CN101646722A - 氢氯氟烯烃的发泡剂组合物 - Google Patents
氢氯氟烯烃的发泡剂组合物 Download PDFInfo
- Publication number
- CN101646722A CN101646722A CN200880010501A CN200880010501A CN101646722A CN 101646722 A CN101646722 A CN 101646722A CN 200880010501 A CN200880010501 A CN 200880010501A CN 200880010501 A CN200880010501 A CN 200880010501A CN 101646722 A CN101646722 A CN 101646722A
- Authority
- CN
- China
- Prior art keywords
- foaming agent
- class
- agent composition
- hydrogen chlorine
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08J2300/104—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08J2300/106—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
在此披露了一种用于热固性泡沫的发泡剂。该发泡剂占主导的是单独的氢氯氟烯烃(HCFO)HFCO-1233zd的反式异构体或与一种氢氟烯烃(HFO)、氢氟烷(HFC)、氢氯氟烯烃(HCFO)、一种烃的组合。该发泡剂作为热固性泡沫生产中的一种发泡剂是有效的。
Description
发明领域
本发明涉及用于热固性泡沫的发泡剂。更具体地说,本发明涉及单独的氢氯氟烯烃(HCFO)HCFO-1233zd或在一个组合中在热固性泡沫的生产中作为一种发泡剂的用途。本发明的HCFO-1233zd占主导的是反式异构体。
发明背景
用于臭氧层保护的蒙特利尔议定书(于1987年10月签署)命令逐步淘汰氯氟烃类(CFC)的使用。对臭氧层更“友好”的材料,例如氢氟烷类(HFC)(例如HFC-134a)取代了氯氟烃类。后者的化合物已证明是温室气体,温室气体引起全球变暖并且受关于气候变化的京都议定书(于1998年签署)所管辖。所出现的替代材料(氢氟丙烯类)表明是环境可接受的,即具有零臭氧消耗潜势(ODP)以及可接受的低全球变暖潜势(GWP)。
当前使用的用于热固性泡沫的发泡剂包括HFC-134a、HFC-245fa、HFC-365mfc(具有相对高的全球变暖潜势),以及烃类(例如可燃的并且具有低能量效率的戊烷异构体类)。因此,正在寻找新的可替代的发泡剂。卤化的氢烯烃类物质(例如氢氟丙烯类和/或氢氯氟丙烯类)作为HFC的代替物已产生了的兴趣。这些材料在低层大气中的固有的化学不稳定性提供了所希望的低的全球变暖潜势以及零或接近零的臭氧消耗潜势。
本发明的目的是提供可充当用于热固性泡沫的发泡剂的新颖的组合物,该组合物提供了独特的特性来满足低的或零臭氧消耗潜势、更低的全球变暖潜势的需要并且显示出低的毒性。
发明内容
本发明涉及基于不饱和的卤化的氢烯烃的发泡剂的用途,该发泡剂具有可忽略的(低的或零)臭氧消耗和低的GWP。此类发泡剂包括氢氯氟烯烃(HCFO),单独的1-氯-3,3,3-三氟丙烯(HCFO-1233zd)或在一个组合中,该组合包括一种氢氟烯烃(HFO)、一种氢氯氟烯烃(HCFO)、一种氢氟烷(HFC)、一种烃、一种醇、一种醛、一种酮、一种醚/二醚或二氧化碳。本发明的HCFO-1233zd占主导的是HCFO-1233zd的反式异构体。
反式(E)和顺式(Z)展示如下:
反式或E 顺式或Z
氢氯氟烯烃(HCFO)HCFO-1233已被提议作为发泡剂,这类发泡剂表现出低的全球变暖潜势以及低的臭氧消耗值。低的全球变暖潜势以及低的臭氧消耗值是氢卤烯烃类的大气降解作用的一个结果。
通过混入一种多元醇类混合物中,占主导的氢氯氟烯烃HCFO-1233zd的反式异构体(单独的或在与HFO的组合中)可以作为用于热固性泡沫的一种发泡剂而使用。所生成的产物显示出优越的品质,包括减小的密度以及改进的k-因数。该发泡剂在热固性聚合物中容易溶解,并且提供了足以生产可接受的泡沫的一定程度的增塑作用。在环境温度下,HCFO 1233zd是一种液体,这允许了不同工业(特别是聚氨酯泡沫)所希望的处理上的减轻。优选的HFO组分典型地含有3或4个碳,并且包括但不局限于五氟丙烯,如1,2,3,3,3-五氟丙烯(HFO 1225ye);四氟丙烯,如1,3,3,3-四氟丙烯(HFO 1234ze)、2,3,3,3-四氟丙烯(HFO1234yf)、1,2,3,3-四氟丙烯(HFO1234ye);三氟丙烯,如3,3,3-三氟丙烯(1243zf)。本发明优选的实施方案是正常沸点(低于大约60℃的不饱和的卤化的氢烯烃类的发泡剂组合物。
在生产聚氨酯以及聚异氰脲酸酯泡沫中使用的多元醇混合物中,本发明优选的发泡剂组合物(单独的HCFO-1233zd(反式异构体占主导)或在一个组合中)表现出良好的溶解性。本发明的HCFO-1233zd组分中大部分是反式异构体。在AMES中,发现反式异构体展现出比顺式异构体显著更低的遗传毒性。HCFO-1233zd的反式异构体与顺式异构体的一个优选的比率是低于该组合重量的大约30%的顺式异构体,并且优选低于大约10%的顺式异构体。最优选的比率是低于大约3%的顺式异构体。优选的发泡剂组合产生了具有所希望水平的绝缘值的泡沫。
本发明的HCFO-1233zd可以用于与其他发泡剂的组合中,包括但不局限于:(a)氢氟烷类,包括但不局限于二氟甲烷(HFC32);1,1,1,2,2-五氟乙烷(HFC125);1,1,1-三氟乙烷(HFC143a);1,1,2,2-四氟乙烷(HFC134);1,1,1,2-四氟乙烷(HFC134a);1,1-二氟乙烷(HFC152a);1,1,1,2,3,3,3-七氟丙烷(HFC227ea);1,1,1,3,3-五氟丙烷(HFC245fa);1,1,1,3,3-五氟丁烷(HFC365mfc)以及1,1,1,2,2,3,4,5,5,5-十氟戊烷(HFC4310mee)。(b)氢氟烯烃类,包括但不局限于:四氟丙烯类(HFO1234)、三氟丙烯类(HFO1243)、所有的四氟丁烯异构体类(HFO1354)、所有的五氟丁烯异构体类(HFO1345)、所有的六氟丁烯异构体类(HFO1336)、所有的七氟丁烯异构体类(HFO1327)、所有的七氟戊烯异构体类(HFO1447)、所有的八氟戊烯异构体类(HFO1438)、所有的九氟戊烯异构体类(HFO1429);(c)烃类,包括但不局限于戊烷异构体类、丁烷异构体类;(d)C1至C5的醇类、C1至C4的醛类、C1至C4的酮类、C1至C4的醚类和二醚类以及二氧化碳;(e)HCFO类,例如2-氯-3,3,3-三氟丙烯(HCFO-1233xf)以及二氯三氟丙烯(HCFO1223)。
根据本发明,本发明的可起泡的组合物总体而言包括能够形成泡沫(具有一种总体上多孔的结构)的一种或多种组分以及一种发泡剂,典型的是在一个组合中。在某些实施方案中,该一种或多种组分包括一种能够形成泡沫的热固性组合物和/或可起泡的组合物。热固性组合物的实例包括聚氨酯以及聚异氰脲酸酯泡沫组合物,以及还有酚类的泡沫组合物。在此类热固性泡沫的实施方案中,包括本发明的一种或多种组合物作为在一种可起泡的组合物中的一种发泡剂或发泡剂的一部分,或作为一种两部分或多部分的可起泡组合物的一部分,该可起泡组合物优选包括在适当的条件下能够反应和/或能够起泡以形成一种泡沫或多孔结构的一种或多种组分。
