description 2
- 240000001910 Momordica cochinchinensis Species 0.000 description 2
- 235000009812 Momordica cochinchinensis Nutrition 0.000 description 2
- 235000018365 Momordica dioica Nutrition 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 235000000832 Ayote Nutrition 0.000 description 1
- 244000036905 Benincasa cerifera Species 0.000 description 1
- 235000011274 Benincasa cerifera Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000219193 Brassicaceae Species 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 208000030453 Drug-Related Side Effects and Adverse reaction Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Pesticidal combinations and preparation method thereof, its suspending agent is by weight percentage, comprising: capillary 1%~30%, Rynaxypyr 1%~30%, wetting dispersing agent 2-8%, safener 0.5%~2.5%, capillary complex materials 1%--3%, antifreezing agent 1%~5%, thickener 0.1%~2%, defoaming agent 0.1%~0.5%, preservative 0.1%~0.4%, deionized water polishing.Pesticidal combination of the invention is safer and more reliable during desinsection, applied widely.Even if extreme environment, using still avoidable phytotoxicity occurs for dosage.
Description
Technical field
The present invention relates to pesticide fields more particularly to a kind of Pesticidal combination and preparation method thereof.
Background technique
Capillary is called chlorfenapyr, belongs to aryl pyrrole compounds, to pest have stomach toxicity and certain action of contace poison and
Systemic activity；Be isolated from the metabolite of streptomyces fungi by American Cyanamid Company in 1985 two dislike pyrroles it is mould
A kind of desinsection, mite killing, the nematicide succeeded in developing on the basis of element.To the preventive effect of brill moth, sucking pest and harmful mite
Excellent, the lasting period is medium, and insecticidal mechanism is the phosphorous oxide acylation for blocking mitochondria.
Registered at present using crop crop have tea tree, Chinese cabbage, wild cabbage, cucumber, section melon, cabbage mustard, pear tree, timber, apple,
Apple tree, eggplant, brassicaceous vegetable, soil, pakchoi, poplar.There are stringent points for attention in its use process: 1, to west
The crops such as melon, cucurbita pepo, balsam pear, muskmelon, muskmelon, wax gourd, pumpkin, Trivhosantnes Kirilouii Manim, sponge gourd are sensitive, phenomena such as burning leaf easily occur.2, it keeps away
Between exempting from high temperature, florescence, Seedling Stage medication, prevent phytotoxicity.
Monitor regional Populations of Diamondback Moth, Plutella Xylostella at present increased capillary resistant multiple compared with 2014, and it is medium extremely
High-level resistant population is concentrated mainly on the southern vegetables production area such as Hunan, Guangdong, Hainan, Yunnan, and (to capillary, resistant multiple is
27~555 times), wherein Sanya, Hainan population is all highest to 3 kinds of drug resistance multiples.With constantly mentioning for pest resistance to insecticide
Height, peasant household also continue to increase the dosage of medicament, this just is difficult to control along with dosing, and Adverse drug events happen occasionally, right
Agricultural production causes massive losses, the maximum limiting factor that this phenomenon is promoted and applied at capillary insecticides.It cracks
This problem has theory and practice meaning very much, and positive promotion will be played to the application development for the compound for being also easy to produce phytotoxicity
Effect, the undoubtedly creative value under the increasingly difficult environment of pesticides discovery.
Specifically, since one of effective component capillary raw medicine is when in use to seedling stage crop in cruciferae and melon spy
It is not watermelon, balsam pear, sponge gourd, cucurbita pepo easily generates and burns leaf phenomenon, and under high temperature environment, overdose, super concentration uses
Phytotoxicity is more serious, causes massive losses to agricultural production, allows means of agricultural production personnel popularization to get up overcautious, this is also pushed away at medicament
The maximum limiting factor extensively applied.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, provide a kind of Pesticidal combination with and preparation method thereof.
To achieve the above object, present invention employs following technical solutions:
On the one hand, the present invention provides a kind of Pesticidal combination, by weight percentage, including capillary 1%~30%, chlorine
Worm benzamide 1%~30%, wetting dispersing agent 2-8%, safener 0.5%~5%, capillary complex materials 1%--3%,
Antifreezing agent 1%~5%, thickener 0.1%~2%, defoaming agent 0.1%~0.5%, preservative 0.1%~0.4%, deionization
Water polishing.
