CN102150684A - Ultralow-volume liquid containing ethofenprox - Google Patents
Ultralow-volume liquid containing ethofenprox Download PDFInfo
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- CN102150684A CN102150684A CN2011100435211A CN201110043521A CN102150684A CN 102150684 A CN102150684 A CN 102150684A CN 2011100435211 A CN2011100435211 A CN 2011100435211A CN 201110043521 A CN201110043521 A CN 201110043521A CN 102150684 A CN102150684 A CN 102150684A
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Abstract
The invention relates to an ultralow-volume liquid containing ethofenprox and application thereof in a paddy field. The ultralow-volume liquid is prepared by compounding ethofenprox with one effective component, such as chlorpyrifos, thiamethoxam, meta-tolyl-N-meth ylcarbamate, isoprocarb or fenobucarb and is used for controlling piercing and sucking type agricultural destructive insects of rice planthopper, aphid, leafhopper, aleyrodid, scale insect and the like. The ultralow-volume liquid is adopted for controlling the insects by applying an ultralow-volume spraying method. Water does not need to be added for diluting the liquid during the use, liquid applying efficiency is high and control efficiency is remarkable. Compared with the traditional liquid applying method, a large quantity of manpower and material resources can be saved.
Description
Technical field
The present invention relates to a kind ofly contain the ultra low volume liquids of ether chrysanthemum ester and prevent and treat the application of rice hoppers at paddy field.
Background technology
Rice fulgorid is one of the primary pest in harm China south and middle and lower reach of Yangtze River rice district, wherein brown planthopper and white-backed planthopper are intermittent big insect of taking place, with become, the nymph rice strain base portion of trooping inhales juice, cause that the rice plant Huang is withered, the deliquescing of stem stalk or the lodging of rotting, the harm of brown planthopper is the most serious, according to statistics, only 2005 and hazard area in 2006 are about about 2.5 hundred million mu, general paddy rice loss 5～10%, the outbreak year paddy rice underproduction 10～20%, it is about 40～50% that the heavy field piece of part loses, even total crop failure.Small brown rice planthopper harm mainly be with become, nymph by the juice of sucking (as the stripe disease) plant that suffers from virus disease after, become the band virion, it not only constantly passes to healthy plant with virus, also passes to its offspring, is continued to propagate by the offspring.From 2004～2007 years continuous 4 years in Jiangsu, Shanghai, Anhui and part rice district, Zhejiang small brown rice planthopper wildness cause disaster, cause the big generation of stripe disease, according to relevant plant protection department statistics, the incidence of disease of stripe disease in recent years, the rice seedling bed: 1～5%, heavy field piece 10～20%, the field piece 30～50% of especially severe, this class field piece is often ploughed and is replanted, and the household economy loss is serious; Transplant field: because the harm of small brown rice planthopper transmitted virus, the apparent disease of dancing leaf blight morbidity forms weak stubble, dead seedling causes the loss of the underproduction suitable with brown planthopper.As seen, the harm of rice fulgorid grain-production of serious threat China and safety.
Ether chrysanthemum ester (Buprofezin) belongs to thiadiazine ketone chitin synthesis inhibitor.Low toxicity is extremely light to skin and eye irritation effect.Strong to the insect action of contace poison, stomach poison function is also arranged.It is synthetic to suppress insect chitin, disturbs metabolism, causes nymph cast off a skin deformity or wing deformity and slowly dead.Just can find out effect in 3～7 days after the general dispenser, adult not had direct killing power, but can shorten its life-span, reduce egg laying amount, and output be mostly addle-egg, even the also very fast death of larva hatching.Leafhopper, plant hopper and aleyrodid of control Semiptera and scale insect are active high.The drug effect phase reached more than 30 days.To pest natural enemy and insect pollinator safety.There is not mutual pesticide resistance problem with other insecticides.
But the agricultural chemicals of a kind of active ingredient of long-term single use will cause the generation of resistance very soon, thereby loses its using value.Itself and other pesticide active ingredient is combined into composite insecticide, is at present in exploitation with develop a kind of mode effectively and efficiently commonly used in the new insecticide pesticide.Main purpose with the composite back use of some single insecticidal constituents, except being its consumption of minimizing, improve insecticidal effect, reduce outside toxic action and the adverse effect the environment generation, another important purpose is exactly in order to solve the pesticide resistance that insect is produced the single component agricultural chemicals, make drug effect descend or be close to invalid agricultural chemicals and recover insecticidal effect again, even can also improve effect.Rule during agriculture chemical compounding is to guarantee that the composition of assembly should lack as far as possible under certain desinsection control efficiency prerequisite.