本发明还涉及从一种聚合物泡沫配制品制备的泡沫,并且优选闭孔泡沫,该聚合物泡沫配制品含有包括本发明的组合物的一种发泡剂。然而在其他的实施方案中,本发明提供了可起泡的组合物,这类组合物包括热固性泡沫,例如聚氨酯以及聚异氰脲酸酯泡沫,优选柔性或刚性的低密度泡沫。
本领域的那些普通技术人员将理解到,本发明的发泡剂组合形成和/或加入可起泡的组合物的顺序和方式总体上不影响本发明的可操作性。例如,在聚氨酯泡沫的情况下,有可能该发泡剂组合的不同组分(以及甚至本发明的组合物的多个组分)不在引入发泡设备之前混合,或者甚者这些组分不加入该发泡设备中的同一位置。因此,在某些实施方案中,可能希望在一台共混机中引入该发泡剂组合的一种或多种组分,预期这些组分将在该发泡设备中汇合到一起和/或以这种方式更有效地运作。尽管如此,在某些实施方案中,使该发泡剂组合中的一种或多种组分提前结合,并且一起引入该起泡组合物中(直接地或作为预混合料的一部分),然后进一步加入该可起泡组合物的其他部分。
实例
实例1
每一个所测试的配制品(都具有114的ROH Iso Index)都含有Rubinate M(从Huntsman可得的一种聚合物亚甲基联苯二异氰酸酯(MDI));Jeffol R-425-X(来自Huntsman的一种多元醇);Voranol 490(来自Dow Chemical的一种多元醇)、Terate 2541(来自Invista的一种多元醇)。Antiblaze 80是来自Rhodia的一种阻燃剂;Tegostab B 8404是来自Goldschmidt Chemical Corporation的一种表面活性剂。Polycat 8和5(五甲基二亚乙基三胺,PMDETA)从AirProducts可得。总体发泡水平是24.5mls/g。表1概述了所测试配方的特性。
表1
用一台手动搅拌机将A侧(MDI)与B侧(多元醇、表面活性剂、催化剂、发泡剂、以及添加剂的混合物)进行混合,并且分配到一个容器中以形成一种自由发起的泡沫。当制作一种自由发起的泡沫时,被分配的物质允许在一个开放式容器中膨胀。所得到的泡沫具有26-秒的胶凝时间、以及41-秒的失粘时间、1.69lb(s)/ft3(lb/ft3)的自由发起密度。当制作一种模制的泡沫时,被分配的物质允许在一个封闭式容器中膨胀。在释放泡沫前,使模具保持封闭几分钟。在10°F与130°F之间对所得到的泡沫进行k-因数测量(ASTM C518)。在使用带锯机除去泡沫皮后的24小时内,获得初始的k-因数。更低的k-因数表明更好的绝缘值。
表2概述了结果。
表2
温度 K
°F Btu.in./ft2.h.°F
17.6 0.1271
32.0 0.1285
50.0 0.1320
75.2 0.1398
104.0 0.1499
实例2
在以下实例中,除非另外指明,泡沫是由小型聚氨酯配料器制得。该配料器由两个承压的汽缸构成,一个用于A侧(MDI)并且另一个用于B侧(多元醇混合物)。可以通过调节器调节汽缸内的压力。将B侧的混合物进行预混合,并且然后装入承压的汽缸内。然后向B侧的汽缸内加入发泡剂并且充分混合。该汽缸与配有静态混合器的一个喷液枪相连。调节两个汽缸内的气压,这样可以实现所希望的A侧与B侧之比。每一个所测试的配制品(都具有一个在110的ROH IsoIndex)含有Rubinate M(从Huntsman可得的一种聚合物亚甲基联苯二异氰酸酯(MDI));Jeffol SG-360和R-425-X(来自Huntsman的一种多元醇);TEAP-265(来自Carpenter Company的一种多元醇)。从Evonik-Degussa可得的一种表面活性剂TegostabB 8465。Jeffcat TD33A和ZR-70是来自Huntsman的催化剂。NP 9.5,来自Huntsman的一种增容剂。总体发泡剂水平是26.0mls/g。表3概述了本研究的配方。
表3配方
在10°F与130°F之间对所得到的泡沫进行k-因数测量(ASTM C518)。表4概述了结果。在使用带锯机除去泡沫皮后的48小时内,获得初始的k-因数。更低的k-因数表明更好的绝缘值。结果表明,使用反式HCFO1233zd发成的泡沫的k-因数优于使用HFO1234ze或HFC134a发成的泡沫。
表4泡沫的k-因数的比较
表5表明,在相同的发泡剂水平下,使用反式HCFCO1233zd发成的泡沫比使用HFO1234ze或HFC134a发成的泡沫显示出更低的密度以及更高的发泡效率。
表5HFC134a与HCFO 1233zd(反式)泡沫的自由发起密度的比较
虽然在此参照特定的实施方案对本发明进行了展示和说明,但无意将所附的权利要求限制为所示的细节。相反,在此预期本领域的普通技术人员可对这些细节做出不同的变更,这些变更仍然会在所要求的主题的精神和范围之内,并且在此企望对这些权利要求进行相应的诠释。
Claims (20)
1.一种用于热固性泡沫的聚合物发泡剂组合物,包括大约70wt%的或更多的氢氯氟烯烃1233zd的反式立体异构体。
2.如权利要求1所述的聚合物发泡剂组合物,其中所述氢氯氟烯烃1233zd包括大约90wt%的或更多的反式立体异构体。
3.如权利要求1所述的聚合物发泡剂组合物,其中所述氢氯氟烯烃1233zd包括大约97wt%的或更多的反式立体异构体。
4.如权利要求1所述的聚合物发泡剂组合物,进一步包括一种氢氟烷。
5.如权利要求5所述的聚合物发泡剂组合物,其中所述氢氟烷是选自下组,其构成为:二氟甲烷(HFC32);1,1,1,2,2-五氟乙烷(HFC125);1,1,1-三氟乙烷(HFC143a);1,1,2,2-四氟乙烷(HFC134);1,1,1,2-四氟乙烷(HFC134a);1,1-二氟乙烷(HFC152a);1,1,1,2,3,3,3-七氟丙烷(HFC227ea);1,1,1,3,3-五氟丙烷(HFC245fa);1,1,1,3,3-五氟丁烷(HFC365mfc)以及1,1,1,2,2,3,4,5,5,5-十氟戊烷(HFC4310mee)。
6.如权利要求1所述的聚合物发泡剂组合物,进一步包括一种氢氟烯烃。
7.如权利要求6所述的聚合物发泡剂组合物,其中所述氢氟烯烃是选自下组,其构成为:四氟丙烯类(HFO1234);三氟丙烯类(HFO1243);四氟丁烯异构体类(HFO1354);五氟丁烯异构体类(HFO1345);六氟丁烯异构体类(HFO1336);七氟丁烯异构体类(HFO1327);七氟戊烯异构体类(HFO1447);八氟戊烯异构体类(HFO1438);以及九氟戊烯异构体类(HFO1429)。
8.如权利要求1所述的聚合物发泡剂组合物,进一步包括选自下组的一种添加剂,该组的构成为:烃类、C1至C5的醇类、C1至C4的醛类、C1至C4的酮类、C1至C4的醚类、二氧化碳、以及C1至C4的二醚类。
9.如权利要求8所述的聚合物发泡剂组合物,其中所述烃是选自下组,其构成为:戊烷异构体类以及丁烷异构体类。
10.如权利要求1所述的聚合物发泡剂组合物,进一步包括HCFC-1233zd之外的一种氢氯氟烯烃。
11.一种聚氨酯泡沫的发泡方法,包括将多个聚合物泡沫组分与包含大约70wt%或更多的氢氯氟烯烃1233zd反式立体异构体的一种泡沫发泡剂进行混合。
12.如权利要求11所述的方法,其中所述氢氯氟烯烃1233zd包括大约90wt%的或更多的反式立体异构体。
