CN106259408A - A kind of clothianidin-containing and the composition pesticide of lufenuron - Google Patents
A kind of clothianidin-containing and the composition pesticide of lufenuron Download PDFInfo
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- CN106259408A CN106259408A CN201610638562.8A CN201610638562A CN106259408A CN 106259408 A CN106259408 A CN 106259408A CN 201610638562 A CN201610638562 A CN 201610638562A CN 106259408 A CN106259408 A CN 106259408A
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- lufenuron
- clothianidin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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Abstract
The invention provides the composition pesticide of a kind of clothianidin-containing and lufenuron, can effectively prevent and treat Bradysia fungus gnat.The effective ingredient of described composition pesticide is clothianidin and lufenuron, the mass ratio of the two be 1:0.1 1:20, clothianidin and lufenuron be 2 80% at the mass fraction of described composition pesticide.The dosage form prepared by known method by the compositions of the present invention, have that insecticide quick-acting is good, the relatively small number of advantage of lasting period length, consumption, can effectively prevent and treat Bradysia fungus gnat, also can be widely used to the pest control of Semen arachidis hypogaeae, vegetable, Semen Tritici aestivi and Camellia sinensis, and control of grubs, aphid, diamondback moth, thrips, aleyrodid and smaller green leaf hopper, using value is big, and economic and social benefit is notable.
Description
Technical field
The present invention relates to technical field of agricultural insecticide, be specifically related to the pesticide combination of a kind of clothianidin-containing and lufenuron
Thing.
Technical background
Clothianidin is a kind of insecticide in anabasine, is a class highly effective and safe, high selective novel pesticide,
Researcher Chris doctor Connolly at nearly University of Dundee's environmental change and mankind's adaptive faculty center studies discovery: thiophene worm
Although amine is similar to Diacloden and imidacloprid chemical property, but can't have adverse effect on Apis.Its effect and cigarette
Alkali acetylcholine receptor type seemingly, have tag, stomach toxicity and systemic activity.It is mainly used on Oryza sativa L., vegetable, fruit tree and other crops
Anti-eliminate aphis, leafhopper, thrips, Semiptera, coleoptera, Diptera and the insecticide of some Lepidoptera class pest such as plant hopper, have
Efficiently, wide spectrum, consumption is few, toxicity is low, drug effect lasting period length, to crop without poisoning, use safety with conventional pesticide no interactions resist
Property etc. advantage, have brilliance interior suction and osmosis, be substitute high-toxic organic phosphorus pesticide another kind.Its novel structure, spy
Very, performance is the most excellent compared with tradition nicotinic insecticide, it is possible to become international large-scale insecticide variety.
Lufenuron, ISO adopted name Lufenuron, chemical name RS-1-[2,5-bis-chloro-4-(1,1,2,3,3,3-six
Fluorine propoxyl group) phenyl]-3-(2,6-difluoro benzoyl) urea, white crystals body.Latest generation substituted urea class insecticide.Medicament
By acting on insect larvae, stoping exfoliating process to kill off the insect pests, especially the food leaf caterpillars such as fruit tree there are is outstanding preventive effect, right
What thrips, rust mite, trialeurodes vaporariorum had a uniqueness kills mechanism, is suitable to prevent and treat that pyrethroid and organophosphorus pesticide are produced resistance evil
Worm.The lasting period of medicament is long, advantageously reduces laxative number of times；To crop safety, Semen Maydis, vegetable, Citrus, Cotton Gossypii, Rhizoma Solani tuber osi, Portugal
Grape, Soybean and Other Crops all can use, and are suitable for Integrated pest and administer.
Bradysia fungus gnat, Bradysia odoriphaga Yang et Zhang, belong to Diptera, eye Sciaridae.Main harm
The liliaceous vegetables such as Folium Allii tuberosi, Herba Alii fistulosi, Bulbus Allii Cepae, Herba Alii fistulosi, Bulbus Allii, the most also endanger Caulis et Folium Lactucae sativae, green vegetable, Herba Apii graveolentis etc., are allium vegetableses
One of primary pest.Worm state has adult, ovum, larva, pupa, is gathered in the bulb of Folium Allii tuberosi underground part and tender stem with larva
Cause harm.Newly hatched larvae is first caused harm the upper end of Folium Allii tuberosi leaf sheath base and bulb.Spring, the young stem of Folium Allii tuberosi of mainly causing harm in season in autumn two cause corruption
Rotten, make fragrant-flowered garlic leaf withered and yellow and dead, larva activity downwards in summer is eaten into into bulb, and severe one bulb rots, and whole pier is dead.It is thus desirable to it is a kind of
Can effectively prevent and treat and kill insecticide or the composition pesticide of Bradysia fungus gnat.