In the above-mentioned technical solutions, further, which is characterized in that the safener is hemin.
Further, capillary complex materials are glucosyl group-β-cyclodextrine.
In the above-mentioned technical solutions, further, the wetting dispersing agent is polycarboxylate, lignosulfonates, alkyl
Phenol polyethenoxy ether formaldehyde condensation products sulfate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkyl phenol polyoxy second
One of alkene ether, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, glycerol fatty acid ester polyoxyethylene ethe are a variety of.
In the above-mentioned technical solutions, further, the antifreezing agent be one of ethylene glycol, propylene glycol, glycerine or
It is a variety of.
In the above-mentioned technical solutions, further, the thickener is xanthan gum, hydroxymethyl cellulose, hydroxy ethyl fiber
One of element, methylcellulose, aluminum magnesium silicate, polyvinyl alcohol are a variety of.
In the above-mentioned technical solutions, further, the defoaming agent is silicone oil, silicone compound C10-20 saturated fat
One of acid compounds, C8-10 fatty alcohols compound are a variety of.
In the above-mentioned technical solutions, further, the preservative is Kathon CG.
In the above-mentioned technical solutions, further, percentage, comprising: capillary 10%, Rynaxypyr
10%, wetting dispersing agent 5%, safener 0.5%, capillary complex materials 2%, antifreezing agent 5%, thickener 0.25%, defoaming
Agent 0.4%, preservative 0.3%, deionized water polishing.
On the other hand, the present invention also provides a kind of preparation methods of Pesticidal combination:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；
Hemin, thickener, antifreezing agent, preservative are added in compounding kettle, stirs evenly.
Further, it is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less.
Drug effect is safer and more reliable in use for Pesticidal combination of the invention, and the scope of application is wider.Even if extreme
Under environment, using still avoidable phytotoxicity occurs for dosage.
In addition, Pesticidal combination preparation method of the invention is rationally effective, suspension is made in medical fluid, convenient for playing medicine
Effect.
Specific embodiment
With reference to embodiments, a specific embodiment of the invention is further illustrated.The present invention is not limited to following embodiments
Description.
Embodiment 1
Present embodiment discloses a kind of Pesticidal combinations, by weight percentage include: capillary 10%, chlorine worm benzoyl
Amine 10%, wetting dispersing agent 5%, safener 0.5%, capillary complex materials 1%, antifreezing agent 5%, thickener 0.25% disappear
Infusion 0.4%, preservative 0.3%, deionized water polishing.
The production stage of the present embodiment includes:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Embodiment 2
Present embodiment discloses a kind of Pesticidal combinations, by weight percentage include: capillary 20%, chlorine worm benzoyl
Amine 10%, wetting dispersing agent 5%, safener 0.8%, capillary complex materials 2%, antifreezing agent 5%, thickener 0.2%, defoaming
Agent 0.4%, preservative 0.3%, deionized water polishing.
The production method of the Pesticidal combination includes:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Embodiment 3
Present embodiment discloses a kind of Pesticidal combinations, by weight percentage include: capillary 30%, chlorine worm benzoyl
Amine 10%, wetting dispersing agent 5%, safener 1.5%, capillary complex materials 3%, antifreezing agent 5%, thickener 0.15% disappear
Infusion 0.4%, preservative 0.3%, deionized water polishing.
The production method of the Pesticidal combination includes:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Embodiment 4
Present embodiment discloses a kind of Pesticidal combination, the component including following weight percent: capillary 1%, chlorine worm
Benzamide 1%, wetting dispersing agent 2%, safener 0.5%, capillary complex materials 1%, antifreezing agent 1%, thickener
0.1%, defoaming agent 0.1%, preservative 0.1%, deionized water polishing.
The wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Embodiment 5
Present embodiment discloses a kind of Pesticidal combinations, it includes the component of following weight percent: capillary 30%, chlorine
Worm benzamide 30%, wetting dispersing agent 8%, safener 5%, capillary complex materials 3%, antifreezing agent 5%, thickener 2%,
Defoaming agent 0.5%, preservative 0.4%, deionized water polishing.
The wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Embodiment 6
Present embodiment discloses a kind of Pesticidal combinations, by weight percentage include: capillary 16%, chlorine worm benzoyl
Amine 8%, wetting dispersing agent 5%, safener 0.5%, capillary complex materials 2%, antifreezing agent 5%, thickener 0.25%, defoaming
Agent 0.4%, preservative 0.3%, deionized water polishing.
