CN105660679A - Electrostatic oiling agent containing SYP-9080 - Google Patents
Electrostatic oiling agent containing SYP-9080 Download PDFInfo
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- CN105660679A CN105660679A CN201610104185.XA CN201610104185A CN105660679A CN 105660679 A CN105660679 A CN 105660679A CN 201610104185 A CN201610104185 A CN 201610104185A CN 105660679 A CN105660679 A CN 105660679A
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- chlorantraniliproles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an electrostatic oiling agent containing SYP-9080. The SYP-9080 and an active component II are taken as active ingredients; the active component II is cycloxaprid or epoxy thiacloprid; the electrostatic oiling agent is prepared from the following raw materials in percentage by weight: 0.1-10 percent of the SYP-9080, 0.1-20 percent of the epoxy thiacloprid, 0.1-15 percent of surfactant, 0.1-10 percent of conductive agent, 0.1-5 percent of penetrant and the balance of solvent. The electrostatic oiling agent has the advantages of synergistic interaction, resistance to rainwater scour, long lasting period, low environmental toxicity, and the like, conventional pesticide application labor intensity can be reduced, the labor cost is lowered, environment pollution is reduced, and the pesticide utilization rate is increased.
Description
Technical field
The present invention relates to a kind of electrostatic oil agent containing four chlorantraniliproles, belong to pesticide field, realize the effectively green preventing and treating to tobacco-plant pest-insect mainly through electrostatic spray.
Background technology
Nicotiana tabacum L., from sowing, results to shelf time, all has multiple insect pest to occur, causes great harm to the yield and quality of Nicotiana tabacum L.. In China, Insect Pest of Tobacco has reached 75 kinds, causes yield of flue-cured tobacco loss about 5% every year because disease pest causes harm, reaches 10～30% time serious. Wherein, hazardness than more serious be subterranean pest-insect, sucking insect, To Leaf-feeding Insects, moth property of diving insect, other Field Pests and stored tobacco pests. Carry out integrated control technique, to improve Nicotiana tabacum L. integrated pest prevention and control level, reduce yield of tobacco loss, alleviate environmental pollution, improve quality of tobacco tool be of great significance. The electrostatic oil agent that the present invention is based on the preventing and treating insect that occurs under various complex situations of Nicotiana tabacum L. and develops.
Four chlorantraniliproles, the noval chemical compound that Shi Zhonghua agrochemical company limited and Shenyang Chemical Engineering Inst develop jointly, the bromo-N-(2 of chemical name: 3-, 4-bis-chloro-6-(methylformamide) base)-1-(3,5-dichloro-2-pyridyl base)-1H-pyrazoles-5-Methanamide, it belongs to ryanodine receptor activator insecticides, it is combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion and be sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein binding, cause muscle contracts last. Insect bodies Symptoms is tic, refusing to eat, finally dead. Four chlorantraniliproles are low toxicity, broad spectrum pesticide, lepidoptera pest is respectively provided with good activity, can be widely applied to the injurious insect control of the crops such as Oryza sativa L., vegetable, Cotton Gossypii, have the advantages such as low toxicity, Environmental security, high activity.
Cycloxaprid (Cycloxapyrid) is a kind of novel nicotinamide insecticide, East China University of Science formulate. This compound has interior suction, stomach toxicity and action of contace poison, can be used for Homoptera, the coleopteran pest of preventing and treating on crops, and no interactions resistances such as imidacloprid, Acetamiprid, cycolxylidin, and lepidoptera pest is also effective.Cycloxaprid using dosage is low, environmentally safe, to beneficial organism non-hazardous or endanger minimum. The aphid of the crops such as Semen Tritici aestivi, Cotton Gossypii, Oryza sativa L., fruit tree, vegetable, aleyrodid, plant hopper, flea beetle, bollworm, diamondback moth, Prodenia litura, armyworm etc. there is higher insecticidal activity.
