CN106889067B - A kind of containing chromafenozide and the compound pesticide compositions of chlorine tebufenozide and application thereof - Google Patents
A kind of containing chromafenozide and the compound pesticide compositions of chlorine tebufenozide and application thereof Download PDFInfo
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- CN106889067B CN106889067B CN201710107851.XA CN201710107851A CN106889067B CN 106889067 B CN106889067 B CN 106889067B CN 201710107851 A CN201710107851 A CN 201710107851A CN 106889067 B CN106889067 B CN 106889067B
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- tebufenozide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The invention discloses a kind of containing chromafenozides and the compound pesticide compositions of chlorine tebufenozide and application thereof, and the Pesticidal combination is using ring tebufenozide and chlorine tebufenozide as active insecticidal components, wherein the weight ratio of ring tebufenozide and chlorine tebufenozide is 50：1~1：50.The Pesticidal combination can generate higher synergistic function, overcome and delayed pest resistance to insecticide, and desinsection speed is fast, and the lasting period is long, reduce drug cost, and control efficiency is apparently higher than the use of its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, be used especially for prevention and treatment bollworm, snout moth's larva, and effect is apparently higher than the use of its single dose.
Description
Technical field
The invention belongs to pesticide fields, and in particular to a kind of killing as principle active component using ring tebufenozide and chlorine tebufenozide
Worm composition and its application.
Background technique
Ring tebufenozide (Chromafenozide), chemical name：N- tert-butyl-N'- (3- methoxyl group -2- toluyl
Base) -3,5- dimethylbenzohydrazide.For bishydrazide insecticide, inhibit feed after pests in a few houres, while causing to do harm to
Worm casts off a skin in advance leads to death.Ring tebufenozide not only to mammal, birds, aquatic organism low toxicity, but also to arthropod class, catch
Feeding habits acarian, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.
Chlorine tebufenozide (Halofenozide), molecular formula：C18H19ClN2O2.Structural formula is：
Chlorine tebufenozide is the two hydrazides insecticides of non-sterol developed by Rohm and Haas Company (US) Independenec Mall West, Philadelphia, Pennsy Lvania 1 of the U.S..Its mechanism of action master
If moulting hormone concentration in insect bodies is caused to reduce, caused with causing insect that can not start husking and being unable to complete molting process
Extremely.Chlorine tebufenozide is lower but very high to coleopteran-active to the activity of Lepidoptera, has distinguished soil interior suction to make
With having good killing effect to chafer larva and soil pests.It can be used for preventing and treating in herbage, turf and ornamental plant
Coleoptera and lepidoptera pest.
Insecticide variety containing single component often existing defects in pesticide control of insect：Continuous use is easy to produce anti-
Pharmacological property, insecticidal spectrum is narrow, and comprehensive protection, peasant's drug cost height etc. cannot be provided for crop.By two or more
The combination of various active constituents can overcome disadvantages mentioned above to a certain extent.Two or more work with synergistic effect
Property ingredient combination mixture, can be improved preventive effect, with reducing effective component dosage, save the cost, slow down pest resistance occur,
And prevention spectrum can be expanded, it plays that more worms are simultaneous to be controlled, reduces the use cost of peasant.
Summary of the invention
The object of the present invention is to provide the compound pesticide compositions of a kind of containing chromafenozide and chlorine tebufenozide, the Insecticidal combinations
Object is the multifunctional insecticide composition for preventing and treating lepidoptera pest.
It is a further object of the present invention to provide the Pesticidal combinations in the insecticidal materials for preparing prevention and treatment resistance lepidoptera pest
On application, especially preparation prevention and treatment bollworm or snout moth's larva insecticidal materials on application.
The purpose of the present invention is what is be achieved through the following technical solutions：
A kind of compound pesticide compositions of containing chromafenozide and chlorine tebufenozide, the compound pesticide compositions with ring tebufenozide and
Chlorine tebufenozide is principle active component, wherein the weight ratio of ring tebufenozide and chlorine tebufenozide is 50：1~1：50.
In this compound pesticide compositions, the weight ratio of ring tebufenozide (A) and chlorine tebufenozide (B) is preferably 1~50：1~50,
Further preferably 20：1~1：20, the weight of ring tebufenozide (A) and chlorine tebufenozide (B) in some most preferred technical solutions
Than 50：Isosorbide-5-Nitrae 0：1,30：1,20：1,10：1,5：1,2：1,1：1,1：5,1：10,1：20,1：30,1：40,1：In 50 ranges into
Row selection.
This compound pesticide compositions can contain only active constituent ring tebufenozide and chlorine tebufenozide, can also be in use or preparation
Other components are added into active constituent, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In compound pesticide compositions of the present invention, both ring tebufenozide and chlorine tebufenozide are in the compound pesticide compositions
Weight percentage is 3%~80%.Preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention are using ring tebufenozide and chlorine tebufenozide as active constituent or principle active component and agriculture
Medicine auxiliary agent and excipient are at any one dosage form allowed on pesticide, the preferred missible oil of the dosage form, suspending agent, wettable
Pulvis, aqueous emulsion, microemulsion or water dispersion granule.