13.如权利要求11所述的方法,其中所述氢氯氟烯烃1233zd包括大约97wt%的或更多的反式立体异构体。
14.如权利要求11所述的方法,其中所述泡沫发泡剂进一步包括一种氢氟烷。
15.如权利要求14所述的方法,其中所述氢氟烷是选自下组,其构成为:二氟甲烷(HFC32);1,1,1,2,2-五氟乙烷(HFC125);1,1,1-三氟乙烷(HFC143a);1,1,2,2-四氟乙烷(HFC134);1,1,1,2-四氟乙烷(HFC134a);1,1-二氟乙烷(HFC152a);1,1,1,2,3,3,3-七氟丙烷(HFC227ea);1,1,1,3,3-五氟丙烷(HFC245fa);1,1,1,3,3-五氟丁烷(HFC365mfc)以及1,1,1,2,2,3,4,5,5,5-十氟戊烷(HFC4310mee)。
16.如权利要求11所述的方法,其中所述泡沫发泡剂进一步包括一种氢氟烯烃。
17.如权利要求16所述的方法,其中所述氢氟烯烃是选自下组,其构成为:四氟丙烯类(HFO1234)、三氟丙烯类(HFO1243)、四氟丁烯异构体类(HFO1354)、五氟丁烯异构体类(HFO1345)、六氟丁烯异构体类(HFO1336)、七氟丁烯异构体类(HFO1327)、七氟戊烯异构体类(HFO1447)、八氟戊烯异构体类(HFO1438)、以及九氟戊烯异构体类(HFO1429)。
18.如权利要求11所述的方法,其中所述泡沫发泡剂进一步包括选自下组的一种添加剂,该组的构成为:烃类、戊烷类、丁烷类、C1至C5的醇类、C1至C4的醛类、C1至C4的酮类、C1至C4的醚类、二氧化碳、以及C1至C4的二醚类。
19.如权利要求11所述的方法,其中所述泡沫发泡剂进一步包括HCFC-1233zd之外的一种氢氯氟烯烃。
20.如权利要求19所述的方法,其中所述氢氯氟烯烃是选自下组,其构成为:2-氯-3,3,3-三氟丙烯(1233xf)以及二氯三氟丙烯(HCFO1223)。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510147758.2A CN104744721A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃的发泡剂组合物 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90875107P | 2007-03-29 | 2007-03-29 | |
US60/908,751 | 2007-03-29 | ||
US60/972,037 | 2007-09-13 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510147758.2A Division CN104744721A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃的发泡剂组合物 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101646722A true CN101646722A (zh) | 2010-02-10 |
Family
ID=39808678
Family Applications (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200880010501A Pending CN101646722A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃的发泡剂组合物 |
CN201510455772.9A Active CN104962070B (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN2008800101448A Active CN101652412B (zh) | 2007-03-29 | 2008-03-28 | 氢氟丙烯与氢氯氟烯烃的发泡剂组合物 |
CN201410244732.5A Active CN103992498B (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN200880010511A Pending CN101646723A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN200880010224A Pending CN101652413A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
Family Applications After (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510455772.9A Active CN104962070B (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN2008800101448A Active CN101652412B (zh) | 2007-03-29 | 2008-03-28 | 氢氟丙烯与氢氯氟烯烃的发泡剂组合物 |
CN201410244732.5A Active CN103992498B (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN200880010511A Pending CN101646723A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
CN200880010224A Pending CN101652413A (zh) | 2007-03-29 | 2008-03-28 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
Country Status (9)
Country | Link |
---|---|
US (8) | US9279039B2 (zh) |
EP (3) | EP2129715B1 (zh) |
JP (3) | JP5416086B2 (zh) |
CN (6) | CN101646722A (zh) |
AT (3) | ATE518905T1 (zh) |
CA (3) | CA2681838C (zh) |
ES (3) | ES2367542T3 (zh) |
PL (3) | PL2129715T3 (zh) |
WO (3) | WO2008121790A1 (zh) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102532582A (zh) * | 2010-10-28 | 2012-07-04 | 霍尼韦尔国际公司 | 包含1,1,1,3,3,3-六氟丁烯和1-氯-3,3,3-三氟丙烯的混合物 |
CN102850571A (zh) * | 2012-09-28 | 2013-01-02 | 关志强 | 保温聚氨酯塑料的发泡剂 |
CN103237864A (zh) * | 2010-12-03 | 2013-08-07 | 阿克马法国公司 | 包含1,1,1,4,4,4-六氟丁-2-烯和3,3,4,4,4-五氟丁-1-烯的组合物 |
CN103881131A (zh) * | 2014-03-17 | 2014-06-25 | 浙江衢化氟化学有限公司 | 一种环保型发泡剂组合物 |