The existing preparation of ether chrysanthemum ester mainly contains missible oil, granule, wetting powder, water dispersible granules, microemulsion, suspending agent and film-spreading oil solution etc.And ether chrysanthemum ester ultra low volume liquids is not appeared in the newspapers both at home and abroad.
The ultra low volume spraying technology abroad just begins one's study as far back as the forties, and up to the initial stage sixties, the U.S. has solved after the ultra low volume spraying agent, and this pesticide application technology just begins many countries in the world and grows up gradually.Because the benefit of this technology is very remarkable, used by dozens of country so far, carry out ultra low volume spraying as countries such as the U.S., Canada, Australia aircraft, the tractors of adopting, the ultra low volume spraying machine of main employing such as Thailand, Brazil and China, hand-held, backpack carries out small-scale spray pesticide more.
Summary of the invention
The objective of the invention is according to above-mentioned situation, provide a kind of by a kind of and composite ultra low volume liquids that forms of ether chrysanthemum ester in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.Not only can eliminate pierce-suck type pest such as aphid, plant hopper, leafhopper, aleyrodid to because a large amount of uses of ether chrysanthemum ester may cause the resistance that produces, its control efficiency is obviously improved.
Active ingredient of the present invention is a kind of and ether chrysanthemum ester in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.
With the composite ultra low volume liquids of a kind of active ingredient in ether chrysanthemum ester and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa, be used to prevent and treat rice hoppers, aphid, leafhopper, aleyrodid, reach the pierce-suck type pest.
Its part by weight is a kind of/ether chrysanthemum ester=1.0～40.0/1.0～30.0 in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.The preferred weight ratio is a kind of/ether chrysanthemum ester=2.0～35.0/2.0～25.0 in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.With it composite after, can not only delay the generation of pierce-suck type pest resistances such as aphid, plant hopper, leafhopper, aleyrodid, sucking pests such as aphid, plant hopper, leafhopper, aleyrodid are all had certain synergistic effect.
It is ether chrysanthemum ester 1.0%～40.0% that this ultra low volume liquids includes the effective constituent mass fraction, is preferably 2.0%～25.0%; Chlopyrifos, thiophene worm piperazine, Mobucin, Bassa or meta-tolyl-N-methylcarbamate (MTMC) are respectively 1.0%～40.0%, are preferably 2.0%～35.0% respectively, cosolvent 1.0%～10.0%, and surplus is a solvent.Chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and ether chrysanthemum ester composition ratio are 40: 1～2.
The cosolvent that is fit to is selected from cyclohexanone, methyl-sulfoxide, or N-Methyl pyrrolidone.
The solvent that is fit to is many Fluhyzons, as line oil or two wires wet goods, heavy aromatics, vegetable oil such as turpentine oil or cottonseed oil, corn oil.Preferred two wires oil or the above aromatic hydrocarbons of C10.
Ultra low volume liquids of the present invention adopts the manner known in the art preparation, normally active ingredient and cosolvent, solvent is fully mixed and forms.
Adopt this agricultural chemicals to use ultra low volume spraying method control rice fulgorid.
The target crop that is fit to is cereal crops such as paddy rice, wheat, economic crops such as soybean, peanut, cotton, tea tree, vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon, fruit tree crops such as grape, oranges and tangerines, apple, pear tree, peach.
Adopting agricultural chemicals of the present invention to use the ultra low volume spraying method prevents and treats.Ultra low volume liquids of the present invention is fit to control rice thrips, rice gall midge, rice fulgorid, rice leafhopper, and wheat mythimna separata, aphid, aleyrodid, scale insect etc. are specially adapted to the ultra low volume spraying method and prevent and treat rice hoppers.
The present invention carries out the composite ultra low volume liquids that forms by ether chrysanthemum ester and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa, with the rice hoppers is research object, the comparative study proof of imitating by composite synergistic effect, field not only can reduce or eliminate the pierce-suck type pest to because a large amount of uses of ether chrysanthemum ester etc. cause the resistance that produces, and its control efficiency is obviously improved.Result of study sees attached list 1～5.