The production stage of the present embodiment includes:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, chlorine worm benzene first is added
It opens and is sanded after the mixing of amide raw medicine；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Hemin, thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and makes
Obtain the capillary and its compounding suspending agent of a kind of highly safe type.
Comparative example 1
In this embodiment, a kind of Pesticidal combination: including: capillary 10%, Rynaxypyr 10%, wetting and dispersing
Agent 5%, antifreezing agent 5%, thickener 0.25%, defoaming agent 0.4%, preservative 0.3%, deionized water polishing.
A kind of above-mentioned capillary and its production stage for compounding suspending agent include:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and Rynaxypyr raw medicine is added, high speed shear 30 minutes, opens sand milling after mixing is added；?
It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and obtains a kind of capillary
And its compounding suspending agent.
Comparative example 2
In this embodiment, a kind of Pesticidal combination is formulated by following weight percent composition: including: capillary
20%, Rynaxypyr 10%, wetting dispersing agent 5%, antifreezing agent 5%, thickener 0.2%, defoaming agent 0.4%, preservative
0.3%, deionized water polishing.
A kind of above-mentioned capillary and its production stage for compounding suspending agent include:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and Rynaxypyr raw medicine is added, high speed shear 30 minutes, opens sand milling after mixing is added；?
It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and obtains a kind of capillary
And its compounding suspending agent.
Comparative example 3
In this embodiment, a kind of Pesticidal combination is formulated by following weight percent composition: including: capillary
30%, Rynaxypyr 10%, wetting dispersing agent 5%, antifreezing agent 5%, thickener 0.15%, defoaming agent 0.4%, preservative
0.3%, deionized water polishing.
A kind of above-mentioned capillary and its production stage for compounding suspending agent include:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and Rynaxypyr raw medicine is added, high speed shear 30 minutes, opens sand milling after mixing is added；?
It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less；
Thickener, antifreezing agent, the preservative of recipe requirements are added in compounding kettle, stirs evenly and obtains a kind of capillary
And its compounding suspending agent.
Experiment one
Comparative example 1 is the comparative example of embodiment 1, and the difference of the two is that peace is not added in comparative example 1
Full agent and capillary complex materials；Comparative example 2 is the comparative example of embodiment 2, and comparative example 3 is embodiment 3
Comparative example.
Capillary made from Examples 1 to 3 and the literary Examples 1 to 3 of comparison is floated into agent with compounding for Rynaxypyr,
In 4 leaf phase of leaf vegetables progress safety testing and insect killing effect test, the results are shown in Table 1:
Experiment two
Capillary made from Examples 1 to 3 and the literary Examples 1 to 3 of comparison is floated into agent with compounding for Rynaxypyr,
Safety testing is carried out to cucurbita pepo at a temperature of 35 degree and insecticidal effect, test result are as shown in table 2:
The 4 leaf phase of 1 leaf vegetables of table carries out safety testing and insect killing effect test result
Illustrate the safener hemin and capillary complex materials grape that this patent is added according to the above test result
Glycosyl-β-cyclodextrine greatly improves low age leaf vegetables to the tolerance of medicament, under 250 times of high concentration according to
Right normal growth, no phytotoxicity spot generates, and Revision insect recluced rate reaches 90% or more after seven days, and comparative example is at 1000 times
Spot of also burning under concentration generates, and serious phytotoxicity occur in other processing.
Safety testing and insecticidal effect are carried out to cucurbita pepo at a temperature of 2 35 degree of table
Illustrate the safener hemin and capillary complex materials grape that this patent is added according to the above test result
Glycosyl-β-cyclodextrine greatly improves cucurbita pepo to the tolerance of medicament, even if extreme environment (under 35 degree of high temperature) according to
Right normal growth, no phytotoxicity spot generate, and Revision insect recluced rate reaches 85% or more after seven days, and comparative example is in dilution 3000
Spot of also burning under concentration again generates, and serious phytotoxicity occur in other processing.
The result shows that using all treatment regions of the invention, the west still sensitive to medicament either on low age leaf vegetables
On cucurbit, either high concentration does not occur burn Deng phytotoxicity phenomenon, and after seven days using still extreme environment (35 degree of high temperature)
Revision insect recluced rate reaches 85% or more.
