CN1265268A - Pesticide composition containing fipronil - Google Patents
Pesticide composition containing fipronil Download PDFInfo
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- CN1265268A CN1265268A CN 99126078 CN99126078A CN1265268A CN 1265268 A CN1265268 A CN 1265268A CN 99126078 CN99126078 CN 99126078 CN 99126078 A CN99126078 A CN 99126078A CN 1265268 A CN1265268 A CN 1265268A
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- compound
- cis
- sharp strength
- phoxim
- imidacloprid
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Abstract
The pesticide composition includes fipronil and at least one of compound composed of Imidan, phoxim, monosultap, sanmite,abamectin and alpha-crpermethrin and may be produced to wettable powder, suspending agent and granulated product. It has high pesticidal efficiency and can be used in preventing and killing rice borers, plant hopper, thrips, aphid, leafhopper and other crop pests.
Description
The present invention relates to have highly active Pesticidal combination.Compound (A) and at least a specific insecticide (B) as the active ingredient representative are wherein arranged.
The chemical name of compound (A) is (±)-5-amino-1-(2.6-two chloro-2,2,2-three chloro-[β-tolyl)-4-trifluoromethyl sulfonyl pyrazoles-3-carbonization nitrile.Be a kind of highly active insecticide, can be used for preventing and treating crop pests such as fruit tree, vegetables, grain.In order to enlarge insecticidal spectrum, delaying drug resistance produces, and it can use with other compound, and sharp strength spy belongs to a brand-new compound family for existing insecticide, both at home and abroad also not mentioned it and other compound compositions of patent.
The objective of the invention is the effect that Pesticidal combination showed of compound (A) and some specific compound composition or the stack that activity level has exceeded each composition activity, or enlarged the insecticidal spectrum of one pack system compound.The Pesticidal combination that the present invention is based on this compound (A) and the formation of some specific compound has synergy or enlarges the insecticidal spectrum sphere of action provides one group of Pesticidal combination.
Pesticidal combination provided by the invention is characterised in that to comprise the special and at least a one group of compound (B) that is selected from Imidacloprid (imidacloprid), phoxim (phoxim), desinsection list, pyridaben (pyridaben), acetamiprid (abamecin), cis-, trans-cypermethrin (alphacypermethrin), composition of (A) sharp strength.Their chemical name is respectively and is:
Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine (imidacloprid B
1)
Phoxim: o, o-diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2).
Desinsection list: 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (B
3).
Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone (pyridaben B
4).
Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1Compound (the abamecfin B that b forms
5).
Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-alpha-cyano-(3-benzyloxy phenoxy base)-3 (2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (alphacypermethrin B
6).
Weight ratio between compound in the Pesticidal combination of the present invention (A) and the compound (B) generally is:
For (A) and Imidacloprid (B
1) be preferably 5-25 for 1-50
For (A) and phoxim (B
2) be preferably 1.5-25 for 1-50
For (A) and desinsection list (B
3) be preferably 5-25 for 1-50
For (A) and pyridaben (B
4) be preferably 5-20 for 1-50
For (A) and acetamiprid (B
5) be preferably 0.5-20 for 0.1-5
For (A) and cis-, trans-cypermethrin (B
6) be preferably 1-5 for 0.1-5
The effective component content of Pesticidal combination of the present invention is 5-90%.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Can be used for preventing and treating the insect such as diamond-back moth, aphid, snout moth's larva, plant hopper, thrips, rice beetle, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of crops such as vegetables, grain, fruit tree.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Preferably suspending agent, granule, also wetting powder.
Adoptable surfactant has anionic surfactant and nonionic surface active agent.It comprises alkylsurfuric acid salt, alkyl sulfonic acid alkali metal salt and amido, dialkyl group succinate sodium sulfonate salt, alkylphenol polyoxyethylene formaldehyde condensation products succinic acid half ester sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol alkylphenol polyoxyethylene sulphate, alkylnaphthalene sulfonate, fatty acid or fatty acid ester sulphate, alkylphenol polyoxyethylene and fatty alcohol-polyoxyethylene ether etc., and that can give an example has farming newborn 8000 series, lignosulfonates, NNO, a dispersing agent MF etc.
The mixture that contains each active component in the wetting powder, inert carrier and filler and one or more wetting agents, carrier is generally mineral inert carrier such as kaolin, bentonite etc.It is more excellent in 10-80% that the wetting powder of the Pesticidal combination of this invention contains 5-90% (weight) usually) active mixture, 1-20% (more excellent is 1-10%) (weight) dispersant, the wetting agent of 1-10% (more excellent is 2-8%) (weight), 1-10% (more excellent is 2-5%) (weight) bleeding agent, inert solid carrier and the filler of 5-70% (weight) (more excellent is 10-80%), the Pesticidal combination of forming jointly by them.