Summary of the invention
It is an object of the invention to for solve above-mentioned in technical problem, it is provided that one has potentiation, can effectively prevent and treat
The composition pesticide that the clothianidin-containing of Bradysia fungus gnat and lufenuron compound.
The technical solution adopted in the present invention is:
A kind of clothianidin-containing and the composition pesticide of lufenuron, it is characterised in that effective ingredient is clothianidin and lufenuron,
The mass ratio of the two is: 1:0.1-1:20.
The effective ingredient clothianidin of described compositions and the mass ratio of lufenuron are 1:0.5-1:5.
Described clothianidin and lufenuron are 2-80% at the mass fraction of described composition pesticide.
Described clothianidin is 1-60% at the mass fraction of described composition pesticide, and described lufenuron is in described pesticide combination
The mass fraction of thing is 1-60%.
Described composition pesticide dosage form includes suspending agent, aqueous emulsion, microemulsion, wettable powder, soluble powder, water
Dispersible granule, microcapsule, effervescent tablet.
Described composition pesticide insecticide-applying way is foliar spray, mix soil, pouring root, seed treatment.
Described composition pesticide is preventing and treating the application of Bradysia fungus gnat.
The composition pesticide of the present invention has the following technical effect that
1, can effectively prevent and treat and kill Bradysia fungus gnat, and based on the clothianidin mechanism of action different with lufenuron, to Bradysia
Each worm state of fungus gnat, especially larval stage, there is the preventive effect of excellence；
2, Semen arachidis hypogaeae, vegetable, Semen Tritici aestivi and Camellia sinensis it are but also widely used for, for control of grubs, aphid, diamondback moth, thrips, aleyrodid
And smaller green leaf hopper, using value is big；
3, equal notable synergistic and lasting period are long compared with two kinds of single doses, can reduce times for spraying, and reduce field rate, have
Effect reduces pesticide residues in environmental pollution and soil；
Detailed description of the invention:
Enforcement one, clothianidin joint toxicity measuring to fragrant-flowered garlic maggot larva mixed with lufenuron
Method: filter paper is moistened by the medicinal liquid being diluted with water to variable concentrations, is layered in 9cm culture dish, by Folium Allii tuberosi (white portion
Point) it is cut into 3cm segment, always soak 10s in variable concentrations difference medicinal liquid.Take out 6 sections to be placed in culture dish, then by brush pen gently
Ground shifts three larvas of the same size.Often process 50-60 head, repeat for 3 times, set clear water comparison simultaneously.It is the most right that every 12h checks
According to insect and each situation of enlivening processed, record dead borer population after 48-60 hour, finally calculate each medicament EC50.
Theoretical toxicity index A of mixture preparation: the ∑ (percentage of this effective elements of the medicine in the toxicity index * mixture of certain medicine
Rate)
The actual toxicity index of co-toxicity coefficient CTC=/theory toxicity index * 100 of mixture preparation
CTC > 120 is potentiation, and ＜ 80 is antagonism, and 80-120 is addition
Table 1 clothianidin joint toxicity measuring to fragrant-flowered garlic maggot 1 instar larvae mixed with lufenuron
From data, clothianidin is 0.5217mg/L to the LC50 of fragrant-flowered garlic maggot 1 larva, and lufenuron is to fragrant-flowered garlic maggot 1 larva
LC50 be 5.1598mg/L, clothianidin is mixed with lufenuron 1:0.1/1:0.5/1:2.5/1:5/1:12.5/1:20, its altogether poison
Coefficient ＞ 120, potentiation is notable.