CN104628978A (zh) * | 2014-07-10 | 2015-05-20 | 合肥华凌股份有限公司 | 组合物、硬质聚氨酯泡沫材料及制冷设备 |
CN105885080A (zh) * | 2016-05-05 | 2016-08-24 | 巨化集团技术中心 | 一种发泡剂组合物及其制备方法 |
CN106750488A (zh) * | 2016-12-26 | 2017-05-31 | 浙江衢化氟化学有限公司 | 一种低碳环保型发泡剂组合物 |
CN107033848A (zh) * | 2010-11-19 | 2017-08-11 | 霍尼韦尔国际公司 | 包含1‑氯‑3,3,3‑三氟丙烯的类共沸物组合物 |
CN107207758A (zh) * | 2015-03-24 | 2017-09-26 | 旭化成建材株式会社 | 酚醛树脂发泡体及其制造方法 |
CN108026488A (zh) * | 2015-07-27 | 2018-05-11 | 旭硝子株式会社 | 溶剂组合物、清洗方法、涂膜的形成方法、热传递介质和热循环系统 |
CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
CN111925775A (zh) * | 2013-03-14 | 2020-11-13 | 霍尼韦尔国际公司 | 用于高温热泵应用的低gwp流体 |
CN113201313A (zh) * | 2008-05-07 | 2021-08-03 | 科慕埃弗西有限公司 | 可用作热传递组合物的组合物 |
CN115052921A (zh) * | 2020-02-04 | 2022-09-13 | 科慕埃弗西有限公司 | 用于pir泡沫的成核剂 |
Families Citing this family (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
TWI626262B (zh) † | 2005-06-24 | 2018-06-11 | 哈尼威爾國際公司 | 發泡體及其產品 |
US9695267B2 (en) * | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
JP5763338B2 (ja) * | 2007-03-29 | 2015-08-12 | アーケマ・インコーポレイテッド | ヒドロフルオロオレフィンとヒドロクロロフルオロオレフィンの発泡剤組成物 |
US20100210747A1 (en) * | 2007-07-20 | 2010-08-19 | E.I. Du Pont De Nemours And Company | Compositions and use of trans-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
US8333901B2 (en) | 2007-10-12 | 2012-12-18 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
US8512591B2 (en) | 2007-10-12 | 2013-08-20 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
US8628681B2 (en) | 2007-10-12 | 2014-01-14 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
GB201002625D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
WO2009047542A1 (en) * | 2007-10-12 | 2009-04-16 | Ineos Fluor Holdings Limited | Heat transfer compositions |
WO2009089400A1 (en) * | 2008-01-11 | 2009-07-16 | E. I. Du Pont De Nemours And Company | Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams |
US20110001080A1 (en) * | 2008-03-07 | 2011-01-06 | Arkema Inc. | Stable formulated systems with chloro-3,3,3-trifluoropropene |
WO2010019428A1 (en) * | 2008-08-13 | 2010-02-18 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams |
US8163196B2 (en) * | 2008-10-28 | 2012-04-24 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
CN102239228A (zh) * | 2008-12-02 | 2011-11-09 | 墨西哥化学阿玛科股份有限公司 | 传热组合物 |
WO2010088320A1 (en) * | 2009-01-29 | 2010-08-05 | Arkema Inc. | Tetrafluoropropene based blowing agent compositions |
US20100216904A1 (en) * | 2009-02-24 | 2010-08-26 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams |
TW201103972A (en) | 2009-04-01 | 2011-02-01 | Solvay Fluor Gmbh | Process for the manufacture of etched items |
US8481605B2 (en) | 2009-05-21 | 2013-07-09 | Huntsman International Llc | Rigid polyurethane foam and system and method for making the same |
CA2761720C (en) * | 2009-06-02 | 2017-07-11 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene |
US20120145955A1 (en) * | 2009-07-27 | 2012-06-14 | Arkema Inc. | COMPOSITION OF HCFO-1233zd AND POLYOL BLENDS FOR USE IN POLYURETHANE FOAM |
DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
SI3812360T1 (sl) * | 2009-09-09 | 2024-02-29 | Honeywell International Inc. | Monoklorotrifluoropropenske spojine in sestavki ter postopki, ki jih uporabljajo |
