RU2009137375A - Система свободнорадикального инициатора и способ свободнорадикальной полимеризации высокого давления для получения полимерного полиэтилена низкой плотности - Google Patents
Система свободнорадикального инициатора и способ свободнорадикальной полимеризации высокого давления для получения полимерного полиэтилена низкой плотности Download PDFInfo
- Publication number
- RU2009137375A RU2009137375A RU2009137375/04A RU2009137375A RU2009137375A RU 2009137375 A RU2009137375 A RU 2009137375A RU 2009137375/04 A RU2009137375/04 A RU 2009137375/04A RU 2009137375 A RU2009137375 A RU 2009137375A RU 2009137375 A RU2009137375 A RU 2009137375A
- Authority
- RU
- Russia
- Prior art keywords
- free radical
- high pressure
- low density
- solvent
- density polyethylene
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 14
- 239000003999 initiator Substances 0.000 title claims abstract 10
- 238000010526 radical polymerization reaction Methods 0.000 title claims abstract 9
- 150000003254 radicals Chemical class 0.000 title claims abstract 8
- 229920000642 polymer Polymers 0.000 title claims abstract 6
- -1 POLYETHYLENE Polymers 0.000 title claims 6
- 239000004698 Polyethylene Substances 0.000 title claims 6
- 229920000573 polyethylene Polymers 0.000 title claims 6
- 239000002904 solvent Substances 0.000 claims abstract 23
- 229920001684 low density polyethylene Polymers 0.000 claims abstract 14
- 239000004702 low-density polyethylene Substances 0.000 claims abstract 14
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 11
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 11
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 11
- 239000006184 cosolvent Substances 0.000 claims abstract 7
- 150000002978 peroxides Chemical group 0.000 claims abstract 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000005977 Ethylene Substances 0.000 claims abstract 3
- 150000001298 alcohols Chemical class 0.000 claims abstract 3
- VCZXRQFWGHPRQB-UHFFFAOYSA-N CC(C)CC(C)(C)C.CC(C)CC(C)(C)C Chemical compound CC(C)CC(C)(C)C.CC(C)CC(C)(C)C VCZXRQFWGHPRQB-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000004122 cyclic group Chemical group 0.000 claims abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract 2
- 239000011707 mineral Substances 0.000 claims abstract 2
- 239000012934 organic peroxide initiator Substances 0.000 claims abstract 2
- 238000006116 polymerization reaction Methods 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 2
- UHBMDLCNWJWZCX-UHFFFAOYSA-N 2-methylundecane 2,2,4,6,6-pentamethylheptane Chemical compound CCCCCCCCCC(C)C.CC(C)(C)CC(C)CC(C)(C)C UHBMDLCNWJWZCX-UHFFFAOYSA-N 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- 238000007765 extrusion coating Methods 0.000 claims 1
- SYJRVVFAAIUVDH-UHFFFAOYSA-N ipa isopropanol Chemical compound CC(C)O.CC(C)O SYJRVVFAAIUVDH-UHFFFAOYSA-N 0.000 claims 1
- 229940094933 n-dodecane Drugs 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90599907P | 2007-03-09 | 2007-03-09 | |
| US60/905,999 | 2007-03-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2009137375A true RU2009137375A (ru) | 2011-04-20 |
Family
ID=39430974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009137375/04A RU2009137375A (ru) | 2007-03-09 | 2008-02-12 | Система свободнорадикального инициатора и способ свободнорадикальной полимеризации высокого давления для получения полимерного полиэтилена низкой плотности |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20100093961A1 (enExample) |
| EP (1) | EP2121592B1 (enExample) |
| JP (1) | JP5415289B2 (enExample) |
| KR (1) | KR20100015430A (enExample) |
| CN (1) | CN101679232B (enExample) |
| AR (1) | AR065665A1 (enExample) |
| BR (1) | BRPI0808310A2 (enExample) |
| CA (1) | CA2680577A1 (enExample) |
| MX (1) | MX2009009638A (enExample) |
| RU (1) | RU2009137375A (enExample) |
| TW (1) | TW200902561A (enExample) |