Table 2 clothianidin joint toxicity measuring to fragrant-flowered garlic maggot 4 instar larvae mixed with lufenuron
From data, clothianidin is 0.9999mg/L to the LC50 of fragrant-flowered garlic maggot 4 larva, and lufenuron is to fragrant-flowered garlic maggot 4 larva
LC50 be 5.2194mg/L, clothianidin is mixed with lufenuron 1:0.1/1:0.5/1:2.5/1:5/1:12.5/1:20, its altogether poison
Coefficient ＞ 120, potentiation is notable.
Comprehensive Tables 1 and 2, when the ratio that clothianidin is mixed with lufenuron is 1:0.5-1:5, has significantly fragrant-flowered garlic maggot larva
Killing effect, Folium Allii tuberosi stem can be prevented effectively from and rotted.
Enforcement two, formulation examples:
The present invention can pass through example 1, example 2, example 3, example 4, example 5, example 6, example 7, example 8 are carried out specifically
Illustrate, but be not limited to this.
Example 1:45% clothianidin 4.5% lufenuron suspension agent
Each component precentagewise is calculated as: the 45% former medicine of clothianidin, the 4.5% former medicine of lufenuron, 3% wetting agent MorwetEFW,
6% dispersant MorwetD-425,4% antifreeze glycol, 0.12% thickening agent xanthan gum, 0.3% suspending agent aluminium-magnesium silicate,
0.25% stabilizer BIT, 2% penetrating agent Nekal BX, deionized water supply 100%.
Operating procedure: first by wetting agent, dispersant, suspending agent, penetrating agent, defoamer, stabilizer, antifreezing agent proportionally
Join in deionized water, stir by high shear dispersion machine；The material of gained adds clothianidin and the former medicine of lufenuron,
Continue to stir；The material of gained is sent into horizontal sand mill and is carried out sand milling, makes the particle diameter of sand milling liquid reach D90≤4.0 μm, adds
Enter thickening agent, stir.
Example 2:20% clothianidin 10% lufenuron suspension agent
Each component precentagewise is calculated as: the 20% former medicine of clothianidin, the 10% former medicine of lufenuron, 1.8% dispersant carboxylate SP-
2728,4% wetting dispersing agent polyethers WELL-SCB, 0.8% suspending agent aluminium-magnesium silicate, 0.3% stabilizer sodium sorbate, 0.2%
Organic silicon defoamer, 5% penetrating agent organosilicon ethyoxyl modification trisiloxanes, 2% antifreezing agent
Polyethylene Glycol, 0.16% thickening agent xanthan gum, pH adjusting agent make suspending agent pH value be 6～7 in right amount, deionized water is mended
Foot 100%.
Operating procedure: first by dispersant, wetting dispersing agent, suspending agent, penetrating agent, defoamer, stabilizer, antifreezing agent according to
Ratio joins in deionized water, stirs by high shear dispersion machine；The material of gained adds clothianidin and lufenuron
Former medicine, continues to stir；The material of gained is sent into horizontal sand mill and is carried out sand milling, makes the particle diameter of sand milling liquid reach D90≤4.0
μm, adds thickening agent, and regulation pH value stirs to 6～7.
Example 3:10% clothianidin 10% lufenuron suspension agent
Each component precentagewise is calculated as: the 10% former medicine of clothianidin, the 10% former medicine of lufenuron, 3% wetting dispersing agent YUS-
SC3,2% dispersant YUS-TXC, 3% antifreezing agent propylene glycol, 0.2%pH regulator, 0.3% organosiloxane defoamer,
0.3% preservative S-30,0.8% suspending agent aluminium-magnesium silicate, 0.16% thickening agent xanthan gum, deionized water supply 100%,.
Operating procedure: first by dispersant, wetting dispersing agent, suspending agent, penetrating agent, defoamer, stabilizer, antifreezing agent according to
Ratio joins in deionized water, stirs by high shear dispersion machine；The material of gained adds clothianidin and lufenuron
Former medicine, continues to stir；The material of gained is sent into horizontal sand mill and is carried out sand milling, makes the particle diameter of sand milling liquid reach D90≤4.0
μm, adds thickening agent, and regulation pH value stirs to 6～7.