CA2778518C (en) * | 2009-10-23 | 2017-11-28 | Arkema Inc. | Tetrafluorobutene blowing agent compositions for polyurethane foams |
US8846754B2 (en) * | 2009-12-16 | 2014-09-30 | Honeywell International Inc. | Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene |
KR20220104282A (ko) | 2009-12-22 | 2022-07-26 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 2,3,3,3-테트라플루오로프로펜, 1,1,2,3-테트라클로로프로펜, 2-클로로-3,3,3-트라이플루오로프로펜, 또는 2-클로로-1,1,1,2-테트라플루오로프로판을 포함하는 조성물 |
GB201002622D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
US8821749B2 (en) * | 2010-04-26 | 2014-09-02 | E I Du Pont De Nemours And Company | Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene |
BR112012029453A2 (pt) | 2010-05-20 | 2017-03-07 | Mexichem Amanco Holding Sa | "composições para transferencia de calor, formação de espuma e pulverizavel, dispositivos para transferencia de calor e para geração de energia mecanica, uso de uma composição, agente para expansão, espuma, e, métodos para esfriar um artigo, para aquecer um artigo, para extrair uma substancia de biomassa, para limpar um artigo, para extrair um material de uma solução aquosa, para extrair um material de uma matriz sólida particulada, para reformar um dispositivo para transferência de calor, para reduzir o impacto ambiental decorrente da operação de um produto, para preparar uma composição e para gerar crédito de emissão de gás de efeito estufa" |
PL2571956T3 (pl) | 2010-05-20 | 2016-06-30 | Mexichem Fluor Sa De Cv | Kompozycje do wymiany ciepła |
GB2481443B (en) | 2010-06-25 | 2012-10-17 | Mexichem Amanco Holding Sa | Heat transfer compositions |
US20120043492A1 (en) * | 2010-08-17 | 2012-02-23 | Honeywell International Inc. | Compositions Containing 1-Chloro-3,3,3 Trifluoropropene And 1-Fluoro-1,1 Dichloroethane |
US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
JP5731008B2 (ja) | 2010-11-17 | 2015-06-10 | エフオーエムオー、プロダクツ、インク | 膨張発泡断熱材による壁空洞の充填方法 |
EP3543311B1 (en) * | 2010-11-25 | 2022-11-09 | Arkema France | Use of compositions of chloro-trifluoropropene and hexafluorobutene |
MX2013007318A (es) | 2010-12-21 | 2013-07-22 | Dow Global Technologies Llc | Formulaciones del poliol para curacion incrementada de revestimiento a temperaturas frias de espumas rigidas de poliuretano. |
US9724684B2 (en) | 2011-02-21 | 2017-08-08 | The Chemours Company Fc, Llc | Selective catalytical dehydrochlorination of hydrochlorofluorocarbons |
FR2977256B1 (fr) * | 2011-07-01 | 2013-06-21 | Arkema France | Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene |
RU2016137830A (ru) * | 2011-07-28 | 2018-12-12 | Ханивелл Интернешнл Инк. | Пены и огнестойкие изделия, полученные из пен, содержащих 1-хлор-3, 3, 3-трифторпропен (1233zd) |
US9896558B2 (en) | 2011-08-01 | 2018-02-20 | Basf Se | HFO/water-blown rigid foam systems |
BR112014002392B1 (pt) | 2011-08-01 | 2020-11-10 | Basf Se | processo para produzir espumas de poliuretano rígidas, uso de uma mistura de agente de sopro, e, espuma de poliuretano rígida |
ES2841988T3 (es) | 2011-10-14 | 2021-07-12 | Dow Global Technologies Llc | Polioles poliéster-poliéter híbridos para una expansión del desmoldo en espumas rígidas de poliuretanos mejorada |
