CN101808738A - 制备碳纳米管生产用的催化剂的方法 - Google Patents

制备碳纳米管生产用的催化剂的方法 Download PDF

Info

Publication number
CN101808738A
CN101808738A CN200880109383A CN200880109383A CN101808738A CN 101808738 A CN101808738 A CN 101808738A CN 200880109383 A CN200880109383 A CN 200880109383A CN 200880109383 A CN200880109383 A CN 200880109383A CN 101808738 A CN101808738 A CN 101808738A
Authority
CN
China
Prior art keywords
catalyst
gas
temperature
drying
spray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN200880109383A
Other languages
English (en)
Chinese (zh)
Inventor
S·布克霍尔茨
V·米歇尔
L·姆莱茨科
R·贝林格豪森
A·沃尔夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of CN101808738A publication Critical patent/CN101808738A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0004—Apparatus specially adapted for the manufacture or treatment of nanostructural devices or systems or methods for manufacturing the same
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1271—Alkanes or cycloalkanes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1273—Alkenes, alkynes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
CN200880109383A 2007-09-27 2008-09-13 制备碳纳米管生产用的催化剂的方法 Pending CN101808738A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102007046160.9 2007-09-27
DE102007046160A DE102007046160A1 (de) 2007-09-27 2007-09-27 Verfahren zur Herstellung eines Katalysators für die Herstellung von Kohlenstoffnanoröhrchen
PCT/EP2008/007614 WO2009043445A1 (de) 2007-09-27 2008-09-13 Verfahren zur herstellung eines katalysators für die herstellung von kohlenstoffnanoröhrchen

Publications (1)

Publication Number Publication Date
CN101808738A true CN101808738A (zh) 2010-08-18

Family

ID=40256920

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880109383A Pending CN101808738A (zh) 2007-09-27 2008-09-13 制备碳纳米管生产用的催化剂的方法

Country Status (8)

Country Link
US (1) US20090087372A1 (https=)
EP (1) EP2197579A1 (https=)
JP (1) JP5335796B2 (https=)
KR (1) KR20100059913A (https=)
CN (1) CN101808738A (https=)
DE (1) DE102007046160A1 (https=)
TW (1) TW200932354A (https=)
WO (1) WO2009043445A1 (https=)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102502591A (zh) * 2011-11-28 2012-06-20 深圳市贝特瑞纳米科技有限公司 纳米碳纤维的制备方法和设备
CN103827027A (zh) * 2012-01-11 2014-05-28 Lg化学株式会社 碳纳米管及其制备方法
CN103987659A (zh) * 2012-01-11 2014-08-13 Lg化学株式会社 碳纳米管及其制备方法
CN104475313A (zh) * 2010-09-14 2015-04-01 应用奈米结构公司 长有碳纳米管玻璃基板及其制造方法
CN110330008A (zh) * 2019-06-20 2019-10-15 徐成德 一种碳纳米管的连续生产方法
CN114340787A (zh) * 2019-09-05 2022-04-12 赢创运营有限公司 包含碳-嵌入的镍纳米粒子的材料、其生产方法和作为非均相催化剂的用途
CN114405513A (zh) * 2022-01-29 2022-04-29 江门道氏新能源材料有限公司 一种金属复合材料及其制备方法和应用
CN116603536A (zh) * 2023-05-10 2023-08-18 湖北冠毓新材料科技有限公司 一种碳纳米管催化剂的制备方法
CN117563625A (zh) * 2023-11-16 2024-02-20 江西金碳合新材料有限公司 一种钴系碳纳米管催化剂其制备方法及应用