It is aforementioned to can be applied to insecticides adjuvant of the invention and be not particularly limited, including but not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), nonylphenol polyoxyethylene ether etc., it is aforementioned to answer
Also be not particularly limited for excipient of the invention, including but not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..The above auxiliary agent, excipient and other auxiliary materials can be applied alone or be used in combination.
Compound pesticide compositions of the present invention are easy to produce a variety of Semipteras and Lepidoptera of resistance to planthopper and snout moth's larva etc.
Pest has good preventive effect；And pest is inhibited to produce the drug resistance of single formulation (ring tebufenozide or chlorine tebufenozide are any)
It is raw.
Application of the above-mentioned compound pesticide compositions on preparation prevention and treatment resistance lepidoptera pest insecticidal materials, is especially making
Application effect on standby prevention and treatment bollworm or snout moth's larva insecticidal materials is significant.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, the composition antagonism lepidoptera pest
Such as bollworm, snout moth's larva have obvious synergistic function, overcome and delayed pest resistance to insecticide, expand prevention spectrum, desinsection speed
Fastly, hence it is evident that improve control efficiency；(2) prevention and treatment recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) it has concurrently quick-acting
With it is long-acting；(5) with ring tebufenozide compared with chlorine tebufenozide single dose, production and application cost is reduced；(6) inhibit lepidoptera pest pair
The resistance of pesticide enhances, and effect is apparently higher than the use of its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, but do not limit the invention in any way.
Indoor biometrics experiment：
Indoor synergy bioassay is carried out using feed plus malicious method, selects resistant bollworm and green vegetables cabbage caterpillar for target evil
Worm, every processing are repeated 3 times, and every concentration handles 60, calculate each medicament antagonism bollworm and rice-stem borer with probability value method
Toxicity regression equation and lethal concentration of 50 LC50, use LC50Value calculates co-toxicity coefficient by Sun Yunpei's Method, and the specific method is as follows：
Using single dose a certain in mixture as standard agent (generally selecting LC50 junior), calculated：
Single dose toxicity index=standard agent LC50/ single dose LC50 × 100
Theoretical toxicity index=A single dose toxicity index × A single dose proportion+B single dose in mixture toxicity index
× B single dose proportion in mixture
Survey toxicity index=standard single dose LC50 value/mixture value × 100 LC50
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient classification：Mixture has synergetic when CTC is greater than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
It the results are shown in Table 1,2：
1 ring tebufenozide of table and chlorine tebufenozide compounding and the toxicity test of single dose antagonism bollworm
As shown in Table 1, ring tebufenozide and chlorine tebufenozide compounding, co-toxicity coefficient are all larger than 120, show to cooperate with increasing well
Effect effect.
2 ring tebufenozide of table and chlorine tebufenozide compounding and single dose are to the toxicity test of striped rice borer
Table 2 is it is found that ring tebufenozide and chlorine tebufenozide compounding, co-toxicity coefficient are all larger than 120, show good synergy
Effect.
Field control effectiveness test：
Prevention and treatment bollworm and striped rice borer pharmacodynamic test are carried out to listed embodiment 1-12, comparison medicament is 10% tebufenozide ME
It with 5% ring tebufenozide SC, is diluted according to the extension rate in table 3 and table 4, looks into 3 days after medicine, 7 days, 14 days knots
Fruit, processing result are shown in Table 3 and 4：
Table 3：Ring tebufenozide-chlorine tebufenozide compounding antagonism bollworm field test results
Field efficacy the result shows that, there is ring tebufenozide chlorine tebufenozide composition antagonism bollworm excellent prevention and treatment to imitate
Fruit, control efficiency are better than the effect that single dose kind directly acts on.
Table 4：Field test results of the ring tebufenozide-chlorine tebufenozide compounding to rice-stem borer
Field efficacy the result shows that, ring tebufenozide chlorine tebufenozide composition there is excellent prevention and treatment to imitate rice-stem borer
Fruit, control efficiency are better than the effect that single dose kind directly acts on.
Embodiment 1：
Weigh 50g ring tebufenozide, 1g chlorine tebufenozide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、600#
1g, 200# solvent naphtha 13g, add water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle high speed
Mixing forms the ring tebufenozide chlorine tebufenozide aqueous emulsion that principle active component weight percentage is 51%.
Embodiment 2：
Weigh 30g ring tebufenozide, 1g chlorine tebufenozide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g、600#
1g, 150# solvent naphtha 13g, add water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle high speed
Mixing forms the ring tebufenozide chlorine tebufenozide aqueous emulsion that principle active component weight percentage is 31%.
Embodiment 3：
Weigh 20g ring tebufenozide, 1g chlorine tebufenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, 600#1g, cyclohexanone 10g, add water to 100g.The method that the above raw material routinely prepares microemulsion is thrown
Enter in mixing kettle and mix, forms the ring tebufenozide chlorine tebufenozide microemulsion that principle active component weight percentage is 21%.