Cycolxylidin (Cycloxylidin) belongs to anabasine insecticide, Wuhan Engineering Univ formulate. This compound has interior suction, stomach toxicity and action of contace poison, and structure is close with imidacloprid, but activity is higher than imidacloprid, and the sucking pest such as aphid, aleyrodid is had higher activity.
Electrostatic oil agent technical scheme about four chlorantraniliproles and cycloxaprid or cycolxylidin combination has no report at present.
Summary of the invention
It is an object of the invention to provide the electrostatic oil agent containing four chlorantraniliproles, there is the advantages such as Synergistic, resistance of rainwater washing against, lasting period length, environmental toxicity be low.
The electrostatic oil agent containing four chlorantraniliproles that the present invention makes, composite for active component with four chlorantraniliproles and active component II, all the other complement to 100% with surfactant, conductive agent, penetrating agent and solvent.
Described active component II is cycloxaprid or cycolxylidin.
The described electrostatic oil agent containing four chlorantraniliproles, the weight percent content of four chlorantraniliproles is 0.1～10%, and the weight percent content of active component II is 0.1～20%; The weight percent content of surfactant is 0.1～15%, and the weight percent content of conductive agent is 0.1～10%, and penetrating agent weight percent content is 0.1～5%, and solvent complements to 100%.
The described electrostatic oil agent containing four chlorantraniliproles, the weight percent content of its active component four chlorantraniliprole is preferably 0.1～6%, and the weight percent content of active component II is preferably 0.1～12%; The weight percent content of surfactant is preferably 0.1～10%, and the weight percent content of conductive agent is preferably 1～6%, and the weight percent content of penetrating agent is preferably 0.1～3%.
Described surfactant is at least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether or OPEO.
Described penetrating agent is azone, thiophene ketone or oozes at least one in T soon.
Described conductive agent is calcium dodecyl benzene sulfonate or dodecylbenzene sodium sulfonate.
Described solvent is at least one in dimethylbenzene, trimethylbenzene, durene, o-dichlorohenzene, methyl naphthalene, dimethyl sulfoxide, N-Methyl pyrrolidone, N,N-dimethylformamide, ethanol, n-octyl alcohol, terpineol, benzyl alcohol, methyl anyl alcohol, soybean oil, Petiolus Trachycarpi oil, vegetable oil acid methyl ester, vegetable oil acid ethyl ester, Oleum Terebinthinae, Oleum Gossypii semen, Testa oryzae oil, Oleum Brassicae campestris, two wires oil, Semen Maydis oil or dimethyl carbonate.
The preparation method of the described electrostatic oil agent containing four chlorantraniliproles is, in the mixing kettle of belt stirrer, first with partial solvent by after active component stirring and dissolving, add surfactant, penetrating agent, conductive agent and remaining solvent, it is sufficiently stirred for mix homogeneously, obtains the electrostatic oil agent containing four chlorantraniliproles; Technological parameter is: it is 60～150 revs/min that mixing speed controls, and mixing time is 15～60 minutes, and temperature is room temperature, and pressure is normal pressure.
The Target crops being suitable for is Nicotiana tabacum L..
The electrostatic oil agent of the present invention is suitable for preventing and treating cigarette beetle, maduca sexta, cigarette aphid, the little phycitid of bollworm, hair Hubei Province steinernema, leaf roller tumor phycitid, tumor phycitid, double cut Pennisetum centrasiaticum Tzvel snout moth's larva, leaf miner, silk arteries and veins psychid, blows cotton a red-spotted lizard, wide wing plant hopper and white armored scale etc.
The method for optimizing using the electrostatic oil agent of the present invention is electrostatic spray, and according to controlling object, a situation arises determines suitable dosage, and usual formulation rate is 50～3000ga.i./hm2。
Electrostatic oil agent of the present invention has the advantages such as Synergistic, resistance of rainwater washing against, lasting period length, environmental toxicity be low. Conventional dispenser labor intensity can be reduced, reduce cost of labor, reduce environmental pollution, improve pesticide utilization rate.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described, but does not limit the scope of the invention.