Illustrate a kind of capillary of highly safe type provided by the invention and its compound the preparation method of suspending agent, provides
Capillary compounding suspending agent joined safener hemin, brassicaceous vegetable can be improved after being added and melon to worm mite
The tolerance of nitrile preparation expands the application range of capillary.Capillary complex materials glucosyl group-β-cyclodextrine is created
The addition of property has mitigated the rate of release of capillary, further improves its safety, enhances its compound stability, extends
Insecticidal effect, so that capillary, in brassicaceous vegetable and melon upper security application, even if extreme environment, dosage uses can also
Avoid the generation of phytotoxicity.
In addition, discovery embodiment 1-6 all has brassicaceous vegetable and melon insect pest good by actual use test
Good insecticidal effect, and drug effect is safe and reliable.
It has been surprisingly found that in the process, the compound synergic effect of capillary and Rynaxypyr is fabulous, and has carried out experiment and surveyed
It tries (see Table 3 for details):
| Medicament and proportion | LC50 (95% confidence limit) | Toxicity regression line slope | Co-toxicity coefficient |
| Rynaxypyr L | 16.173 | Y=3.2007+1.4885x | |
| Capillary C | 8.244 | Y=3.6582+1.4646x | |
| L:C=1:16 | 6.290--9.389 | Y=3.8199+1.5417x | 135.85 |
| L:C=1:8 | 5.303-8.057 | Y=3.8329+1.5777x | 142.14 |
| L:C=1:4 | 4.781-7.101 | Y=3.8581+1.6082x | 148.35 |
| L:C=1:2 | 4.520-6.673 | Y=3.8159+1.4523x | 159.65 |
| L:C=1:1 | 4.225-6.226 | Y=3.5899+1.5922x | 179.10 |
The toxicity test of 3 Rynaxypyr of table and capillary antagonism diamondback moth
It is mixed with mass ratio 1:1,1:2,1:4,1:8,1:16 to can be seen that Rynaxypyr and capillary for result from table
The total drugs coefficient of timing, antagonism diamondback moth is respectively 179.10,159.65,148.35,142.14,135.85, is all larger than
120, there is apparent synergistic effect, wherein it is maximum with co-toxicity coefficient when 1:1 mixture, up to 179.10.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist
Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention
Protection scope.
Claims (10)
1. a kind of Pesticidal combination, it is characterised in that: the component including following weight percent: capillary 1%~30%, chlorine worm
Benzamide 1%~30%, wetting dispersing agent 2%~8%, safener 0.5%~5%, capillary complex materials 1%~3%, antifreezing agent 1%
~5%, thickener 0.1%~2%, defoaming agent 0.1%~0.5%, preservative 0.1%~0.4%, deionized water polishing.
2. Pesticidal combination according to claim 1, it is characterised in that: the safener is hemin.
3. Pesticidal combination according to claim 1, it is characterised in that: the capillary complex materials are glucosyl group-
β-cyclodextrine.
4. Pesticidal combination according to claim 1, it is characterised in that: the wetting dispersing agent is polycarboxylate, wooden
Plain sulfonate, APES formaldehyde condensation products sulfat, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium
Salt, alkyl phenol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, glycerol fatty acid ester polyoxyethylene ethe
One of or it is a variety of.
5. Pesticidal combination according to claim 1, it is characterised in that: the antifreezing agent is ethylene glycol, propylene glycol, the third three
One of alcohol is a variety of.
6. Pesticidal combination according to claim 1, it is characterised in that: the thickener is xanthan gum, hydroxylmethyl cellulose
One of element, hydroxyethyl cellulose, methylcellulose, aluminum magnesium silicate, polyvinyl alcohol are a variety of.
7. Pesticidal combination according to claim 1, it is characterised in that: the defoaming agent is silicone oil, silicone compound
One of C10-20 saturated fat acid compounds, C8-10 fatty alcohols compound are a variety of.
8. Pesticidal combination according to claim 1, it is characterised in that: the preservative is Kathon CG.
9. Pesticidal combination according to claim 1, it is characterised in that: percentage, comprising: capillary
10%, Rynaxypyr 10%, wetting dispersing agent 5%, safener 0.5%, capillary complex materials 2%, antifreezing agent 5%, thickener
0.25%, defoaming agent 0.4%, preservative 0.3%, deionized water polishing.