Granule is with active ingredient and fine grainly is dispergated carrier, adds that granulations such as binding agent, colouring agent, dispersant form.It is 1-20% (weight) (the more excellent 1-10% of being) that granule contains effective composition.
The suspending agent of this insecticides is water-soluble relatively poor active component constantly to be stirred in water with emulsifier, dispersant, wetting agent etc. pulverize, make it evenly to disperse and suspend, can suitably add suitable suspending agent such as thickener, antifreezing agent, stabilizing agent, bleeding agent, defoamer as required, comprise the active substance of 1-80% (weight) (the more excellent 5-50% of being).
Pesticidal combination provided by the present invention possesses the insecticide efficiency height, can effectively prevent and treat the insect such as snout moth's larva, plant hopper, thrips, rice beetle, diamond-back moth, aphid, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of the crop of causing harm.Control is significantly higher than compound alone (A), or the preventive effect of compound alone (B), and has reduced the application dosage of every kind of active substance significantly.The present invention simultaneously can replace the insecticide pesticide kind of present high poison, high residue.The present invention not only has ecological significance, also has important environment protection significance simultaneously.
Following examples describe the present invention in detail, and embodiment mainly is for the present invention is described but not is used for limiting the present invention.
Embodiment 1 is the formulation preparation example, and embodiment 2-7 is a biological Examples.Embodiment 1:(1) suspending agent:
Active component A with 5% (purity 95%) and 10% and active component B
1(purity 93%) and 5% is as 33 of emulsifier
#, 4% NNO, 0.2% thickener xanthans, 3% sodium lignin sulfonate, 0.5% stabilizing agent benzoic acid, 2% antifreeze glycol as wetting agent as dispersant, mix with the proper quantity of defoaming agent n-butanol, in high-speed shearing machine, evenly pulverize and mix.(2) granule:
Active component A with 1.5% (purity 95%) and 3% active component B
1Produce granule with 2% binding agent, 0.5% colouring agent, 40% potter's clay, 2% dispersant and filler by coating method.(3) with 3% active component A (purity 95%) and 22% active component B
1(purity 93%) and 5% is evenly mixed through ultramicro grinding as the JFC of bleeding agent etc. as wetting agent and calcium lignosulfonate, 4% NNO as dispersant, 2% and to be produced.Embodiment 2 sharp strength are held with Imidacloprid and used with water rice hopper control efficiency place: period is investigated in the Xinyi: the 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | ????20 | ????7.4 | ????60 | |
| Sharp strength spy | ????25 | ????7.6 | ????64.2 | |
| Imidacloprid | ????10 | ????5.0 | ????62.8 | |
| Imidacloprid | ????15 | ????4.8 | ????64.8 | |
| Sharp strength spy+Imidacloprid | ????20+10 | ????6.6 | ????89.2 | ????85.17 |
| Sharp strength spy+Imidacloprid | ????25+10 | ????5.2 | ????90.1 | ????86.7 |
| Sharp strength spy+Imidacloprid | ????20+15 | ????5.9 | ????87.4 | ????85.9 |
| Sharp strength spy+Imidacloprid | ????25+15 | ????8.0 | ????93.3 | ????87.4 |
Conclusion: sharp strength is special to be used preventive effect with Imidacloprid and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with Imidacloprid.Embodiment 3 sharp strength are special to be used with snout moth's larva of rice control efficiency place with the insecticide list: Xinyi spraying times a: control time: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.0 | ?62.1 | |
| Sharp strength spy | 25 | ?9.8 | ?63.8 | |
| Insecticide | 400 | ?12 | ?60.9 | |
| Insecticide | 450 | ?9.0 | ?59.2 | |
| Sharp strength spy+insecticide | 20+400 | ?8.5 | ?87.3 | ?85.2 |
| Sharp strength spy+insecticide | 20+450 | ?9.6 | ?86.7 | ?84.5 |
| Sharp strength spy+insecticide | 25+400 | ?7.3 | ?89.3 | ?85.6 |
| Sharp strength spy+insecticide | 25+450 | ?6.8 | ?90.1 | ?85.3 |
Conclusion: the special preventive effect of using with the insecticide list of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with the insecticide list.
