CN101679232B - 自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 - Google Patents

自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 Download PDF

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Publication number
CN101679232B
CN101679232B CN200880015358.4A CN200880015358A CN101679232B CN 101679232 B CN101679232 B CN 101679232B CN 200880015358 A CN200880015358 A CN 200880015358A CN 101679232 B CN101679232 B CN 101679232B
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free radical
high pressure
solvent
density polyethylene
low density
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CN200880015358.4A
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Chinese (zh)
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CN101679232A (zh
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彼得·埃尔茨
奥托·伯比
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN200880015358.4A 2007-03-09 2008-02-12 自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 Expired - Fee Related CN101679232B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90599907P 2007-03-09 2007-03-09
US60/905,999 2007-03-09
PCT/US2008/053677 WO2008112373A1 (en) 2007-03-09 2008-02-12 A free radical initiator system and a high pressure, freeradical polymerization process for producing a low density polyethylene polymer

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CN101679232A CN101679232A (zh) 2010-03-24
CN101679232B true CN101679232B (zh) 2014-02-12

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Country Link
US (1) US20100093961A1 (enExample)
EP (1) EP2121592B1 (enExample)
JP (1) JP5415289B2 (enExample)
KR (1) KR20100015430A (enExample)
CN (1) CN101679232B (enExample)
AR (1) AR065665A1 (enExample)
BR (1) BRPI0808310A2 (enExample)
CA (1) CA2680577A1 (enExample)
MX (1) MX2009009638A (enExample)
RU (1) RU2009137375A (enExample)
TW (1) TW200902561A (enExample)
WO (1) WO2008112373A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471388B (zh) * 2009-07-14 2014-08-06 埃克森美孚化学专利公司 高压自由基聚合方法
EP2576688B1 (en) * 2010-05-27 2017-01-18 Dow Global Technologies LLC Polymer compositions, methods of making the same, and articles prepared from the same
FR2971510B1 (fr) * 2011-02-10 2013-03-22 Arkema France Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite
WO2013078018A2 (en) 2011-11-23 2013-05-30 Dow Global Technologies Llc Low density ethylene-based polymers with broad molecular weight distributions and low extractables
WO2013078224A1 (en) 2011-11-23 2013-05-30 Dow Global Technologies Llc Low density ethylene-based polymers with extracts at lower molecular weights
RU2664104C2 (ru) * 2013-04-25 2018-08-15 Инфиана Джемени Гмбх Унд Ко. Кг Способная к линейному раздиру многослойная пленка
EP3483188A1 (en) * 2014-08-05 2019-05-15 ExxonMobil Chemical Patents Inc. Process for manufacturing ethylene polymers and using modifiers
KR102571535B1 (ko) * 2015-06-30 2023-08-29 다우 글로벌 테크놀로지스 엘엘씨 고압 자유 라디칼 중합
FR3041645B1 (fr) * 2015-09-29 2017-09-08 Arkema France Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite
JP6946331B2 (ja) 2016-04-22 2021-10-06 ダウ グローバル テクノロジーズ エルエルシー 清浄な押出コーティング処理のための低揮発性管状低密度エチレン系ポリマーを製造する方法
TWI648328B (zh) * 2016-07-01 2019-01-21 旭化成股份有限公司 Polyethylene resin composition
CA2960665A1 (en) * 2017-03-14 2018-09-14 Nova Chemicals Corporation Method to control melt elasticity in ldpe
JP7171628B2 (ja) 2017-06-28 2022-11-15 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーを生成するための高圧フリーラジカル重合
KR102410623B1 (ko) 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
US11684904B2 (en) 2021-10-14 2023-06-27 Chevron Phillips Chemical Company Lp Initiator injection into high pressure LDPE reactors

Citations (3)

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US3775341A (en) * 1971-08-02 1973-11-27 Ppg Industries Inc Liquid dialkyl peroxydicarbonate composition
US3956396A (en) * 1974-04-12 1976-05-11 Pennwalt Corporation Safe diacyl peroxide solution compositions
CN1487958A (zh) * 2001-01-23 2004-04-07 �����ɷ� 通过高压法制备乙烯聚合物

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Publication number Priority date Publication date Assignee Title
DE1795294B2 (de) * 1968-09-06 1979-04-26 Basf Ag, 6700 Ludwigshafen Verfahren zum Herstellen von Homo- oder Copolymerisaten des Äthylens
BE756426A (fr) * 1969-09-23 1971-03-22 Basf Ag Procede de preparation d'homo- ou de copolymeres de l'ethylene
DE3486145T2 (de) * 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
US4777230A (en) * 1985-05-30 1988-10-11 Pennwalt Corporation Solution polymerization of acrylic acid derived monomers using tertiary alkyl(ηC5)hydroperoxides
DE3912975A1 (de) * 1989-04-20 1990-11-08 Basf Ag Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen
US5322912A (en) * 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
DE19829399A1 (de) * 1998-07-01 2000-02-03 Buna Sow Leuna Olefinverb Gmbh Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte
DE10021886A1 (de) * 2000-05-05 2001-11-15 Basell Polyolefine Gmbh Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren
KR101216515B1 (ko) * 2004-11-02 2012-12-31 다우 글로벌 테크놀로지스 엘엘씨 저 밀도 폴리에틸렌 조성물의 제조 방법 및 이로부터생성된 중합체

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775341A (en) * 1971-08-02 1973-11-27 Ppg Industries Inc Liquid dialkyl peroxydicarbonate composition
US3956396A (en) * 1974-04-12 1976-05-11 Pennwalt Corporation Safe diacyl peroxide solution compositions
CN1487958A (zh) * 2001-01-23 2004-04-07 �����ɷ� 通过高压法制备乙烯聚合物

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Publication number Publication date
WO2008112373A1 (en) 2008-09-18
CN101679232A (zh) 2010-03-24
JP2010520936A (ja) 2010-06-17
EP2121592B1 (en) 2012-05-23
KR20100015430A (ko) 2010-02-12
TW200902561A (en) 2009-01-16
US20100093961A1 (en) 2010-04-15
RU2009137375A (ru) 2011-04-20
CA2680577A1 (en) 2008-09-18
BRPI0808310A2 (pt) 2014-07-08
MX2009009638A (es) 2009-09-22
EP2121592A1 (en) 2009-11-25
AR065665A1 (es) 2009-06-24
JP5415289B2 (ja) 2014-02-12

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