AU2012325962B2 (en) | 2011-10-20 | 2016-05-19 | The Chemours Company Fc, Llc. | Azeotrope-like compositions of E-1-chloro-2,3,3,3-tetrafluoropropene and uses thereof |
WO2013082964A1 (en) * | 2011-12-09 | 2013-06-13 | Honeywell International Inc. | Foams and articles made from foams containing hcfo or hfo blowing agents |
WO2013096727A1 (en) * | 2011-12-22 | 2013-06-27 | Honeywell International Inc. | Azeotrope-like compositions including cis-1-chloro-3,3,3-trifluoropropene |
US8921621B2 (en) | 2012-02-15 | 2014-12-30 | Honeywell International Inc. | Process for the production of HCFC-1233zd |
US9000239B2 (en) * | 2012-05-15 | 2015-04-07 | Honeywell International Inc. | Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene |
US20150118476A1 (en) | 2012-05-25 | 2015-04-30 | Dow Global Technologies Llc | Production of polyisocyanurate foam panels |
CN104781315B (zh) * | 2012-09-07 | 2019-03-08 | 巴斯夫欧洲公司 | 减小收缩的硬质聚氨酯泡沫 |
FR3000094B1 (fr) * | 2012-12-26 | 2019-10-18 | Arkema France | Composition comprenant du 1,1-difluoroethane et du 3,3,3-trifluoropropene |
EP3495407B1 (en) | 2013-03-15 | 2024-01-03 | Owens Corning Intellectual Capital, LLC | Processing aids for use in manufacturing extruded polystyrene foams using low global warming potential blowing agents |
US20150210818A1 (en) * | 2014-01-27 | 2015-07-30 | E I Du Pont De Nemours And Company | Cryogenic insulation foam |
EP3137525A4 (en) * | 2014-04-30 | 2017-12-27 | Honeywell International Inc. | Flexible, open-cell thermoset foams and blowing agents and methods for making same |
US10330364B2 (en) | 2014-06-26 | 2019-06-25 | Hudson Technologies, Inc. | System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant |
CA2955293C (en) * | 2014-07-16 | 2023-03-28 | Owens Corning Intellectual Capital, Llc | Non-voc processing aids for use in manufacturing foams using low global warming potential blowing agents |
JP6626674B2 (ja) * | 2014-10-08 | 2019-12-25 | 積水ソフランウイズ株式会社 | 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法 |
KR102589518B1 (ko) * | 2015-03-24 | 2023-10-16 | 세키스이가가쿠 고교가부시키가이샤 | 페놀 수지 발포체 및 페놀 수지 발포체의 제조 방법 |
EP3984986A1 (en) | 2015-05-21 | 2022-04-20 | The Chemours Company FC, LLC | Hydrofluorination of 1233xf to 244bb by sbf5 |
CH712779A1 (de) * | 2016-07-20 | 2018-01-31 | Brugg Rohr Ag Holding | Barriereschichten. |
US10131758B2 (en) | 2016-07-25 | 2018-11-20 | Accella Polyurethane Systems, Llc | Polyurethane foam-forming compositions, methods of making low density foams using such compositions, and foams formed therefrom |
CN108102333A (zh) * | 2017-12-27 | 2018-06-01 | 上海东大聚氨酯有限公司 | 一种超低温保温箱用组合聚醚、聚氨酯原料组合物、聚氨酯泡沫及其制备方法 |
WO2020022478A1 (ja) * | 2018-07-27 | 2020-01-30 | セントラル硝子株式会社 | 溶剤組成物 |
CN110105520B (zh) * | 2019-05-05 | 2021-09-21 | 深圳市盈石科技有限公司 | 一种保温硬质聚氨酯泡沫及其制备方法 |
WO2022009801A1 (ja) * | 2020-07-08 | 2022-01-13 | Agc株式会社 | 組成物およびその用途 |
CN114149790B (zh) * | 2021-11-10 | 2023-09-05 | 浙江巨化新材料研究院有限公司 | 一种共沸或类共沸组合物及其制备方法 |
WO2023221693A1 (zh) * | 2022-05-20 | 2023-11-23 | 海信容声(广东)冰箱有限公司 | 硬质聚氨酯泡沫、制备方法及包含聚氨酯泡沫的保温材料、冰箱和冰柜 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2039008A (en) | 1932-07-28 | 1936-04-28 | Burgess Lab Inc C F | Method of making a material for absorbing sound |
JPH02221388A (ja) | 1989-02-23 | 1990-09-04 | Asahi Glass Co Ltd | 脱脂洗浄剤 |