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101007184B1 (ko) * 2008-10-17 2011-01-12 제일모직주식회사 탄소나노튜브 합성용 담지촉매, 그 제조방법 및 이를 이용한 탄소나노튜브
KR101007183B1 (ko) * 2008-10-23 2011-01-12 제일모직주식회사 탄소나노튜브 합성용 담지촉매, 그 제조방법 및 이를 이용한 탄소나노튜브
CN106829925A (zh) * 2009-07-17 2017-06-13 西南纳米科技公司 用于制备多壁碳纳米管的催化剂和方法
DE102009038464A1 (de) * 2009-08-21 2011-02-24 Bayer Materialscience Ag Kohlenstoffnanoröhrchen-Agglomerat
KR101018660B1 (ko) 2009-12-22 2011-03-04 금호석유화학 주식회사 다중벽 탄소나노튜브 제조용 촉매조성물
RU2476268C2 (ru) * 2010-06-15 2013-02-27 Общество с ограниченной ответственностью "НаноТехЦентр" Способ получения металлоксидных катализаторов для выращивания углеродных нанотрубок из газовой фазы
KR101241034B1 (ko) * 2010-08-10 2013-03-11 금호석유화학 주식회사 분무 열분해 방법을 이용한 고수율 탄소나노튜브 합성용 촉매조성물의 제조 방법
CN102363525B (zh) * 2011-07-01 2013-01-23 中国平煤神马集团开封炭素有限公司 干料加热器
KR101330364B1 (ko) * 2012-03-09 2013-11-15 재단법인 한국탄소융합기술원 고분자 복합체용 탄소나노튜브 펠렛 합성 방법
JP5497109B2 (ja) * 2012-07-03 2014-05-21 昭和電工株式会社 複合炭素繊維
DE102013214229A1 (de) * 2013-07-19 2015-01-22 Bayer Materialscience Ag Verfahren zur Herstellung eines effizienten Katalysators für die Produktion mehrwandiger Kohlenstoffnanoröhrchen, mehrwandiges Kohlenstoffnanoröhrchen und Kohlenstoffnanoröhrchenpulver
JP6237311B2 (ja) * 2014-02-17 2017-11-29 東洋インキＳｃホールディングス株式会社 カーボンナノチューブ合成用触媒
KR101783446B1 (ko) * 2014-09-30 2017-09-29 주식회사 엘지화학 중공형 탄소 캡슐의 제조 방법
KR101701973B1 (ko) * 2015-06-05 2017-02-03 금호석유화학 주식회사 페라이트 금속 산화물 촉매의 제조방법
KR102669941B1 (ko) * 2016-02-27 2024-05-27 니폰 제온 가부시키가이샤 섬유상 탄소 나노 구조체의 제조 방법
US10065244B2 (en) * 2016-04-18 2018-09-04 Taiwan Powder Technologies Co., Ltd. Method for fabricating porous spherical iron-based alloy powder
WO2019055998A1 (en) * 2017-09-18 2019-03-21 West Virginia University CATALYSTS AND PROCESSES FOR MULTI-WAFER CARBON NANOTUBES WITH TUNABLE BASIC GROWTH
KR102303667B1 (ko) 2017-10-31 2021-09-16 에스케이이노베이션 주식회사 탄소 나노 튜브 합성용 촉매 및 탄소 나노 튜브의 제조 방법
CN109745984B (zh) * 2017-11-08 2022-02-18 中国科学院金属研究所 一种金属单原子掺杂碳纳米管的制备方法
CN108101026B (zh) * 2017-12-21 2020-11-03 江苏天奈科技股份有限公司 一种酸洗碳纳米管的干燥方法
EP3789111A1 (en) 2019-09-05 2021-03-10 Evonik Operations GmbH Materials comprising carbon-embedded iron nanoparticles, processes for their manufacture, and use as heterogeneous catalysts
EP3789112A1 (en) 2019-09-05 2021-03-10 Evonik Operations GmbH Materials comprising carbon-embedded cobalt nanoparticles, processes for their manufacture, and use as heterogeneous catalysts
EP4035775A4 (en) * 2019-09-27 2023-11-01 Zeon Corporation PRODUCTION PROCESS FOR CATALYST SUPPORT AND PRODUCTION PROCESS OF A FIBROUS CARBON NANOSTRUCTURE
WO2022163371A1 (ja) * 2021-01-28 2022-08-04 日本ゼオン株式会社 触媒担持体および繊維状炭素ナノ構造体の製造方法
CN114433055B (zh) * 2022-03-10 2022-12-23 苏州大学 一种具有高度开放多级孔结构的碳催化剂及其制备方法和应用
CN114923125B (zh) * 2022-05-23 2023-11-03 中国计量大学 一种利用悬浮纳米颗粒吸附增强氢气稀释的安全排放装置
CN121372433B (zh) * 2025-12-24 2026-03-24 山西万联中科新材料技术有限公司 一种用于合成单壁碳纳米管的负载型催化剂及其制备方法和应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105572A (en) * 1976-03-31 1978-08-08 E. I. Du Pont De Nemours And Company Ferromagnetic toner containing water-soluble or water-solubilizable resin(s)
CA1175616A (en) 1981-01-05 1984-10-09 Exxon Research And Engineering Company Production of iron monoxide and carbon filaments therefrom
US4663230A (en) 1984-12-06 1987-05-05 Hyperion Catalysis International, Inc. Carbon fibrils, method for producing same and compositions containing same
US4717559A (en) * 1986-06-03 1988-01-05 E.C.C. America Inc. Kaolin calciner waste heat and feed recovery system and method
ZA907803B (en) 1989-09-28 1991-07-31 Hyperion Catalysis Int Electrochemical cells and preparing carbon fibrils
EP0868942A1 (en) * 1993-11-08 1998-10-07 The Gillette Company Method of forming particles using a supercritical fluid and aerogel particles formed thereby
US6102024A (en) * 1998-03-11 2000-08-15 Norton Company Brazed superabrasive wire saw and method therefor
CA2347332A1 (en) * 2000-05-13 2001-11-13 Korea Carbon Black Co., Ltd. Carbon fibrils and method for producing same
EP1154050A1 (en) * 2000-05-13 2001-11-14 Korean Carbon Black Co., Ltd., Degussa Group Carbon fibrils and method for producing same
CN1141250C (zh) * 2001-05-25 2004-03-10 清华大学 一种流化床连续化制备碳纳米管的方法及其反应装置
JP4068056B2 (ja) 2001-07-03 2008-03-26 ファキュルテ ユニヴェルシテール ノートル−ダム ド ラ ペ 触媒担体およびその上で生成されたカーボンナノチューブ
WO2003043734A1 (en) * 2001-11-22 2003-05-30 Sasol Technology (Proprietary) Limited Ferrihydrite and aluminium-containing fischer-tropsch catalysts
US7250148B2 (en) * 2002-07-31 2007-07-31 Carbon Nanotechnologies, Inc. Method for making single-wall carbon nanotubes using supported catalysts
US20090124496A1 (en) * 2004-11-03 2009-05-14 Gerardus Petrus Lambertus Niesen Attrition Resistant Particulate Catalyst
DE102004054959A1 (de) 2004-11-13 2006-05-18 Bayer Technology Services Gmbh Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator
EP1674154A1 (fr) * 2004-12-23 2006-06-28 Nanocyl S.A. Procédé de synthèse d'un catalyseur supporté pour la fabrication de nanotubes carbone
US20060148653A1 (en) * 2005-01-04 2006-07-06 Keller William W Light weight carriers
EP1797950A1 (en) * 2005-12-14 2007-06-20 Nanocyl S.A. Catalyst for a multi-walled carbon nanotube production process
DE102006007147A1 (de) 2006-02-16 2007-08-23 Bayer Technology Services Gmbh Verfahren zur kontinuierlichen Herstellung von Katalysatoren
DE102006017695A1 (de) * 2006-04-15 2007-10-18 Bayer Technology Services Gmbh Verfahren zur Herstellung von Kohlenstoffnanoröhrchen in einer Wirbelschicht