One, Toxicity Determination
The Application Example of the present invention is the method adopting Toxicity Determination and field control effectiveness test to combine. First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80 < CTC < 120 are summation action, CTC > 120 is potentiation, on this basis, then carry out field control effectiveness test.
Embodiment 1 insecticide of the present invention is to determination experiment in the indoor poison of planthopper
During Toxicity Determination, tetrachloro insect amide and cycloxaprid is measured according to the ratio that four chlorantraniliproles and cycloxaprid mass ratio are 5～1:5～9, being configured to certain mother solution with acetone be positioned in the refrigerator of 4 DEG C and save backup, experiment institute with medicament is used that 0.01% tween 80 solution dilution. Taking the dactylethrae 27 of clean sterilizing after medicine, each process arranges three repetitions, one dactylethrae of each repetition, each dactylethrae is put 3～4 age nymph 20. First rice stem and leaf sheet is cut into the segment of 6～7cm, taking out after soaking 30S, after indoor are dried, the rayon balls soaked with clear water encases root and puts into (high 10cm* diameter 2cm) at the bottom of finger-type pipe, putting into room temperature 26 ± 1, the photoperiod is in the constant incubator of L'D=16:8. After medicine, 24h changes rice stem and clears up culture dish. After medicine, 24h, 48h and 72h observe the survival condition of planthopper, calculate mortality rate and the corrected mortality of planthopper, and calculate the lethal concentration of 50 (LC of 72h50), correlation coefficient and regression equation, the co-toxicity coefficient (CTC) of intermixture is calculated with reference to the abundant method of Sun Yun.
Table 1 four chlorantraniliprole and cycloxaprid mixed agent to 3～4 age planthopper toxicity test
As shown in Table 1, four chlorantraniliproles, the cycloxaprid LC to planthopper50Respectively 96.85mg/L and 125.28mg/L, the toxicity index of four chlorantraniliproles is lower than the toxicity index of cycloxaprid, four chlorantraniliproles and cycloxaprid mixture in 7:3～1:9 proportioning all show obvious synergistic function, and when the percentage by weight of four chlorantraniliproles Yu paichongding is 5:5, co-toxicity coefficient is 154.32, and co-toxicity coefficient is the highest. When the weight ratio of four chlorantraniliproles and cycloxaprid is 9:1 and 8:2, co-toxicity coefficient shows as summation action.
The Toxicity Determination of Pyrausta nubilalis (Hubern). is tested by the mixed agent of embodiment 2: four chlorantraniliprole and cycolxylidin
During Toxicity Determination, tetrachloro insect amide and cycolxylidin is measured according to the ratio that four chlorantraniliproles and cycolxylidin mass ratio are 5～1:5～9, being configured to certain mother solution with acetone be positioned in the refrigerator of 4 DEG C and save backup, experiment institute with medicament is used that 0.01% tween 80 solution dilution. Taking 24, the culture dish of clean sterilizing after medicine, each process arranges three repetitions, one culture dish of each repetition, puts 3 instar larvae 30 in each culture dish. First cabbage leaves is cut into the fritter of 6-7cm, takes out after soaking 5S, after indoor are dried in blade is put into the culture dish accessing Pyrausta nubilalis (Hubern)., with wet cotton balls moisturizing.Within after medicine 24 hours, change cabbage leaves and clear up culture dish. After medicine 24,48 and 72 time observe the survival condition of Pyrausta nubilalis (Hubern)., calculate the mortality rate of Pyrausta nubilalis (Hubern). and corrected mortality, and the lethal concentration of 50 (LC when calculating 7250), correlation coefficient and regression equation, the co-toxicity coefficient (CTC) of intermixture is calculated with reference to the abundant method of Sun Yun.
