KR20100015430A - 저밀도 폴리에틸렌 중합체를 제조하기 위한 고압 자유라디칼 중합 방법 및 자유라디칼 개시제 시스템 - Google Patents
저밀도 폴리에틸렌 중합체를 제조하기 위한 고압 자유라디칼 중합 방법 및 자유라디칼 개시제 시스템 Download PDFInfo
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- KR20100015430A KR20100015430A KR1020097021002A KR20097021002A KR20100015430A KR 20100015430 A KR20100015430 A KR 20100015430A KR 1020097021002 A KR1020097021002 A KR 1020097021002A KR 20097021002 A KR20097021002 A KR 20097021002A KR 20100015430 A KR20100015430 A KR 20100015430A
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- free radical
- weight
- radical initiator
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- high pressure
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- 230000008025 crystallization Effects 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 150000002237 fumaric acid derivatives Chemical class 0.000 description 1
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- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
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- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
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- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- KXYJPVZMZBJJBZ-UHFFFAOYSA-N tert-butyl 2-ethylbutaneperoxoate Chemical compound CCC(CC)C(=O)OOC(C)(C)C KXYJPVZMZBJJBZ-UHFFFAOYSA-N 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
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| US90599907P | 2007-03-09 | 2007-03-09 | |
| US60/905,999 | 2007-03-09 |
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| KR20100015430A true KR20100015430A (ko) | 2010-02-12 |
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|---|---|
| US (1) | US20100093961A1 (enExample) |
| EP (1) | EP2121592B1 (enExample) |
| JP (1) | JP5415289B2 (enExample) |
| KR (1) | KR20100015430A (enExample) |
| CN (1) | CN101679232B (enExample) |
| AR (1) | AR065665A1 (enExample) |
| BR (1) | BRPI0808310A2 (enExample) |
| CA (1) | CA2680577A1 (enExample) |
| MX (1) | MX2009009638A (enExample) |
| RU (1) | RU2009137375A (enExample) |
| TW (1) | TW200902561A (enExample) |
| WO (1) | WO2008112373A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| BR112012000909B1 (pt) * | 2009-07-14 | 2018-10-16 | Exxonmobil Chemical Patents Inc | processo para a fabricação de homo e copolímeros de etileno e uso de um c3 a c4 hidrocarboneto ou uma mistura dos mesmos |
| CN102985476B (zh) * | 2010-05-27 | 2015-08-19 | 陶氏环球技术有限责任公司 | 聚合物组合物、其制备方法、以及由该组合物制备的制品 |
| FR2971510B1 (fr) * | 2011-02-10 | 2013-03-22 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
| BR112014012268B1 (pt) | 2011-11-23 | 2020-09-29 | Dow Global Technologies Llc | Polímero a base de etileno, composição e artigo |
| ES2767367T3 (es) | 2011-11-23 | 2020-06-17 | Dow Global Technologies Llc | Polímeros a base de etileno de baja densidad con distribuciones amplias de pesos moleculares y contenido de extraíbles bajo |
| EP2988933A1 (de) * | 2013-04-25 | 2016-03-02 | Infiana Germany GmbH & Co. KG | EINE LINEAR WEITERREIßBARE MEHRSCHICHTFOLIE |
| EP3483188A1 (en) * | 2014-08-05 | 2019-05-15 | ExxonMobil Chemical Patents Inc. | Process for manufacturing ethylene polymers and using modifiers |
| KR102571535B1 (ko) * | 2015-06-30 | 2023-08-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 고압 자유 라디칼 중합 |
| FR3041645B1 (fr) * | 2015-09-29 | 2017-09-08 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite |
| ES2803232T3 (es) | 2016-04-22 | 2021-01-25 | Dow Global Technologies Llc | Método para producir polímeros a base de etileno tubulares de baja densidad y bajo contenido de volátiles para un procedimiento de revestimiento por extrusión limpio |
| TWI648328B (zh) * | 2016-07-01 | 2019-01-21 | 旭化成股份有限公司 | Polyethylene resin composition |