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104475313A (zh) * 2010-09-14 2015-04-01 应用奈米结构公司 长有碳纳米管玻璃基板及其制造方法
CN104475313B (zh) * 2010-09-14 2017-05-17 应用奈米结构公司 长有碳纳米管玻璃基板及其制造方法
CN102502591B (zh) * 2011-11-28 2013-09-04 深圳市贝特瑞纳米科技有限公司 纳米碳纤维的制备方法和设备
CN102502591A (zh) * 2011-11-28 2012-06-20 深圳市贝特瑞纳米科技有限公司 纳米碳纤维的制备方法和设备
CN103987659A (zh) * 2012-01-11 2014-08-13 Lg化学株式会社 碳纳米管及其制备方法
CN103987659B (zh) * 2012-01-11 2017-02-22 Lg化学株式会社 碳纳米管及其制备方法
CN103827027A (zh) * 2012-01-11 2014-05-28 Lg化学株式会社 碳纳米管及其制备方法
CN103827027B (zh) * 2012-01-11 2017-10-24 Lg化学株式会社 碳纳米管及其制备方法
CN110330008A (zh) * 2019-06-20 2019-10-15 徐成德 一种碳纳米管的连续生产方法
CN114340787A (zh) * 2019-09-05 2022-04-12 赢创运营有限公司 包含碳-嵌入的镍纳米粒子的材料、其生产方法和作为非均相催化剂的用途
CN114340787B (zh) * 2019-09-05 2024-03-19 赢创运营有限公司 包含碳-嵌入的镍纳米粒子的材料、其生产方法和作为非均相催化剂的用途
CN114405513A (zh) * 2022-01-29 2022-04-29 江门道氏新能源材料有限公司 一种金属复合材料及其制备方法和应用
CN116603536A (zh) * 2023-05-10 2023-08-18 湖北冠毓新材料科技有限公司 一种碳纳米管催化剂的制备方法
CN117563625A (zh) * 2023-11-16 2024-02-20 江西金碳合新材料有限公司 一种钴系碳纳米管催化剂其制备方法及应用