Example 4:10% clothianidin 20% lufenuron suspension agent
Each component precentagewise is calculated as: the 10% former medicine of clothianidin, the 20% former medicine of lufenuron, 4% dispersant fatty alcohol polyoxy
Vinyl Ether, dispersion moisture agent 3% alkylphenol polyoxyethylene, 5% penetrating agent Nekal BX, 0.13% thickening agent xanthan gum,
0.32% defoamer SAG622,3% antifreezing agent propylene glycol, 0.4% preservative sodium benzoate, surplus is deionized water.
Example 5:5% clothianidin 20% lufenuron suspension agent
Each component precentagewise is calculated as: the 5% former medicine of clothianidin, the 10% former medicine of lufenuron, 3% wetting dispersing agent YUS-
FS3000,2% dispersant YUS-EP60P, 4% antifreeze glycol, thickening agent xanthan gum 0.18%, 0.2%pH regulator,
0.2% organosiloxane defoamer, 0.3% preservative sodium benzoate, 0.6% suspending agent aluminium-magnesium silicate, deionized water are supplied
100%,.
Operating procedure: first by dispersant, wetting dispersing agent, suspending agent, penetrating agent, defoamer, stabilizer, antifreezing agent according to
Ratio joins in deionized water, stirs by high shear dispersion machine；The material of gained adds clothianidin and lufenuron
Former medicine, continues to stir；The material of gained is sent into horizontal sand mill and is carried out sand milling, makes the particle diameter of sand milling liquid reach D90≤4.0
μm, adds thickening agent, and regulation pH value stirs to 6～7.
Example 6:10% clothianidin 10% lufenuron wettable powder
Clothianidin 10%, lufenuron 10%, sodium lauryl sulphate 1.5%, lignin sulfonic acid sodium salt 2.5%, LOMAR PWA EINECS 246-676-2
Sodium salt 3%, white carbon 5%, Kaolin complements to 100%, i.e. obtains 10% clothianidin 10% louse after mix homogeneously comminution by gas stream
Demodicid mite urea wettable powder.
Example 7:10% clothianidin 10% lufenuron water dispersible granules
Clothianidin 10%, lufenuron 10%, sodium lauryl sulphate 2.5%, polycarboxylate sodium 1.5%, naphthalene sulfonate salt
4%, corn starch 15%, Kaolin complements to 100%, and the pelletize that adds water after mix homogeneously comminution by gas stream i.e. obtains 10% thiophene after drying
Worm amine 10% lufenuron water dispersible granules.
Example 8:10% clothianidin 10% lufenuron effervescent tablet
Clothianidin 10%, lufenuron 10%, dodecylbenzene sodium sulfonate 2%, calcium lignosulfonate 3.5%, sodium naphthalene sulfonate
Salt 2%, citric acid 10%, calcium carbonate 10%, kieselguhr complements to 100%, adds ethanol pelletize and dry after mix homogeneously comminution by gas stream
10% clothianidin 10% lufenuron effervescent tablet is i.e. obtained after Gan.
Enforcement three, field efficacy evaluation
(1) select above example to carry out the field control effectiveness test of Folium Allii tuberosi root maggot, determine the effect of preventing and treating Folium Allii tuberosi root maggot, test
Synergistic effect after card is compounding.Experiment place: Nanchang to Village, the pool, experimental period: the 15-5 month 30 in February, 2016.Tool
Body experimental technique is as follows；
With reference to " agricultural experiment criterion (two)-insecticide control Folium Allii tuberosi fragrant-flowered garlic maggot, root maggot ", often processing 3 times and repeat, every community is put down
Row 5 samplings of jump, calculating root worm amount is radix, if clear water comparison.3 days, 14 days, 45 days investigation remnants borer populations alive after medicine.
Add up total borer population and the remnants borer population alive of each process, calculate Revision insect recluced rate and the Rectifying efficacies of each process.
Radix * 100 before Revision insect recluced rate=(borer population of living after radix-medicine before medicine)/medicine
Rectifying efficacies=(chemicals treatment Revision insect recluced rate-CK Revision insect recluced rate)/(100-CK Revision insect recluced rate) * 100
Field test shows: the worm amount of each treatment agent is greatly decreased, and the effect of compounding embodiment is substantially better than list
Agent effect, clothianidin is compounding with lufenuron has potentiation.Estimating according to field, normally there is not poisoning in plant growth.Examination
Finding during testing, example three and example four also have good preventive effect to root-knot nematode.