10. a kind of preparation method of Pesticidal combination, characterized by the following steps:
Wetting dispersing agent, defoaming agent and deionized water are mixed in proportion；
Capillary raw medicine and glucosyl group-β-cyclodextrine mixing is added, high speed shear 30 minutes, Rynaxypyr is added
It opens and is sanded after raw medicine mixing；It is ground 2~3 hours in sand mill, makes partial size at 2~3 microns or less
Hemin, thickener, antifreezing agent, preservative are added in compounding kettle, stirs evenly.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113040154A (en) * | 2021-03-25 | 2021-06-29 | 烟台科达化工有限公司 | Pesticide and preparation method thereof |
| CN113519537A (en) * | 2021-08-19 | 2021-10-22 | 南京保丰农药有限公司 | Chlorantraniliprole-chlorfenapyr-containing suspending agent |
| CN114223663A (en) * | 2021-12-29 | 2022-03-25 | 青岛润农化工有限公司 | Suspending agent containing chlorantraniliprole and chlorfenapyr and preparation method thereof |
| CN114642211A (en) * | 2021-04-06 | 2022-06-21 | 山东统防生物科技有限公司 | Chlorantraniliprole and chlorfenapyr composition and preparation method thereof |
| CN116019109A (en) * | 2022-11-01 | 2023-04-28 | 山东曹达化工有限公司 | Insecticidal composition and application thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1934944A (en) * | 2006-10-24 | 2007-03-28 | 南京农业大学 | Chlorohemin contaning plant growth regulator |
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN101163399A (en) * | 2005-04-22 | 2008-04-16 | 恩德拉（共同）股份公司 | New biologically active formulation |
| CN101801191A (en) * | 2007-07-30 | 2010-08-11 | 纳幕尔杜邦公司 | Fly control method |
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| WO2018224915A1 (en) * | 2017-06-09 | 2018-12-13 | Upl Ltd | Novel pesticidal combinations |
-
2018
- 2018-12-18 CN CN201811548524.9A patent/CN109329287A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN101163399A (en) * | 2005-04-22 | 2008-04-16 | 恩德拉（共同）股份公司 | New biologically active formulation |
| CN1934944A (en) * | 2006-10-24 | 2007-03-28 | 南京农业大学 | Chlorohemin contaning plant growth regulator |
| CN101801191A (en) * | 2007-07-30 | 2010-08-11 | 纳幕尔杜邦公司 | Fly control method |
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| WO2018224915A1 (en) * | 2017-06-09 | 2018-12-13 | Upl Ltd | Novel pesticidal combinations |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113040154A (en) * | 2021-03-25 | 2021-06-29 | 烟台科达化工有限公司 | Pesticide and preparation method thereof |
| CN114642211A (en) * | 2021-04-06 | 2022-06-21 | 山东统防生物科技有限公司 | Chlorantraniliprole and chlorfenapyr composition and preparation method thereof |
| CN114642211B (en) * | 2021-04-06 | 2024-05-28 | 山东统防生物科技有限公司 | Chlorantraniliprole and chlorfenapyr composition and preparation method thereof |
| CN113519537A (en) * | 2021-08-19 | 2021-10-22 | 南京保丰农药有限公司 | Chlorantraniliprole-chlorfenapyr-containing suspending agent |
| CN114223663A (en) * | 2021-12-29 | 2022-03-25 | 青岛润农化工有限公司 | Suspending agent containing chlorantraniliprole and chlorfenapyr and preparation method thereof |
| CN114223663B (en) * | 2021-12-29 | 2024-01-26 | 青岛润农化工有限公司 | Suspending agent containing chlorantraniliprole and chlorfenapyr and preparation method thereof |
| CN116019109A (en) * | 2022-11-01 | 2023-04-28 | 山东曹达化工有限公司 | Insecticidal composition and application thereof |
| CN116897925A (en) * | 2023-09-14 | 2023-10-20 | 山东新势立生物科技有限公司 | Nanometer pesticide containing cyenopyrafen and chloranil |
| CN116897925B (en) * | 2023-09-14 | 2023-12-08 | 山东新势立生物科技有限公司 | Nanometer pesticide containing cyenopyrafen and chloranil |
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