The mixed agent of table 2 four chlorantraniliprole and cycolxylidin to 3 age corn borer larvae toxicity test
As shown in Table 2, four chlorantraniliproles, the cycolxylidin LC to Pyrausta nubilalis (Hubern).50Respectively 97.45mg/L and 129.47mg/L, the toxicity index of four chlorantraniliproles is higher than the toxicity index of cycolxylidin, four chlorantraniliproles and cycolxylidin mixture in 9:1～3:7 proportioning all show obvious synergistic function, and when the percentage by weight of four chlorantraniliproles Yu cycolxylidin is 4:6, co-toxicity coefficient is 156.27, and co-toxicity coefficient is the highest.
Two, resistance of rainwater washing against embodiment
The resistance to rainwater of electrostatic oil agent of the medicaments such as embodiment 1: four chlorantraniliprole washes away capability study test
Prepare the embodiment 2 that preparation is prepared in embodiment respectively, embodiment 6, the preparation 100ml such as embodiment 8 and embodiment 12, take out 0.1ml, it is diluted with water to 100ml constant volume respectively, it is electrostatic spray on the wood of 1m with the medicinal liquid prepared to diameter 20mm length, take 5% cycloxaprid LC simultaneously, 40% cycolxylidin SC, the 5% 4 each 0.1ml of chlorantraniliprole LC, it is diluted with water to 100ml constant volume respectively, with the medicinal liquid prepared, the wood that diameter 20mm length is 1m is carried out routine to spray, it is simulated rainfall with DIK-6000 rainfall simulation device (Beijing Ha Weisiting Science and Technology Ltd.) after medicinal liquid on wood is dry, rainfall is 15mm/h. flushing time is respectively set to 2h and 4h, compares wood not coating. take the rainwater sample 25.0g of above-mentioned collection to carry out extracting according to NYT761-2008 method and the pre-treatment such as purification. then adopt meteorological and liquid-phase chromatographic analysis sample active constituent content, calculate active constituent content in rainwater. measure the turnover rate for the treatment of agent on wood.
Number of dropouts=sample size * gross rainfall
Table 3 test medicine resistance of rainwater washing against Journal of Sex Research
Result of the test shows, electrostatic oil agent can effectively reduce pesticide active ingredient turnover rate. Under approximate equally effective Ingredient Amount, its resistance of rainwater washing against ability and be much better than cycloxaprid, cycolxylidin and four chlorantraniliprole non-electrostatic oil preparation single doses. Showing, under approximate equally effective Ingredient Amount, electrostatic oil agent adopts electrostatic spraying processes resistance of rainwater washing against ability to be better than the preparations etc. such as water dispersible granules, cream and suspending agent simultaneously.
Three, embodiment prepared by preparation
Embodiment 1:10.1% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Preparation technology: in the mixing kettle of belt stirrer, first with partial solvent by active component by after four chlorantraniliproles and cycloxaprid stirring and dissolving, add surfactant, penetrating agent, conductive agent and remaining solvent, it is sufficiently stirred for mix homogeneously, obtains 10.1% 4 chlorantraniliprole cycloxaprid electrostatic oil agent; Technological parameter is: it is 60～150 revs/min that mixing speed controls, and mixing time is 15～60 minutes, and temperature is room temperature, and pressure is normal pressure.
According to the step of preparation process identical with embodiment 1, it is possible to preparation following example.
Embodiment 2:13% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Embodiment 3:14% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Embodiment 4:17% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Embodiment 5:17% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Embodiment 6:20.1% tetra-chlorantraniliprole cycloxaprid electrostatic oil agent
Embodiment 7:10.1% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 8:12% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 9:14% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 10:17% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 11:20% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 12:20.1% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
Embodiment 13:2% tetra-chlorantraniliprole cycolxylidin electrostatic oil agent
The prepared electrostatic oil agent outward appearance containing four chlorantraniliproles is oily liquids;Low temperature compatibility is good, under 5 DEG C of conditions, and cold preservation 7d not crystallization and float; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, without poisoning; Employing remain silent method measure, flash-point is more than 70 DEG C; Viscosity is less than 30mPa s; Conductivity is 1 × 10-6～1 × 10- 10Within the scope of s/cm.