Utilization DPS software carries out statistical analysis, it is equivalent and adopt the abundant method of Sun Yun to obtain the co-toxicity coefficient of each mixed ratio with reference to NY/T 1154.7-2006 to obtain test toxicity regression line (Y=a+bx) of medicament and correlation coefficient (r) value, LC50, LC90, selects optimal proportion.Toxicity Determination result shows, chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa are mixed co-toxicity coefficient to brown planthopper all greater than 100 with 5 different proportions of ether chrysanthemum ester respectively, illustrate that it is to have certain synergistic effect that two composite reagents are used to prevent and treat rice fulgorid, can use in practice.
According to subordinate list 1-5, the field control effectiveness test data all show, ether chrysanthemum ester and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa carry out the composite ultra low volume liquids that forms to the quick-acting of rice fulgorid, lasting effect, anti-efficient significantly better than the contrast medicament.Do not need the thin up soup in the use, dispenser work efficiency height, preventive effect is remarkable.Traditional application method of comparing can be saved a large amount of manpower and materials.
Embodiment
The present invention is by the composite two yuan of Recompounded pesticides that form of a kind of and ether chrysanthemum ester in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa, its a kind of by in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa, the composite ultra low volume liquids that forms of ether chrysanthemum ester and proper assistant and carrier.A kind of content that contains in the complex preparation in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa is 1.0～40.0%, and ether chrysanthemum ester content is 1.0～30.0%.
The present invention describes with the following example, but does not limit the scope of the invention.
Embodiment 1, ether chrysanthemum ester, chlopyrifos ultra low volume liquids
A, 2.0% ether chrysanthemum ester chlopyrifos ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, chlopyrifos 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
B, 12.0% ether chrysanthemum ester chlopyrifos ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 2.0kg, chlopyrifos 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
C, 30.0% ether chrysanthemum ester chlopyrifos ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 6.0kg, chlopyrifos 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
D, 41.0% ether chrysanthemum ester chlopyrifos ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, chlopyrifos 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
Embodiment 2, ether chrysanthemum ester, thiophene worm piperazine ultra low volume liquids
A, 2.0% ether chrysanthemum ester thiophene worm piperazine ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, thiophene worm piperazine 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
B, 12.0% ether chrysanthemum ester thiophene worm piperazine ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 2.0kg, thiophene worm piperazine 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
C, 30.0% ether chrysanthemum ester thiophene worm piperazine ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 6.0kg, thiophene worm piperazine 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
D, 41.0% ether chrysanthemum ester thiophene worm piperazine ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, thiophene worm piperazine 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
Embodiment 3, ether chrysanthemum ester, meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
A, 2.0% ether chrysanthemum ester meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
B, 12.0% ether chrysanthemum ester meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 2.0kg, meta-tolyl-N-methylcarbamate (MTMC) 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
C, 30.0% ether chrysanthemum ester meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 6.0kg, meta-tolyl-N-methylcarbamate (MTMC) 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
D, 41.0% ether chrysanthemum ester meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
Embodiment 4, ether chrysanthemum ester, Mobucin ultra low volume liquids
A, 2.0% ether chrysanthemum ester Mobucin ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, Mobucin 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
B, 12.0% ether chrysanthemum ester Mobucin ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 2.0kg, Mobucin 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
C, 30.0% ether chrysanthemum ester Mobucin ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 6.0kg, Mobucin 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
D, 41.0% ether chrysanthemum ester Mobucin ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, Mobucin 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
Embodiment 5, ether chrysanthemum ester, Bassa ultra low volume liquids
A, 2.0% ether chrysanthemum ester Bassa ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, Bassa 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
B, 12.0% ether chrysanthemum ester Bassa ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 2.0kg, Bassa 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
C, 30.0% ether chrysanthemum ester Bassa ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 6.0kg, Bassa 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
D, 41.0% ether chrysanthemum ester Bassa ultra low volume liquids 100kg
With finished product ultra low volume finish is that weight 100% is calculated, ether chrysanthemum ester 1.0kg, Bassa 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, after up-to-standard, the metering encapsulation is finished product.