Embodiment 4 sharp strength are special to be used with flower Ji, paddy rice rice plant skipper control efficiency with phoxim
Place: Xinyi spraying times: once
Investigation period: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.7 | ?59.2 | |
| Sharp strength spy | 25 | ?8.2 | ?63.1 | |
| Phoxim | 1500 | ?10.3 | ?63.4 | |
| Phoxim | 2000 | ?9.8 | ?64.2 | |
| Sharp strength spy+phoxim | 20+1500 | ?6.5 | ?87.2 | ?85.1 |
| Sharp strength spy+phoxim | 20+2000 | ?5.4 | ?88.7 | ?85.4 |
| Sharp strength spy+phoxim | 25+1500 | ?9.8 | ?89.2 | ?86.0 |
| Sharp strength spy+phoxim | 25+2000 | ?10.2 | ?90.4 | ?86.8 |
Conclusion: the special preventive effect of using with phoxim of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with phoxim.The sharp strength of embodiment 5 are special to be used with cotton aphid control efficiency place with pyridaben: Pei County, Jiangsu spraying times: second survey period: 7 day time behind the medicine for the second time: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 1000 | ?8.9 | ?64.3 | |
| Sharp strength spy | 1500 | ?9.0 | ?62.5 | |
| Pyridaben | 1000 | ?7.3 | ?60.1 | |
| Pyridaben | 1500 | ?8.4 | ?63.4 | |
| Sharp strength spy+pyridaben | 1000+1000 | ?9.2 | ?88.1 | ?85.8 |
| Sharp strength spy+pyridaben | 1500+1500 | ?10.8 | ?89.4 | ?86.3 |
Conclusion: the special preventive effect of using with pyridaben of sharp strength is higher than it and uses the expectancy theory preventive effect with, proves that sharp strength spy has used synergistic effect with pyridaben.The sharp strength of embodiment 6 are special to be used with Chinese cabbage diamond-back moth control efficiency place with acetamiprid: Shouguang, Shandong dispenser period: larva stage of invasion spraying times: once investigate period: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.6 | ?60 | |
| Sharp strength spy | 25 | ?6.3 | ?62.1 | |
| Acetamiprid | 15 | ?5.2 | ?55.0 | |
| Acetamiprid | 20 | ?4.8 | ?60.0 | |
| Sharp strength spy+acetamiprid | 20+15 | ?8.4 | ?87.3 | ?85.0 |
| Sharp strength spy+acetamiprid | 25+20 | ?7.9 | ?87.4 | ?86.0 |
| Sharp strength spy+acetamiprid | 25+15 | ?10.2 | ?84.5 | ?82.3 |
| Sharp strength spy+acetamiprid | 25+20 | ?9.8 | ?89.7 | ?84.5 |
Conclusion: sharp strength is special to be used preventive effect with acetamiprid and is higher than it and uses the expectancy theory effect with, proves that sharp strength is special to have used synergistic effect with acetamiprid.The sharp strength of embodiment 7 are special uses control efficiency place to colorado potato beetle with cis-, trans-cypermethrin: Guangdong dispenser period: larval phase spraying times: once investigate period: the 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 15 | ?10.2 | ?59.3 | |
| Sharp strength spy | 20 | ?9.8 | ?62.4 | |
| Cis-, trans-cypermethrin | 1 | ?7.8 | ?56.7 | |
| Cis-, trans-cypermethrin | 1.5 | ?7.3 | ?58.3 | |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1 | ?8.3 | ?83.7 | ?82.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1.5 | ?8.4 | ?85.1 | ?83.0 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1 | ?5.6 | ?86.3 | ?83.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1.5 | ?6.0 | ?88.7 | ?84.3 |
Conclusion: the special preventive effect of using with cis-, trans-cypermethrin of sharp strength is higher than it and uses the expectancy theory preventive effect with,
Illustrate that sharp strength spy has used synergistic effect with cis-, trans-cypermethrin.
Claims (5)
1 one groups of Pesticidal combinations is characterized in that comprising compound (A) (sharp strength spy) and at least a specific following one group of compound (B); The structural formula of A is:
Compd B is respectively:
Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine
(imidacloprid?B
1)；
Phoxim: o, o-diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2);
Desinsection list: 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (B
3);
Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone
(pyridaben?B
4)；
Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1The change that b forms
Compound (abamecfin B
5);
Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-alpha-cyano-(3-benzyloxy phenoxy
Base)-3 (2, the 2-dichloroethylene)-2, the 2-dimethyl cyclopropane carboxylic acid
Ester (alphacypermethrin B
6);
2 Pesticidal combinations according to claim 1 is characterized in that the weight ratio between compound in the composition (A) and the compound (B) is:
For (A) and Imidacloprid (B
1) be preferably 5-25 for 1-50
For (A) and phoxim (B
2) be preferably 1.5-25 for 1-50
For (A) and desinsection list (B
3) be preferably 5-25 for 1-50
For (A) and pyridaben (B
4) be preferably 5-20 for 1-50
For (A) and acetamiprid (B
5) be preferably 0.5-20 for 0.1-5
For (A) and cis-, trans-cypermethrin (B
6) be preferably 1-5 for 0.1-5
3 Pesticidal combinations according to claim 1, the effective component content that it is characterized in that composition is 5-90%.