| CA2960665A1 (en) * | 2017-03-14 | 2018-09-14 | Nova Chemicals Corporation | Method to control melt elasticity in ldpe |
| WO2019005812A1 (en) | 2017-06-28 | 2019-01-03 | Dow Global Technologies Llc | HIGH PRESSURE FREE RADICAL POLYMERIZATIONS FOR PRODUCING ETHYLENE POLYMERS |
| KR102410623B1 (ko) | 2017-10-19 | 2022-06-17 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조 방법 |
| US11684904B2 (en) | 2021-10-14 | 2023-06-27 | Chevron Phillips Chemical Company Lp | Initiator injection into high pressure LDPE reactors |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1795294B2 (de) * | 1968-09-06 | 1979-04-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Homo- oder Copolymerisaten des Äthylens |
| BE756426A (fr) * | 1969-09-23 | 1971-03-22 | Basf Ag | Procede de preparation d'homo- ou de copolymeres de l'ethylene |
| US3775341A (en) * | 1971-08-02 | 1973-11-27 | Ppg Industries Inc | Liquid dialkyl peroxydicarbonate composition |
| US3956396A (en) * | 1974-04-12 | 1976-05-11 | Pennwalt Corporation | Safe diacyl peroxide solution compositions |
| DE3486145T2 (de) * | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| US4777230A (en) * | 1985-05-30 | 1988-10-11 | Pennwalt Corporation | Solution polymerization of acrylic acid derived monomers using tertiary alkyl(ηC5)hydroperoxides |
| DE3912975A1 (de) * | 1989-04-20 | 1990-11-08 | Basf Ag | Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen |
| US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| US6407191B1 (en) * | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| DE19829399A1 (de) * | 1998-07-01 | 2000-02-03 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte |
| DE10021886A1 (de) * | 2000-05-05 | 2001-11-15 | Basell Polyolefine Gmbh | Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren |
| DE10102937A1 (de) * | 2001-01-23 | 2002-07-25 | Basf Ag | Verfahren zur Herstellung von Ethylenpolymerisaten im Hochdruckverfahren |
| BRPI0516921B1 (pt) * | 2004-11-02 | 2016-04-12 | Dow Global Technologies Inc | homopolímero ou copolímero de etileno e processo de polimerização com iniciação via radical livre |
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2008
- 2008-02-12 KR KR1020097021002A patent/KR20100015430A/ko not_active Withdrawn
- 2008-02-12 US US12/529,787 patent/US20100093961A1/en not_active Abandoned
- 2008-02-12 CA CA002680577A patent/CA2680577A1/en not_active Abandoned
- 2008-02-12 WO PCT/US2008/053677 patent/WO2008112373A1/en not_active Ceased
- 2008-02-12 EP EP08729613A patent/EP2121592B1/en not_active Not-in-force
- 2008-02-12 CN CN200880015358.4A patent/CN101679232B/zh not_active Expired - Fee Related
- 2008-02-12 BR BRPI0808310-0A patent/BRPI0808310A2/pt not_active IP Right Cessation
- 2008-02-12 RU RU2009137375/04A patent/RU2009137375A/ru unknown
- 2008-02-12 JP JP2009552785A patent/JP5415289B2/ja not_active Expired - Fee Related
- 2008-02-12 MX MX2009009638A patent/MX2009009638A/es not_active Application Discontinuation
- 2008-03-07 TW TW097108111A patent/TW200902561A/zh unknown
- 2008-03-07 AR ARP080100972A patent/AR065665A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20100093961A1 (en) | 2010-04-15 |
| EP2121592B1 (en) | 2012-05-23 |
| WO2008112373A1 (en) | 2008-09-18 |
| CN101679232A (zh) | 2010-03-24 |
| CA2680577A1 (en) | 2008-09-18 |
| CN101679232B (zh) | 2014-02-12 |
| EP2121592A1 (en) | 2009-11-25 |
| BRPI0808310A2 (pt) | 2014-07-08 |
| JP2010520936A (ja) | 2010-06-17 |
| TW200902561A (en) | 2009-01-16 |
| JP5415289B2 (ja) | 2014-02-12 |
| MX2009009638A (es) | 2009-09-22 |
| AR065665A1 (es) | 2009-06-24 |
| RU2009137375A (ru) | 2011-04-20 |
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