Also Published As

Publication number Publication date
DE102007046160A1 (de) 2009-04-02
JP2010540220A (ja) 2010-12-24
EP2197579A1 (de) 2010-06-23
TW200932354A (en) 2009-08-01
US20090087372A1 (en) 2009-04-02
KR20100059913A (ko) 2010-06-04
JP5335796B2 (ja) 2013-11-06
WO2009043445A1 (de) 2009-04-09

Similar Documents

Publication Publication Date Title
JP5335796B2 (ja) カーボンナノチューブを製造するために用いる触媒の製造方法
JP4685454B2 (ja) 担持触媒を用いた単一層カーボンナノチューブの製造方法
US20100276644A1 (en) Method for producing nitrogen-doped carbon nanotubes
JP5702043B2 (ja) 不均一触媒でガス状炭素化合物を分解することによりカーボンナノチューブを製造するための触媒
JP5898618B2 (ja) カーボンナノチューブ凝集体
CN101384358B (zh) 催化剂的连续制备方法
KR101007183B1 (ko) 탄소나노튜브 합성용 담지촉매, 그 제조방법 및 이를 이용한 탄소나노튜브
CN101374762B (zh) 合成碳纳米管的方法
WO2004070094A1 (ja) カーボンナノファイバの製造方法及び装置
CN105451883A (zh) 制造用于生成多壁碳纳米管的有效催化剂的方法、多壁碳纳米管和碳纳米管粉末
JP6403144B2 (ja) 気相法微細炭素繊維の製造方法
CN117563625A (zh) 一种钴系碳纳米管催化剂其制备方法及应用
KR101440417B1 (ko) 초음파 열분해법을 이용한 탄소나노튜브 합성용 촉매의 제조방법 및 그로부터 제조된 촉매를 이용한 탄소나노튜브
JP2011255382A (ja) ナノカーボン材料製造用触媒の製造方法及びナノカーボン材料の製造方法
KR20070082141A (ko) 탄소나노튜브 합성용 촉매의 제조방법
JP2008093494A (ja) ナノカーボン材料製造用触媒及びナノカーボン材料製造用触媒の製造方法
HK1118248A (en) Catalyst for producing carbon nanotubes by means of the decomposition of gaseous carbon compounds on a heterogeneous catalyst
HK1130852A (en) Method for the production of carbon nanotubes in a fluidized bed
HK1170717A (zh) 碳纳米管聚集体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20100818