JP2751428B2 (ja) * | 1989-06-30 | 1998-05-18 | 旭硝子株式会社 | 3,3―ジクロロ―1,1,1,2,2―ペンタフルオロプロパン系組成物 |
JPH05179042A (ja) * | 1991-11-18 | 1993-07-20 | Daikin Ind Ltd | フルオロプロペンからなる発泡剤およびプラスチック発泡体の製造方法 |
US5710352A (en) | 1996-09-19 | 1998-01-20 | Alliedsignal Inc. | Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene |
EP0864554B1 (en) | 1997-03-11 | 2002-09-18 | Central Glass Company, Limited | Method for purifying crude 1,1,1,3,3-pentafluoropropane |
US6013846A (en) * | 1998-03-05 | 2000-01-11 | Elf Atochem North America, Inc. | Azeotrope of HF and 1233zd |
US20050096246A1 (en) * | 2003-11-04 | 2005-05-05 | Johnson Robert C. | Solvent compositions containing chlorofluoroolefins |
EP2314653A3 (en) * | 2002-10-25 | 2014-07-23 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US9796848B2 (en) * | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US9499729B2 (en) | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
US7098176B2 (en) | 2004-04-16 | 2006-08-29 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene |
ES2366706T3 (es) | 2004-12-21 | 2011-10-24 | Honeywell International Inc. | Composiciones de yodocarbono estabilizadas. |
US20060243945A1 (en) * | 2005-03-04 | 2006-11-02 | Minor Barbara H | Compositions comprising a fluoroolefin |
US20060243944A1 (en) * | 2005-03-04 | 2006-11-02 | Minor Barbara H | Compositions comprising a fluoroolefin |
TWI657070B (zh) | 2005-06-24 | 2019-04-21 | 美商哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物及其用途 |
TWI626262B (zh) * | 2005-06-24 | 2018-06-11 | 哈尼威爾國際公司 | 發泡體及其產品 |
CA2681832C (en) | 2007-03-29 | 2016-01-26 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
CN100488925C (zh) | 2007-04-11 | 2009-05-20 | 西安近代化学研究所 | 1,3,3,3-四氟丙烯的制备方法 |
-
2008
- 2008-03-28 US US12/532,202 patent/US9279039B2/en active Active
- 2008-03-28 PL PL08744563T patent/PL2129715T3/pl unknown
- 2008-03-28 CA CA2681838A patent/CA2681838C/en active Active
- 2008-03-28 PL PL08744561T patent/PL2129714T3/pl unknown
- 2008-03-28 ES ES08744561T patent/ES2367542T3/es active Active
- 2008-03-28 CN CN200880010501A patent/CN101646722A/zh active Pending
- 2008-03-28 CN CN201510455772.9A patent/CN104962070B/zh active Active
- 2008-03-28 JP JP2010501245A patent/JP5416086B2/ja active Active
- 2008-03-28 AT AT08744561T patent/ATE518905T1/de not_active IP Right Cessation
- 2008-03-28 AT AT08744559T patent/ATE547459T1/de active
- 2008-03-28 PL PL08744559T patent/PL2129713T3/pl unknown
- 2008-03-28 US US12/532,194 patent/US20100087557A1/en not_active Abandoned
- 2008-03-28 CA CA2681642A patent/CA2681642C/en active Active
- 2008-03-28 CN CN2008800101448A patent/CN101652412B/zh active Active
- 2008-03-28 CA CA2681872A patent/CA2681872C/en active Active
- 2008-03-28 WO PCT/US2008/058607 patent/WO2008121790A1/en active Application Filing
- 2008-03-28 CN CN201410244732.5A patent/CN103992498B/zh active Active
- 2008-03-28 AT AT08744563T patent/ATE528341T1/de not_active IP Right Cessation
- 2008-03-28 CN CN200880010511A patent/CN101646723A/zh active Pending
- 2008-03-28 EP EP08744563A patent/EP2129715B1/en active Active
- 2008-03-28 US US12/532,189 patent/US20100056657A1/en not_active Abandoned
- 2008-03-28 JP JP2010501249A patent/JP5539854B2/ja active Active