Directly the above-mentioned finished product that is mixed with is added in the ultra low volume spraying device during use, opening sprayer unit just can the effective pest control of large tracts of land.
Subordinate list 1 ether chrysanthemum ester and chlorpyrifos mixture ultra low volume liquids and single agent control rice fulgorid field efficacy result
Subordinate list 2 ether chrysanthemum esters and Thiamethoxam compound ultra low volume liquids and single agent control rice fulgorid field efficacy result
Subordinate list 3 ether chrysanthemum esters and the composite ultra low volume liquids of meta-tolyl-N-methylcarbamate (MTMC) and single agent control rice fulgorid field efficacy result
Subordinate list 4 ether chrysanthemum esters and the composite ultra low volume liquids of Mobucin and single agent control rice fulgorid field efficacy result
Subordinate list 5 ether chrysanthemum esters and fenobucarb composite ultra low volume liquids and single agent control rice fulgorid field efficacy result
Claims (5)
1. ultra low volume liquids that contains ether chrysanthemum ester, it is characterized in that:, be used to prevent and treat rice hoppers, aphid, leafhopper, aleyrodid, reach the pierce-suck type pest with the composite ultra low volume liquids of a kind of active ingredient in ether chrysanthemum ester and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.
2. the ultra low volume liquids that contains ether chrysanthemum ester according to claim 1 is characterized in that: its part by weight is a kind of/ether chrysanthemum ester=1.0～40.0/1.0～30.0 in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.
3. the ultra low volume liquids that contains ether chrysanthemum ester according to claim 1 and 2 is characterized in that: the preferred weight ratio is a kind of/ether chrysanthemum ester=2.0～35.0/2.0～25.0 in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.
4. the ultra low volume liquids that contains ether chrysanthemum ester according to claim 1 is characterized in that: chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and ether chrysanthemum ester composition ratio are 40: 1～2.
5. the ultra low volume liquids that contains ether chrysanthemum ester according to claim 1 is characterized in that: adopt agricultural chemicals of the present invention to use the ultra low volume spraying method and prevent and treat.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100435211A CN102150684A (en) | 2011-02-23 | 2011-02-23 | Ultralow-volume liquid containing ethofenprox |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011100435211A CN102150684A (en) | 2011-02-23 | 2011-02-23 | Ultralow-volume liquid containing ethofenprox |
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| CN102150684A true CN102150684A (en) | 2011-08-17 |
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| CN2011100435211A Pending CN102150684A (en) | 2011-02-23 | 2011-02-23 | Ultralow-volume liquid containing ethofenprox |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
| CN102626069A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN102626070A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN106689190A (en) * | 2016-12-27 | 2017-05-24 | 浙江新农化工股份有限公司 | Insecticidal composition containing chlorpyrifos-methyl and etofenprox as well as preparation and application thereof |
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| JPH0930903A (en) * | 1995-07-25 | 1997-02-04 | Zaiensu:Kk | Termite-proofing agent |
| CN1729782A (en) * | 2005-08-26 | 2006-02-08 | 刘东卫 | Pyrethroid and organic phosphorus composite synergic pesticide and its application |
| CN1863513A (en) * | 2003-08-06 | 2006-11-15 | 格吕伦塔尔有限公司 | Abuse-proffed dosage form |
| CN1943357A (en) * | 2006-10-12 | 2007-04-11 | 江苏省农业科学院 | Composite pesticide of one class preventing and control rice pests |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH0930903A (en) * | 1995-07-25 | 1997-02-04 | Zaiensu:Kk | Termite-proofing agent |
| CN1863513A (en) * | 2003-08-06 | 2006-11-15 | 格吕伦塔尔有限公司 | Abuse-proffed dosage form |
| CN1729782A (en) * | 2005-08-26 | 2006-02-08 | 刘东卫 | Pyrethroid and organic phosphorus composite synergic pesticide and its application |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
| CN102626069A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN102626070A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN102626070B (en) * | 2012-03-29 | 2013-07-31 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN106689190A (en) * | 2016-12-27 | 2017-05-24 | 浙江新农化工股份有限公司 | Insecticidal composition containing chlorpyrifos-methyl and etofenprox as well as preparation and application thereof |
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Application publication date: 20110817 |