4 one or multinomial a kind of preparation of compositions methods according to claim 1-3 is characterized in that, medicament can be processed into wetting powder, suspending agent and granule etc.
Pesticidal combination described in the 5 claim 1-3 can be used for preventing and treating the multiple kinds of crops insect pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1265268A true CN1265268A (en) | 2000-09-06 |
| CN1129358C CN1129358C (en) | 2003-12-03 |
Family
ID=5284315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99126078A Expired - Fee Related CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1129358C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340169C (en) * | 2005-08-11 | 2007-10-03 | 徐克华 | Compound pesticide of fipronil and pridaphenthione |
| CN100364979C (en) * | 2006-02-28 | 2008-01-30 | 浙江大学 | Aryl pyrazole inulin acidamide compound and use thereof |
| CN100433979C (en) * | 2007-01-18 | 2008-11-19 | 江苏太湖地区农业科学研究所 | Compound insecticide containing fipronil and Etrofolan |
| JP2010510193A (en) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for increasing dry biomass in plants |
| WO2011161071A2 (en) | 2010-06-23 | 2011-12-29 | Basf Se | Nematicidal mixtures for use in sugar cane |
| CN102726435A (en) * | 2011-04-09 | 2012-10-17 | 浙江森得保生物制品有限公司 | Specifically effective formula for controlling Pleonomus canaliculatus Faldemann |
| CN102771503A (en) * | 2012-08-03 | 2012-11-14 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN104522006A (en) * | 2014-12-19 | 2015-04-22 | 湖南化工研究院有限公司 | Composition for preventing and controlling lepidoptera and homopteran pests |
| US9271448B2 (en) | 2010-06-09 | 2016-03-01 | Basf Se | Method for cultivating sugar cane |
| CN105686963A (en) * | 2016-03-19 | 2016-06-22 | 上海申亚动物保健品阜阳有限公司 | Insectifuge pet shampoo |
| US9615503B2 (en) | 2011-09-23 | 2017-04-11 | Basf Se | Method for cultivating sugar cane |
| US9913473B2 (en) * | 2006-11-10 | 2018-03-13 | Basf Se | Crystalline modification of fipronil |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101204155A (en) * | 2007-12-12 | 2008-06-25 | 海南利蒙特生物农药有限公司 | Fipronil and monosultap compound pesticide |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19548872A1 (en) * | 1995-12-27 | 1997-07-03 | Bayer Ag | Synergistic insecticidal mixtures |
| CN1102023C (en) * | 1998-07-08 | 2003-02-26 | 安万特杭州作物科学有限公司 | Firponil compounded pesticide |
-
1999
- 1999-12-15 CN CN99126078A patent/CN1129358C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340169C (en) * | 2005-08-11 | 2007-10-03 | 徐克华 | Compound pesticide of fipronil and pridaphenthione |
| CN100364979C (en) * | 2006-02-28 | 2008-01-30 | 浙江大学 | Aryl pyrazole inulin acidamide compound and use thereof |
| US9913473B2 (en) * | 2006-11-10 | 2018-03-13 | Basf Se | Crystalline modification of fipronil |
| JP2010510193A (en) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for increasing dry biomass in plants |
| CN100433979C (en) * | 2007-01-18 | 2008-11-19 | 江苏太湖地区农业科学研究所 | Compound insecticide containing fipronil and Etrofolan |
| US9271448B2 (en) | 2010-06-09 | 2016-03-01 | Basf Se | Method for cultivating sugar cane |
| WO2011161071A2 (en) | 2010-06-23 | 2011-12-29 | Basf Se | Nematicidal mixtures for use in sugar cane |
| CN102726435A (en) * | 2011-04-09 | 2012-10-17 | 浙江森得保生物制品有限公司 | Specifically effective formula for controlling Pleonomus canaliculatus Faldemann |
| US9615503B2 (en) | 2011-09-23 | 2017-04-11 | Basf Se | Method for cultivating sugar cane |
| CN102771503A (en) * | 2012-08-03 | 2012-11-14 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN102771503B (en) * | 2012-08-03 | 2014-01-08 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN104522006A (en) * | 2014-12-19 | 2015-04-22 | 湖南化工研究院有限公司 | Composition for preventing and controlling lepidoptera and homopteran pests |
| CN105686963A (en) * | 2016-03-19 | 2016-06-22 | 上海申亚动物保健品阜阳有限公司 | Insectifuge pet shampoo |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1129358C (en) | 2003-12-03 |
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Granted publication date: 20031203 Termination date: 20131215 |