| WO (1) | WO2008112373A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011008197A1 (en) * | 2009-07-14 | 2011-01-20 | Exxonmobil Chemical Patents Inc. | High pressure radical polymerization process |
| WO2011150052A1 (en) * | 2010-05-27 | 2011-12-01 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
| FR2971510B1 (fr) * | 2011-02-10 | 2013-03-22 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
| JP6302412B2 (ja) | 2011-11-23 | 2018-03-28 | ダウ グローバル テクノロジーズ エルエルシー | 広い分子量分布を持ち、抽出可能性の低い低密度のエチレン系ポリマー |
| BR112014012268B1 (pt) | 2011-11-23 | 2020-09-29 | Dow Global Technologies Llc | Polímero a base de etileno, composição e artigo |
| CA2907849C (en) * | 2013-04-25 | 2020-03-31 | Infiana Germany Gmbh & Co. Kg | Multilayer film resistant to linear tear propagation |
| CN109679000B (zh) * | 2014-08-05 | 2022-05-03 | 埃克森美孚化学专利公司 | 制造乙烯聚合物和使用改性剂的方法 |
| CN107873035B (zh) * | 2015-06-30 | 2021-04-09 | 陶氏环球技术有限责任公司 | 高压自由基聚合 |
| FR3041645B1 (fr) * | 2015-09-29 | 2017-09-08 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite |
| JP6946331B2 (ja) | 2016-04-22 | 2021-10-06 | ダウ グローバル テクノロジーズ エルエルシー | 清浄な押出コーティング処理のための低揮発性管状低密度エチレン系ポリマーを製造する方法 |
| TWI648328B (zh) * | 2016-07-01 | 2019-01-21 | 旭化成股份有限公司 | Polyethylene resin composition |
| CA2960665A1 (en) * | 2017-03-14 | 2018-09-14 | Nova Chemicals Corporation | Method to control melt elasticity in ldpe |
| ES2889762T3 (es) | 2017-06-28 | 2022-01-13 | Dow Global Technologies Llc | Polimerizaciones de radicales libres a alta presión para producir polímeros a base de etileno |
| KR102410623B1 (ko) | 2017-10-19 | 2022-06-17 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조 방법 |
| US11684904B2 (en) | 2021-10-14 | 2023-06-27 | Chevron Phillips Chemical Company Lp | Initiator injection into high pressure LDPE reactors |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1795294B2 (de) * | 1968-09-06 | 1979-04-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Homo- oder Copolymerisaten des Äthylens |
| BE756426A (fr) * | 1969-09-23 | 1971-03-22 | Basf Ag | Procede de preparation d'homo- ou de copolymeres de l'ethylene |
| US3775341A (en) * | 1971-08-02 | 1973-11-27 | Ppg Industries Inc | Liquid dialkyl peroxydicarbonate composition |
| US3956396A (en) * | 1974-04-12 | 1976-05-11 | Pennwalt Corporation | Safe diacyl peroxide solution compositions |
| KR930000892B1 (ko) * | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
| US4777230A (en) * | 1985-05-30 | 1988-10-11 | Pennwalt Corporation | Solution polymerization of acrylic acid derived monomers using tertiary alkyl(ηC5)hydroperoxides |
| DE3912975A1 (de) * | 1989-04-20 | 1990-11-08 | Basf Ag | Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen |
| US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| US6407191B1 (en) * | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| DE19829399A1 (de) * | 1998-07-01 | 2000-02-03 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte |
| DE10021886A1 (de) * | 2000-05-05 | 2001-11-15 | Basell Polyolefine Gmbh | Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren |
| DE10102937A1 (de) * | 2001-01-23 | 2002-07-25 | Basf Ag | Verfahren zur Herstellung von Ethylenpolymerisaten im Hochdruckverfahren |
| BRPI0516921B1 (pt) * | 2004-11-02 | 2016-04-12 | Dow Global Technologies Inc | homopolímero ou copolímero de etileno e processo de polimerização com iniciação via radical livre |
-
2008
- 2008-02-12 MX MX2009009638A patent/MX2009009638A/es not_active Application Discontinuation
- 2008-02-12 CA CA002680577A patent/CA2680577A1/en not_active Abandoned
- 2008-02-12 WO PCT/US2008/053677 patent/WO2008112373A1/en not_active Ceased
- 2008-02-12 RU RU2009137375/04A patent/RU2009137375A/ru unknown
- 2008-02-12 BR BRPI0808310-0A patent/BRPI0808310A2/pt not_active IP Right Cessation
- 2008-02-12 EP EP08729613A patent/EP2121592B1/en not_active Not-in-force