Embodiment 4：
Weigh 10g ring tebufenozide, 1g chlorine tebufenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, is formed main effective
The ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 11%.
Embodiment 5：
Weigh 20g ring tebufenozide, 4g chlorine tebufenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, is formed main effective
The ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 24%.
Embodiment 6：
Weigh 20g ring tebufenozide, 10g chlorine tebufenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, is formed main effective
The ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 30%.
Embodiment 7：
Weigh 10g ring tebufenozide, 10g chlorine tebufenozide, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, is formed main effective
The ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 20%.
Embodiment 8：
Weigh 4g ring tebufenozide, 20g chlorine tebufenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, is formed main effective
The ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 24%.
Embodiment 9：
Weigh 2g ring tebufenozide, 20g chlorine tebufenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, forming system mainly has
Imitate the ring tebufenozide chlorine tebufenozide missible oil that Ingredients Weight percentage composition is 22%.
Embodiment 10：
Weigh 1g ring tebufenozide, 20g chlorine tebufenozide, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g,
150# solvent naphtha is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, it is main to form preparation
The ring tebufenozide chlorine tebufenozide missible oil that effective component weight percentage is 21%.
Embodiment 11：
Weigh 1g ring tebufenozide, 30g chlorine tebufenozide, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and its sulfuric acid
Salt 4g, xanthan gum 0.15g, ethylene glycol 5g, silicon oxidative ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in sand mill
Under the action of formed principle active component weight percentage be 31% ring tebufenozide chlorine tebufenozide suspending agent.
Embodiment 12：
Weigh 1g ring tebufenozide, 50g chlorine tebufenozide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
The above raw material is formed the weight of principle active component by polyvinyl alcohol 5g, borax 2g, diatomite 21g by water dispersible granular agent method
Measure the ring tebufenozide chlorine tebufenozide water dispersion granule that percentage composition is 51%.
Claims (9)
1. the compound pesticide compositions of a kind of containing chromafenozide and chlorine tebufenozide, it is characterized in that the compound pesticide compositions are with ring worm
Hydrazides and chlorine tebufenozide are active insecticidal components, wherein the weight ratio of ring tebufenozide and chlorine tebufenozide is 50：1~1：50.
2. the compound pesticide compositions of containing chromafenozide according to claim 1 and chlorine tebufenozide, it is characterized in that described
The weight ratio of ring tebufenozide and chlorine tebufenozide is 20：1~1：20.
3. the compound pesticide compositions of containing chromafenozide according to claim 2 and chlorine tebufenozide, it is characterized in that described
The weight ratio of ring tebufenozide and chlorine tebufenozide is 20：1~5：1,1：5~1：20.
4. the compound pesticide compositions of containing chromafenozide according to claim 1 and chlorine tebufenozide, it is characterized in that ring worm acyl
The weight percentage of both hydrazine and chlorine tebufenozide in the compound pesticide compositions is 3% ~ 80%.
5. the compound pesticide compositions of containing chromafenozide according to claim 4 and chlorine tebufenozide, it is characterized in that ring worm acyl
The weight percentage of both hydrazine and chlorine tebufenozide in the compound pesticide compositions is 5% ~ 55%.
6. the compound pesticide compositions of containing chromafenozide according to claim 1 and chlorine tebufenozide, it is characterized in that this is compound
Pesticidal combination is configured to the dosage form allowed on pesticide using ring tebufenozide and chlorine tebufenozide as active insecticidal components and insecticides adjuvant.
7. the compound pesticide compositions of containing chromafenozide according to claim 6 and chlorine tebufenozide, it is characterized in that described dose
Type is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of containing chromafenozide described in claim 1 and chlorine tebufenozide prevent and treat resistance Lepidoptera in preparation
Application on the insecticidal materials of pest.
9. application according to claim 8, it is characterized in that the compound pesticide compositions in preparation prevention and treatment bollworm or
Application on the insecticidal materials of snout moth's larva.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710107851.XA CN106889067B (en) | 2017-02-27 | 2017-02-27 | A kind of containing chromafenozide and the compound pesticide compositions of chlorine tebufenozide and application thereof |
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| CN201710107851.XA CN106889067B (en) | 2017-02-27 | 2017-02-27 | A kind of containing chromafenozide and the compound pesticide compositions of chlorine tebufenozide and application thereof |
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| CN106889067B true CN106889067B (en) | 2018-11-20 |
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| JP2009209124A (en) * | 2008-02-06 | 2009-09-17 | Nissan Chem Ind Ltd | Insect- or acarian-controlling composition |
| CN103300000B (en) * | 2012-03-12 | 2016-04-06 | 陕西韦尔奇作物保护有限公司 | A kind of Pesticidal combination containing ring worm hydrazides and amide-type |
| CN104782630A (en) * | 2015-04-15 | 2015-07-22 | 南开大学 | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide |
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