Four, field efficacy embodiment
The field efficacy measurement result carried out below in conjunction with the application embodiment of the present invention further illustrates beneficial effects of the present invention:
Application Example 1:
Controlling object: cigarette aphid.
Experiment place: agricultural college of Guangxi University teaching farm.
Application method: electrostatic spray.
Comparison is arranged: 5% cycloxaprid LC, 25% cycolxylidin SC and 200 g/l of four chlorantraniliprole SC, is diluted with water to the spraying of 30L routine.
Formulation rate: each consumption that processes is calculated according to unified drug cost.
Table 4: prevent and treat tobacco smoke aphid field control effectiveness test result
As can be seen from Table 4: the electrostatic oil agent employing electrostatic spraying processes dispenser of the present invention prevents and treats tobacco smoke aphid, and than comparison medicament routine spraying, quick-acting is strong, prevention effect good, the lasting period is longer.
Application Example 2
Controlling object: cigarette beetle.
Experiment place: agricultural college of Guangxi University teaching farm.
Application method: electrostatic spray.
Comparison medicament: 10% cycloxaprid AS, effective ingredient mu consumption 10g, is diluted with water to the spraying of 30L routine; 200 g/l of four chlorantraniliprole SC, is diluted with water to the spraying of 30L routine.
Formulation rate: be calculated according to unified drug cost.
Table 5: preventing and treating cigarette beetle field control effectiveness test result
As can be seen from Table 5: the electrostatic oil agent of the present invention adopts electrostatic spraying processes dispenser preventing and treating cigarette beetle, and than comparison medicament routine spraying, quick-acting is strong, prevention effect good, the lasting period is longer.
Claims (6)
1. containing the electrostatic oil agent of four chlorantraniliproles, it is characterised in that be grouped into by the one-tenth of following percentage by weight: four chlorantraniliproles 0.1～10%, active component II 0.1～20%; Surfactant 0.1～15%, conductive agent 0.1～10%, penetrating agent 0.1～5%, solvent complements to 100%; Described active component II is cycloxaprid or cycolxylidin.
2. the electrostatic oil agent containing four chlorantraniliproles according to claim 1, it is characterised in that be grouped into by the one-tenth of following percentage by weight: four chlorantraniliproles 0.1～6%, active component II0.1～12%; Surfactant 0.1～10%, conductive agent 1～6%, penetrating agent 0.1～3%, solvent complements to 100%.
3. the electrostatic oil agent containing four chlorantraniliproles according to claim 1, it is characterized in that, described surfactant is at least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether or OPEO.
4. the electrostatic oil agent containing four chlorantraniliproles according to claim 1, it is characterised in that described penetrating agent is azone, thiophene ketone or oozes at least one in T soon.
5. the electrostatic oil agent containing four chlorantraniliproles according to claim 1, it is characterised in that described conductive agent is calcium dodecyl benzene sulfonate or dodecylbenzene sodium sulfonate.
6. the electrostatic oil agent containing four chlorantraniliproles according to claim 1, it is characterized in that, described solvent is at least one in dimethylbenzene, trimethylbenzene, durene, o-dichlorohenzene, methyl naphthalene, dimethyl sulfoxide, N-Methyl pyrrolidone, DMF, ethanol, n-octyl alcohol, terpineol, benzyl alcohol, methyl anyl alcohol, soybean oil, Petiolus Trachycarpi oil, vegetable oil acid methyl ester, vegetable oil acid ethyl ester, Oleum Terebinthinae, Oleum Gossypii semen, Testa oryzae oil, Oleum Brassicae campestris, two wires oil, Semen Maydis oil or dimethyl carbonate.
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Application publication date: 20160615 |