(2) select above example to carry out the field test of cabbage aphid, determine the anti-effect eliminated aphis, after checking is compounding
Synergistic effect.Specific experiment method is as follows:
With reference to " agricultural experiment criterion ()-insecticide control potatoes and other crops aphid ", 100,3 times, every community weight
Multiple, the aphid number (aphid number ＞ 1000) of every community investigation at least 10 strain plant, if clear water comparison.Radix, medicine is investigated before medicine
Latter 1 day, 3 days and 7 days investigation remnants borer populations alive.Add up total borer population and the remnants borer population alive of each process, calculate the insect population of each process
Decline rate and Rectifying efficacies.
Radix * 100 before Revision insect recluced rate=(borer population of living after radix-medicine before medicine)/medicine
Rectifying efficacies=(chemicals treatment Revision insect recluced rate-CK Revision insect recluced rate)/(100-CK Revision insect recluced rate) * 100
Table 3 20% clothianidin lufenuron SC is to cabbage aphid efficiency test data
Field experiment shows: prove from table 3 test data, and clothianidin is compounding with lufenuron obvious to the preventive effect of cabbage aphid
Being better than compareing single dose, clothianidin is compounding with lufenuron has potentiation.Estimating according to field, normally there is not medicine in plant growth
Evil.Finding in process of the test, example three and example four also have good preventive effect to thrips and aleyrodid.
Claims (7)
1. a clothianidin-containing and the composition pesticide of lufenuron, it is characterised in that effective ingredient is clothianidin and lufenuron, two
The mass ratio of person is: 1:0.1-1:20.
A kind of clothianidin-containing the most according to claim 1 and the composition pesticide of lufenuron, it is characterised in that described combination
The effective ingredient clothianidin of thing and the mass ratio of lufenuron are 1:0.5-1:5.
A kind of clothianidin-containing the most according to claim 1 and the composition pesticide of lufenuron, it is characterised in that described thiophene worm
Amine and lufenuron are 2-80% at the mass fraction of described composition pesticide.
A kind of clothianidin-containing the most according to claim 1 and the composition pesticide of lufenuron, it is characterised in that described thiophene worm
Amine is 1-60% at the mass fraction of described composition pesticide, and described lufenuron is 1-at the mass fraction of described composition pesticide
60%.
A kind of clothianidin-containing the most according to claim 1 and the composition pesticide of lufenuron, it is characterised in that described agriculture
Drug composition dosage form includes suspending agent, aqueous emulsion, microemulsion, wettable powder, soluble powder, water dispersible granules, microcapsule
Agent, effervescent tablet.
A kind of clothianidin-containing the most according to claim 1 and the composition pesticide of lufenuron, it is characterised in that described agriculture
Drug composition insecticide-applying way is foliar spray, mix soil, pouring root, seed treatment.
The composition pesticide of a kind of clothianidin-containing the most according to claim 1 and lufenuron is preventing and treating answering of Bradysia fungus gnat
With.
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| CN201610638562.8A CN106259408A (en) | 2016-08-05 | 2016-08-05 | A kind of clothianidin-containing and the composition pesticide of lufenuron |
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Citations (3)
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| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
| EP2471364A1 (en) * | 2006-02-09 | 2012-07-04 | Syngenta Participations AG | Ternary fungicidal compositions comprising sedaxane |
| CN102630695A (en) * | 2012-04-01 | 2012-08-15 | 广西田园生化股份有限公司 | Ultra low volume concentrate containing lufenuron and nicotine insecticides |
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2016
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2471364A1 (en) * | 2006-02-09 | 2012-07-04 | Syngenta Participations AG | Ternary fungicidal compositions comprising sedaxane |
| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
| CN102630695A (en) * | 2012-04-01 | 2012-08-15 | 广西田园生化股份有限公司 | Ultra low volume concentrate containing lufenuron and nicotine insecticides |
Non-Patent Citations (1)
| Title |
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| 宋健 等: ""常用低毒杀虫剂对韭菜迟眼蕈蚊防治效果评价"", 《安徽农业科学》 * |
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