- 2008-03-28 EP EP08744561A patent/EP2129714B1/en active Active
- 2008-03-28 CN CN200880010224A patent/CN101652413A/zh active Pending
- 2008-03-28 ES ES08744563T patent/ES2372785T3/es active Active
- 2008-03-28 EP EP08744559A patent/EP2129713B1/en not_active Revoked
- 2008-03-28 ES ES08744559T patent/ES2380080T3/es active Active
- 2008-03-28 WO PCT/US2008/058604 patent/WO2008121787A1/en active Application Filing
- 2008-03-28 WO PCT/US2008/058602 patent/WO2008121785A1/en active Application Filing
- 2008-03-28 JP JP2010501247A patent/JP5416087B2/ja active Active
-
2014
- 2014-06-16 US US14/305,287 patent/US9228071B2/en active Active
- 2014-07-24 US US14/339,732 patent/US20140336293A1/en not_active Abandoned
-
2015
- 2015-12-10 US US14/964,896 patent/US20160090462A1/en not_active Abandoned
-
2016
- 2016-02-04 US US15/015,184 patent/US9914815B2/en active Active
- 2016-08-24 US US15/245,412 patent/US20160362531A1/en not_active Abandoned
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113201313A (zh) * | 2008-05-07 | 2021-08-03 | 科慕埃弗西有限公司 | 可用作热传递组合物的组合物 |
US11512239B2 (en) | 2008-05-07 | 2022-11-29 | The Chemours Company Fc, Llc | Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene |
CN105273218A (zh) * | 2010-10-28 | 2016-01-27 | 霍尼韦尔国际公司 | 包含1,1,1,4,4,4,-六氟丁烯和1-氯-3,3,3-三氟丙烯的混合物 |
CN102532582A (zh) * | 2010-10-28 | 2012-07-04 | 霍尼韦尔国际公司 | 包含1,1,1,3,3,3-六氟丁烯和1-氯-3,3,3-三氟丙烯的混合物 |
CN105273218B (zh) * | 2010-10-28 | 2018-11-16 | 霍尼韦尔国际公司 | 包含1,1,1,4,4,4,-六氟丁烯和1-氯-3,3,3-三氟丙烯的混合物 |
CN107033848A (zh) * | 2010-11-19 | 2017-08-11 | 霍尼韦尔国际公司 | 包含1‑氯‑3,3,3‑三氟丙烯的类共沸物组合物 |
CN103237864B (zh) * | 2010-12-03 | 2015-06-10 | 阿克马法国公司 | 包含1,1,1,4,4,4-六氟丁-2-烯和3,3,4,4,4-五氟丁-1-烯的组合物 |
CN103237864A (zh) * | 2010-12-03 | 2013-08-07 | 阿克马法国公司 | 包含1,1,1,4,4,4-六氟丁-2-烯和3,3,4,4,4-五氟丁-1-烯的组合物 |
CN102850571A (zh) * | 2012-09-28 | 2013-01-02 | 关志强 | 保温聚氨酯塑料的发泡剂 |
CN111925775A (zh) * | 2013-03-14 | 2020-11-13 | 霍尼韦尔国际公司 | 用于高温热泵应用的低gwp流体 |
CN103881131A (zh) * | 2014-03-17 | 2014-06-25 | 浙江衢化氟化学有限公司 | 一种环保型发泡剂组合物 |
CN104628978A (zh) * | 2014-07-10 | 2015-05-20 | 合肥华凌股份有限公司 | 组合物、硬质聚氨酯泡沫材料及制冷设备 |
CN104628978B (zh) * | 2014-07-10 | 2018-02-13 | 合肥华凌股份有限公司 | 组合物、硬质聚氨酯泡沫材料及制冷设备 |
CN107207758A (zh) * | 2015-03-24 | 2017-09-26 | 旭化成建材株式会社 | 酚醛树脂发泡体及其制造方法 |
CN108026488B (zh) * | 2015-07-27 | 2020-11-06 | Agc株式会社 | 溶剂组合物、清洗方法、涂膜的形成方法、热传递介质和热循环系统 |
CN108026488A (zh) * | 2015-07-27 | 2018-05-11 | 旭硝子株式会社 | 溶剂组合物、清洗方法、涂膜的形成方法、热传递介质和热循环系统 |
CN105885080A (zh) * | 2016-05-05 | 2016-08-24 | 巨化集团技术中心 | 一种发泡剂组合物及其制备方法 |
CN106750488B (zh) * | 2016-12-26 | 2019-05-17 | 浙江衢化氟化学有限公司 | 一种低碳环保型发泡剂组合物 |
CN106750488A (zh) * | 2016-12-26 | 2017-05-31 | 浙江衢化氟化学有限公司 | 一种低碳环保型发泡剂组合物 |
CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
CN115052921A (zh) * | 2020-02-04 | 2022-09-13 | 科慕埃弗西有限公司 | 用于pir泡沫的成核剂 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101646722A (zh) | 氢氯氟烯烃的发泡剂组合物 | |
JP6441983B2 (ja) | ヒドロクロロフルオロオレフィンの発泡剤組成物 | |
CN107043472A (zh) | 发泡剂和含氟取代烯烃组合物以及起泡方法 | |
CN102575046A (zh) | 用于聚氨酯泡沫的四氟丁烯发泡剂组合物 | |
JP2011518924A (ja) | ポリマーフォーム用の発泡剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C12 | Rejection of a patent application after its publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20100210 |