- 2008-02-12 US US12/529,787 patent/US20100093961A1/en not_active Abandoned
- 2008-02-12 KR KR1020097021002A patent/KR20100015430A/ko not_active Withdrawn
- 2008-02-12 CN CN200880015358.4A patent/CN101679232B/zh not_active Expired - Fee Related
- 2008-02-12 JP JP2009552785A patent/JP5415289B2/ja not_active Expired - Fee Related
- 2008-03-07 TW TW097108111A patent/TW200902561A/zh unknown
- 2008-03-07 AR ARP080100972A patent/AR065665A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20100093961A1 (en) | 2010-04-15 |
| KR20100015430A (ko) | 2010-02-12 |
| TW200902561A (en) | 2009-01-16 |
| CN101679232B (zh) | 2014-02-12 |
| BRPI0808310A2 (pt) | 2014-07-08 |
| CA2680577A1 (en) | 2008-09-18 |
| WO2008112373A1 (en) | 2008-09-18 |
| MX2009009638A (es) | 2009-09-22 |
| AR065665A1 (es) | 2009-06-24 |
| JP5415289B2 (ja) | 2014-02-12 |
| JP2010520936A (ja) | 2010-06-17 |
| EP2121592B1 (en) | 2012-05-23 |
| CN101679232A (zh) | 2010-03-24 |
| EP2121592A1 (en) | 2009-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Cao et al. | Expanding the Scope of Polymerization‐Induced Self‐Assembly: Recent Advances and New Horizons | |
| Zou et al. | Polar‐functionalized, crosslinkable, self‐healing, and photoresponsive polyolefins | |
| Shaplov et al. | Polymeric ionic liquids: comparison of polycations and polyanions | |
| Qiu et al. | Performance of vanadium redox flow battery with a novel amphoteric ion exchange membrane synthesized by two-step grafting method | |
| Shi et al. | Conducting polymer hydrogels as a sustainable platform for advanced energy, biomedical and environmental applications | |
| MX2009009638A (es) | Un sistema iniciador de radical libre y un proceso de polimerizacion de radical libre, de alta presion, para producir un polimero de polietileno de baja densidad. | |
| JP2010520936A5 (enExample) | ||
| Xia et al. | Hybrid block copolymer synthesis by merging photoiniferter and organocatalytic ring‐opening polymerizations | |
| CN109161046B (zh) | 一种聚四氟乙烯接枝膜及其制备方法 | |
| GB1550874A (en) | Process for producing fluorinated copolymer having ion-exchange groups | |
| Chen et al. | Emerging Synthetic Strategies for Core Cross‐Linked Star (CCS) Polymers and Applications as Interfacial Stabilizers: Bridging Linear Polymers and Nanoparticles | |
| Zhao et al. | Lewis Pair Catalyzed Regioselective Polymerization of (E, E)‐Alkyl Sorbates for the Synthesis of (AB) n Sequenced Polymers | |
| CN104927079B (zh) | 一种碱性阴离子交换膜的制备方法 | |
| DE602004014718D1 (de) | Vernetztes Druckrohr aus Polyethylen und Verfahren zu seiner Herstellung | |
| Zheng et al. | Temperature‐Selective Dual Radical Generation from Alkyl Diiodide: Applications to Synthesis of Asymmetric CABC Multi‐Block Copolymers and Their Unique Assembly Structures | |
| Singha et al. | Separation of isopropyl alcohol–water mixtures by pervaporation using crosslink IPN membranes | |
| Reichelt et al. | Tailoring the structural properties of macroporous electron-beam polymerized cryogels by pore forming agents and the monomer selection | |
| CN106589272B (zh) | 基于水性大分子光引发剂的两亲性嵌段共聚物的制备方法 | |
| CN110120541B (zh) | 质子传导膜和燃料电池 | |
| Choudhury et al. | Synthesis and characterization of novel functional poly (vinyl alcohol-co-styrene sulfonic acid) copolymers | |
| JPS5761012A (en) | Production of thermoplastic elastic elastomer | |
| Hwang et al. | Mechanically robust and thermally stable electrochemical devices based on star-shaped random copolymer gel-electrolytes | |
| Hu et al. | Synthesis of unsaturation containing P (VDF‐co‐TrFE‐co‐CTFE) from P (VDF‐co‐CTFE) in one‐pot catalyzed with Cu (0)‐based single electron transfer living radical polymerization system | |
| CN103071427B (zh) | 一种含poss的可聚合型表面活性剂及其制备方法 | |
| Wang et al. | Enhanced Ionic and Electronic Conductivity of Polyacetylene with Dendritic 1, 2, 3‐Triazolium‐Oligo (ethylene glycol) Pendants |